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  • Primenenie Ftoridnyh Solevyh Sistem Dlya Polucheniya Titana Metodom Elektroliza

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    Дина Николаева
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    © All Rights Reserved
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    5 views3 pages

    Primenenie Ftoridnyh Solevyh Sistem Dlya Polucheniya Titana Metodom Elektroliza

    Uploaded by

    Дина Николаева

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
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    Vanectun Tonexoro nanurexnmeckora ysuoapcitera, 2007.7. 311. N23 YyaKee148 46.16 TPMMEHEHVE ®TOPMHbIX CONEBbIX CMCTEM DAA MONYYEHMA TUTAHA METOJOM 3IEKTPONM3A B.A. Kapenis, 0.8. Kawenena Ceeepcxa rocyaapcTaeon TevonoriyeckanakageNMA E-mail vadmiraseersk tomsknet ns oearroxe npnuvinvansno wos ops cnoco6 cnTe3a BICOKOMACTOFO METANIHNECKOrO NOROU TATBHa 3 MpHpORN OX- ‘gun KononTparoa. B zasepuacule Cosy Teexononeckoro NpoYecta ankpawe HCNOM3094 INeKTPONUTHNECKI METOR Pa ‘rox Terpadhropita Travia Bhaconnaekor 2aTeKnie cTopwa0 Coney wenOvNEX MeTannos. HnorssoeanvesTorocncoda 8 poweaurenton apakraxe n0280NAT MCRTICNTs 38CpR3HeHHe CKPYKACUEN Cpe BDEAHNM XHMUNECRHIMH BEUECTBONE H NONYYATs ReUeBE BICOROSACTh METANNWMECKHN ROPOWOK THN Hirihopataun no ponopoaoxyy poceTaHoReHIO Ta sooSpaaien droprizos TyToMARBKENX MerATTOD coTe- 2xYETCH Y MHOFOUITEAEMHN Hay uRBDX GK [14]. Baarmoaeitetnie rasoo6pasioro terparproprtaa ‘TuTaHa ¢ BOTOPOIOM OMTHCHIBAETER CyMMADHEIN YPa- bileHest peak TIF y+ 2Hy,=Ti.,+4HF, ° TIporpeceussocts Toro mpouecca craHowuTes ‘O¥eBILLHOM 8 CHAS c COMAHHIEN saNKHYTOM TEXHOMO- THIvecKolt exeMBI, B KoTOpolt MeTAIHYECKHE OTXOMEL ‘iraia ropupylores aiewestisim (propo. OSpaso- nasuuuiien Topi] oceTaHantunaetes BOLOpOAOM € TosyyeHHew noryhaGpHkata, a BpuxensoULles dpro~ PobosOpOA HoMHepraeTeH AteKTpOAMSY H pactLlaBe KELF, cmroaysenitem dpropa st soxopoma. Kpowe toro, a ragonoit dass TIF, © notoporoM MoxHO ¢bopwmpo- ¥ATB garoTOBKHt WI Meat pasHooGpasHot hops, KoTopsie TpyaHo, a MlOTyAC HeBOIMOIKHO MITOTORITD pyri Metoaav, TIpouece nozoposioro noceTa~ Honnenwa TIF, Menoabayior Ana HaHeceHHA 13 Ta30- soft bases MOKpBITIt #3 THTaka HETH ero cIAABO® pas~ mieaHoro HanHaNeH Boropoantomy crocosy noaysenite TiTatta 119 ero ‘etpagopiiza mprcyurn cyitecrRenttse 1 ONeBITHBIE enocTarkn, [rapibsit 19 HHX COCTOHT B TOM, #T0 TO- oreHoro mpoTeKaHis peakui (*) He HaGmOMETeR Tpit ocaokeHMH Ha pRYTpeHeHT NonepKHocTH OGorpe- BaeMott TpYGKHC BnLToTE 0 900 °C [5] w m0 1200 *C — Tipit ocaxkZeHttH Ha HapYAHOH TOBEPXHOCTHE TOTAOK- Kit 8 o@BeNe peakTopa [6]. TowtoresHoe npoTeKaHHe pACeMATpHBAENOf peaAKUMH B OBKEME peaKTOpA NpO- exo smut pH Texmeparype neste 1400 °C. Fpo- luece BoceTaroRexia TiF, HOAOPOLOM MPH CON BE~ CCOKIX Tenreparypax OByeHORIeH HATEHCHBHOH Kop- ppostlell matepuata peakropa Ho ¢broplicTonoopoA- Hof cpere. Kpowe Toro, mpi nponexesmst npotiecca Ha MOROAKe HaGnogAeTeH MHSKH MpAMOR BHIXO ‘irava 13 eitaBHo pas6atsieHHoTO HOOPOAOM TA3080- To MoToKa TeTpacpropHaa THTaHA H HH3KAs MPOHsBo- “aiTenbit0cTe peakTOpA, Hawn mpopereHst HeetexonaHnit to rloayueHito BHCOKONHETEKX MopouIKoB THTaHa. sueKTpONHTHYe~ KIM paxtOxeHNeM TeTpadpTOpHAA THTala HAM. TeK- caropotiranata Kanna (K:TiF,) 8 pacretane Hit3K0- aankoit aBTeKTIKH ropmAABX corel WenouHEX weranzon [7]. Jax ori ueneft Hawt HecTeronaHEt tpoitite spTekTuveckite cweci (bropuaHbKx conell LiF-KF-NaF # pexomerszonaxa aa mpaxruseeKoro enionssonauiua aprexrika 0,5M LiF — 0,39M KF — O.1IM NaF, umerouas 4,=472 °C 0 xauGomsuyto SHeKTPONPOBOAHOCTE Mo EpABHeHO C SBTEKTHKANIE Ha octione xtopHtHBix comet (8) ‘crepunetTansian Nacte m oBcyxstehte pesynbraTos Jia mponenenis sxenepHNeHTanBHBIX HeeTen0- AHH 10 oeyiecTaeno Mpoutecca sneKTpOIMTHe- ‘exoro pastoxena TiF, Han texcadroporimanata Ka- ait (K:TiF,) 8 abrexmake ¢propianenx cozeit ¢ nary- ¥eltHeN tia Katoze neicoKOSHCTOTO MopoUKa THTaHA, & a axoge snemertTHoro dbropa no peaKuHaN TR, = i 4F, K.TF,=2K" + TR, TRP=T+6F, a karoxe Ti+4e9T, xa auone 4F—4e>2F, HaMiM paspaGorana onbitiag saeKrpomHTHecKaR yetawonxa (pic. 1). 7 Nats 10 D / 6 o cd roa i eaKO i 3 Snot 9 2-18] 3 8 Phe. 1. Crore yeraxosxs nonsense aeetponimyeccro no pouxa natena: 1) anekrponvsep, 2) 2vog, 3) xarOM, *4)a6copbepc XIT-H ana nornowenn 5) anexrpve x38 new, 6) saxyyuiuih nacoc, 7) Gyrwep ¢ TH, 8) snextpose secu, 9} Gannow c wHepraw ras0M NY, 10) eunpaunrens xinana Onesriia stekrpamiTinieckaa YeTAHOBKA COCTOHT 13: = repweritunoro a1eKrpoausepa ~ 1, Kopnye Kppiliika KoToporo HsroToMIeHb! Hs HepxaperOutelt tam I2XISHIOT. ramus xopnyea w KxpBIIKH OxTMKARIOTeA MpoTONOHt noo! yrAoTHEHHE ‘OcYUECTRARETEH € MOMOINBHO HAKYYMHOFH PeIHEL. Antozow exyxn Thremb ~ 2, a KaTOR nBiTOTHEH 1 uae ctepxwa — 3, AHOR H KaTOA W>rOTORTEHM 13 nbicoxouncroro rpairra apt APBY. J pao- Saarennia 20 KoHMeRTpaMT 10...15 06. % BBITe- asioulerooa Ha axone F, W oxTaATEHH OcaNKa TH ‘aH Ha KaTose, MOcME MONHATHA ero HEL pacrura~ BoM SBTeXTHKH 13 PrOpHLAHBIK conelh aneKTpOE- ‘a, B Kopnye snekrporusepa 13 GaLTOHA NomROT Repti ras (a20T); — aGeopSepa — 4, samomHexHoro xmieveckit 0- raoriereteM sopecrkossim (XIT-H) vent apyria ‘THEPIBIM COpEEHTOM ATA TOTTOMIEHA NEITENTIO- ieroes Ha avore snewenTHOrO topa; — aaeKrpiteckofi nesn — 5 08 pacnaanenia 98- TeKTHKH dpropwaHBHX cone (Gropunos Li, K 1 Na) Wt noatepxania sananHo Temmeparypst -rexrpomia (500 °C) mpi anextpomine; — naxyywntoro tacoca ~ 6 ax ynanenita nosAyxa Ht BBAaTH Tloese repMeTHaut ceTeMEs; = enkoori (Syiepa) ~ 7 21a nonast pacxoayeMoro petecrsa — Tetpacpropriaa Turaxa. Ja onpezese- nie KoaecTHA MosaBAeMoOTO HeUIeETHA EMKOCTD yotartontena na azextponnte pects ~ 8; — GixvtoHa ¢ mHleprHBiM TazoM (asoTOM) — 9 21s Mpo- AAYBKHC CHETENB! epes HayaAIOM mMpottecea Me OCTE fo oKOHAHH; — puinpauartensioro yerpotteraa — 10. Alaa npeaorpauienita BEIGpocoB B Xone Mpouecca srexrpomiep, aGcapGep n naKyywnBst taco yerana- BaMnAIOT B BLITLAKOM Kady, Saekrpoandep usteeT xapakrepieTinkH: MponsnomHTeABHOCTS 20 80 r/4 0 TiO, rewmeparypa szexnponutta $00...550 °C; Hack iexie pacriaasa soreKTuKu 4.8 % no TiP,: aHOmKaK nioTHocTs Toa 0,09..0,13 A/ear; Karoaias muor- HocTs Toxa 0,42..0,63 A/ew CoGpanutit u sarpyxenntit spreKTiMecKotl eMe~ aio (bropriaaeex coneth anexTporiNep noeTe npema- irTeTBHOTO BAKYYWMPONAHA TAMOAHAT aD0TOM 1 Hanpewant ao Tewmeparypsl pacntawtentis conetl (472°C), B conenoti paeriaan 13 extkoeTa — 7 nonana- aut TIF, 20 Koruespaunn ~§ % HLaa Toro, 406s! He TpOWcXOAHIO sAGuBAKI HEINOAHOM YacTH TPYOKH OO- ISYIOULHMGS! BpacTLTaRE TexcadhroporHeTaHATOM KA- ‘ia, nexoawsii THF, rosanann nopuniaat mo 50.100 Bate TpyOxy ara nioaaan TIF, noamnwan a pac- Tavow (prOpHAIHENX cone, MpeaBapHTTeNsHO oeNAGHA YynnoTHeHHe B KPBIUIKe aneKrpomlepa. DnekrpoNiNIep ‘oxasxaaum, nose wero TPYGKY tA oaasH TeTparpro- ta Tarawa saensian Ha rpadpiromeit Karoa ‘as pasorpenanis pacrizasa aekrponiTa BKO- ‘warn s1ekrportews — 5 w onyeKatu rpadputrossil KATO bo dbropuasilt anextposut. Tipit npopeneHun a1¢K- ‘poitisa Ha rpapiTonbie Katoa (eTepxeHb) H atioa (rire) noxanatn nocrostKtit TOK, HeMHHEY KOTO- oro napsriponann B nperenax 50...100 MA, a Hanpa- 2xente — B npeneaax 2...10 B. B xone aekTpomGa Ha Tpadirronow kaToe MpoHEXoAHtTo OGpadomAHHE OCA ka (Mopouka TiTaHa B pacrztase ¢bropuaHEsx cozeli), a HaaHoue — aneMeHTHOrO dpropa, KOTOpEII HEIBONILT- (8 uo suekrpomiepa Ht NorTouIaTes B AGcopGepe — 4 Ha XWMSeeKON fHortoTHTere HoBeerKOKOM XTI- (cect 96 % Ca(OH), 4 % NaOH). Jas Toro, «ros Inpit norsouleHHH 4topa He MpovexoaHsIo sarttaRIe- Ms HortoTiTes H5-s2 ero pasorpesAHiA, steMeHT- nti rop pasGanaaan as0TOM 10 KoHeHTpAL 10.15 06, %. Koni¥ecrso noaanteMoro azora npea- RapHTenBHO pOccHHITEINATH, HeXOAR 119 KOTHTYeCTHA

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