Homework seminar 11

Composition of gases :
SO2 7% 1) the oxidation yield reduced after the mixture with cool gas
O2 11% 2) calculate the composition of gases to imput of second bed of catalist
N2 82% 3) the gases composition C`SO2, C´O2, C´SO3 AND C´N2 at output from th
cool gas fr 16% 4) the output gas flow, Df, Nm^3/h
yield after first bed 5) the residual gas flow, Dr, after SO3 absorption, knowing that the asorp
ƞ1 74% 6) the composition of residual gases C´´SO2, C´´O2, C´´SO3 and C´´N2 afte
yield after fourth bed 7) the sulphuric acid production, P, with the concentration C_H2SO4 =96
ƞF 98%
𝐷_𝑀 ((𝑁𝑚^3)/ℎ) COOLING GASES
42000
INITIAL
84 BI
MIXTURE (COOLING G)

1) the oxidation yield reduced after the mixture with cool gas

𝑥 𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑)/(𝑡𝑜𝑡𝑎𝑙 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑔𝑎𝑠𝑒𝑠 𝑚𝑖𝑥𝑡𝑢𝑟𝑒)∗100=(𝑔𝑎𝑠 𝑓𝑙𝑜𝑤 𝑜𝑓 𝑋𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑)/(𝑡𝑜𝑡𝑎𝑙 𝑔𝑎𝑠 𝑓𝑙𝑜𝑤 𝑜𝑓 𝑔𝑎𝑠𝑒𝑠 𝑚𝑖𝑥𝑡𝑢𝑟𝑒)∗100=(𝑁𝑜.

so at the end we got that

ƞ1=(ƞ1 C_SO2 D1/V_M) /( C_SO2 D1/VM) *100=ƞ1`=(moles of SO2 transformed)/(moles of SO2+ moles of SO2 in

0.6216 ƞ1*(1-cooling agent) so a = 0.84

0.74 ƞ1

2) calculate the composition of gases to imput of second bed of cata

No.moles=C_subst * D_M /22,4 NSO2= 0.0014 Compositions

NO2 0.0575 SO2
NN2 0.82 O2
NSO3 0.0686 N2
Ntot 0.9657 SO3

3) the gases composition C`SO2, C´O2, C´SO3 AND C´N2 at output from the reacto

𝐶`_𝑋=𝑁_𝐹𝑋/𝑁_𝐹𝑇 ∗100
𝐶`_𝑋=𝑁_𝐹𝑋/𝑁_𝐹𝑇 ∗100
SO2 0.145 %
O2 7.82 %
COMPOSITIONS RESULTS
N2 84.93 %
SO3 7.1 %

4) the output gas flow, Df, Nm^3/h

DF= 40560 Nm^3/h

5) the residual gas flow, Dr, after SO3 absorption, knowing that the asorption deg

The residual flow is Dr= 37695 Nm^3/h

6) the composition of residual gases C´´SO2, C´´O2, C´´SO3 and C´´N2 after sulphur trioxide

compositions( c´´)

SO2 0.156 %
O2 8.43 %
N2 91.38 %
SO3 0.037 %

7) the sulphuric acid production, P, with the concentration C_H2SO4 =96%

ms H2SO4= 13067kg/h
mixture with cool gas
mput of second bed of catalist
SO3 AND C´N2 at output from the reactor, in volume %

orption, knowing that the asorption degree is ƞ=99,5%

O2, C´´O2, C´´SO3 and C´´N2 after sulphur trioxide absorption, in volume %
he concentration C_H2SO4 =96% in kg/h RESIDUAL
GASES

FINAL SULPH ACID

BII BIII BIV ABSB 99,6%

fter the mixture with cool gas

𝑜𝑓 𝑔𝑎𝑠𝑒𝑠 𝑚𝑖𝑥𝑡𝑢𝑟𝑒)∗100=(𝑁𝑜. 𝑚𝑜𝑙𝑒𝑠 𝑜𝑔 𝑋𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑)/(𝑁𝑜. 𝑡𝑜𝑡𝑎𝑙 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑔𝑎𝑠𝑒𝑠 𝑚𝑖𝑥𝑡𝑢𝑟𝑒)∗100

/(moles of SO2+ moles of SO2 in cooling gas)*100

to imput of second bed of catalist

Compositions
0.145
7.82
84.93
7.1

C´N2 at output from the reactor, in volume %

ow, Df, Nm^3/h

knowing that the asorption degree is ƞ=99,5%

and C´´N2 after sulphur trioxide absorption, in volume %

e concentration C_H2SO4 =96% in kg/h