i (ellrod))Eisthalpy ° Cl) - 1 18 Ke lolef heat. Content of & Systemm~ Ih iS the Stor of ronal onangy and Poessure Volums rad ie =. UF Pev — UWS exdersme prey anal Stak fotki G -u at 7) Eoihaly, AH ; 2 ey “iM pa ; al I and yl cies calud alomatey : co! 2 cea Hp ote Au='p- He He cay vi Hp > HR, AW IS poghue and ee us ahiorbed clumng Hu prowst Such 9 pwest Paid Gitarmit Pr’ it, Herz lip AH Ve and war x oa eta Yo prow, Sach — proust S callid exdthoramrue prnwessRolaron behuson AH and AU tgnsiolt A Gaseous 3B reatluon Fotang plows. wk amnion’ — Prepsun (2) omd pocatine ©): her Wi UI and VI be the | wnikuad ee intemal ony and volume, roe * bk bhese , ee 2 fo Wo. Vo Sound Us pear than + POP ASA ee UO yi PY and \\y = Us + Pe EO + qoaine Ban Curr Py) ~ -O,+ +e) Alt = (0,7 fs ee pve Kicnbau + ep CVEAWD re ae PBS. \ universe) con gad GED PART, Oe £0, de ‘ane Hu telat, no a Inds! oP PON cow ond “ema ceapeekaely ee pv ener and PVo= D2 eT nae phensby 5 2 RT = DRY os pAb) = (D,- DRT od PDV = ANDRT 3 become = [AH= gut APeT RQ She 2 = = OGD yg pe a wile geeif £n £0 hen AH 40 4. ANDO theo DH > AU Le. Apo he AH AU Seqnipiiane of - of A wie broad WhO AL agg #2 Cana bron Fisk Vow thurmoolyna rns? ‘J 4 “4 Aus 4M, Dos a7 pev a= Y= Aut paVv Promo the about Gn unt 00? _ A= %e -Cartat pram) ie, Rota the ew Saal ota thas. ro oot ales volved, at janient peste K fo Tost te Ton :: | | | | | | | Speci _ boat topady |, \ AS de ‘anoounk 4| hoou veg puted lo raue, the teroporahthe em wit mass 4° a bed i or I Ij Le oak ee ("hy Teroperatun, OF IWooke Substarre , Hpreaig ie or IKs Relay bean A (p and cv ' At wenstank Volum, the hear capac , C Is denoted by. Cy and ab ter slow pocssure heat coqauy cis olepoted| ale 4 cenow thar 92 CAT =e ye) We Ak tein stant volume the hea Ww = AY Nei lyatT Ak westant «pressure. w = = CpAT We know the i= are ie & Pye PRT «for Imola of an eel qe ODA sBR es bUmere : jane ae oRie he enthale OW « out RAT on puting py and 4u Volus’ a cy te wr why: Gay ee et le R Cpvty er shes ola reaction - Reachon Cothales . change Gate le) | In @ charmigal “ Yeackyn 1 Yeactonts are bennett, ity grodyets and ls represersted by Qoctanls ——> ‘Products. ¢ C durnng arohenued i rtocken ¢ * tolud Seathon' énthalp ie ahs given by the s4mbo| H Lyn = Sur of Srinal pie of -procuuth 3 Sure» 141 Yeachan me 8 sips ZenStandard | Gn of seacheos \ qr, Stondooud. Entiat - E —reahen) ie \ rm eels ol ae ie owe | ber > Ted care ( parm fost "2) (Ar ee) oe Se ae Se wo we pare Form abt 2 POHL Om 240% feroperaare Standard chhalpy ot Formaher Age : eacrrant Stord nde copmypornal foorr> i ee eee tus th 9 on cl ee ormaken of or. rede of a cormpoand from LB Csrery tn, tux host Shobk, tare | Slandard Stale » tealpy, fosmahen of CO, 15 te Se mie Be, foals 2 1s On? C amd oO, ar - afte | wn ew died abe Sade ieOe Eobalpes bh phate = Tanyas cohen Has en catego : one make 4 a Substane thé portanr hipe of gpsthal pres of phrase > brarshen on 3 i Epinalpy of. furcor tas?) Cu 1k AS te enthalpy qe wher ene | roole shy Solio substance i fo. ul stake” ak U mel _ polok : Mellin, “Solid Is etyblo Hreomuc all enihalpus | [usw ane postiuue % Ennely § VPC eel [gail Suda ~ fe Be is Ya pou!3 Entnalipy of Sublimaler : 113) Tw 2nlhaly ; 2 Beet no yruls a a Selid | SubSahd > 1S decsliy, tonverted, bo. 9a3e0u3 Shale! at iQ’ Jernpemwa ae abs rap nee Hesss 1 ow constant . Heat § suroinako ‘ths bo ‘slakes Hate tro (oral Grihal forall thie me fora. P sca) ov Currunal * prowss Sacre wolethey The yeacken 8 In. Single Slep of IP Senore oes fy © prow iS wnaupender BV (ollowel : ‘ te rus actor lo Wos3s awe xokor place Wn Ge oyeral Sler than Sua ae I15 Shandaxd peachy oe the Suro slandoud = 4 Inter Medluat® yeachor -‘Vurtsalion a “LenswalY DR presen LAL 5g ‘huch Hie venchen & ai| Poa a TS Uepveried fo pooduthS Mf Ina wrovelucng vear change ee tesla hy A wd = brs worovetted a thon to D and - area hoor charge AH, Abe i Bun euording. 1 | wes’s low DIES AU, FARR Als tela) + Y20 ae) Hop 4 4 Hilog ate Art*s —2858 or WD # Yo 4), 2 thog) b 25 -BS ky ]restanataste anole | Crfnall “of corraburiver( AK) Le sts, Tanotf fred as the “ele erty Change wheb » umole " ‘a sugh'S and ys carats - barn lo prenseb © reachoushs anol prooielts a ate Senloe, forrs Gira 924 p 2 CH OY WHelnane » ; 24,0 @) ld ol neh Sinasts Is elie Ep a caine Dy ie lu & Erotwolp Here, (on male, 9 bonols ont aes nf the. fee cy i “obtaur ‘ lh@) sony AtHe s 485:0. 0°74 God cite Ct ra re nmol : of fees bowol)n felhedt sg a loondl'- on nie , } i Ey beds SWope eect | Brrcust, wud i ben id toa ee : » pro tn! Hae has to bend "ussouden | Cnthale P a Fer duahornie. malady — b aes Band Srihalpies 072 Somes oh q) 2 2Htgy Doma HBF ” Standand chtralpy co a aad hond Gntnalpws of sregelans and produck..vn gas phase readluon ~, a AH = Z iyond Gotten 7s Z, ond Goraipes of pds Tthal py of Soluber Goat?) 3 of Soluken 1S tw ob ; ni eg aan laa ee wn co Specie Omewrt. 4 solvers” a Ase? = Dlatie i + the wha of Sut 13 dakormund alus- loli 4 Bape P omde lagdsahon Lm (orn. fone torn pounds « Agol as ie it ding dussos When prea As” (S S yrow fore Solutorht, fa, Poor ne Ayake YS eRe vars fon K hatwce Ep! Eothalpy ais fhe laltic, Gaal 1 ro.H compound \s | fhe oth dé whan ore. mole lone ee chssocunle ‘al loro ‘geen | 68 ~ connot oeenyi alittelty "80 an Indhiverk imralivod Lalo Both, ibeker fsa coe fp. calculate » a; { WOLF 014 cyle Consol a Boi Riel Naw HCl @) —> lax (39) this pe Yollown Seps Qolrol oe S gaxeous Soduun aan TS praess, is cabod S Ublimaton Nag) oS Nag) Asup tt * Nac (iom)—> This prors Fie Not) AY 18 now ooocl rolexul —> dl Aor - The 2 oun tris pred fs ou lend ansdeat rows bend ckvosahen ‘ yo Cl) —seclay Mbond #, ach @ —> dy end He ~ olen —> Cen Bey gpio. Sohal ‘Yooaj Ye) B- “ity a NY@ 0 44 ary do fora is, called Set oan lait } No.*@) +d —> Not) tia ]ta, Serta a Shey se) fe \e Ayondl : Drclig tie : : Nag). og) ete : BW \ z < a sagt a fe [yo ner cl ete Pek Apw? = Asa? c+ AyH Het fe, oe oe Deg 7 Aare. # plata Miz APRs [seu W* + aH + penne & Act dp ot tbh’ det] Agtyes ee chong Sia haliee as Hue & : abi rove bane me 1h donperd ame es lak adi :. Sponaiwoe?. paws ‘ j Was gy preces that plates place woilhouy the help o af any enternetl SAL Watisuad procs, oo 3 ex. foe a cetatey Prom hugh. av) flow >} he bor bel pod i ean bec a Le tonncle Teuense Js olexethon goth is tled crvevershb! em » Nex Ste -— 2? ants Oly 402. >? 2h with She help 4, exteral agen) ils cated pon § ponslanee prowess - Cotter po to spontones Prods Chong ra “4 sgaienn 4S’ Cceneases- porta ve [hb own Ly eal v4 ue eal yahen of Couey ele : wor 8 abwrbed + Onergit [poreasss - ore ay ALGOTMOBNA “a dw 548ke5 : :eS - Yo fh a measure oe yardornngs ot 3 aes tt rea _ dacwtemen wet — Exjerswe pr ae iy 4 As = 37 8, eae t ~ Sold she hos Ce orscosg Ee haue. huchast Ooty d aa 5 - Temp 1) een — anit Corn. enna ai che fairs If a Syste! absosb q @ arcout oT heat seer sibly, COL derpenadune T, thin the Chana e te d ‘ Arak hear AS s ee r Rooted rere Enstiosep Bal 1 sponta oe os Spor Fansous, PaDcess wo tor gen A Hue hropy “Memd) DS bacernes posse A ene The ee Goro a. O n a Sytem Rana s As boat wh AS serarourdhin, lode fuchioocy P2709’ ~ . Ton 0, Spon taneous prow? DSraa° Setnd lan Hor thoraeak lt Gain ee Srased a> oluenys Cored ot fo’ sane cla roe Bhird low of thermo aly ‘Prot | enbrop % | berkeek Ceystalline Sufsyanen bewmres, 2070 weet Obsclute Zo of “oP wits ie (4) 7. | Gu bs Gregg Ca) mee Sk thy sl lay oP arenes Wis defined ayouable ee d., eit a usefal. work: = - ; ca ae fein } Eyrensive proper any! Li \AG Obs Gtr gi X Relakiiso between Aci Al sek as Cutbb's _Equakion We know ° hak oS W- FS So 44 = AW - ATS Acs =" Ait -fras't se At constant terop EO ao AW+ TAS amg £s ae Bragg et 5g Can oF ACK sys = A Piet TAs 4 This 1S ‘known “as eek Gibbs ned ee mes ‘$ + ASurs Poel = Mast ‘ tesa. asysiem whch albsore 9 eam oe roresbly Ak @. tension Bare i 1 eee rte tat = “35 a DS sun ~ ee sto eae aa Bur Bp SMa ON. | Geo as, Diisuy * = Alisgh 5 4 a2 f Qae eer A Hesget 80 gm O) bewnr® ae = A Sar ie ait } On imak Hplgira boy Fr we ger ~TAStarl <= =TA apt At sack “TASteta) = $0 A Gare ‘Ts meget AGsest Zo) Pf. a Si ag anon ‘Asya -ve . At ls tve Gs yi ae Se) eat Q prot ar oqeslibauye! i AStatal =o 5° eee Z (Tre) ; i.| fn hen for Aon, lo be haps | Nosy 8 nopohi | Alo Abt= 4) - TAS EE am Ds rogatun ond As Is 4¥6 be ond the poouR Is abut, Aca 1s obuoms Ve. Syprondangous 2. \f£ born pwand AS one posttus Do oul js pow \ “ye Whar TAs? Air this, be will be Ne Tas? ee Gav's Srey change ( B61) ancl Sgro ae Corstant (k) Tho Stand (allo s Snowy 2 4 O Yeoehen Brot) 1S wed ro toes — Gemsiont- (e) be fre equeled Ber Att = > Rie or poe = - 2302 eT log k ° for Spondorwout proue Xho Volue & k shoald be +ve ~~ ff botn DH and ss aur “VE, Do ron Tos Zoe tha ls