ol 03, 04. 06 PARTI McQ ‘An organic compound containing CH and O only, has 29.6% oxygen by mass. Its relative molecular mass is 270. How many oxygen atoms are Present in a molecule of this organic compound? (relative atomic masses : H= 1: C= 12:0 = 16) Li 2.2 33 44 5.5 How many moles of hydrogen atoms arc preseat in 0.10kg of a solution of ethanol in water containing 10% by mass of ethanol (CHsOH)? (relative atomic masses: H C=12:0=16) 113 2.10.0 3.113 4.52 SiS Calculate the mass of Cas(PO.): required to produce 100g of Ca(H»PO:): according to the equation Cax(POs): + 4HPOs +3CaHPO.)» (relative atomic masses :H = |: O= 16: P= 31: Ca=40) 1g 2 ddg 3. 15g 4132g 5.2268 100.0cm* of a 0.050 mol dm NaOH solution and 50 0cm* of a 0.020 mol dmv HsSOs solution were mixed and the toral volume of the mixnure made up to 250.0cm! with distilled water. The concentration of OH joins in the resultant solution is 1. 0.012 mol da? 3.0020 mol dm? 5. 0.012 mol dm? 2 0.016 mot am? 40.120 mot den ‘An HC! solution contains 36.5% by mass of HCI. The density of the solution is 1-15 g cm? What is the concentration of HCT in the solution in units of mol 1. 0.869 2445 3115 45 5.869 In the titration of 25 Oem portions of NaOH colution with HCI solution, which of the following activities is the most essential? 1. Washing the pipette out with HCT solution 2. Washing the titration flask with NaOH solution 3. Measuring the temperanures ofthe titrating solution 4, Filling the burette up to the zero mask with HCT solution 5. Rinsing the inside of the burette with the HCI solution07. In the reaction 2No2(g) + Hz0 (1) + HINO;(aq) + HNO2(aq) 1. nitrogen undergoes oxidation only nitrogen undergoes reduction only 3. nitrogen undergoes both oxidation and reduction 4. there is no change in the oxidation state of nitrogen 5. water acts both as an oxidizing agent and as a reducing agent For each of the question 08 four responses (a), (b). (¢) and (4) are given. One or more of these is / are correct. Select the correct response / responses. In accordance with the instructions given on your answer sheet, marke 1. sfoly (a) and (b) correct 2. if only (b) and (6) correct, 3. if only (c) and (4) correct 4. if only (@) and (a) correct 5. iffany other number or combination of responses is are comect ‘Summary of Instructions @ @ @) @ ©) ‘any other number or Only (a) and (b) | Only (b) and (c) | if only (c) and (é) | ifonty (é) and |” Comect Comrect correct (@) correct combination of responses is are correct. 08. Which of the following statement / statements pertaining to the composition of a solution prepared by dissolving 18 g of glucose in 180 g of water at 277 Kis/ are true? (molar masses of glucose and water ae 180 and 18g mol, respectively: Density of water at 277 Kis 1.0 gem?) The concentration of gincose in the solution is 0.55 mol dm? The mass fraction of glucose in the solution is 0.10 ‘The molality of glucose in the solution is 0.10 mol kg” Tmt Seci of acon nln by09, 10. L 1B. 14. ‘The number of atoms in 0.0240 g of the !°C isotope is 1, 12.044x 10! 2. 12.044 x 10 3. 12.044x 107 4.6022 x10" 5.6.022 x 10° The number of moles of KMnO. that is required to react completely with I mole of iron (ID oxalate (FeC04) in acidic medium is, 1.5 2.3 35 42 58 An aqueous solution of K2S07 Crx($0s)3'12H20 contains 1.04gdm' of Cs** ions. What is the SO2™ Concentration, in units of mo! day in this solution? (relative atomic masses : H = 1: 0 = 16: § = 32: K=39: Cr=52) 1.001 2.002 3.0.03 4.0.04 5.005 Todine is produced when 10.0cm* of a 0.010 mol dm? solution of K2S20sis to a solution containing I ions according to the equation S,03° + 21 2802+ The minimum volume of 0.015 mol dmx solution of NazS,03 requised to completely react with the iodine so produced in cam? is 1. 50 2.67 3.133 4.200 5.267 64.6 g of sodium amalgam on complete reaction with water liberates a gas whose volume measured at STP is 2.24 dm’ Assume that the gas behaves ideally. (Relative atomic masses : Na= 23: Hg= 200) The mole fraction of Na in the amalgam is 1.1 200.2 3.04 4.06 5.08 ‘which one of the féllowing statements is true segarding titrations? 1. In anacid base titation, the acid should always be placed in the burette 2. The burette should always be filled up to the zero mark at the beginning of a titration 3. The solution remaining at the pipette tip after delivering should be very carefully blown into the titration flask 4. Some titrations do not require an indication to be added to detect the end — point. 5. For the calculation, the average of the two burette reading at the end point should be taken of those two readings are widely different to each other15. The following seaction is used sn submarines to generate On from CO in exhaled air 4K0z + 2C0, > 2K,C03+ KO, Which of the following statements (s) is/are comrect in regard to this reaction? 2) 20 oxidation or reduction occurs v) carbon is oxidized ©) oxygen is subjected to oxidation as well as reduction 4) the oxidation state changes only in 0 of KOz 16. A certain sample of CO has only “'Cs and “Os isotopes. Another sample of CO has Ce has 80s isotopes only. The property that shows a significant difference between ‘the two samples is 1. Chemical reactivity 2. molar mass 3. Molar volume 4. density at S.TP. 5. Percentage compositions of C and O by mass 17 In the reaction between C207 and HO, in an acidic medium, H,02 is oxidized to O2 and C1207" is converted to Cr?*. The correct equation for this reaction is 1. CnO7+8H* + H,0, + 2Cr3* + SH,0+ Oz CnO?-+ 8Ht + 3H, 0, + 2Cr** + 7H,0 + 30, CnO7+4 BHt + SH: 02 3 2Cr3* + 9H20 + 502 Cn0?+ BHt +,7H; 02 > 2Cr3* + 11H,0 + 702 CnO7+ 8H + 9H2 02 > 2Cr?* + 13,0 + 902 18. 5.0 g of the anhydrous chloride of a monovalent metal when completely converted to its anhydrous sulphate, gave 6.0 g of the anhydrous sulphate (H=1: CL = 35.5: $=32, 0 = 16) The selative atomic mass of the metal is 1.20 2.24 3.27 4.35 5.43 19. The solubility of KNOs in water at 25°C is 300 g per kilogramme of water. If a hot solution containing 540 g KNOs in 600 g water is cooled the maximum mass of KNO3 that would crystallise out of the solution at 25°C is 1. 40g 2. 180g 3. 240g 4, 360g 5.540 20. The number of moles of ions present in a solution made by mixing 125cm’ of 0.2 mol dmv NaOH and 125 em! of 0.1 mol dm* H:SOy is 1. 0.0375 2.00625 3.00875 4.0.15 5.03021. Acidified MuOy reacts with HO. producing 02 Mn and #20 Only. The number of moles of Mn MnO, required for the complete rection of mole of HO, in an acidified medinm is 1. 04 20. By treating industrial waste water with OCT in alkaline medium, cyanide ions in water 2.08 3.20 4.25 3.5.0 are converted to N2 and carbomer ions according to the following equation. 2CN~ + SOCI~ + 2OH~ +2COsS+N2t5C1 +O Which of the following statement(s) is / are true regarding this reaction? a) Oxidation number of Oxygen in OCI~ is changed from 0 to -2 'b) Oxidation number of carbon is changed from +2 to +4 ©) Oxidation number of nigrogen is changed from -3 to 0 d) Oxidation number of chlorine is changed from +1 to -1 23. Instructions for question No 23 In question No 23 two statements are given in respect of each question From the Table given below, select the response out of the response (1), (2), (3), (4) and (5) that best fits the two statements given for each of the questions and appropriately on your answer sheet ‘Response | First Statement Second Statement @ True ‘True, and correctly explains the first statement. 2 True Truc, but does not explain the first statement correctly 8) Tme False «@ False ‘Tme © False False CO contains 0.430 g of carbon per gram of | If two elements can combine to form oxygen whereas CO, contains 0.215 g of | more than one compound, they do so carbon per gram of oxygen. (C=12 : O = 16) | in simple atomic ratios, 24. What volume (in cm’) of dilute HNO; solution of deasity 1.10 g cm * and 20% HNO; by mass contains 10g of HNOs? 1 6 215 3.23 4.45 5.9525. Crystalline sodium carbonate has the formula Na,C0310H,0 what is the mass of anhydrous sodium carbonate required to make up 25 litres of 4.0 mol dm? solution? (b= 1: C= 12: 0-16: Na=23) 1 Wsg —-2.286g 3.530g 4.10605. 2860 26. A student intends to titrate 25.00 cm? of solution Y with solution X Which of the following washing proceduces in most suitable ia preparation for this itration? ‘No | Washing buretie with ‘Washing tivation ack with (1) | distilled water Solution Y @ | SolutioaX Solution Y @) | SolutioaX distilled water @ | Solution Y distilled water followed by solution X (5) | distilled water followed by solution X | distilled water 27. When 25.00em? of a NaxCO3 solutions titrated with an HCI solution (in burette), Using Phenolphthalein as indicator, the end point was observed at 25.00em* ‘When the titration was repeated using 25.00cm? of same HCI solution and came ‘NayCOs solution (in busette) and using the same indicator, what will be the observed end point? L. 25.00.cm? 2.12.50 em? 3.50.00 em? 4.37.50 om? 5. an end point canaot be obtained, 28. Xenon is one of she Jeast abundant inest gases in air. The amount of xenon in air is 0.076 parts per million (0.076ppm) by volume What volume of xenon gas, in dm, can ‘be isolated from a given 1000km? cemple of air at the same temperanure and pressure? 176 2.76 x 10" 3.762105 4.76x10? 5.76x10 29. 0.6 mole of zine nitrate and 0.6 mole of irom (II} sulphate are dissolved in water to give a solution with a total volume of 2 dm? Which one of the following has 2 concentration of 0.3 mol dm? 1. sulphate ions 2. negatively charged ions 3. positively charged ions 4 zine ions 5. nitrate ions 30. What is the ratio of the mass percentages of carbon to that of chlorine in the compound Cs Hy Cla? (C= 12. H=1.C1= 35.5) 1 6:2 2.6:1 31:3 4. 5.1:631, 32, 33, 34 38, ‘Which one of the following statements is incorrect? 1. Molality of a solution of glucose in water at 20°C is equal to the molality of the same solution at 30°C nN Molar enthalpy is an intensive property. Pressure is an intensive property aw Concentration of a NaOH sofution containing 0-1 moles of NaOH dissolved in 1 dix} of water is 0-1 mol dm? Concentration of a solution depends on the temperature since the volume of the solution depends on the temperature ‘Which one of the following statements is comect? 1. Concentration is an extensive property 2. Mole Percent is equal to the molality multiplied by 100 3. Mole fraction of glucose in an aqueous solution is dependent on the pressure. 4. Molality of a Naz CO3 Solution containing 0.1 moles of Naz C04 dissolved in 1.0 keg of water is 0.1 mol dm provided the density of water is 1 kg dm™3 5. Molality of a solution is independent of the temperature since mass is independent of temperature 0,(g)in a glass vessel is partially converted to 03(g) by means of an clectric discharge, according to the following equation. 302(g) > 203(9) ‘When 30% of 0,(g) is converted to 04(g) the reduction in the pressure inside the vesselis 1, 5% 2. 10% 3.15% 4.20% 5.25% 1.92 g of the hydrocarbon Co Hzo gave on complete combustion. 594g of CO2(g) and 2.70 g of water vapor The mass of reacted is (H 1. 6.22g 2.4.02g 3386g 4. 864g 5.3.24g ‘The umber of moles of oxidant required to oxidize a give amount of KI to Iris lowest for 1. KxCr,07 2. KMnO, 3.Fecl; — 4.K,Cr0, 5. MnO, A primary standard is a solid of exactly known composition, which can be obtained in a high level of purity and which is stable when stored either as a solid or as a solution, ‘The substance as a primary standard for the standardization of an acid is 1, Mg(OH)2 2.MgCO; 3.NaQH = 4.Na,CO; 5.KOH37. Any two compounds having the same empirical formula should have. 1. the same molecular formula 2. the same molecular mass 3. the same percentage composition of elements 4. the same number of atoms per molecule in each compound the came number of bonds per molecule in each compound. 38. A reaction in which the same chemical species undergoes simultaneous reduction and oxidation, is called disproportionation. Which of the following is a / are disproportionation / disproportionation’s? a) 2H,0, + 2H,0 + 0, b) Cu* + Zn + Cu+ Zn2* ©) Ch + OH" + HOCI+CI @) 2CuCl + CuCl, + Cu 39. Which of the following is a comect step / are corect steps, in the measurement of a given volume of solution using a pipette? 1. When the level of solution in the pipette is adjusted to coincide with the graduated mark, the tip of the pipette must be held immersed in the solution In transferring the solution to the titration flask the pipette tip should be held against, the inner surface of the titration flask 3. In transfer the solution to the titration flask the pipette should be held vertical and flask held inclined. 4, ‘The little bit of solution remaining in the tip of the pipette, after the transfer, should ‘be blown into the flask. ° 40. The oxidation number of the carbonyl carbon in acetaldehyde, (cH -i- #) is 1 2.0 341 4-1 5.2 41. The valency and oxidation of the central atom in $,037ion are respectively 1. Jend+4 24end+6 3.6and+4 4.6and+2 S.4and+442. NaOH Feasts with urea as follows. 2NaOH + NH,CONH, ~ Na,CO; +2NH,t 0.6 g of urea (relative molecular mass of usea=60.0) reacted completely with 25.0cm* of 1. 0mol dm™* NaOH. All NH, was expelled by boiling. The volume of 0.5 moldm’ HCI necessary to neutralize the resulting solution 1.100em3 2.125 5. Fe(WH,) (H20)F; 44. 1.0dm? of 0.2 mol dm? H,S0, and 1.0 dm? of 0.2 mol dm~3 HCL were obtain 2.0 dm? of solution The H* ion concentration of the resulting solati is fully dissociated under these conditions. is 1. 2CrO}" + 2Ht > Cry0F- + He 2. CaCO; > Cad + CO, 3. N30, > 2NO2— r 4.Ca(C00); ~ CaCO; + CO 5.00, + Ho Duje ( f By ad (6. The maze of K,S0, Cr,(S0,)s 24H, 0 (celative molar mass = $94) required to prepare 1.00dm* of 10.4ppm Cr+ Solution (1 ppm = 1 mg dm™3 ; Cr = 52.0) is 1. 8.940 mg 28940g 31788mg 41788mg 5. 8940mg 47. A 10.0cm’ sample if coconut vinegar (density = 1.07 g cm) was titrated with a 0.428 amass percentage (W/ the vinegar, is 1. 0.060 2.0.60 3.30 4.60 412048. When 50.00m? of 0.1 mol dm™3H, $0, solution is added gradually to 25.0Cm? of 0.1 mol dm“? Ba(OH) solution, the variation of total number of ions in the mixture is shown by, i % Volume of HS0, added / Cm? —_, ofKCTin the sample 19.0, C1=35.5) 1.05002 204252 3.03002 40250g 5.0150g 50.1 mol of an organic compound X required 2 mol of O, for complete combustion and produced 2 mol of CO; and 2 mol of HO as the only products. The molecular formula of X is 1. GHy — 2.CHy 3. GHD. CHAO 5S. CHO51. An iron plate with a mass of 40 g was dipped into 250Cm? of a CuSO, solution. After a certain time the mass of the plate was 42 g The mass of the deposited Cu is (Fe = 56, Cu=64), 1 ag 2.16¢ 314g 48 5 The IUPAC name of K; [Fe(CN) sBr] is. 1. Tripotassinm pentacyanobromoferrate (III) 2. Potassium pentacyanobromoferrate( III) 3. Potassium pentacyanobromoferrate IT 4. Potassium bromopentacyanoferrate (II) 5. Postassium bromopentacyanoferrate I 52. Am aqueous solution of MgSO, has a concentration of 0.001 mol din“? Which of the following statements is / are true regnsding this solution? 1. The MgSO, concentration of this solution is 24.0 ppm. The SOZ- concentration of this solution is 96.0 ppm. 3. The MgSO, concentration of this solution is 120.0 ppm 4. The Mg?* concentration of this solution is 2.4 ppm. (1 ppm = 1 mg dm™®; Mg= 24.0, S = 32.0, =160) 53. MSO,xH,0 has 36% of HzO by mass. The value of x is (H = 1.0, 0 = 16.0, S= 32.0, M= 64.0) Lg 24 35 46 3G, 54. The oxidation states of the Sqj and Sc) atoms in the following molecule are respectively. F | F —So—Sq—F | F 1. Hand+3 2.+4and+2 3.4+3emd+] 4.3and-1 5.+2and+2 55. Which of the following requires the highest number of moles to oxidize one mole of T i Gh; 2. K,Cr0, 3.K,Cr,0, 4.FeCl, 5. KMn0, 56. The volume of 0.20 mol din™3 HCI required to react with 1.86 g of aniline is (H=10,C=12.0,N= 140) 1. 150.¢m3 2.10¢em> —3.75em> 4. 200m? 5. 100.em357. When Ti, is heated in the presence of H2(g) another oxide of titanium is formed. IF 1.600 g of TiO, produces 1.440 g of this oxide, the formula of the oxide is (O =16.0, Ti=48.0) 1. Tio 2.Tlz0; 3.Tt20 470% 5. ThO2 58. A mental M was concerted to its sulphate M,(S0,)3 A solution of this sulphate was treated with PO(NO5)> to give Pb(SO4) If 1.04 g of M gave 9.09 g (dry mass) of Pb(S0,) the metal M is (AI=27.0, Cr= 52.0, Fe= 55.8, Co= 58.9, Ga = 69.9 PbS0,= 303.0 1 ar 2c 3.Fe 4.0 4.Ga 59. A solution of urea (NH2CONHz) is decomposed on heating as follows. (WH,CONH,) + 3H,0 > CO, + 2NH,OH The mass of urea required to precipitate AI present in 100.0cm5 of 0.20 mol dar® AI (NO})3 solution is H = 1.0, C = 12.0, N= 14.0, 0-160) 1 180g 2.090g 3.27 4.3602 5.1208 The IUPAC name of [Fe(H:0)sOHT™ is 1. Hydroxopentaquairon (IIDion 2. Pentaaquahydroxyliron({I1) ion 3. Pentaaquahydroxoferrous(I1) ion 4. Hydroxopentaaquairon(ID ion 5. Pentaaquahydcoxoison( ill) ion 60. CO, was passed through 25.00em? of « 0.10 mol dm? NaOH solution until 50% of ‘NaOH was convetted to NazCOs. This solution was titrated with 0.10 mol dmx HCI solution using phenolphthalein as the indicator The ead — point of the titration would be 1. 18.75em’ 2. 20.00em* 3.3750cm> —4.25.00em’ 5.12. 50em* 61. A solution of NarSO+ has been prepared by dissolving 14? mg of Pure NazSOsin water, in a 50cm? volumetric flask and by difuting up to the mark. The Na* ion content in mg dm? units in this solution is. (O= 16.0, Na=230, S= 320) 1. 2.00% 107 2.4.00 10° 3.46 4.92 5.184 62. The mass percentage of Na2$202.5H:0 in an aqueous is 20%. The density of this solution at room temperature is 1.24 g em-3. The molarity of Na2S20s in this solution is (H=1.0, O=16.0, Na=23.0, S=32.0) 1 10 2.1.0x103 3.0050 4.16 5.0.1063. In which of the following groups of molecules/ions, nitrogen is in the oxidation states -3,0,and +3 respectively? 1. NHZ.N,NHz 2. N2O2NaNHi 3. NoHs,N2,NCla 4. NO2,Ns|NOZ 5. HZ, Ns, N203 Instructions for questions No 68 In questions No 68 two statements are give in respect of each question From the Table given below, select the response out of the responses (1), its the two sentiments given for each ins the first statement rue, but does not | st conecily, @ | Tm = ‘An oxidation reaction and a] All chemical reactions are disproportionation 67. When 100cm’ of a hydrocarbon was sletely burnt in 600cm‘ of oxygen, 300cm* of carbon dioxide and 400cm? of water vapor were formed. The oxygen remined unreacted after the combustion was 100cm?. All volumes were measured at the same temperature and pressure. The formula of the hydrocarbon is 1. Cyl, 2.Cylle 3. Call 4. Cale 5.0468. An aqueous solution of Ca(NO,): Contains 20 mg of Ca** ions in 0.500dm*. The concentration of NO} in the solution (in mol dm) is, (Ca=40) 1. 5.0 x 107+ 2.1.0 x 107° 3.2.0 x 107? 4.4.0 x 10-3 5.1.0 x 107 69. When a minutes of 4.0 g of sodium carbonate and sodium hydrogencabonate was heated the loss in mass was 0.31 g. The Percentage of mass of Sodium carbonate in the mixture is, (H=1, C=12, 0= 16, Na=23) 1.95 2.90 3.83 479 5.63 70. A.0.331 g sample of Pb(NOs)2 was dissolved in 100. Oem! of water. Excess HS gas was then bubbled through this solution until the precipitation was complete. The mass of the dried precipitate was 0.200 g The percent purity (w/w) of the sample is approximately. (N=14,0=16, $=32, Pb=207) 1 16 2.47 3.68 479 5.84 71. 1.0dmv? an aqueous solution of H202 was heated to complete dissociation. The volume of oxygen evolved was 8.0dm' at S.TP. The concentration of the HO) solution (in mol dm) is (Volume of 1 mole of O» at S.T_P = 22 4dm') 1 031 2.035 3.062 4.071 5.32 72. A well water sample was found to contain Ca, Nox. HCO3 and CI ions. A 25.0em* portion of the water sample was titrated with 0.010 mol dm? H:SO4 using methyl orange as the indicator. The colour of the solution changed from yellow to pink when the burette reading was 5.00cm?. The temporary hardness of the well water expressed as CaCOs (mg dm) is (Ca = 40, O = 16m, C = 12) 1. 200 2.100 3.75 4.50 5.25 73. The mass of « sample containing only SrCO3 and BaCO3 is 0.800 g. When the sample is dissolved in excess dilute acid, the volume of CO) gas liberated at standard temperature and pressure is 0.112 dm’. The mass Percentage of S1COs in the sample is. (C= 12, = 16, Sr= 88, Ba = 137) 1. 30 2.56 3.70 4.30 6.84