ishnan 1. R. Gurumurthy, K. Sathiyanarayanan, and M. Gop: Unt. J. Chem. Kinet., 24, 953 (1992)] studied the oxidation of Rate x 10*(M/s) qx 1M) Cy X 10%) several phenylmercaptoacetates (A) by chloramine-B (B) in 05767 10 10.00 aqueous cthanol media 1.2788 1s 4st} 10.00 CgHs-S-CH,CO-OC3Hs + C,HsSO,NHC1 + H,0 2.3162 20 10.00. 5.24q 30 10.00 iy 14.5155 50 10.00 CeHls-$-CH,CO-0C,H, + C,H5SO,NH, + HCL 204126 60 10.00 28.0147 70 10.00 The following pH of ea. 6.5. a0 i900 > 200 300 ed 70 11.25 1500 i730 2000 r=k UIC for dat wing eons Y= qe ° n(n ae Ne ogee InialnkeBalscu, by liway vegvesion v.68 iN Pa Sik Cey fhe hc \u To alae & BelnCa by Vito wagvess fea= — 0,06! To Fog Ky ke = Ke a k -0;5 (S442. 8.D. Furrow [Int. J. Chem. Kinet ied the kinetics of the hydroxy i (B) in aqueous solution: 14, 927-932 (1982)] stud- ination of 2-butenoic acid 21, +B +10; +H* +2H,0 5¢ where C is CH, CH(OH)CHICOOH. (a) Furrow used absorbance measurements to monitor the concentration of I, as a function of time for an experiment in which the initial concentrations of I,, B, 10;, and H* were 1.98 x 104, 0.10, 0.025, and 0.10M, respectively. If the rate expression is of the form r= k(l,)"(B)"(0;)(H")! Time 1, x10 (5) (M) 0 1,98 35 1.94 96 1.84 232 1.68 339 1.56 588 1.28 824 1.06 1060 0.856 1290 0.650 1530 0.479 1760 0.350 2000 0.250 2250 0.145 2500 0.063 2750 0.017 where the various orders are either integers or half- integers, use the following data to determine the order of this reaction with respect to 1, and the corresponding value of the pseudo-mth-order rate constant. What assumptions must be made to arrive at numerical values of these parameters?