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    Apznzabuumtvoyuv8dwnczlohgzvuwbm11zjvnaajbpni3paoo4low1fmorzmilwjduorgmfcuer2xdqd3ykeyzvypcy1vcb1olyersrkxhh 38mpzmohkzbjagde 8yytrgzlgfrvh84q x0jth25synu0dcadtupnwkyksaifb1qkxkmidveg6yqr5hkjvj q2v7jzkowvt6ep0frehpl

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    Thịnh Nguyễn

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    A ne yl ee DAT HOC Quéc aia rp WO CHI MIN TRUGNG DAL HOC BACH KHOA Nguyén Thj Thu Van BAI TAP vA SO TAY PHAN TiCH DINH LUONG (Tai ban lan thit sdu) NHA XUAT BAN DAI HQC QUOC GIA TP HO CHi MINH - 2019 Scanned with CamScanner MUC LUC oWAN 1 CAU HOI VA BAL TAP Chuong 1: Bai evong vé héa phiin tich : Chung 2: Nhie lai mot so kién thie edin cho hoa phan tich 6 Chuong 3: Hang sé dic trung cia cdc cain bling hoa hoe don gidn trong nude i : a Chyong 4: Hing sé dic trung dieu kién ciia cae cin bing héa hoc trong nude Chuong 5: Xir ly 17 ligu thye nghiém theo phuong php théng ke 20 a Chuong 7: Phuong phap phan tich thé tich . (phuong phap chuén 46) 24 Chuong 8: Bai tap on tap 33 Chuong 9: Phé nguyén tir 37 Chuong 10: Phé tit ngoai - cha kién (phé kich thich electron) 39 Chuong 11: Phé héng ngoai va phé raman (phé dao dong quay) 43 Chuong 12: Phé huynh quang va lan quang 46 Chuong 13: Phé cong huéng tit 48 Chuong 14: Phuong phap khéi phé (phé khoi lugng) 53 Chuong 15: Bai tap téng hgp cde PPPT phé nghiém 37 Chuong 16: Phuong phap dign kh6i lugng va do dién lugng 39 Chuong 17: Phuong phap phan tich dua vao viée do thé 62 Chuong 18: Phuong phap phan tich volt - ampere 65 Chuong 19: Bai tap phuong phép phan tich sde ky 67 PHAN II LOI GIAI VA DAP 86 1 Chuong 1: Dai cuang vé héa phan tich 3 Chuong 2: Nhic lai mét sé kign thie edn cho héa phan tich 14 Chuong 3: Hing sé dae tring ciia cae can bang héa hoe don gian : trong nude 80 Chuong 4: Hang sé d lic trung diéu kién eta cée can bing hoa hoe trong nuée 7 Chung 5: Xit sé ligu thye nghiém theo phuong php thong ké 110 hhuong phép phan tich khoi lugng 113 : Phuong phap phan tich thé tich (phuong phap shudn 46) Chuong 8: Bai tap on tap 120 : 139 Chuong 9: Phé nguyén tit M1 Chuong 10: Ph8 ti ngoai-Keha kin (phé kich thich electron) 3. Samed wth CamScanner PHAN I cAU HOI VA BAI TAP Scanned with CamScanner chuong 1 DAI CUONG VE HOA PHAN TICH pé xc dinh ham lugng AlpO3, Fe2Os3, CaO, MgO va TiO, ng mot mau dat sét, ngudi ta cn 0,3000g mau chuyén vao chén j va thém vao 3g KOH. Nung chay hén hgp néi trén 6 nhiét 46 ‘ch hgp, lam ngudi va hda tan khdi réin thu duge bing acid HCL. nem nude cat dén thé tich xd dinh. Sau khi thu duge dung dich, ang EDTA dé chuan_ 46 ‘Al, Ca’, Mg’ & diéu_kién thich hgp; Hang 1,10- phenanthroline tao phic 46 cam véi ion Fe (dang Fe”), ang HaOotqo phife mau vang vai Ti rdi dem do. va so sinh gi cde dung dich chita Fe*/chita Ti"* da biét trudc néng 46. Ngudi ta xc dinh duge ham lugng cdc chat khao sat nhu sau: ' FeO; | cao | MgO | Tide Ham lvong (%) 0,08 Hay cho biét: a) Phuong phdp (PP) da duge st! dung dé hda tan mau? PP khs b) Tén goi cia PP da duge sit dung dé dinh lugng Al,Os, 7@)03, Cad, MgO va TiO.: \- Theo ban chat cua PP )- Theo ky thuat phan tich (PT) Bota w {eng - Theo ham lugng chat khao sat. Scanned with CamScanner Ch “ony nuAc Lal MOT SO KIEN THUG CAN CHO HOA PHAN TicH : foreectang falawee the reatums ant deter muay the teatong wel wah 4 Can bang cde phan ting va xae dink n trong biéy ra tte, duong Inong D =“ etta cde chat ¢6 gach dudis —- NaS + 2H,0 — Naso, + *H,0 — NH, + NaCl + Ho — Fe(OH), + 2NaCl — NaznO, + YNaCl +2H.0 —- CaHPO, + -2H,0 — FeCl, + —H,0 — HS + FeCl, + —~ [Ag(NH,),ICl +2 HO — [Cu(cN),” flute ¢ f ne < 10, chek | { — [Fe(CN)el — 32ZnSO, + § +/'H,0 —-i7so, + HS + H,0 —= 2Zn(NO,), + NH,NO, +H,0 — Prcl, 9 Rt xt Scanned with CamScanner Col -rhains heray bRandg CO ght C ueiey edad 96! ets bout # nde tol mot nd Ils hate edn oli ida pli Hol fil ant vate no * “8 — ps ‘ ee tegen Col 9 yr Won + H,80, C180), *KSO, + H,0 13. KMnd, “ko, ¥3H,SO, —= YMNSO, 140, + K,8O, +2H,0. ad 19. PbO, + HO, sseh,c00H —= PvICH,COO), + 0, +yH,0 ipa aed,” WOH = 2ASOS" + 380%" aH, Wed ne 7 a1. Fe(SO)s v2 — "FeSO, + IL + K,SO, 7 4 a5 CHE aig 43H,80, —> SCH {COOH “2MnSO,+ K,S0, H,0 23. ic HOH WK, Ker, HJH,SO, — 3CH,CHO +Cr,{SO,), + K,S0, 4H,0 Cée Base ué néng dé dung dich Cin bao nhiéu gam NaOH dé pha 3 lit dung dich NaOH 10%, bidt dd NaOH 10% ¢6 d= 1,110giml. mgs 2209 Wa = 9829 Xée dinh néng do Cy va néng 49 Cy ca dung dich NaOH 16%, bth MeOH ed» 2azsend Cs a 4M 2 Gye - de dink wong NaOH 40% clin ihdm vao 600y nude dé duge dd © NaOH 10%? Xie dinh lugng Na,0 edn hda tan vao 676g dd chia 160g NaOH dé duge dd NaOH 40%? C6 dd HCl 36,5% (d = 1,180g/ml): - Tinh sé gam HCl nguyén chat trong méi ml dung dich? = 2 = s - Tinh néng d6 mol cla dung dich? - Tinh sd mi dung dich trén can ding dé pha 200ml dd HCl 3M? Cfin thém bao nhiéu ml nuée vao 100ml dd HCl 20% (d = 1,10g/ml) dé 6 dd HCI 5%? Xe dinh lugng nude can hoa tan 44,8 lit HCl (6 diéu kién tiéu chuain) dé duge dd acid chlohydric 14,6%? . Phai hda tan bao nhiéu ml dd HNO; 98% vao 100ml nude dé duge dd HNOs c6 khéi lugng riéng d = 1,200g/ml? Phai ding bao nhiéu ml dd CHj;COOH 98% dé pha 250ml dd acid acetic 1M? - = @ s 10. Xie dinh lugng anhydric acetic (CH,CO),0 va nude can dé pha 500g dd acid acetic 54%? Scanned with CamScanner ; Chwcang y 10 $c % (d = 1,84g/ml) dé pha 1 lit q H. Cin bao nhidu md dd HO, 96% (d = 1,849 A H,SO, 0,54? - ‘ A {i dung bao nhiéu mJ d 1, Mudn pha 5 lit dd HyS0, 0,14 thi phai dung ld M280, 96% (d = 1,835 ¢/n1)? - PO, 6 trong 1 lit dung dich 98,48% (d = iis 9 mol - néng do duong lugng oe mn au nhat, itu va theo ed ba chtic cia dd HyPOx 17,9%? PO, 17,87%; bist Cur = 2,054 3 ; 18, Tinh so gam Hal MM Nite dinh néng theo hai chiie d, 15. Tinh khéi lugng riéng cita dd H. . . 16. Tinh khoi luong NHy nguyén chat 6 trong 1 lit dd aMoning 24,03% (d= 0,910¢/mi)? Cain lay bao nhiéu gam hay bao nhiéy ml dd trén dé pha 1 lit aq amoniac 0,0500M? 17, Cin 2,8614g Na:C0,.10 H,0 haa tan trong nude thinh 250m) ad, Tinh néng dé duong lugng cita dd dé? 18. Tinh khdi Iwong tinh thé Na,S0,.10 H,0 thu duge khi ¢6 cay 500m dung dich NaySO, 2N; bist ring Na,SO, la san pham cia qué trinh trung hoa hoan toan NaOH bing H,SO,. 19. Tinh néng d duong lugng eila dd Al(SOq)3 15% KLKL (d ~ 1,12g/ml); biét ring Ale(SO,)5 14 san pham cda qué trinh trung hoa hoan toan Al(OH); bing dd H.SO,. vo, Xae dinh lugng CuSO, 5H,0 va dd CuSO, 8% can dé pha 560g © dd CuSO, 16469 21. Tinh sé gam KCr0, edn dang dé pha 250ml dung dich 0,050N; biét ring K3Cr,0; sau khi tham gia phan ting bi chuyén thanh Cr'*? . 2. Tinh néng a6 phan mol cla cde thanh phan trong dd CaCl, 10%? 23. Tinh nong d6 phan mol cua cdc thanh phan trong dd chita 40% chloroform (CHCls) va 60% aceton [(CH;),CO]? ete i CamScanner t Chatang 3 HANG 80 DAG TRUNG CUA CAG CAN BANG HOA HOG DON GIAN TRONG HUGE Trang Had edn bang eta he (rong dung dich nude 1, MO ta trang thal efin bing trong nude eum | ay HE b) CHCOOH, cL 8Oy4 a) TLC,04 6) NaOH | ONIN NTC hy KEN: 2) CuO, jy Ma,SO, 2. MO Ui trang, thii cin bhng trong nude cua BaCl, va Na,SO, (46 dung vita dit vdi nhau). 3. Mo ti trang thi cin bling trong nude cia AgNO, va NH, (NH, thita so vdi AgNO,). 4. Viet cde biéu thie dinh luAt bao toan néng dé va bao toan dién tich cho ede hé sau: a) dd nus sia NH, (ndng d@ mol ban dau C,), b) dd nude etia NHy (néng do Cy) va NH,NO; (ndng do C,) ¢) dd nude etia NH, (ndng d@ C;) va HCl (ning dé Cy). Nhdn dign ede doi acid! baz trong nhiing phan itng sau day: 1, Z2n(OH), + 20H" = 70" + 2H,0 On + HO wz 20H 3. NH + NH === NHy + NoHo 4. HNO; + HpSO, 2% NOs + H,SO,* 5. HClO, + NH, ==® ClOy + NoHs* 6 CsHsNH* + (CHa)gN S=® CsHsN + (CHs)3NH* 7. HxCO: + HO =e HCO; + HAO 8. CoHsOH + NH; == CHsO7 + NH PH ctia ede dd 1. Gidi phuong trinh day di nhan duge gid tri pH (lam tron dén hai s6 1é),cda ede dd don acid hose don baz nhv sau: ‘Scanned with CamScanner ‘dd don acid hose dan baz phy HIOy kiwos = 0.70 Cl,CHCOOH pkerencoon = 1.3 HF kur = 3, 17 ‘CH;COOH pkcxsccoon = 441 H2O2 Pkyeoe = 11,70 NH,OH Prine = 924 NH,CI Pkunee = 9,24 Pee COe Pkexaccoon = 4,76 78 0,001 | 0,100 11,10 KON Pkew = 9,21 0,010 70.60 0,001 10,08 és Pad fee mi cia cdc dd trén bing cdch gidi cde phiong ti" at va so sénh v6i cde két qua ti i Phuong trinh day dd cho 6 trén. saa a dae a Scanned with CamScanner n_biing héa hoe don gidn tro, ni g dac trung cua cic cal nude 4 ts phuong trinh day du nhan duge gid tri pH dd diacid hoac dibaz nhu Pee (lam tron dén hai 20 Ie) cua cdc ga giacid Rode aba ee on H 1:20 pkar = 1.25 0,100 - pky2 = 4.27 0,010 ne 2,06 0,001 2,90 | 0.0001 3,89 1 acid o -Phthalic pkst = 2,95 0,100 xt (COOH pha = 5.41 0.010 oe 0,001 a 0,0001 4,02 ‘Acid m -Phthalic pkar = 3,70 0,100 2,38 Cette (COOH)2 Pkaz = 4,60 0,010 207 0,001 aa | 0,0001 4,05 HiCOs | kas = 6,35 0,100 i pkao = 10,32 0,010 0,001 0,001 ., NazCOs kor = 3.68 0,100 - “| phe = 7.35 0,010 * 0,001 0,0001 jacid (hode dibaz) bang cdch xem diacid mn acid (hode don baz) [gidi PT day di ¢ dung cdc PT don Hay tiah pH cita cde di (hod dibaz) tuong duong doi cia don acid (ode don baz) tone duong va s gian hon nia]. tron dén hgp cla baz yéu), ge gid tri pH (lam hn day dé nban 4 d-y6u + baz lien a dém acid (gdm aci baz yéu + acid lién hop cua d - baz nhu sau: 3. Giai phuong tri! hai so 1é) cua cée d acid yéu), dd dém baz (gam dd dém chifa hai chat luone tinh acl Scanned with CamScanner aa ee pe _——— Wma a aang act (CA) v8 n6N9 00 cdgng baz (Cah Hg dd dem i ce 0,100 ‘Acid yéu CHyCOOH 0,010 (kina = 107°") 0,001 va baz (lin hop) 0,100 yéu NaCHsCOO 0,100 0,010 0,010 0,001 Be aol 0,100 676 0,100 0,100 9,24 Baz yéu NHOH 0,010 ent Set (Fem = 107) 0,001 0,001 9,23 va Ee pela 0,100 0,010 8.24 0,100 0,001 7.24 0,010 0,001 8,24 0,010 0,100 10,23 0,001 0,010 40,17 0,001 0,100 10,96 es 0,100 0,100 7.21 iia oe 0010 + 0,010 724 sce ni i 0,001 0,001 7.21 y6u NasHPO, 0,100 0,010 621 0,100 0,001 5.21 9.010 0,001 6,21 9.010 0,100 8.21 0,001 | — 0,010 a2t | 0,100 9,20 sing Hy th PH ciia cde : 0 sénh véi trinh day da cho g a di i é “ am fies dgm trén bing céng thiic £44 a inh duge bling cach gidi phuond) Scanned with CamScanner ¢ trung cia cic clin bang héa hoe don cop pH (lam tron dén hai s6 1) bing ed as . tinh pl g cong the gin di an dung ctia d dusi day: id CH.COOH 5.10°M HH 2.10°M e) Hon hgp f Hon hop @ c@u e) sau khi thém 10 HCI vao 1 tit da g) Hon hop ¢ cau e) sau khi oe 10 “M NaOH vao 1 lit dd h) Hon hop 2,0.10°M NH, va 10 *M NHLCl. 5, Phai thém bao nhiéu mol HC! vao 1 lit dd chtfa 0,010M C! v7 0)010M CH,COONa dé duge da e6 pH 3,02 Me CUSCOOH 6. Tinh 56 ml dd HCI 6,0M phai thém vio 100m! dd 0,1M CHC G6 due dd c6 pH 4,25? 1M CHsCOONa 7, Tinh néng 46 mol cia dd acid acetic cé pH = 3,6? 8, Tinh khéi lugng NH,CI edn 46 pha | lit dd 6 pH = 5,5? Cae bai todn lién quan dén cdc can bang xdy ra trong nuée 1. Cho hai d6i oxy héa khir MnO, (H") / Mn® va ClO," (H*)/ Clr a) Can bing phan cing xdy ra gidia hai doi va xc dinh biéu thite tinh duong lugng cua hai tae chat? by Tinh hiing s6 edn bing eda phan ting 6 pH 0? 2, Tinh K va Hyg ca phan ting x4y ra khi tron 100ml dd Cx0;* 0,1N vao 100ml dd Fe* 0,1N 6 pH 0? 3, Hay xée dinh gid tri hé sO diéu kign cw tir pH 1 dén pH 14, biét Y* Ja anion cia EDTA H.Y v6i fn = 1071; fey = 10% hy = 10°" va ky = 107%, 4, Tron 100ml dd 0,0030M Pb(NOs)e v6 ¢6 thé o6 két tia tao thanh khéng? 5. Cho mot miéng Cu vao dd AgNO 0,05M. Viet phan \ trong dd? Tinh hing sé 47 bing cda phan Ung va néng dé cia cae chat trong dd sau Ichi cain bing dat duge. 6.2,2g NaOH rain duge thém vao 250m! dd FeCl, 0,10M. Tinh lugng tia Fe(OH), tgo thanh va néng 46 Fe" trong dung dich? 1. Them di NH, vio dd CuSO: 01M a6 tao mot phic bén nha. Xe dinh néng d9 Cu” trons ‘dd sau khi can bing da dat duge? § 400ml dd 0,040M Na,SO:, Viet phan ting xdy ra xe dinh Scanned with CamScanner a nong d Ag’ con lai khi thé 0,001M. Cho biét [NHs] = 9, an bling sau day: 8. 'Iinh ndng dé ede phite tao thanh Ny vio dd chita Ag’ vdi [Ag* va trong dd xem nhu chi xy ra I [Agi] Br 312 ‘~ TAQ(NHA)). ¢ NH, S== (Ag(tHa)2 Te 7 10 ; ) “ ne ( 9) Tinh pHT cain dd HyPO, 0,147, biét acid nay 6° 7 ae hs oe J va @ pH nay, tinh néng do can bang on Ag’ + Nia coe phy = 12,2 trong dung dich? es — 10, pif enn dal H,CO,0,15M duge gidi tir PT day dit Ia 3,64. Hay 2c dh - vv he thanh phan é trang thai can bing khi hoa néng 6 cia cae thanh phan a 1558. py = 10°10 0,15 mol 11,CO, vao mot lit nude. Cho har = 10°"; aa = a 1, Xae dinh néng do cia cée thanh phan @ trang thai can bai cua dd H,C,0, 0,1M; biét pH cia dd HaC20« o1M duge giai PT day di a 1,28. Cho ha: =109; haz = 107°". om : : de voi Fe. Phi 12, Ding ligand L 1a 1,10 - phenanthroline tao phic véi Fe**. tao thanh @ cée dang FeL, Fel, va Fels vdi Bi: = 10°; Bis 10 va By = 107. Hay xc dinh néng d6 cia cdc phitc tat thanh va néng d@ Fe” cdn lai trong dd, néu néng do Fe** ban da 1a 0,001M va néng do L 6 can bang 1a 0,1M. 13. Fe** tao vi SCN” thanh phite [Fe(SCN-),]°"* v6i x c6 gid t tir 1+6. Gid tri hang sé bén cia cde phite [Fe(SCN-),]°** 14 lugt nhu sau: Bia = 109%; Baa a - FhUDe Bis = 10" va Bio = 10°, Xde dinh néng d6 cia cdc phitc ta thanh va nong 49 Fe* con lai trong dd khi them SCN- vao d chita [Fe**]p = 0,001M véi: a) [SCN"] = 1M b) [SCN Gia st trong diéu kién dan Ung gitta Fe* va SCN”, 14. Thém KSCN 5.10°°M yao dd chy bm i 10M chtfa [Fe], = 0,0 én'k a ne mau dé ciia phite (Fe(SCN-)} kha ot ae ane i id KSCN (5.10°M ef sit dung had otal r 2+ ea . ie p SCN OF xudt hign khi néng 49 cia ion phite nay én ht 16. ion-g/l (bé qua anh nuéng cla OH- lén io: me ve : mn Fe**). F Scanned with CamScanner ig x6t trong dd chi xdy ra cde pha Chuong 4 HANG SO BAC TRUNG BIEU KIEN cUA CAC CAN BANG HOA HOC TRONG Nude Hing 86 dée trung (HSBT) dieu hign cia cén bing trao déie ne, é 62 eth + 24 1. Tinh ed a cua coe 1Co’ va cla Fe® “/Fe® trong dd KCN du. ce su phite cH tao thanh véi sé ligand lén nhat va bd qua anh huéng cia OH ~ lén ede ion kim loai, ching minh Fe* (duéi dang phue vai CN") sé oxy héa Co” (duéi dang phite vi CN") mot céch hoan toan. Vote Lubing duz Ugamd th (usr tao BAY * om - y wy yo 2, Cho hai déi oxy héa kh: th orn, put ce 6 Ligand WiE Au'+1e° soe Au E°= +1,68V Cu'+ te == Cu Ee = +0,52V Xé6t chiéu phan ung va tinh hing sé cin bing cia phan ung xay ra khi tron hai d6i oxy héa khti néi trén trong hai trubng hyp: a) Khong co sy hién dién cia CN” trong dung dich phan ting. b) C6 sy hién dign ca lugng(thita) CN” trong dung djch phan tng. Cho biét ede can bing phy eda ON’ Ién ede déi oxy hoa khit déu la can bing phy tao phic va bé qua anh hudng cua tat cd cde can bing phu khdc. ~ DKMOt ion kim loai héa tri 2 ¢6 cam (M?/M) = 0,900V. Sau khi trén 25,0 0,100M véi 25,00m dd Y* (EDTA) 0,20 tao béi chp M"*/M néi trén 1a 0,570V- a) Tinh thé oxy héa chudin diéu kign cia cP M*/M néi trén néu bé qua anh huéng cia H* lén y* va anh hudng cua OH lén M”, b) Tinh hing sé bén eda phic ta0 béi kign dé ¢6 thé sit dung Y* chudn do dd M* é pH 10. bing M+ 2e === M voi Er ml dd M** ndi trén cd néng 46 OM; ngudi ta do duge thé M? va Yva cho biét diéu Scanned with CamScanner «rt dé gidi phong ra Hy me 4. Gidi thich tai sao Ag chi tac dung voi HI dé giai phone emi Khong tae dung véi HCI? Cho tich 0 tan eta AgCh Ae Tre va Tyr = 10; EP (Ag'/Ag) = 0,80V. View phan ding xAy a. HDT digu kign ciia can being trao di tiéu phan 1. Tinh pH ciia cdc dd sau day: : 10M; 10°M; 10°M a) dd NHL: ‘i b) dd NH,CN: 10M; 107M; 10°M ¢) dd (NH, )sHPOx: 10° . Gas hon hop: — 5.10°M NaH,PO; + 10°M NaHSO; +10 7 Ni (pk = 4); HB (phe = 7) co néng di 2, Cho hén hgp hai acid HB; méi acid 12107. ; a) Tinh pH cua dung dich? : b) Thém vao 100m/ hén hgp trén 100ml NaOH 10°M. inh p cia dd mdi? 3. Acid boric duoc xem tuong duong mot don acid cé ke = 10°" va biét rang H,BO; dé tao phttc vai mannitol (ky hiéu M, 1a mét da rugu co cong thtic nguyén CgH,40¢) theo:phan ting sau day: HB + M ==> BM + H* B, =10748 BM + M = BM Bo =1079 Trong dd mannito}. :‘nh acid cia H3BO; thay déi thé nao? Cho biét (M],, = LM. 4. Trong dd Cu”* 10"*M, tinh acid cia glycine NH,CHsCOOH cé thay song? Cho biét On khong anh huéng dén céc ion trong dd va hCHsCOOH) = 10°°"*, 8 (NH,CH; COOCuy* = 10% ] ih Tinh dé tan cia CuS tron; anh huéng cia Ht va OH’. 6. Tinh 46 tan eda AgCl (’ 6nd Trscr = 107275 stn / ©6 néng do [NH,] = asc! = 10°") trong moi truéng ammoniac 0,1M trong hai ti . rudng hgp: y a) Khong xét anh huéng cia OH- 7 ; b) Co xét anh hug ; yéu béi lugng Ni eae “ia OH! (pH cia dd duge quyét dinh chi . Scanned with CamScanner ac trung digu kidn cia cde efin bling héa hye trong nuée 19 Cho biét NHs 6 thé tao phtie véi Ag* theo hai can bang sau day: Ag’ +NHy s== (AG(NHs)]" (By = 10%) : [Ag(NHa)] + NHa == {AQ(NHs)2]" (Be = 10°94) OL gay nhiéu lén Ag* voi Bia =10°°; Biz = 10° va B,, = 19°2 7. Ching minh ring HgS khong tan trong HNO, ma tan trong nuée exing thiy (10 HNOs 44 va 3v HCI Aa), Cho biét Hg tao phite voi Cl’ duéi dang HgCl, myn S bi oxy Wa boi NO, |g. Cho dd [Cu°*lp= 10M vao dd EDTA cé [Y"},= 10 *M 6 tao phiie. Néu phic CuY? khong bi anh huéng béi_ H' va OH pian tng tao phic CuY® cé tinh dinh lugng khong? g. Tinh hang 80 bén diéu kién cla phic CuY~ & pH 13? Biét rang cuY*_bi_anh_huéng béi OH do tao phue [CuOHIY? 6 B [Cu(OH] Y* = 10°”. 10. Xét tinh dinh lugng khi dung EDTA chudn do Hg”: a) GO pH = 10? b) Cang 6 pH = 10, nhung trong méi truéng cé CN voi [CN"] = 10°M 11. Tinh hing sé bén diéu kién cia phuc [Fe(SCN)I** 6 pH tir 1 = 4, biét HSB cia phtic trén 1a 10° Fe® bi nhiéu boi OH” voi Bia 10", By = 10°"; Big = 10 va acid HSCN €6 ht. = 10 88, 12, Tinh hing sé bn diéu kién 6 pH ti 4 +7 cua phie Fela voi L Ta anion cia 1,10 - phenanthroline, bist phic tren 6 Bis =10 ; eee ak ee os 556. = 107 [p,,, = 10°" va Fe* bi nhiéu boi OH” voi fia = 10°; Bia = 3 Bas Bia= 10°, Acid HL c6 hy = 10° Scanned with CamScanner Chuong ¢ NGHIEM i LY sO LIEU THYC NG a XU LY énG KE THEO PHUONG PHAP TH og iO, trong mau Ihodng ce dinh ham lugng G TiOz ng m c ne Néu ham lugng thu ctia TiO, 1a 0,125 A 6 mae phai sai so hé thong hay khong & 90 va 99%? ' 99; 7,35; 7,31; 7,33. Tinh: khoang ti y6i hai mtie xtc suat 2. Do 4 lin pH co két qui 7, cay khi P = 90%, 99%. ; ah apt 3. Ham luong (%) Pb trong mau hgp kim duge xc dinh 3 tan vi ke qua nhu sau: 0,184; 0,189; 0,179. Tinh cn tin cy va Ihoang tin 4 cia gid tri trung binh ham lugng % Pb véi xac suat 95%. 4. Khi x4e dinh % SiO, cia mot mau dat sét, két qua cua 5 lan t nghiém thu dugc 1a 55,95; 56,00; 56,04; 56,08; 56,23. Bang cach s sdnh v6i d hoc s hoac ding chudn Q véi P = 95%, cho biét nén gil lai két qua 56,23 hay bé di? 1 5. Fluor 1a tap chat c6 hai trong nuée néu vuot qua ngudng chi ae Qua 4 lan phan tich ham lugng ppm F~ trong mau, két qu thu duge nhu sau: 1,82; 1,28; 1,36; 1,50ppm. Hay xée dinh gigi ha trén cia F” véi xdc sudt 95%. i q nghiém Jan lugt la 0,27; 0,28; 0,32 va 0,37ppm ; 2 Sit dung chudin Q dé cho biét nén gif lai ha: "37 ing v6i cde mie xée suit 90, 95 va 99% b : ' A eee dinh khoang tin cy cla gid tri trun, 8 Voi cdc mite xde suat 90; 95 va 99%, y nén.bé di gid trl g binh ham lugng Fe Scanned with CamScanner Chuong 6 pHUONG PHAP PHAN TICH KHOI LUGNG (PPPTKT) nai mau quang chi: Maul: % d = 1,56; % Pb = 24,02 Mau 2: % d9 dm = 0,58% —% Pb = 24,26 Tinh 9, Két qua phan tich do am mét mau phan b6n photphat bang phap phan tich khéi lygng cho cde s6 liéu nhu sau: 1, Phan tich I ham lugng Pb cla méi mau d dang khé va nhan xét. phuong - Chén sti: . mM, = 9,4358g _ Chén stf c6 mau (chua sy): m; = 11,4585¢ -Chén stf c6 mau (da say): m2 = 11,3762g a) Tinh dé 4m cla mAu phan bon ndi trén? b) Tinh thanh phan % cla P.O5 va Ca(H2PO,)2. H20 trong mau phan bon chua lam khé, biét két qua phan tich ham lugng P20s trong mau da say khé 1a 16,5%. xit sét nang 0,5000g duge lam két tha dudi 3. Mot mau quang o: a can nang 0,4980g. Tinh dang Fe(OH); va nung thanh oxit sat b: ham luong sét dudi dang % Fe va % FeO? 4, Dinh lugng photpho trong méu phan bén, 1,000g mau duge tao tia dudi dang MgNH,PO., Nung tia 600°C duge dang can Mg:P,0; c6 khdi lugng 0,2350g. Tinh % P va % P,0s trong mau phan bén? 5. Mot mau 44 voi edn nang 1,2300g duge hda tan trong acid. Loe ba tila, dung dich qua loc cho tée dung vai NH,OH. Khéi higng cde oxit kim loa hoa tri 3 thu duge 1a 0,0584g. Nhom duge cd lip riéng va dang can thu duge 1a AlzOs nfing 0,0282¢. ‘Tinh % Fe va % Al trong mau? 6. 0,8325g mét hgp kim Cu + Sn + Zn. Phan tich bing PPPTKL * thu duge 0,6728g CuSCN va 0,0423g SnO». Xdc dinh ham lugng cac thanh phdn trong hgp kim. Scanned with CamScanner . {dé 1am ket old = o,g90gin 1 ae ir 0,2008 quing 6 80% Fe’ aa tan v F rong BaClz xH,O, ngudi @m nhu sau: yo hic 4, Phi dang bY ya phan tich ¢ * yong ham Non jot tinh t 8 ON PT ya duige ce kot qual ne nghi - Dia cant m = 167208 _ pia cn eo mauE = 237628 Chen sth my = 927388 “Chen st +4 BaSOy 24 = 9,9464g Tah & Ba, % BaCh ya xde dinh tri s sx trong cong thiie phi 9, Phin hoy 0,1500g mot hgp chat hitu eo c6 cong thite CoHs.C uve jon CY. Két ta ion CP bing Ag’ thu duge 0,4040g AgCl da: qin, Nac dinh x trong cdng thie pl xem Ja nguyén chat). to. Dé xée dinh him lugng cia mot méu KAI(SO,)2xH0, nguoi ’ can 0,5260¢ miu; hoa tan va tgo tia bing dung dich Ba”. Kha re dang can thu duge 1a 0,4591g va tiv dé ngudi ta tinh duge KANSO,)2sHL.O trong mau la 88,7%. Hay xde dinh: ; “ Gi tri euia x trong cong thie phan ti néi trén ) % KAWSO,)p trong mau. , M1. Dé don gidn héa ti iin h6a tinh ton, phai edn mo phai cin m6t lugng phan bén kal 1a bao nhiéu dé ho % : can KCIO,2 10 % KO thu duge bing 100 lan khéi luon, i Ong dan; het Fe jp nucie ain ty, (NHo,Ptc] lc. N la ee an 0.108% Pane NEP 6 ae tia NH," dui dan 9 et dQ thich hg; | Gp, thu dug oH Scanned with CamScanner é tich khdi higng se 23 ppudt enn —<—<—<—— ot hin chi e6 CaS val Zn8. Cin 0,498%¢ mau hoa tan i qe va Zn, Lam két tia het hai kim Joa; bang thuse p dudi dang MeNH,PO,. Nung dén Khi duge khoj lang 0,6987¢ MesP20>. Tinh Ikhéi lvong ZnS 6 bong hin dem phan tich? (Me 1A Zn hay Cd). 16. Mot mau hop kim zirconium (Zr) cé lan mot ith 8, sng tinh chat ha hoc véi nhau. Can 0,2000g mau, hoa tan va an xe via bang acid mandelic (C(l¢CHOHCOOHD. Nung tia 6 nhiet ichoi Ivong khong adi duge 0,1380¢ ZrO2 + HiOe ag thich hop dén piet ti lé ikhdi lugng HO: / ZrO = 0,023. ie 0 a 17, Chi thong qua két qua xdc dinh CO,, ngudi ta tam két luan mot mau hoa chat ¢6 thé 18 SrCO,nguyén chat. Tuy nhién sau khi tién hanh phan tich dinh tinh mét cach ky ludng, ngudi ta thay rang jon St" khong c6 mat ma thay vao dé 1a ion Ca2* va Ba®*. Tinh % ia CaCOs Va BaCOs trong mau hoa chat ndi trén? 18, Phan tich mét dung dich chiét ra tiv mot mau dat bang cdc PPPTKL, thu duge két qua nhu sau: 7,59% Ca0; 5,61% SOs; 2,20% MgO va 5,29% COp. Tir cdc s6 ligu tren, tinh % CaCOs, % MgCOs va % CaSO, trong mau dat khao sat? t khd tinh khiét chi cé thé 14 ZngP20- O (M = 458,1) nang 0,2000g duge Lay 25,00m! dd A dem tao tua (NH,)s (PO;.12Mo0Og) (M = 1876,3) va dem nung tia trén 6 nhiét dg ego dé chuyén thanh (P20s.24MoOs) (M = 3596,6). Khéi lugng dang can thu duge 1A 0,2950g. Cho biét mau hoa chat dem xde dinh 1a ZnzP207 hay Zng(PO«)24H20? b) Hay dé nghi mot PPPT khéi luong khée gidip xée dinh héa chat hon nhiéu so véi PP trén. can tim don gidn va nhanh chong 20, Hoa tan mot méu ‘dé voi chita Ikhoang 0,500g CaCO, réi 1am két tia Ca? bing dd HyC,0, 6 diéu kign thich hgp. Thé tich chung ctia dd lic tg0 tia xong 1a 100m, pH cia dd la 4,0 va [C.0,7"] = 0,010. a) Tinh s6 mg Ca bi mat do tiia bi tan? b) Tia tao thanh duge loc va rua bing dd (NHy)C20; 0,050M. Tia duge ria § lin, méi lan dig 10,0! dd (NH,).C:0,. Tinh sé mg Ca bi mat do qua trinh rua tua? ©) Tinh sai sé tuong adi cia phép phan te tia va rita tia gay nén? 15. dd c6 h hop a afnium (Hf) e6 19. a) Mot mu hoa cha (M = 304,7) hode Zn3(PO4)2-4H2 hoa tan thanh 200ml (dd A). h do qua trinh tao Scanned with CamScanner he phuong PHA © oxy “nn dua tre” aia nid of rie 1 den duge tin! a a thi rong 4 hoan an va U bd qui at hoa tan thar id 0: tinh khiét (H2C20+ sh oom! dd nay ding ¢ an d g2,40ml dd KMn0x. ve gag ci 68 OETA rand /FeSO? ang sit can nang 1,79508 duge hoa tan rol kh j va pha chi nh xdc thanh 250,0ml dd phan tich. Bié KMnO, ¢ dd nay da duge chudn do b T= ,001842g/ml. ‘Tinh % Fe trong quang? ] tinh khiét thanh 500ml dd chuai , Hoa tan 0,24868 K,Cr07 YeGrs0, Hat 25,00m1 4d nA, them mot lugng HCl va KI thich hyp roi chudn 49 bing 95,50ml dd NasS,03. Tinh néng a6 duon, Iugng cia dd NasS,0s va 6 chudn cia dd dé. 4 Mi le 6 FeCl; can nang 4,8900g duge hoa tan thanh 250ml id phan tich, 25,00ml dd nay duge chuén do bing 32,10ml de NayS.03 0,0923N tr a ‘ b ‘ong méi trud F a oar Tinh % FeCl, trong m: a i truéng acid trung binh va co du KI. 5. Hoa tan 0,2136g mot mai NasC,0. tinh k 186g mot miu quing chia M . aay ahaa i ais moi truing H,SO. ne ae 0,40208 ay ra hoin toi, chudn d6 lai lugne C.0.2- ‘au khi phan « 10, 0,000 Tey ee luong C,02- bE i phan dni Hinton 1864 ee ba ing 24,20m dd : et mi ding. ; dang Cr thank a miu the ang KMn0,. Big IM réi chug, a8 thue hi ig win dp we hién phan ung #08l Ota TN cay a aa ns MM hie bee ting gid = 35,28m, nO, na , zh) J 4 Nay tn. Th Gr ne sore 100ml dl ig mAu thép? “ ‘pe Scanned with CamScanner puro PI o bai tgp uit 7+ 12 duge tinh todn trén gid thiet cée phan Ca an toan va co tinh dén sai 86 chi thi trong qué trink ag xy 7 HO pun Far : vin do 20,0oml ad Fe" 0,050N bing dd KMnO, 0,100N pki J itinh thé tich dd KMn0O, 0, 100N céin dung dé dat didn Wong Jong. os 7 p) Tinh sai § so chi thi va thé cua dd khi thém vao dd chudn do: gon; 10,00md va 10, 10ml KMnO, 0,100N. Cho BE? (MnO, /Mn**) = 1,51V; E° (Fe**/Fe**) = 0,77V va é diéu ian chuan dd, ngoai H* khong con cdu tit nao gay nhiéu cho hé phan tng. . Can 1,6057g mau KMn0O, va héa tan thanh 500,0ml dd A. Dé hudn d6 100,0ml dd Fe®* 0,100M 4 pH 0, phai ding 100ml dd A via ha 6 trén. a) Tinh néng a6 duong lugng cla dd A va % KMn0Q, trong mau an dau (b_qua-saisé-chudn 46). inh sai s0 chudn d6 va thé cia dd tai diém cudi, biét ring trong ‘1 dd KMnO, da sit dung, ngudi ta da ding thira 040ml. ¢) Tinh % KMnO, thuc chia trong mau ban dau. . Chudin dé 50,0 dd Fe** 0,100M bing dd K,Cr,0; 0,050 6 pH =0. a) Tinh thé tich dd KyCr,O; 0,050M can ding dé dat diém tuong duong. b) Tinh sai sé chi thi khi dimg chat chi thi diphenylamine sulfonate ‘a (E* = 0,85V; n; = 2e) dé x4c dinh diém_cudi. Cho E° (Cr,0;"/Cr**)-=-1,88V; Bh (Fe®/Fe”*) = 0,77V va 6 diéu ién chudn dé, nee Hy 4 ER ‘6 sy hién dién cua mot cdu tr iéu nao khac. wry Cyn E 0. Uhudn dé dd lee wale dd Fee trong méi truéng Hd = = 1M.

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