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0,6
U (V) @ i = 0,5A/cm2
0,58
0,56
0,54
0,52
0,5
0 20 40 60 80 100 120
Oxygen content, %
Figure 5-3: Stack assembly showing three out of 38
Figure 5-1: Dependence of HTPEM fuel cell voltage cells.
on oxygen content in the cathode feed at a current
density of 0.5 A cm-2.
Dependence of current density on pressure, PBI FC, 160C
0,8
0,7
0,6
U (V) @ i = 0,5 A/cm2
0,5
H2 - air
0,4 H2 - 50%O2 in N2
H2 - O2
0,3 Poly. (H2 - air)
Poly. (H2 - 50%O2
0,2 in N2)
Poly. (H2 - O2)
0,1
0
0 2 4 6 8 10 12
pressure, barg
5.2. Liquid cooled HTPEM Fuel Cell development In Phase 1 of testing an overall of 137 cycles (approx.
51min/cycle) including 24 full thermal cycles were
A 1 kW class liquid cooled HTPEM fuel cell stack was performed during the 24 days of actual testing from
developed to be used in the long term closed loop test. 15.04.2011 to 17.06.2011. The stack operated in a stable
The terrestrial, air cooled design was changed to and reliable manner. The liquid cooling of the stack by
incorporate liquid cooling channels, knowing that the oil circulation worked satisfactory, giving precise and
power density on this design was far too low for a space efficient temperature control.
unit. The idea was to first focus on functionality rather
than performance. This design demonstrates the In order to use this fuel cell stack in a closed loop
feasibility, and the performed change was needed for a system, the stack needed to be installed in a pressure
space stack at a later stage. tight vessel. A cylindrical pressure vessel was designed
and manufactured to enclose the fuel cell. This
The stack consists of MEAs clamped between bipolar enclosure was designed to allow higher operating
plates, current collectors, insulating plates and end pressures (up to 3 bar), and worked also as an external
plates as shown in Figure 5-3 (MEAs are not shown). oxygen manifold to the stack. The vessel was partly
Current collector plates form the positive and negative made of glass to allow visual inspection of the stack
ends of the stack. Uniform clamping pressure is during the long term test.
provided by the end plates with corresponding spring
bars.
demand
Power supply to simulate photovoltaic power
Reactant storage tanks
Liquid cooling loop for the fuel cell
Pressure controllers for pressure control in the
fuel cell
Circulation pumps for circulation of reactants
in the fuel cell
Safety measures to detect and handle
hazardous situations
Real time control system for autonomous
Figure 5-5: 3D Model of HTPEM FC stack inside a control and system monitoring
pressure vessel with glass cylinder Thermal hardware for heat removal and water
recirculation
6. Demonstration of a closed loop H2/O2 Most of the components used were terrestrial off-the-
Regenerative Fuel Cell System (RFCS) shelf components
Under ESA Contract no. 22556/09/NL/PM the activities 6.2. Closed loop RFCS test results
aimed to design, manufacture and set-up a closed-loop
regenerative fuel cell system (RFCS) for the Fuel cell stack performance
demonstration of functionality, durability, cycle life and The closed loop RFCS breadboard demonstrator
obtaining performance data. The objective was to operated as a closed loop system for the whole testing
perform a breadboard demonstration of a closed loop period. Oxygen and hydrogen were generated by the
H2/O2 RFCS. Closed loop implied that a fixed amount electrolyser and stored in gas tanks. They were supplied
of reactants was introduced in the system once before to the FC stack by means of pressure controllers. Both
the start, which should then only be converted between oxygen and hydrogen were circulated in their respective
water and gaseous H2 and O2 for the complete lifetime loops by gas pumps, so that a significant amount of gas
of the system. In addition to the FC and the ELY, the was moving through the stack all the time, while fresh
system included water management and thermal control. gas was added stoichiometrically to compensate for the
It was designed to model a RFCS cycle life of 15 years consumption. Fuel cell condensate was returned to the
in orbit, corresponding to 1350 charging cycles. tanks and re-used by the electrolyser to generate oxygen
The following test requirements were defined: and hydrogen.
Target number of eclipse cycles: 1350 (lasting
from 11 to 72 minutes, around 51 minutes in
average per cycle)
Output power in FC mode: 1 kW-class
Output pressure of ELY: up to 10 bar
Reactants: pure O2, pure H2, water
All reactants required for complete lifecycle
supplied before 1st cycle
Pressures:
o FC mode: 1 - 4 bar-a
o ELY mode: 1 - 10 bar-a
Temperatures:
o FC: 160 °C Figure 6-1 HTPEM FC stack used in testing of
o ELY: 65 °C the closed loop RFCS breadboard demonstrator
(here without thermal insulation)
6.1. Development of RFCS breadboard The closed loop RFCS breadboard demonstrator was
demonstrator successfully operated for two months from 28.09.2012
to 27.11.2012 continuously. It experienced initial
A complete stand alone, fully autonomous RFCS was problems at start-up related to migration of phosphoric
developed for the purpose of the closed loop test. It acid from the membranes of the FC stack, but they were
included all the necessary functions of a RFCS: resolved by installing ion-exchange filters on the FC
Fuel cell for power generation condensate line. Since then the system operated in a
Electrolyser for hydrogen and oxygen fully automated mode and required minimal operator
generation attention while producing a total of 1362 fuel cell cycles
Electronic load to simulate payload power and approximately double amount of electrolyser
cycles. The system behaviour during the test period was Figure 6-3 Effect of reactants pressure
very good and reliable. A total of six thermal cycles was increase on the total FC stack current. Stack voltage
performed on the FC stack during the test period. 25,5 V (0,671 V/cell), cell active area 45 cm2. FC
stack has performed 1362 cycles.
The degradation of the stack performance during testing
is shown on Figure 6-2 Stack current has increased from 8,48 A to 11,76 A
(0,188 A/cm2 to 0,261 A/cm2) with reactants pressure
increase from 1,05 to 1,6 bar and amounted to 38,7 %,
I stack, A
20
25 V which is quite prominent. Although the data has not
29 V
been collected above 1,6 bar pressure, the data points
15
were fitted to a curve, and calculation suggests that at 3
bar pressure it would be reasonable to expect an
increase of the stack current to over 16 A, or 93% at
10
25,5 V (average 0,671 V/cell).
In line with earlier single cell experiments, as described
5
above, increased operating pressure of FC stack in a
closed loop RFCS breadboard demonstrator is a very
Cycle number
promising way of increasing stack output.
0
0 200 400 600 800 1000 1200 1400
16
14
12
10
4 Measured
Curve fit y=a+bx+cx2
2
0
1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8
P, bar
7. Conclusion and future work contract no. 18312/04/NL/JD, August 2005
Prime contractor: CMR Prototech
CMR Prototech in partnership with other R&D
Sub contractor: New Energy Systems
companies and Primes have conducted a series of
[4] Ø. Torvanger, “Summary Report”, ESA
projects for ESA related to the development of a RFCS
project: “Innovative Gas Storage on Satellites”, ESA
for telecommunication satellites.
contract no. 19399/05/ NL/PM, November 2007
The experimental tests have shown that RFCS has the
Prime contractor: CMR Prototech
potential to last for the entire lifetime of 15 years in
Sub contractor: IFE
orbit for a satellite, with a satisfactory degradation
[5] H. Weydahl, “Summary Report”, ESA project:
below 0,01 U/cycle. Besides showing the feasibility of
“Advanced Energy Storage System”, CCN 1 to ESA
the technology, an ongoing system study of a RFCS
contract no 19399/05/ NL/PM, November 2007
with MH storage tanks, for storage of hydrogen and
Prime contractor: CMR Prototech
heat, shows that a MH storage tank solution has the
[6] D. Bokach, J. Farnes, “Final Report”, ESA
potential to save significant mass of the thermal
project: “Demonstration of a closed loop H2/O2 RFCS”,
hardware, and thus of the total mass of the RFCS.
ESA contract no. 22556/09/NL/LvH
Preliminary results of the system study covering a
Prime contractor: CMR Prototech
RFCS for a 38kW satellite shows that an optimised
Sub contractor: Astrium (Friedrichshafen)
RFCS will potentially result in an energy density of
[7] ESA project, “Metal Hydride Hydrogen &
260Wh/kg or higher for the entire RFCS.
Heat Storage System”, ESA contract no.
4000105330/12/NL/CLP, Ongoing project
In a current project CMR Prototech has started the
Prime contractor: CMR Prototech
design of a new HT PEM fuel cell and high pressure
Sub contractor: FOTEC/FHWN (Austria)
PEM electrolyser. The aim of this project is to develop
[8] I. Nann, “Technical note 5 – Trade-off Li-ion-
light weight technologies for use in telecommunication
RFCS”, ESA project: Fuel Cells for Telecom Systems –
satellites. The fuel cell operate at 10 bars and
System Study, ESA contract no. 21349/09/NL/LVH,
temperatures up to 200°C. The electrolyser will be
November 2008
designed for operation up to 100 bars. The project
Prime contractor: Thales Alenia Space (Cannes)
includes testing in short stacks. The results from
Sub contractor: CMR Prototech
previous and ongoing projects will give a sound basis
for development of a complete RFCS elegant
breadboard. An optimised RFCS includes further
development on many system elements, including the
fuel cell, electrolyser, reactant storage system, thermal
hardware, balance of plant components, and so on. This
development must be done is a series of parallel
activities, in collaboration between several R&D
environments.
8. Aknowledgement
The work presented here was performed within projects
supported by the European Space Agency. The authors
want to thank the European Space Agency and all the
individual partners in the projects.
REFERENCES
[1] J. Byrknes et.al, “Summary Report”, ESA
project: “Hydrogen Storage Technologies”, ESA
contract no. 17925/04/NL7CP, December 2005
Prime contractor: CMR Prototech
Sub contractor: IFE
[2] I. Nann, H. Weydahl,“Technical Note 4 –
System Design and System Study”, ESA project: Fuel
Cells for Telecom Systems – System Study, ESA
contract (AO/1-5525/07/NL/LvH), September 2008
Prime contractor: Thales Alenia Space (Cannes)
Sub contractor: CMR Prototech
[3] J. Byrknes, J. W. Sørensen, “Final Report”,
ESA project: “Regenerative H2/O2 Fuel Cell”, ESA