LoviLtbz2 nu Lo POCCMIACKOE ATEHTCTBO lo IATEHTAM 4 TOBAPHBIM SHAKAM ® RU" 2217407" C1 (61) Mnk? C 07 C 19/08, 19/10, 17/20 (2) ONVCAHVE V3OBPETEHMA K NATEHTY POCCUMCKON SEQEPALINN (21), 22) Sanka: 2002129539/04, 03.09.2002 (24) fava wavana aeficrsun narenra: 03.09.2002 (48) Hava nyOnvnaunn: 27.11.2003 (68) Ceuner xYPHAN PocCHAcKOrO XVMVHECKOTO OBLIECTBA 1M. 2.1. MEHIENEEBA, 2000, 1.44, BbIT 2,c. 113 4 1114. RU 2001900 C1, 30.10.1993. RU 2180654 (C1, 20.03.2002. SU 1150819 A, 15.05.1986. US 4885416 A, 05.12.1989, (98) Aapec ane nepenvox 1613040, Kupoackas o6n.,r. Kposo-HeneuK, rep. Toxaprit, 7, OAO KUXK, Hasarmnny ONTMC BM. Baxrany (72) Voc6perarens: ASpawos 0.6. Avppeiwarenno B.B., ANapyx O.B.,. BrHHos MAB. , Bupaxofina E.C., Fony6ee Ai, enoe ‘AC. Saxapos B.10., Kanyoran WM., KyaHeyos BH. Hosunosa Mf, Openfax B.M., WaBannn AA (73) Narerroobnagerens: Orapuiroe aKitonephoe o6uecrB0 "kuposo-Yeneuxnih xuMMocenil KONGHHAT HM BI. Koncranrmioea" (64) CNOCOB NONYYEHIA {M@TOPX/OPMETAHA, (67) Pesbepar: Veodperenive oTHocHToR « xmNenYecKor TexHonomn, a MWeHHO K —nponsBoncTay ropxnopyrnesoaopoqos, KoHKpeTHO ‘Avcpropxnopwerava (xnagowa 22, R22, HCFC 22), worioneayeMoro Kak Os0HOGesonacHtiA xnagarenr, nponenneyt, nopocpasoaarens, Chipse BIR nOny\IeKA cbropmoHoMepC®. Gnoco6"——_ocyuecrensiot ——_nytem "agpocbropyposanns xiopodbopma vcnapenH propversim —sonoponoM 8 npwcyrcreMA KaTanwsaropa naTWxNOpHCTOR cypeM obasron — xnopa. PeaKyMonisie rast NpoMeiealor Bono c= onyveHveM KORWSHTPHPOBAHHOA —conAHO —_KUCHOTE, Heirpanvayior OcraTowbie KOnMYeCTsa KACTEK KoMnoWeHTOB, KOMIIPHMHYIOT, KOHeHCHPYIOT Vis vonwgencata pecucmaunen aigensor ueneso# —npoaykr. —KyGo8yio—_cbpaxuio NonBepraior a3eoTPONHOR OcyLiKe ¢ OTGOPOM @ TonosHyio YacTS soAb!, nNpwcyTeTEyOWjeH B yGoa0R cppaxynm —OGessoxeHisiA ocTarox pexrucbruapyior ¢ sbinenenve Cpropganopwerana vw wenpopearmponaBLiero xnopochopwa, xoTopHie sosepalyaior Ha cranio Tunposropapoeanna. Nepepasomy Ky6oBoA Cbpawyin—npeanowrwTensHo Becta npa aTMoctbepHoN Aasneni, rpWMeM OCyLiKY - Np 15:30°C, a pacruchyKayun oBaaa0KeHHoro cerarka - npr §5:85°C, Texxnveckad pesynbrar = yMoHbweHNe fesaKTMaa\yn KaranAsaTopa Cchuokaune Boanevicramn Ha oxpyKaiuiyio cpeny. Tan. ms, 17860 e2i7407 Ci RULoviLtbz2 nu Lo RUSSIAN. AGENCY FOR PATENTS AND TRADEMARKS: (2) ABSTRACT OF INVENTION ® RU" 2217407" C1 (61) int C17 C 07 C 19/08, 19/10, 17/20 (21), (22) Application: 2002128839104, 03.09.2002 (24) Effective date for property rights: 03.09.2002 (48) Date of publication: 27.11.2003 (8) Mail address 613040, Kirovekaja obl., g. Kirovo-Chepetsk, per. Pozhamnyj, 7, ORO KCHKNK, nachal'niky OPTIS VM. Bakiinu (72) Inventor Abramov 0.8, ‘Andrejchatenko V.V., Andrukh OV. Blinov LB. , Vyrazhojkin E.S., Golubev A.N., Dedov AS. , Zakharov V.Ju., Kapustin 1M., Kuznetsov VIN. Novikova M.D., Frendak V.M., Shabalin DA, (73), Proprietor: Otkzyioe akisionemoe obshchestvo *Kirovo-Chepelskij Khimichesklj kombinat im. BP. Konstantinova® (G4) METHOD OF PRODUCTION OF DIFLUOROCHLOROMETHANE (67) Abstract FIELD: chemical industy, technology of fucrochlorohydrocarbons production SUBSTANCE: invention presents the method of production of fluorochlorohydrocarbons, in panigular - difluorochioromethane {chladone 22, R22, HCFC 22), used as the ozone-safe Teffigerant, — propelient, —porophore, raw material for production of fuorine-monomers. The method is realized by hydrofluonination of chloroform by vaporized fuorine hydride at the presence of the catalyst - ‘pentachlorated antimony with the additive of chlonne, The reaction gases are wash out with water and obtain the concentrated hydrochloric acid, the residual amount of the sour components _ is neutralized, compressed, condensed, The target product is produced by rectification ‘of the condensation moisture, The shell sill fraction is exposed to _azeotropic dehydration with evacuation of the waler present in the shell stil fraction to the shell stil head part, The dehydrated residual Is rectified with extraction of difuorochloromethane and the neutral Chloroform, that are to be relumed on a stage of hydrofluorination. Processing of the shell stil fraction is preferable to conduct under atmospheric pressure, and ts dehydration - at 15 - 30 C, and rectification of the dehydrated residual at 55 - 85 C, EFFECT: effeci(resull) - decrease of deactivation of the catalyst, decrease of environmental impact, 2 cl, 1 tbl e2i7407 Ci RULOovLezz nu oO VacGpeterne OTHOOHTEA K XAMMEKOR Texionornt, a mWeHHO x. npowsBoneray Aydropxnopwerana (snanona 22, R22, HCFC 22), vononssyemoro 8 xavecTBe xnagarenra NoTeran WoTOWeHAA oxDHORCrO | croA oTopoTe oTHocuTeNsHo.¢roprpwxnopweTaHa Cocraanser 0,050, ounoHeHTa cMecesux nagarewroe, HievoreuneparypHoro Nponennesa, nopoogpasosarena np NonyweHnn neHonnacros, Capes ANA noMyeHMR ropconepKauyn onedios VaaecTen cnoco6_nonywennn Avgropxnopweraia nyrew ssanwonecTenn xnopadopwa ¢ dyopveTum sonoponOM 8 Npvoyrcrsun naruxnopctoN cypeMey B aNectée KaranzsaTopa. Mpouece Benyt npA amwocsbepHon pasnennn uw Tewneparype 15425°C. fina woxmiovenma oxcrpanan IATHKRO_HCTOR. cypeNtA ADAM. cTOpMCTEM sonopaRoM, npHBoAAWeR x CHIKEHNO NpowssoanrensHoct# —npowecta, —abTopvoTaiA sonopon enonssyior 8 ras0o6pasHoM coctomn (aar. co. 513963, wn C 07 C 49108, ony6n. 1505.76) OhwaKo @ TOM npoyecce uMeeT wecro sacravne paanoxeve NATHROPACTOR cypeMs © oGpasosaiem TpexBaneNTHOR cypeM NpwBonAuee K HOKOTOPONY CHHNBHINO akrueHocri wararwsaropa, ‘ina nwsernaunn venocrarsa npensiayiyero enocoba NpenAOKeHO NeHTaXNOpAA CypEMbl NpensapuTensso pacTeopATs 8 xnopOGOpMe @ ronentpaunn 20-30 06.%, mM npouecs Iwapopropnposanna —secth nyrew Gapoormposatn cbropwcToro soopara vepes Peanyronnye waccy 8 nproyToTBiM xnopa, BeonMoro 8 KonMecTES 0,05-0,2% oF Macc: xnopochopaa, npoyece BeryT nx Teunepatype 60:1 10°C w aaanenna 7-13 ar (apr. ca. COOP 1160619, Kn. C 07 C 19/08, 17/20, ony6n, 150586). Poxym —GapCormposanun onpenenferoa KoncrpyKuveA Capdorapyroutero yetpoverea (om. Hanpawep. ast. =, CCCP 1180013, an. 8 01 F 5/00, 304, onyén. 180485). Touecc nonysesinn_mucbropxnopwerana xapaxrepwayeren OOpasoeaiweN noo4senc npoaykToa ~ Tpubropwerana (xnanow 23) @ropammropwerana (wagon 21), a TaioKe Nenonvon vonbepeuei nexoaWoro XAopbopMa Tpmdropweran—yrenwsupyet ——nyrew -RononvinensHoA — pexTicbrKauan —_nerko payin, oOpaayioujencn npn suennnn Usnesoro nponyxta 3 ra30a cnTesa (nareKr Pe 2001900, xn. C07 C 19/08, 17/20, onyon 30.10.93). Obpasyieuynica cpropamenopweran enpopearaposasuni xnoporbopm asiensior sosspauiaor 8 wine HavGones ndgpoSHo cnoco6 nanysexna ycropxnopwerara, orpaxaut CospenenHoe necTay‘ouee NporsaoRsTeO xnanowa 22, WSPONeN Ha” STpaninyax Poconcroro sammvecvoro xypvana OXyoHaN Poconcnoro xnMMvecxoro oOuecTEa . f.M. 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AANA sTOro yKasaHKyio yCoaylo cbpanyno HanpaENHOT a OTCTORHNK Ans pasnenenin Ky6oBor dparynn Ha nereAh BOAHUIA CIO M TAKEN OpraHMYECKAA CNOA, Conepmauinit @ropaWTOpMETaN, xnopO*opM, a TakK® pACTACPEHHIE KOMNpeCcOpHOE MAGNO ccrarkn enara, Bonk cho” ma oTcTomKnka BeGoRT HM Hanipagnaier a oTnapKy OT acTBopeHHLX —@TopAKNOpMeTaHA xnopochopwa, a TAKeNSIA opraanueckHi ono NonaieT Ha OpoWeKNe KONOHHs! aseoTPONHOR ‘oyun. TlocnesHiow BeslyT nM arMocpepHoM gaunennn w Tewnepatype Bepxa roroMtist 48°C. Aseorpon sons: # cbropayanopwerana Konnevcwpyior M Hanpansior @ ykasaHHetit [Bolle OTCTORHAK, OOeSBOKEHMBIA B peaynieraTe: Pekrucbrkaunn ——coBMeCTHiIA —pacraop: epropaixnopwerana, —xntopopopwa_— ownpeccopyoro wacna BbIEORRT Me. 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