2, WATER & ENVIRONMENTAL / RAPID TESTS
Measuring high levels of free
chlorine in water
Measuring high eves of free chlorine canbe problematic;
Colorimeters used to test tree chlorine are based on a colour
change test; The DPD 1 (NN«iethy!p-phenylenediamine)
method for residual chlorine was fst introduced by Palin in
1957, Over the years thas become the most widely used
method for determining free chlorine in water and wastewater.
Hach introduced its frst Chlorine test based on DPD chemistry
in 1973 A DPO 1 tablet is add to the water sample and this
causes a pink colour change. The intensity ofthe colours then
measured by the meter to give @ reading In mg/L or ppm free
chlorine
High levels of combined chlorine (cloramines) can cause false
. posttves with these kits, Low to moderate levels of combinedchlorine are neutralized in most DPD kis, but combined chlorine
can occasionally build up to such a point that it seems to
Indicate @ level of tree chlorine is present when, in fac, there
tt
‘Another problem can be caused by high sanitizer levels, when
may be none.
the D20 indicators “leached out” A Nash of pink colour accute
whee the indiator ie added and then uieMly becomes
colourless. This can happen when testing is performed very
s00n ater dosing, (the high levels of ‘ee chlorine. are
exhausting the levels of reagents added and the test does not
reach a steady stat)
act's DPD powder reagents are quite stable when protected
from moisture, light and temperature extremes, Excellent
reagent stabilty is achieved by sealing the reagent in unitdose
foil pouches, AccuVac® DPD reagent ampoules are air
evacuated and hence are protected ffom oxidation and
‘moisture. tis recommended that all OPO reagents, both iquiés
and powders, be stored between 10 0 25°C (50 t0 77°F).
To measure free and total Chlorine (total Chlorine is free and
combined Chlorine) n water the Hach Pocket Colorimeter Mil
ie simple handheld device in routine disinfectant applications
‘Small ghtweight and batery operated this meter is a tue ‘go:
anywhere’ instrument. It can accurately measure fee Chlorine
between 0.0220 mg/L. To read a higher concentration ofchlorine with the same pocket colorimeter you can use
this sample cell -cm/10-mi this changes the way the meter can
measure the colour concentration and allows you to measure
chlorine levels up to 8.0 mg/L/. This option is detailed on the
Hach method sheet.
If high levele of free chlorine are suspected and you need to
measure above 8.0 mg/L, there are other chlorine meters that
Use tablet reagents that canbe chosen,
you want a meter that can measure both high and low ehlrine|
ranges the compact chlorometer duo will do the jab; this tests
for Chlorine (0PD) 0.01 - 5 mg/l, Chlorine HR, 1 - 250
ray), and is @ compact fully waterproof meter thats both
simple to use and highly accurate. If you just need to measure
chlorine at a high range the MD100 pocket colerimeter will
‘measure in the range of -200mg/
For more information please us ethe contact form or give our
technical team a ring on 01954239 120
| cLoRBK Fs, ARI, MORNE MASUR, UH, COVHON, LINES
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