R.K.MALIK'S NEWTON CLASSES JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X CBSE TEST PAPER-04 CLASS - XII CHEMISTRY (Haloalkanes and Haloarenes) Top Identification Question CH,CH,CH, Br 2225 (¥) 5 (Y) #5 (2) An organic compound “A’ having molecular formula C3Hg on treaiment with aqueous HxSO, given’ B’ which on treatment with Lucas reagent gives ‘C’. The compound ‘C’ on treatment with ethanolic KOH gives back on compound ‘A’, Identify A, B, & C. An organi¢ compound ‘A’ on heating with NHy-and cuprous oxide at high pressure gives compound ‘B’. The compound ‘B* on treatment with ice Cold solution of NaNO2 and HC! gives “C” , which on heating with copper turning and HCI gives “A’ again, Identify A) B & C compound alc A Ghar —cry HBr x 5 Y HBr peroxide 5 OH Br. 7 alc KOH A 2 B 6 NaNo. CuBr C,H; NH, —aqyp*+—> A —— B H ,H 7 NaQH s FD 623K, Pressure A compound ‘A’ contains carbon and hydrogen only and has molecular mass of 72. Its photo chlorination gives a mixture containing only one monochloro and two dichloro hydrocarbons. Deduce the structure of A and chlorinated products. Office.: 606 , 6th Floor, Harlom Tower, Circular Roai Ph.: 0651-2562523, 9835508612, 8507613968 ‘www.newtonclasses.net