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Preparation of An SBS Latex Modified Bitumen Emulsion and Performance Assessment
Preparation of An SBS Latex Modified Bitumen Emulsion and Performance Assessment
To cite this article: H. M. Cai , T. Wang , J. Y. Zhang & Y. Z. Zhang (2010) Preparation of an
SBS Latex–Modified Bitumen Emulsion and Performance Assessment, Petroleum Science and
Technology, 28:10, 987-996, DOI: 10.1080/10916460902939436
1. Introduction
Modified bitumen emulsion is a new kind of binder used in road surfaces, which has
the advantages for both modified bitumen and bitumen emulsion. Some properties will
be improved, such as the thermal stability, high- and low-temperature performance,
durability, as well as adhesive property with aggregates. It also has better crack resistance
than pure bitumen emulsion at low temperature. Using a modified bitumen emulsion
can save bitumen by 10–20%. There is a wide range in using it, especially in slurry
seal (International Slurry-Surfacing Association, 1991) and microsurfacing technologies
(International Slurry-Surfacing Association, 1996). Hence, the preparation of modified
bitumen emulsion with good properties is necessary and there is a large market for it.
Styrene-butadiene-styrene (SBS) block copolymers can increase the elasticity of
bitumen and they are probably the most appropriate polymers for bitumen modification
(Becker et al., 1999). When SBS is used as a modifier, modified bitumen emulsion
is prepared through the process of SBS mixing with bitumen by means of high shear
Address correspondence to H. M. Cai, State Key Lab of Heavy Oil, China University of
Petroleum (East China), Dongying Shandong, 257061, China. E-mail: caihm123@163.com
987
988 H. M. Cai et al.
2. Experimental
Table 1
The optimized technology parametersa
Through orthogonal test and single-factor research (Cai and Zhang, 2006), the opti-
mized technology parameters were obtained, which are given in Table 1.
2.3.2. Bitumen Tests. Conventional bitumen tests such as penetration, softening point,
and ductility tests were performed on base bitumen and SBS-LMBE. For evaluating
the effect of emulsifier on SBS-LMBE, storage stability was performed. In addition,
base bitumen and SBS-LMBE were fractionated by saturates, aromatics, resins, and
asphaltenes (SARA) analysis.
Table 2
Properties of the base bitumen
3.1.2. Performance Analysis. The performance was analyzed according to the corre-
sponding standard analytical methods of China, as shown in Table 3.
The analysis of SBS latex properties shows that solid content is 40.68%, which
satisfies the specification of over 40%. Particles with a positive charge which let latex
can be mixed with all cationic emulsified bitumen. The average particle size is 1.97 m,
which matches the size of emulsified bitumen particles (1–2 m). The pH shows that latex
is acidic, which may enhance the adhesion between bitumen and aggregates. Viscosity
and mechanical stability satisfy the specifications. Usually, the mechanical stability is
characterized by the residue content after mechanical mixing. A latex with poor mechan-
ical stability will break when stirred by strong mechanical or hydraulic shear.
From the analysis above, it is shown that the SBS latex has good dispersity and
stability, and the properties indicate that it is a qualified latex.
Table 3
Properties of SBS latex
SBS Analytical
Properties latex Specification method a
is a significant large decrease in the penetration values and considerable increase in the
softening point and ductility based SBS latex at 7%. The increase of softening point
is favorable because bitumen with a higher softening point may be less susceptible to
permanent deformation (rutting). The changes of penetration value and 5ı C ductility are
also favorable, which made bitumen have better rutting and crack resistance. So adding
SBS latex to bitumen emulsion improved the performance of bitumen.
SBS latex improves the properties of bitumen emulsion because SBS copolymers
transfer their strength and elasticity from physical and cross-linking of the molecules to
a three-dimensional network in the evaporation residue of SBS-LMBE. The polystyrene
end blocks impart the strength to the polymer and the polybutadiene rubbery matrix
blocks give the material its exceptional viscosity. When SBS is blended with bitumen,
the elastomeric phase of the SBS copolymer absorbs the oil fractions from the bitumen
and swells up to nine times as much as its initial volume (Isacsson and Lu, 1995). At
suitable SBS concentration, a continuous polymer phase is formed through the polymer-
modified bitumen and significantly modifies the bitumen properties (Cavaliere and Diani,
1996).
Table 4
The components analysis and colloidal index of base bitumen and SBS-LMBE
the CI shows that SBS-LMBE has better stability of colloid system than that of base
bitumen. However, it is not the bigger of CI the more stable of system, four fractions
should have a suitable ratio in a bitumen, and each component is essential.
4. Conclusions
Conclusions can be drawn as follows:
1. The results of light microscopy and scanning electron microscopy showed that pre-
pared SBS latex has good dispersion and stability. The analysis of properties show
that it is a qualified latex.
2. The maximum stability of SBS-LMBE was obtained at emulsifier concentration 1.0%.
The addition of SBS latex increases the difficulty of bitumen emulsification.
3. SBS latex can make the penetration decrease and softening point and 5ı C ductility
increase, which means that SBS latex can play a role in improving the properties of
bitumen.
4. SBS latex causes the chemical component and colloidal index of bitumen to change.
Saturates and aromatics decrease, whereas resins and asphaltenes increase. Through
analysis of the relationship between the components and properties it is shown that
the component changes of SBS latex make it beneficial to the properties of bitumen.
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