tt Addition compounds! —A)_ Deuble salts” i) these which lese_thel fey _ In Sojutien a : 11D Ton de fet Lose thei, _ own _ identi ——______il) ton gives Ceve) test YD Stable only iN Selid Stale ex? 1 . & 1) Canglite Kt M9chk tHe ——S kel mgcy, CH ex EOC mg te Cite! ! 2) Alum. ‘2Soyt Ala Seu) +24 He —S kisey «Al, Gau),-Dub | 3) mnehs & Soi eee FeSey+ WHY), Soy +6.re a Hae fe os 4 permatlen of compex compand Lith et eee —_—_— She ote: KV + FeCcNhy —> bs Dre” Cand — CNo.. 1S Devble_o¢ most erin onl stibe- 4 KN + 20 (CW) > & | AOL] tT Come KC Ap |: 1 Ks Lect co] 3 # | tyes of Compesti | sa Se [~* ’ oat ! 1) Perfect Complex? A) Ke High b) Stab Soe <) Lonisghk 22 1» dj Neo P-P-T- ¥x with eagend | 2 ‘ e) is Low Cute key > ks Lev), | WY a + 31h Lev Coda] 8 No pT. ») unstable _ SO Tonisrbie_nabore 7 Panes | High 12) im mperitct cmp eM Sip begat dd) PPT. deaction iS possible = mnagies renee erie ieee elk LeanHE Presentation. of complex _coMmpecnd - xLM Lap. X —> Tonic sphere/ Counte ion Co] =? coordination sphere M —> CMmA/cM1_CL-A-) Lo > Ligand ChB) MN > ne. o¢ Ligand yY Charge of Ceowling ben “Sphere oe LTYpS of compex’ oO basis of joni past 2)._¥+ TreCome] => et [recone]. Simple cation 4 Con plex anion 2) [AdCWH, CO 35 Uacwayy rer : : - LR Compiex_certion A simpe Goon eeex 4 en Cowinaticn,. sphere has ai Charze Cover Chgeno) ii a ghd) on basis of Charge.Oat FSitmoapie [ae ely Jee | oe Apo mh Pte HT Hydvidos | Nie co eo se ee eee ee See Mat tid o- eo Ns Azide ~~ { “N37 Mitaide ft Suipha te | ——E— r Sez Sujphito Z Ca banile _Hse=$Acetyi Jac t CH Acciats i 2) tVve Ligands? Z t - No* Mt30 Sonlem Nes * Nitaeniem Nas" Hydrazinicm _Pre | 5 detest Ligands © apt oteta ee Oe “WhO Awa | NO mers | | Wate Caxbeny | “CoH Benzene 4 ~ PH3 Phespin Nw Ammine La Pyxidyl Naty tybazine | OCH) Dimethyl tha. | SCéHa)) Di j # dassicice Hon _O€ Ligands. On basis of. pENTECITy _ 4) _menalentate Ligands = io L-p- + So MA. _| @sP3 one densx atem = one + -R j ey ae = © HO Not | = Nn Nay— SS Aff — Peay 2. b) | Biden tate Ligands. — — | het ee ea ‘3 4). 202_ethylens diamine +" ea Cs aesne : wits soc oS i a NG, £ Sy 7 - > Formation ef ding with Gnd 2 She adie ce > _ugand > Chaighing Ligand Nae > 5mm ben >-ing ! No- of yiNg => 1 =? mmetric Ligand 2) fy 1 prcpylencdiamine - eae Yi sn Os eho T cH —— CH, PS pied sige = | > _onsymmeeic Ligand _ => _ Smembey Sing eee—————) QE=0 . q J No- OF 109. Lt — symmebic Liggnd > 6 membe Ligand = _ prepare -1,3-digmine deci discabicacbabicmct cht bassthaidihioninbainabamecbitinidnaadasssdiiisadidtidiai tialsDT ae, nacck yacetenabe 4: q ihe Ro bee I ee | } +H —Cm € = On CHs DC a ene, i. ia ( 2 : H a pe | , a :2) dipy idipyrtayl -——— eL) > 5 mpmbex | =? 1 ring. 35 member = SS _1>ing emai seh ana2) Polydenta te Ligands: ) den * dicthylenctaiamin He CH2 CHe NH CH a = | ip ee a Vv Syn > Nos 0f ving >2 DET apaol é oe N= CH — CH, = 6 2 M * Les Cette] ' ; ae enn O. Ot We ere cee “Dim a Pe eA or — “ 4 el co & ea iS fe Dentisity of | C ah TSR ee = cn? 6 memain ting 28 : ———_—_—_ aes .. AZOa) Tt is Help Fel ie n_estimaion 25 cath mgt? ion ——_ Rey ved 8) Used In estimation oF Nit ion | 9-2 feund 19 P-P-T- feam 7 | “Note 3/4 member ving => unstable _* t 5,6 member xing Stbiec } 4,9, Member ring > UNsabe tt Ro atom is not donating LP. Amem- ing ay 4 wastabe & ne SS| NANA A Ame Cu. © 7m poaieend Ng ses — NOs _* aa = = = RO Vien = RON te Sen Mt Si J mecn => Cygide MeN Isocyanide \ T Cyne =ci=i cyanide "NV I 2am S DINE No, 3 Nipro = mm -ONo"=9 Ni tx to eK alee imitates O i ~~ ThiccYanate na — o> M& NCS F Iso thi ocyantte T = + ic MZ NCO 2 Tso Qyang be 1 1 | __ mites = TT a cf Dime sen >. Thiocranate 2 Thiocram te =s 4 yma oon 3. ~Gagate cyanate ~ ro ae ma seF > Thiesuipmtes § Me 5/24 PThitwipinten 3oe Neg > e 4) Me-Nos” > Thionive -N b) "g* => Thionitao7~O © Nossm > Tthiiteo -S @ Define the dentisity 4 denar site ©givenL! 4) CHAN, ON meng 2) (cH), NH aa netn Aleman enone a 3) Crs), win em | cman eee ©). PCH), PCM) 5 : RQ why azide 8 bycbgzine behaves ar mne dente! ANS. ABIde! 4-MeMbe y => ng 1S Wet re Semel “idoeide’chelating Ligand ¢ 1) Polydentate Ligans foams one 9% mee *ing with Cad are Called Chelating Ligqnas : 1 Of ; . 2) Process of Paamabicn “Chelle is Chel #108) ga Chelgtes are mee Slape Ean rdingsy Comper — in which Ligand 1 IS) Monodentate ~ 4) stabiity due due ke Cheigtion is e_effe Ne. af sing B® Stability & : 2 [Densis ity 2) : . > Cassificguien OfL. Lenbasis. Of INkeagetion bly ia : TLhthe Ligany £ the Cm 9 _ciasice impielLigant LEIP. Ponea|* ) Hen ciassical oe Bageid or Aacepiss Li und S accept e& Clacd from Cen teal_qtem ox ion inte its Vacant ABna on d- orbital thae.gh back bending. - Alss donate _L-p- Tie Phenareng is led Syneagic Bending aS Qaee Q Z —Ge GO.a, —-] is. mag ot SB a yee k sy neagic PO 5 SB a YreS~ Ot 2 A= — =e in Me avi ae | caste Baal . = a on —— + ¢niba se ve Chatge_is ion GmAL D> E tet of 5 : lone Bre te Charge is on cma > Etech of $8 : 2 (72 NN # Nor of ein ABMO As BLN, Do R eG OT Tt SPS Tn _CSe_ of Sd-orbi taj" BL- oS Phe “4¢ order Of A-acePtos acidic. Stang en = / es qi co Ln LB. | oi | <= >Le. j : ‘L 4 \ eae 4 # ordey of Co bend Length in cot ,Co-MCce), _— t45* B) Pe-cs WE PEWS,» cosadination nem bes : dt CN = No-oF Ligand * Dentisit, cx ; eke be Ce |RSS cx ee acre g | => [cocedtay] 3 1%6 = 64 | 3D Uwiceow] SS 4xt = 4 | 2 EAN. Effective Atomic Mum ber 1 [EAN == 0% J z= atomic Ne. . 1 ex. 7 1) Ge LRCo.] > Gé-3) + Cor) = oe > 35 = 29 Tee Ch TS SCs ye —— 4 SaaS ) DCD + C4 v2) 3) Wwtce J Se 4) ka [Pt cle] —s Ga-4) + Cer?) ewe => 86 5.) LAg Cvs), Ja > OF) + @x2) =a > SoeDifference A cha age Mest be_ mig: Ben Wy Aa, EFeCcws No] a } eos — a He “Sidg wick Thesoys orl mn Cos]. a Tine] Ze Tat : 3C¢ = Ge35 + er [mnccsre] =S—> Cmnccor] 25rl2 onl" 3€ = 3? ht 4? j ox. Ma Coe) 16 == 4) es ee | 2) deus ST Be 3) $= llax.)- G42) x7 = 2 4) > Sorare — = 36axidation Wumbey * y Ore —— wat Lr@)c| +h - Ye) txtE CL) =5 k ADVANCE Level_om chaaae 5 So SF fe = {felled i Be capone?K Leo Cti9), C9>), Coz) | > aan ©) rn 2 vaca a &, oe cases % PAC oat eee qét_ case wl - ata Oxi" Stabe +2 he Gm = ase Pe ES Cine) Cond, Cop) —— _ Case 1 Cs, 6 a) 7 a B - a) 4<. neanest L ineak At “AL. 9 sit eee ole => FAN = 36 get FAN= 86 — qo > oxidising — Agent CSeif=poketion)