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Successful Field Implementation of CO2-Foam Injection for Conformance
Enhancement in the EVGSAU Field in the Permian Basin
Amit Katiyar and Armin Hassanzadeh, The Dow Chemical Company; Pramod Patil, Rock-Oil Consulting Group;
Michael Hand, Alejandro Perozo, Doug Pecore, and Hosein Kalaei, ConocoPhillips; Quoc Nguyen, The University
of Texas at Austin
This paper was prepared for presentation at the SPE Improved Oil Recovery Conference originally scheduled to be held in Tulsa, OK, USA, 18 – 22 April 2020. Due
to COVID-19 the physical event was postponed until 31 August – 4 September 2020 and was changed to a virtual event. The official proceedings were published
online on 30 August 2020.
This paper was selected for presentation by an SPE program committee following review of information contained in an abstract submitted by the author(s). Contents
of the paper have not been reviewed by the Society of Petroleum Engineers and are subject to correction by the author(s). The material does not necessarily reflect
any position of the Society of Petroleum Engineers, its officers, or members. Electronic reproduction, distribution, or storage of any part of this paper without the written
consent of the Society of Petroleum Engineers is prohibited. Permission to reproduce in print is restricted to an abstract of not more than 300 words; illustrations may
not be copied. The abstract must contain conspicuous acknowledgment of SPE copyright.
Abstract
This paper presents the performance of a CO2 foam injection pilot implemented in the East Vacuum
Grayburg San Andres Unit (EVGSAU) by ConocoPhillips in cooperation with The Dow Chemical
Company. The pilot project focuses on a single CO2 injection pattern, consisting of one injector and eight
producers, selected due to signs of early gas breakthrough and poor overall sweep efficiency.
To solve these conformance issues and increase overall pattern production performance, a new foaming
surfactant with low adsorption and high gas partitioning characteristics was developed and experimentally
tested at simulated reservoir conditions. A "water alternating surfactant-in-gas" injection strategy was
created utilizing a history matched reservoir simulation model and an empirical foam model. This reservoir
model was also utilized to better understand the dependency of surfactant concentration on foam generation
and fluid diversion. Injection profile logs (IPLs) were also run, in both water and CO2 phases, prior to pilot
implementation to establish baseline injection performance.
This paper will detail several performance indicators that illustrate sustained improvement in pattern
injection and production after more than 15 cycles of alternating water, CO2+surfactant, and CO2-only
injection. During each cycle, gas injectivity trends were calculated and compared to the baseline to monitor
foam strength and performance. Four additional IPLs were run, which indicated continuous improvement
in vertical sweep efficiency and ultimately resulted in uniform injection distribution between the upper and
lower sections of the producing zone. Finally, the most significant result of the trial was the uplift in pattern
oil production. It has averaged ~20% above the baseline production forecast throughout the entire pilot
period and peaked within the first six months at ~60% above the baseline.
The success of this pilot illustrates the benefits of using a low adsorbing and CO2 soluble foaming
surfactant to address reservoir conformance issues for CO2 floods. Further optimization of the pilot based
on the simulation forecast is planned to improve long-term pilot economics.
2 SPE-200327-MS
Introduction
In situ injection of miscible supercritical CO2 (scCO2) to reduce residual oil saturation and increase oil
production has been widely applied in the United States since the early 1970s. According to the Department
of Energy (DOE), in 2014 an average of 3.1 billion cubic feet per day (Bcfd) of CO2 was utilized in CO2
enhanced oil recovery (EOR) applications (DOE/NETL-2014/1648), which contributed to about 6% of the
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US crude oil production.
Despite the overall success of CO2 EOR, the characteristically high mobility of CO2 compared to that
of the in-situ reservoir fluids can lead to poor areal and vertical conformance and reduce overall sweep
efficiency. Poor injection conformance can result in early gas breakthrough, high gas-oil ratio (GOR), sub-
optimal gas utilization (GUR), and ultimately lower oil recoveries. Water-Alternate-Gas (WAG) injection
has been mostly applied in gas-EOR implementation to limit such conformance issues, however, WAG
injection alone has limited effectiveness (Harpole and Hallenbeck 1996). Other conformance solutions such
as polymer gel injection or well-bore cementing (Sydansk, 1998) are effective if the root cause and location
of the conformance problem is well understood, but these methods are potentially irreversible and are limited
to near well-bore (Seright, 1988). In comparison, CO2-foam EOR (Al Ayesh et al. 2016, Blaker et al. 2002,
Heller 1994, Patil et al. 2018) is a robust technique to control CO2 mobility in regions near the well-bore
as well as deep into the reservoir.
CO2 foam EOR utilizes CO2-in-brine emulsion (foam) generated in situ by injecting a chemical agent
(surfactant) via either CO2 or brine. Figure 1 illustrates an example of how CO2-foam injection improves
CO2 sweep efficiency in a reservoir. The foam forms in the existing high permeability/preferential flow
channels and gas injection is diverted to the un-swept/bypassed oil zones (Heller 1994, Hirasaki and Lawson
1985, Abbas et al. 2012, Abbaszadeh et al. 2014, Blaker et al. 2002, Patil et al. 2018).
Previous pilots where CO2-foam technology was implemented in the field have shown success in
achieving mobility control and some conformance improvement (Heller et al. 1985, Holm and Garrison
1988, Jonas et al. 1990, Chou et al. 1992, Stephenson et al. 1993, Hoefner and Evans 1995, Henry et
al. 1996), but despite the well documented technical success, the conformance correction did not always
prove to be economically viable. Some of the factors leading to poor economics in previous trials including
inefficient surfactant foaming due to gas-water segregation and the use of water-soluble surfactants, higher
surfactant adsorption to reservoir rock, and implementation of sub-optimal injection strategies. This paper
SPE-200327-MS 3
presents the performance analysis of a pilot aimed at addressing those key issues, which ultimately led to
a more economic project.
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Grayburg/San Andres reservoir was then unitized in 1978 with the aim of flooding the unitized intervals
with water and gas. The unit includes both the Grayburg and San Andres formations, but the main zone
of interest is the San Andres, and the majority of the injection and producing wells are perforated in this
formation (King 1972). Although surrounding units began water injection at an earlier date, water flooding
in EVGSAU did not begin until 1980s. The goal of water flooding was to displace oil and increase reservoir
pressure above minimum miscibility pressure (MMP) in preparation for CO2 flooding, which began in
1985 with a WAG ratio of 2:1. CO2 flooding has continued since that time and has recovered an additional
12-13% of the original oil-in-place (OOIP) in the unit. Details regarding the implementation of the WAG
flood in EVGSAU have been previously published (Harpole and Hallenbeck 1996). Some of the difficulties
encountered during the EVGSAU CO2 flood include low reservoir pressure in parts of the unit and low
sweep efficiency of the CO2. Even with these difficulties, unit oil recovery has exceeded 150 MMSTBO
and the overall oil recovery factor in the CO2 flooded areas is above 55 % OOIP.
Across the northern and central portion of the field, the San Andres formation is divided into the upper
and lower intervals by the Lovington Sandstone (Figure 2). In contrast to the Upper San Andres (U-SA),
the Lower San Andres (L-SA) is characterized by thicker, higher permeability flow units that display at
least some degree of vertical communication. However, in general, the EVGSAU field is characterized with
poor vertical communication, and injectivity in the L-SA has historically been higher than that in the U-SA
(Harpole and Hallenbeck 1996). As noted in Table 1, the geology does have anhydrite minerals which can
be dissolved over time in a WAG flood, causing further conformance problems. In a previous study, it was
noted that within 10 years of the WAG flood in EVGSAU, flow channels or thief zones with up to 200 mD
permeability were created, causing severe vertical conformance issues. These severe conformance issues
led to a Department of Energy (DOE) funded CO2-foam treatment conducted in the mid 1990's (Martin
1995) that was deemed a technical success but was ultimately unsuccessful due to poor economics driven
by high surfactant adsorption.
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Figure 2—3229-W007 gas injection profile log illustrating the flow
units that makeup the primary producing formation in EVGSAU
The lab experiments used a PVT cell to measure the surfactant partition coefficient between brine and
scCO2 at simulated reservoir conditions of 101°F and ~2000 psi. First, the cell was loaded with brine and a
known concentration of surfactant solution at reservoir pressure and temperature. Next, the same volume of
CO2 was bubbled through the cell containing the brine/surfactant solution, and the three fluids were kept in
the cell for 24 hrs to allow for equilibration. Finally, small volumes of the solution were aliquoted out of the
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cell in steps, while maintaining constant pressure and temperature, to quantify the surfactant concentration in
brine at equilibrium. The surfactant partition coefficient at reservoir conditions was calculated as the ratio of
the mass fraction of surfactant in scCO2 to the mass fraction of surfactant in brine. The results indicated that
the mass fraction of surfactant in the scCO2 was 22 times greater than the mass fraction in the brine, meaning
the surfactant achieved the desired outcome of preferential partitioning in scCO2. Tests also indicated that
surfactant solubility in scCO2 improves with increasing pressure, which indicates that it can potentially be
transported deeper into the reservoir and not just near wellbore for conformance improvement.
• As surfactant concentration increases, apparent foam viscosity measures 2-3 orders of magnitude
greater than the viscosity of brine or scCO2 alone.
• As total injection rate increases, shear thickening rheology was observed up to an optimal injection
rate, but shear thinning rheology was observed as injection rates increased to above optimum rate.
• There is an optimal injection gas fraction to achieve the highest quality foam. As the injection gas
fraction increases beyond this optimal point, the foam begins to dry out and foam strength begins
to deteriorate.
• The final core flood experiment involved the introduction of crude oil into the system. These tests
indicated that the foam destabilizes when it encounters a sufficient volume of mobile oil (~10-15%
mobile oil fraction). This is a favorable characteristic because in a field implementation, the foam
will destabilize as the CO2 is diverted into previously bypassed areas of the reservoir with higher
oil saturations.
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with six surrounding vertical wells, which is a similar pattern alignment to other patterns in the field. There
are also two horizontal wells that have at least a portion of their horizontal sections inside of the pattern, and
for that reason they were included in the analysis; however, the team expected most of the foam response
to be observed in the vertical wells.
Figure 3—EVGSAU Field Map showing location and layout of the foam pilot pattern
injected out OOZ (Table 2). The IPL run during a CO2 cycle indicated the same conformance issue with
75% of the gas being injected into the L-SA and 46% being injected OOZ (Table 2).
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The complete IPL history was then combined with hydrocarbon pore volume (HCPV) data previously
calculated from well logs to estimate the cumulative hydrocarbon pore volume injected (HCPVI) in both the
U-SA and L-SA formations. Figure 4 clearly shows that because of the poor vertical conformance, the U-
SA has had <30% HCPV of CO2 injected while the L-SA has received most of the historical injection with
>60% HCPV of CO2 injected. This large variance in injection illustrated that the U-SA remained relatively
unprocessed from an EOR standpoint, and if the foam surfactant was able to re-direct CO2 from the L-SA
to the U-SA, there was an opportunity to significantly improve oil recovery in the pattern.
8 SPE-200327-MS
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Figure 4—Percent HCPV injected between the upper and the lower San Andres
Injection Strategy
The CO2 flood at EVGSAU operates as a constant pressure-controlled injection system and the available
injection pressures for water and CO2 are ~1,300 and 1,800 psi respectively. Once surfactant injection starts
and foam begins to form downhole, the gas injection rate within the pattern should begin to drop due to
the reduced gas mobility. Although the change in mobility may improve the volumetric sweep, the lower
gas injection rate may adversely impact production due to the reduced volume of CO2 contacting oil in the
reservoir. To best address this issue, the team developed a surfactant injection strategy with the following
WAG constraints:
SPE-200327-MS 9
• The total fluid injection in a year would remain the same as the baseline period to maintain reservoir
pressure and CO2 processing rate; this was achieved by increasing the GWR (gas-water ratio) in
each WAG cycle compared to the baseline. Relatively higher GWR not only limits the loss in gas
processing rate but also helps achieve a higher gas-water mixing ratio that generates stronger foam.
• WAG cycle duration was reduced to the lowest operationally feasible time to mimic the same co-
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injection environment observed in the core flood experiments. These shorter cycles maximize the
impact of surfactant in generating stronger foam.
• Each foam WAG cycle would follow the same injection pattern. The cycle starts with a fixed
volume slug of water, followed by surfactant injected with CO2, and finally surfactant injection is
stopped, and pure CO2 is injected to meet the GWR target. The initial target volume of CO2 with
surfactant (i.e. surfactant concentration) was about 20% of the total gas volume in a single cycle.
• In order to definitively attribute any oil production uplift to the foam injection at 3229-W007 and
not changes from any other outside factors, the four offset injection patterns were maintained at
their baseline WAG schedules throughout the entirety of the pilot.
Gas Injectivity
The baseline gas injectivity was calculated by taking the arithmetic average of daily gas injectivity for the
six latest gas cycles in the three-year baseline period (2015-2017). The two figures below show that the
baseline gas injectivity at the beginning of a gas cycle is ~0.3 bbl/d/psi and increases to ~1 bbl/d/psi over
a period of ~35 days before eventually plateauing at ~1.0-1.2 bbl/d/psi. This injectivity behavior is typical
of all the WAG patterns in EVGSAU when switching from water to CO2, and it is caused by the injection
gas gradually displacing the column of water near wellbore.
Figure 5 shows the calculated gas injectivity for each of the first six cycles of the pilot. For each of the
cycles there was an immediate drop in injectivity (>50%) compared to the baseline, which indicates strong
foam generation downhole. However, in most of the cycles, gas injectivity began to return to baseline values
after a week of surfactant injection (Cycle 3, 5, and 6 injectivity remained lower due to factors outside of
the pattern operation i.e. lower field injection pressure). The team believed that this was due to the presence
of larger void space conduits that existed further out into the reservoir. As the foam slug propagated deeper
into the reservoir, there was not enough foam in the early stages of the pilot to fill the larger void spaces;
therefore, the CO2 was able to regain mobility and the injectivity returned to baseline values.
10 SPE-200327-MS
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Figure 5—Cycle 1-6 gas injectivity vs. baseline
During Cycle 7, the 3202-012 producer was taken offline to perform a workover to optimize the downhole
production equipment. While working on the well it was discovered that the well suffered from a collapsed
casing that could not be repaired, and the well eventually had to be plugged and abandoned (P&A). The
overall production impact of the 3202-012 will be discussed in detail in a later section of the paper, but at
a high level it is important to note that this well improved the most after surfactant injection started, so the
team believed that there was direct communication between the 3202-012 and the injector through large
void space conduits. As shown in Figure 6, the cycles following the P&A of 3202-012 maintained reduced
injectivity for the entirety of the cycle, which is a distinct change in behavior compared to cycles 1-6. The
team hypothesized that after the 3202-012 was P&A'ed and the localized reservoir pressure around that
wellbore began to increase, there was a period of areal injection re-distribution that occurred, and gas was no
longer flowing through the conduit that existed between 3202-012 and the 3229-W007 injector. This change
in injectivity behavior was also observed in the production response which will be covered in a later section.
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immediately after generating the foam, when it would theoretically be at maximum foam strength. The
3rd IPL was also collected during the 5th foam cycle, however, it was collected at the end of the CO2 only
portion of the cycle in order to evaluate how well the foam strength was maintained after stopping surfactant
injection. The 4th IPL was taken during the 11th foam cycle, more than 1.5 years after the previous IPL, and
was a clear illustration of how the foam maintains conformance improvement over long periods of time
with continued application.
Table 3—Injection profile log data by formation zone – baseline vs. foam pilot
• OOZ injection losses were eliminated - The first IPL indicated that there was no more gas was
being injected OOZ below layer H, and this remained true throughout all the subsequent IPLs.
• More uniform injection distribution between U-SA and L-SA - Due to the elimination of the OOZ
injection, 21% of the gas that had previously been lost was re-distributed into both the U-SA and
the L-SA
• Conformance improvement was maintained over time – The 4th IPL was a positive indication that
foam strength and conformance improvement can be maintained for long periods of time with the
continued application of the surfactant-based conformance solution.
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Figure 7—Monthly average percent run time for 3236-009
• Average pattern uplift throughout the pilot has been 20% above baseline.
• Baseline decline was adjusted after the 6th cycle due to the 3202-012 shut-in and subsequent P&A.
• Gas Utilization Ratio improved by 16% indicating a more efficient use of injected gas.
• Overall pattern recovery to date has been 31 MBO above the baseline.
SPE-200327-MS 13
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Figure 8—Pattern Production and GOR
• Wells such as the 3236-009 and the 3202-012, which were identified as high GOR "problem" wells
prior to starting the pilot, were the first to see uplift after starting surfactant injection. Both wells are
offset to the 3229-W007 injector in an E-W direction, which has been identified across this portion
of EVGSAU as the dominant permeability direction; therefore, it makes sense that the surfactant
injection would address these high permeability channels first.
• Wells such as the 3202-019 that lie N-S relative to the injector (perpendicular to dominant
permeability direction) did not see production uplift until several months after injection. This
difference in uplift timing is potentially an indication that the foam works its way through the
reservoir over time addressing the highest permeability channels first and is capable of eventually
achieving improved areal sweep efficiency.
• The two horizontal wells, 3236-001 and 3229-013, did not seem to exhibit any change in production
related to the surfactant injection. Only a small section of these wellbores lie within the pattern
boundary, so the team included them in the analysis but did not expect to see any significant
impacts.
14 SPE-200327-MS
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Figure 9—Examples of individual well responses to the foam injection
Geological Model
The original geological model was generated based on available field geological data. This model was
carved out of a wider geological model to mainly focus on foam pilot pattern while including at least one
offset injector on each side (Figure 10). The model consists of uniform grid spacing of 150 ft × 150 ft in
the areal direction and 57 layers with variable depth in the vertical direction. The layers were set based on
permeability to porosity ratio. The average areal permeability of the area covered by the model is ~10 md
and the vertical permeability were set at 5% of the areal permeability for all the grid cells.
SPE-200327-MS 15
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Figure 10—Geological reservoir model
Table 4—Model prediction vs. IPL – before and after surfactant injection
The results of history matching the oil, water and gas production are shown in Figure 11. The cumulative
result is shown for all eight producer wells in the pilot. Gas production in the horizontal well (3236-001)
caused the model to overpredict gas production as shown in the figure.
16 SPE-200327-MS
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Figure 11—History match of cumulative Production (oil, water and gas) of 8 pattern producers
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Figure 12—Gas mobility multiplier after surfactant injection (Sept 2019) around
the pattern injector (Note: The multiplier in the grid blocks with no color is one).
The results shown in Figure 12 and Table 4 confirm the capability of the empirical foam model to history
match the vertical conformance correction as surfactant was injected in the reservoir. This model predicts a
significant change in areal distribution of gas flow around the pilot injector (areal conformance correction).
As shown in Figure 13, a strong gas flow connectivity is predicted by the model between the pilot injector
and the producers located on the west side of the pattern. The length of the arrows shown in this figure
represents the intensity of gas flux in each grid bock. Comparing the graphs from before and after surfactant
injection, there is a clear reduction in gas flux towards the west side of the pattern while the gas saturation
is about the same. This result agrees with the pump runtime data for producer well 3236-009 (Figure 7).
Figure 13—Aerial view of gas flux (arrows) and gas saturation (color) in an OOZ layer, before and after surfactant injection
Model Forecast
The developed model was utilized to forecast surfactant performance under four different injection
concentrations (Table 5). Gas flow distribution between the Upper and Lower San Andres was used as the
main indicator of how foam behaves at each concentration. As surfactant concentration reduced from the
18 SPE-200327-MS
current level to zero, gas flow to the Upper San Andres reduced from 45% to 27%. This change in the
flow distribution was predicted to occur in only a few weeks after altering the concentration, showing that
according to the model the foam stability is very sensitive to the surfactant concentration. This is mainly
due to relatively high volumetric flow of gas going into the OOZ layers resulting in a fast drop in surfactant
concentration in these layers. Since foam strength is a direct function of surfactant concentration, any change
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in injection concentration has a significant effect on the foam performance.
The model was also utilized to forecast the effect of long-term interruption in surfactant injection
(injection cease) on production. This effect was more pronounced on producer 3236-009 located on the
west side of the pattern, which was due to the strong connectivity between the pattern injector and this
producer (per production analysis). In Figure 14, the model forecast was initiated from the beginning of year
2020 by setting all the producer wells (including 3236-009) on constant bottom-hole-pressure constraints.
Two injection schemes were tested, 1) surfactant injection was continued at the current concentration (solid
line), and 2) surfactant injection was ceased in mid-2020 by keeping the rest of the variables (such as WAG
ratio) the same (dash lines). The model results showed about 15-20% jump in GOR right after surfactant
injection is interrupted. This quick response was mainly due to gas finding its way to this producer via
OOZ layers (thief zone) after surfactant injection ceases. In the field, such an increase in gas rate will result
in reduction in pumping efficiency at the producer and eventually lower the total liquid production. The
difference between the GOR curves in the figure gets more pronounced long-term, reaching ~35% in few
years due to a gradual reduction in oil production rate after the surfactant injection ceases. As shown in
Table, ceasing of surfactant injection results in a significant change in gas distribution between the Upper
and Lower SA, which adversely affects oil sweep efficiency from the Upper SA. In addition, a gradually
increasing GOR in simulation prediction suggests the need for dynamic optimization of WAG injection
strategy if it is realized in the field.
SPE-200327-MS 19
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Figure 14—Model forecast for producer 3236-009 showing effect of surfactant cease in mid-2020
Conclusions
ConocoPhillips and Dow successfully implemented a surfactant enabled CO2 foam injection pilot in the
EVGSAU field utilizing an improved foaming surfactant chemistry. A novel injection strategy was executed
that made the pilot both a technical and economic success and proved that CO2 foam injection is a viable
solution for correcting conformance issues. The key conclusions are summarized below:
1. The scCO2-soluble surfactant used in this pilot can provide desired mobility control with low
surfactant concentrations and minimum adsorption to reservoir rock, which results in faster foam
propagation and conformance correction.
2. Complete elimination of OOZ injection and redistribution of CO2 into previously un-swept flow
intervals.
3. Elimination of direct gas breakthrough resulted in increased runtime in high GOR wells.
4. Improved volumetric sweep efficiency resulted in significant pattern uplift; uplift peaked at 60%
above baseline and has averaged ~20% above baseline throughout the entire pilot.
5. Pilot uplift resulted in incremental oil recovery of 31 MBO compared to the baseline forecast.
6. The simulation forecast suggests that surfactant injection should be continued to maintain uniform
flow distribution between the Upper and Lower San Andres. However, the project economics will
ultimately determine how long the surfactant will continue to be injected in the pattern.
Acknowledgements
The authors acknowledge the lab technicians, engineers, and leadership team at The Dow Chemical
Company and ConocoPhillips for their support during this project.
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