MISCELLANEOUS Quesry, ONS BA. ON ICSE EXAMINATION “? 5, 1. Write the balanced equatio the folowing compounds (as the major produey ebaration nm re and using only one other substance : § trom (@ Iron (II) chloride (4) Tron (ID) chloride (c) Iron (IT) sulphate (@) Iron (1) sulphide ‘Ans. (a) Iron (II) chloride can be Prepared as Fe+Cl, —> FeCl, or Fe+2HCi| —> FeCl, + H, (6) Iron (III) chloride can be prepared as - 2Fe+3Cl, —> 2FeCl, (c) Iron (11) sulphate can be prepared as Fe +H,SO, ——> FeSO, + H, (d) Iron (II) sulphide can be prepared as Fe +S —— FeS ue wo Arundeep's Chemistry 70th2. Write balanced reactions for the following conversions(A, » i 0 oh Fe Ss FeCl, 8» Feo, C+ Fe(NOs > Fey” Ans. Fe —A-y FeCl, Fe + 2HCI + FeCl, + Hy [A] FeCl, 8, FeCO, FeCl, + Na,O, —+ FeO; (B) FeCO, £4 Fe(NO,), FeCO, + 2HNO, —» Fe(NO,), * H,O + CO, (cl Fe(NO,), —2-> Fe(OH), Fe (NO,), + 2NaOH ——» Fe(OH), + 2NaNO, (D] Q. 3. The preparation of Lead sulphate from Lead carbonate is a two-step process. (Lead sulphate cannot be prepared by adding dilute Sulphuric acid to Lead carbonate.) (a) What is the first step that is required to prepare lead sulphate from lead carbonate ? (6) Write the equation for the reaction that will take place when this first step is carried out. (c) Why is the direct addition of dilute Sulphuric acid to Lead carbonate an impractical method of preparing Lead sulphate ? Ans. (a) Treatment with nitric acid to form soluble lead nitrate. (6) PbCO, + 2HNO,; —> Pb(NO,), + H,0 + CO? Insoluble (c) Directaddition of dil. sulphuric acid to lead carbonate will lead to deposition of lead sulphate on the surface of lead carbonate = Which stops further reaction of sulphuric acid on it. Q. 4. (a) What are the terms defined by the following ? (i) A salt containing a metal ion molecules. + 2NaCl surrounded by other ions 134 Arundeep's Chemistry 1"iy A base which Is soluble in water Mi soluble salts, (i) tka (b) Making use only of substances chosen from those given bel pilute sulphuric acid wodlum carbonate Zine sodium sulphite Lead calcium carbonate ive the equations for the reactions by which you could obtain : ( hydrogen (ii) sulphur dioxide (iii) carbon dioxide (iy) zine carbonate (two steps required) ans. (i) 204 HS0, —>+ miso, + Hy 1 Zine Dil. sulphuric acid Hydrogen {iy NSO, + H)S0, —> Naso, + SO, 1 1,0 Sodium dilute Sulphur : Sulphite sulphuric acid dioxide CaCO, + HySO, —> CaSO, + H,0 + CO, Carbon: dioxide (iii) Calcium Dilute carbonate sulphuric acid iv) Zn + HySOQ, —> ZnSO, + Hy t Zine Dil. sulphurie acid zine sulphate ZnSO, + NajCO, —+ ZnCO, + Na,SO, \ Zine sulphate Sodium Zine carbonate carbonate 2009 (a) The acid which contains four hydrogen atoms ... ( Formic (ii) Sulphuric (iii) Nitvie (iv) Acetic-acid Ans. (iv) Acetic-acid ith di (b) A black coloured solid which on reaction with dilute sulphuric acid forms a blue coloured solution Atundeep’ ‘eep's Chemistry 10th 135> i) Carbon @w are’ ee a : 7 (iii) Lead [II] oxide (iv) Copper [ — ide Ans. (iv) Copper [II] oxi : _— _ (c) Solution A is strong acid B weak ete kay () Which solution contains solute m addin, ition, \ ater molecules | i o Which solution gives gelatinous white ppt yi,, 7 sulphate, ppt disappears im excess (iii) Give example of weak alkali. (i) Solution B — weak acid ; (ii) Solution C — strong alkali , (iii) Ammonium hydroxide — weak alkali (a) Write the equation[s] for a reaction sulphate from lead carbonate. Ans. Is] to prepare ic. Ans. PBCO; - 2HNO; —> Pb(NO;), ~ HO =Co, Lesdeutonte Nini acd Lead nitrate donde PO(NOS). = Hy SO, —> Peso, ~ 2 Lead nate slpbaric acid Lead sulphate Nise ane (e) Define the following term — Neutralization, Ans. Neutralisation : The Teacti ion in which an aci base to form salt and water i id reacts with z is knoy WN as neutralisation. Example : NaOH +Hcl —, NaCl-H,0 on base acid salt war ¢ diagram given is ide it 7 taba below is to Prepare Iron (IID) chloride iaa (j What is substance B > (ji) What is the purpose of B > iii) Why is iron (III) chtoride © container ? to be stored in g closed ») Write the equati (iv) Write the equation for the react chlorine. action between iron and js. 1i) Anhydrous calcium chloride ans: : ji) To absorb water vapours, jis) Ferric chloride is hight ly deliquesc i moisture from the surrot iran i: it absorbs unding air and dissolves in it to mn. Hence it is stored in air tight (iv) 2Fe + 3Clp —>+ 2FeCl, 2010 4) Select the correct answer from A, B,C, D and E- (i Nitroso Iron (11) sulphate (ii) Iron (II1) chloride (ii) Chromium sulphate (iv) Lead chloride (¥) Sodium chloride. A. A deliquescent compound. B. A compound soluble in hot water but insoluble in cold water. C. A compound which in the aqueous solution state, is neutral in nature. Ans. (i) Iron (III) chloride (ii) Lead chloride (iii) Sodium chloride (b) Select the correct answer from A, B, C and D - (i) A weak organic acid is : A: Formic acid B : Sulphuric acid C: Nitric acid D : Hydrochloric acid Mts. A: Formic acid “) A complex salt is : A Zine sulphate 8B: Sodium hydrogen sulphate baw Nace 5 's Chemistry 10th 137 ,C: Iron [ammonium sulphate] SL D: Tetrammine copper [II] sulphate ; Ans. D: Tetrammine copper [II] sulphate (©) Give equations for the following conversions 4 4, - B 20,4» 220, 2 + zn(no,, E c zo +2 zn0m, Ams.A: ZNSO, + NaCO, > ZcO, + Na,So, inc sulphate sodium carbonate zinc carbonate Sodium suphay B: ZnCO; +2HNO, Zn(NO3), +H,0 + Co, 4 zine carbonate nitric acid i Water carbon dior C:Zm(NO;)) + 2NaOH _y ZMOH),) + 2NaNo, Zine nitrate sodium hydroxide zinc hydroxide sodium nitrate D:Zn(OH), _a, Zn0 + Ho zine hydroxide Zine oxide water - E:Z00 + so, 5 ZnSO, + H,0 zine oxide sulphuric acid zine sulphate water (4) For the preparation of the following salts give a balanced equation in each case, Ans.(i) Cup ez ——> — Cuso, + -H,0 Copper (II) oxide Copper sulphate Arundeep’s Chemistry 10th >». _wh > ech Verric chloride chlorine ww" Komp above »xou | USO," 280, + 2H,0 , 2 5 wit pydronide Potassium sulphate .pco, + THNO, > Pb(NO,)) + H,0 + CO, ea waboate Lead nitrate soluble sl) (Soluble salt) a pp(NO,)y | HCl > PbCl, + 2HNO, Lead nateate Lead chloride 2011 ia) Write the balanced chemical equation : Lead nitrate solution is added (0 sodium chloride solution ns. Pb (NO,), + 2NaCl > PPCI, + 2NaNO, (by State what happens to crystals of was 2 Name the phenomenon exhibited. ing soda when exposed to ai Ans It oses its water of crystallisation and becomes amorphous This phenomenon is known as efflorescence, Na,CO,. 10H,0 _» Na,CO,* 10H,O Washing soda Sodium carbonate (©) Name the method used for preparation of the following salts from the list given below: (i) Sodium nitrate (ii) Lead ehtoride \*) Sodium hydrogen sulphate. 139 (ii) Iron (111) chloride (iv)Zine sulphate ‘Arundeep's Chemistry 10thoe ™ Lint ; (A) Simple displacement (C) Decomposition by acid (E) Direct synthesis Ans. (i) (B) Neutralization Gi) (E) Direct synthesis Gili) (D) Double-de-composition (iv) (A) Simple displacement (¥) (C) Decomposition by acid. (B) Neutralization (D)Double decompositi, n 2012 (a) Match the following : Column A Column B (i) Acid salt (A) Ferrous ammonium sulphate (4) Double sait (B) Contains only ions (ii) Ammonium (C) Sodium hydrogen sulpahte hydroxide solution (7) Dilute hydrochloric (D) Contains only molecules acid (%) Carbon tetrachloride (E) Contains ions and molecules Ans. Column A Column B () Acid salt (C) Sodium hydrogen suipahte (ii) Double salt (A) Ferrous ammonium sulphate (ii) Ammonium (E) Contains ions and molecules hydroxide solution (i) Dilute hydrochloric acid (B) Contains only ions ) nt etachloride (D) Contains only molecules “Mate our observation = A zine i sulphate eter Sranule is added to copper Am ie Pus Colour of copper sulphate Solution discharge, “a c alanced equation for the reaction. Silver nitrate ition and Sodium chloride Solution. Ans. Agi % ABNO, (ag.) « Nac} (aq.) _, AgCl) +Na NO. (aq.) 140 Arundeep’s Chemistry 10tha 2013 select the word/s given which are required to correct » complete the blanks — 4 ¥ ‘ymmonia, ammonium carbonate, carbon dioxide, hydrogen, hydronium, hydroxide, precipitate, salt, water] olultion M turns blue litmus red, so it must contain i. jons ; another solution © turns red litmus blue fand hence, must contain (2) .....ions. ji) When solution M and O are mixed together, the products will be (3) ww and (4) « jan it piece of magnesium was put into a solution M, e gas would be evolved. ans) hydronium, (2) hydroxide (i) G) salt, (4) water (id) @) hydrogen. (by Give a suitable chemical term for : (i) A salt formed by incomplete neutralisation of an acid by a was base. (iA definite number of water molecules bound to some salts. (iii) The process in which a substance absorbs moisture from the atmospheric air to become moist, and ultimately dissolves in the absorbed water. ans. (i) Acid salt (i) Water of crystallisation (ji) Deliquescence (@) Choosing the substances from the list given : Dilute Sulphuric acid, Copper, Iron, Sodium Copper (1) carbonate, Sodium carbonate, Sodium chloride, Zine nitrate Write balanced equations for the reactions which would be used in the laboratory to obtain the following salts : (i) Sodium sulphate (ii) Zine carbonate (ii) Copper (11) sulphate {iv) Iron (II) sulphate. Ans, (i) Sodium sulphate Na,CO, + H,SO, —> Na,SO, + H_0 + CO, (ii) Zine carbonate Zn(NO,), + NaCO, —> ZnCO, + 2NaNO, Ai) Copper (11) sulphate CuCO, + H,S0, —+ CuSO, + H,0 = CO: ) Tron (II) sulphate. Fe~Hs0, —+ FeSO, + H, Arun . deep's Chemistry 10th 141ae following Will not produ, \7 (2) Which are Co, NO, (a) SO," Way a as. (a) CO 2014 the blank from the choices Biven ; The tt Ce) Fm bn the ba 13, 1, 4}. My, ici Acid is 1. “(© Draw the ructore afte stable postive eee eee dissolves in water. sms, HCI+H,0 —> H,0" + Cr H-O-H H (©) State the inference drawn from the obs Salt Sis prepared by reactin; oxide. Identify 5. ns. The compound or sat $ is copper sulphate Cus, CuO + H.S0, —> CuSO, + H,0 @) Give balanced chemica following salts : © Lead sulphate ~ fro (4) Sodium suiphate — (i) Copper chloride — (A) Lead sulphate from lead ion for, servation; 3 dilute sulphuric acid wig, ip, 0, I equations for the Preparation og m lead carbonate. using dilute sulphuric acid, | using copper carbonate, carbonate, POCO, + HNO, = __, POINO,), + HO +O) 4 POINO,), + H,S0, PbSO, + 2HNO, Sodium sulphate using dilute sulphuric acid, Naco, + LSO,(dil) _, Naso, + HO + (0, Copper chloride using Copper carbonate, CuO, + Hex — cl, + Ho +0 (lasolubie) ' 2015 ') From the list of salts AgCl, M; 7 NO, ses eats 24C0, KND, CH) Biven by : ip? *PPropriately fits the descti?! we 142 Arundeep’s chemist!— wen insoluble chloride . — Na,Q, SQ, Si ) Prem LO, SO, SIO, ALO,, NipQ, OO, select aan wide ud which dissolves in water forming am acid. ans y MgC 8 deliquescent sat vn Age] san nsolable chomie an oxide which dissolves in waner forming an acid * SO. 20s Mateh the salts given in C.tuun J with preparation given im Columm I : Column 1 Colume (i) Ph(NO,), from PbO (A) Simple displacement (i) MgCl, from Mg (8) Titration (iii) FeCl, from Fe (C) Newtreizenes (iv) NaNO, from NaOH (D) Precipitation (v) ZaCO, from ZnSO, () Combimanos Ans. Column 1 Colume 1 (i) PBONO,), from PbO (©) Newralizaon (ii) MgCl, from Mg (A) Simple dispiecemen (iii) FeCl, from Fe (E) Combination (iv) NaNO, from NeOH (B) Tisrstion (») 200, from ZnSO, (D) Precipitation ___apprmionat questions __— Q. 1. What will be the effect of the following solations on biwe 143 Arandecp’s Chemistry 120