‘ March - Qeis taeanan tse Abe og No. of Printed Pages : 16 4683 en etal 8 [alele b| TANT PART -IM Goughufluss / CHEMISTRY (sip Med auysl / Tamil & English Versions) Gpmb :3 wasll ] [ Guomds WALLET : 150 Time Allowed : 3 Hours ] [Maximum Marks : 150 ailajor: @) smodg Aersse58 sfucs Berd edrargr ccruseon sAuriggd Gandara. sei GeAo copdigiide sens sdrsraaiiiurenfiii oLemurss Os faléssay. P) ford scirelay ancy eiploner oi OC crepgiasheli UMeLOSS Coain@s. ULtedr umragie Queda uueiGssay. Instructions: (IY Check the question paper for fairness of printing. If there is any lack of fairness, inform the Hall Supervisor immediately. (2) Use Black or Blue ink to write and pencil to draw diagrams. @Piy : Cgoouwnen GisAo uw aveoysss, swenuserer ays. Note Draw diagrams and write equations wherever necessary wuw. UsSafitdask Com ug -1/PART-1 Sey: () semendg AenrdsigGESe eloorvicllssayh 30x1=30 (i) sfuren Be ous GaisIsOin owss Note: (i) Answer all the questions (ii) Choose and write the correct answer. 1 9G Gord Al? g Werallnas EsmalUuGd aostprénsaiiér Gordsches erebranflisens : (a3 (9)1 (@) 2 (m) 4 ‘The-number of moles of electrons required to discharge one mole of Al** is : @ 3 (ob) 1 © 2 @) 4 { Beotiyys / Torn over é Ke Com au. Use ful Des Com Mall - settwww. Usa fiDosk. Cony 2 Epacin_aibgicr obs Gewadgoep oi@uraggid sréHunorengi? (#) 4H >0,a5>0 (2) AH <0, 45 >0 (Q) SH>0,as0,aS>0 (b) AH <0,48>0 () AH>0,As<0 (@) AH <0,48<0 pose CL rene sifu egayougs (2) 2Quseirin senpsd (9) eGumGLrcunin Gengenar (@) Gets Cergenen (#) Lredreo eflenan’s Qunger Methyl Ketones are usually characterised by (a) the Febling’s solution (b) _ the lodoform test (c)_ the Schif’s test (d)__ the Tollen’s reagent Ascari Senencs Gunga sunflés goiquing } Low (©) Zero (a) Very low. XeF,-ar agent (21) prrengpd (9) orateranal (Q) soregind (F) nO ‘The shape of XeF, is : (a) tetrahedral (b) octahedral (c) square planar (d)_ pyramidal Bergen siGadr sunflés UeniGis 2Comsssacna : (2) 2.QuiGpr @Grmb (<9) Qaucirsenib (Q) op SGymd (#) &ALamat The alloy used in the manufacture of resistance wires is (a) Ferro - chrome (b) Bronze ()_ Nichrome (a) Steliite { Bgiys / Tum over tous: Use ful Darke. Cowsdots? Use Rs Dare: Coon 6 20. Geraugaararppld ag) Ueciig, stéeony? 4683, (21) 5&Cpre (3) QsagiGerciv (Q) wraGLrev (mF) pminIGenreto Which one of the following is a polysaccharide ? (a) Sucrose b) Cellulose (©) Maltose (a) Raffinose 21. bee Lnsé Hd Gi BG sLagdrer Gigs senssoflé ceinanflésens = (a)1 (a) 2 )3 (mF) 4 ‘The total number of atoms per unit cell of bee is : @ 1 © 2 () 3 @ 4 22. pi SMDtY OOM shop aSumdsler cren_Gom wrdpw aoepGu = 0.228 JK~? wohpyid +0260 JK~1 ered s1im_ Shen ram Gym wombmi + (<1) —0.0313 JK-1 (<9) #010313 JK-2 q (Q) +0877 JK-1 (#) -0.877 Jk-1 The change in entropy for a system and surrounding are ~ 0.228 JK~' and +0.260 JK™1 respectively. Then entropy change of the universe is (a) =0.0313 JK~1 +(e) #00813 JK-} (c) +0877 JK~1 (d) -0.877 JK-! 23. QLiifiLréadafler Qaused (91) galsGsitams (-25) pdblgonar G58 massgb OSs Qedeipand (Q) ses gren wri (=) gafiscromn UBS gud Aung ‘The function of ferridoxin is (a) photosynthesis (b) storage and transport of oxygen (©) electron transfer (A) sensitiser teese Usefud Dark. ComBa 5 A . 26. canter sinalparer Gumi ris) A G) 052920-F cm 4 (Q) 05291076 em The vat radius for hydrogen (@) 0.529108 em : ) 0529%1 )-§ em i 27. Apsdr Csiwischd cHGeind GGyrowd EEarar1O Cersmenis ecucmg? 7 (1) CuCl, (9) HeCl (Q@) Zc, Which of the following compounds will not give posit (a) CuCl, (0) MgC, (ZnCl, 28. afar apaAgger Se: (21) DG Bever Siflundlésgy (Q) BeFgtardgd sero (93) LAS Gaim g (F) wags acrowyjeriugs Oxygen atom of ether is : q (a) very reactive (b) laceable > (©) oxidising (d) comparatively inert [Agius / Tun over 1 Loesed Usa fll Derk. Com4683 29, Wwww- USO fl D a9 k + Cova 8 posta Aertapysde CsmatuGd oGauls spe : (21) Quss sapped (2) GeopGsres K. () K. UGH - 1/ PART GML: © sagqud uUlmenigy Bemis sds len wefl 15x3=45 Note : 31. 32. @ gadamgG AerrsAMHpGd gery) sdog Drom arssumsoe Blaruah @) Answer any fifteen questions. (i) Bach answer should be in one or two sentences. Qaésations csorup, Define hybridisation. Gengenan qparid GULL dGi-c) @ WILLY 193A, smiiafer gD ePID OITA crafly ASdsciler sen yjse5 SarsAGS. ‘The experimental value of d(Si—c) is 1.93 A. If the radius of carbon is 0.77 A, calculate the radius of silicon. toww: Use ful Dark. Com* } Wows? Use fil Das ke. ca ms “} ; - “eel aablipsa créapred ercren? ogy eda 54st UOADSI? . i, ‘What is pints eainven? How can it be ae | : es ‘ | 37. eran saat GanO Aaliadgisrer siflefu Write the principle behind the Hydrogen bomb 38. seremmy réieurg e@anedng? = . ’ How are glasses formed ? b . 39. cre Cpr creypre crete? sigs IBIGEET BM). What is entropy ? Write its units. PY {B@2us / Tom over W3WwUd. Use fbDas Com)Uses? Use fui Das Cama, 4683 10 40. Som dluilér asgiasens ogls. State Le-chatlier’s principle. 41, craw ppb Aaseoren aAlenenasdr crepe oréen? What are simple and complex reactions ? 42. app asons lenamilen lene Gaus worifleSuSlér nglLsty 1.54%10~Fsee* erated Sa@rarpa sTagos sardéAGS. ‘The rate constant of a first order reaction is 154 10~%sec™1. Calculate its half life period. 43, lene Gas wrbpl crérpra erénen? pt oOSHh5TO SES What is catalysis ? Give an example. ~ 44. aycvamadyen Sigsd APeuw sg. State Ostwald’s dilution law. 45, Acromds slogsslen Z wig E sienaiyseoar smi Os. Give the structures of Z and E forms of cinnamic acid, 46. ypiGudr 2-96 wig 20wsGe ypOCudr-2-34 ydlucrdonp Cagudsgnd MG GaPud Gengoensener sG5. Give two chemical tests to distinguish propan - 2 - ol and 2-methylpropan - 2 - ol. 47, Quérmsd ayoagord, Deore AnseAuid yCrrenoy dGsg ereoungy Qupsugangs? How is benzyl alcohol obtained from phenyl magnesium bromide ? Uduww* Use ful Dos ke ComBias 24 / 52. gpadag apni Geméteesenu of Explain the postulates of Moleculor orbital phisih igen STE bg ereueITD, How is gold extracted from its are? @ / Tum over4683 54. 55. 56. 57. 58. 59. 60. www. Usa fal Doar Com 12 eongenenGeailar uuséisanar erqgaue. Write the uses of Lanthanides. 555 sraQ AZo smana worpGud opybd weRwurgd wnpSlusssener Pardes. Explain coordination and ionisation isomerism with examples. 1Giey - 4, / SECTION - B sLydar apppadler AptiMud seer 55s. Give the characteristics of free energy. PCI; Magid Ameige K, opgid K, onpdlsepésnon swan @sonar augailésaaytd. ¥ + * Derive the expressions K, and K, for decomposition of PCls, . Wsdacs Aenenuier ApCOudr send Uggs. Write the characteristics of first order reaction, 25°C -d) Zn—Ag Uienswssler emf -Qs seinGOy. [Zn2+]=0.001M toiiptd [Ag*]=0.1M (B°ig , 25°C -& =1.56V) Calculate the e.mf of the Zn —Ag cell at 25°C when [Zn?+]=0.001M and [Ag*]=0.1M (Econ at 25°C =1.56¥) wifey - @) / SECTION - C ML orAd mpi Gerad sjeeepLen crcvamgy clever yASlngs? (31) O,f Sam Agr_iny (2) HI (2igl6 oeT9y) — (@)) PCls How does diethyl ether react with the following reagents ? (a) O,/long contact () Hl in excess © PCs Www. Use fl Dark. Com61. 62. 63. Wow: USa hADark Corr, 13 4683 SILL Tdyoan® FOULOdiot GHG Borne Ges cAlenemden efleoen eufponpenus aflauti. Explain the mechanism of acetaldehyde involved crossed aldol condensation. erage Cainomsdr QudremGs slasAA GB sreourg GupLuGApsy (a1) orld QucrenGu, (3) Guéressd gasanre (Q) Guéndesr How are the following compounds obtained from benzoic acid ? (a) Ethyl benzoate (b) Benzyl aleohol (Benzene . = Biinggudt eAiiscnan’s Up orepgis. sone Boss cued Hlourpanflaaiess usc wig? a ‘Write briefly on antibiotics. In what way antispasmodics are helpful ? oer » Usa hlDagk Com US Iv /PNRT- TV ea [SHAE © Gongs wrone Bomnss epg aerwll 4x10=40 Note : 64. (i) Slant creit 70-8 smunors, Serwatsal Ud Cassin id. Usqpdrr Menrésala Geen epsrp Aerése5eq Slo wiahissayn. (Answer four questions in all (i) Question number 70 is compulsory and answer any. three from the remaining questions. (21) cr@scgreit saut saromodssiren LneSiis sareSiLen.. Blau (<3) CuGermenp sah gigs yCornflen cdicry GAs@sOsso GAs)? (a) Explain Pauling’s scale of electronegativity (b) How is fluorine isolated from fluorides ? woes - USe, ful Demk «Cor, | BOLUEY Tom overeee wus UsAs Darke + Cok 4683 4 65. (<91) [Co(NH,),Cly] NO, crénp sionenray Geinog glen @ TUPAC Quwit (i) @now 2Gars swell (iii) refl (iv) Sonera, Caren Sler Denso (v) Stenenray erat BAueujoy EHNAIPs. (9) sBfwds sive sre Bltemus epsom ofeufl. (a) Mention the following for the complex [Co(NH),Cl)NO), () TUPAC name (i) Central metal ion (ii) Ligand (iv) Charge on the Co-ordination sphere () Co-ordination number iol . = —. ey (b) Explain about Radio Carbon dating. ~ owe USe Pol Dor dom 66. (21) qWAAILQstsaer ApLGWaLsenaT cTUDEIE. (2) OG mppo gisellér Derseweu aang HirexmLiumis? @) ain the characteristics of ionic crystals. (b) How can you determine the charge of the sol particles ? 67. (21) Bed ardyen Sissed Aow Aende. (44) aLgor ayon@deld EMF -&G1 a drat Qgm_ frou lout (a) Explain Ostwald’s dilution law. (b) Discuss the relation between free energy and EMF. Www: Use fu Dar ks Cam68. 69. wsusws- USefudDarke » Cow 15 (21) QaidCunvtsd vppb CurcyAGumotscar CupUOses (24) Acreugib eBlenonsssnen lout. (i) HVZ Genes @) ombgy cravtgns ese aBlenen (i) QugsAe sroAC@r a Gange (a) Differentiate between Enantiomer and Diastereomer. (©) Explain the following reactions : (i) HVZ reaction (ii) Trans esterification (ii) Methyl salicylate formation (21) qflenoens, Fflenamus pI EpeAenamus -suBérsenor Capdsass (24) Lip nevadler Senolid créiaung sEaASSLLIOApE Tenens ATES, (@)_ Distinguish between Primary, Secondary and Tertiary amines. (b) Elucidate the structure of fructose. . (91) GH, ore Gnade, ambtun® Ganeim (A) orénp Gehob end sobs Quit Lnfuts QuromissGantGLén eBlenem.yfij5g1 CHO, stamp epasengy aumiscur@ eeu @) orenp Caioges sosing. Cab (©) -g 57D Aras GCarrn7 Ger Getsg Gasusudss CH,O stép ambi Qaren (C) Gat a garding). (A), 8) oppd O-8 som ilpgi. Aenensanor flores. s (<4) 2 yb QsreA wpgid 4 4 Agro snipe, fab saps Goveinantip s@lob (A) ALi spo sWlasgiiér Alemany fibg 50; amiss Qasl@was (B) -~g carp isd 2LeU BEADS. B) sens) Genqurb au aniuGe Qrér Aeon fig, Gore Coraw GariuGsge scfibyacild UwctiLS eau Gano (C)-g sGAng- (A), (B) opm (Org sem sflig), aAlenonsenar flere. . 10s) és. Safa Dastes Caml Bore / memes Pan4683, (Q) (F) (a) () ©) (@) Lous Usefyl Das: Com 16 GH, cep qpesmm oumisunG eeu sfwé Gsitow (A), V0; YaMoade sniper Aeenyfsg, CHO cep rodsmag amiiT® e@Lw Csi (B)-g smding. Geto (@) -g AsAub slau aantoy@ Aaran® @GSstd Gaiiu, CHO crénm gpasep amiiin® eeu Gero (C)-e s@dingi. (A), (B) opmb (©) -g sem Mes Slenenscoar flare. Saar Sidsd wig 01M AeflaAled sigs mdesslen soren sLagid Aner apenpCus 390.7 wip 5.2 Gor. Ge ? A.sorenbdt se. Dhlos fg, Ht swell Gefla oop aagder Alene wml gAuaipenp serbAOs. ‘An organic compound (A) of molecular formula C,H, reacts with alkaline potassium permanganate and gives compound (B) of molecular formula C5H,O). Compound (B) when heated with anhydrous zinc chloride forms (C) of molecular formula CHO. Identify A, B and C and explain the reactions. An element (A) belongs to group number 12 and period number 4, bluish white in colour reacts with Conc. H,SO, to give its salt (B)-with the liberation of SO, gas. Compound (B) reacts with sodium bicarbonate to give (C) whichis used as ointment for curing skin diseases. Identify A, B and C and explain the reactions. oR ‘An organic compound (A) of molecular formula C;Hg on oxidation with air and in presence of VO; to form (B) of molecular formula CjH,O. (B) on reduction with lithium aluminium hydride toform (C) of molecular formula C;H,0. Identify (A), (B) and (C) and explain the reactions. Equivalent conductivity of acetic acid at infinite dilution is 390.7 mho cm? gm. equit’~! and for 0.1 M acetic acid is 5.2 mho em? gm. equiv~. Calculate degree of dissociation, H+ ion concentration and dissociation constant of the acid. -000- tite 7 Ps casts facabeote cam Jusehys Dak Shana ws igi stor U8a LADeak- Conn