No. of Printed Pages : 15 6233 usiey erat B Register Number| PART - II SEPTEMBER 2016 Geusluluiev / CHEMISTRY (skp WM —apdle uy) / Tamil & English Versions) Gpmb : 3 werfl | (Quorgs wAUGueinsdr : 150 Time Allowed : 3 Hours ] [Maximum Marks : 150 ABleyeor: Q) soasg Aearésep shuns uPardl ocrangr crotugeer sfumtégs Gancrnay sisatuged GenouiGuder siopssdraneiurorfiti aLergunss Ashelssayo. Q) fab saeg sGby oolme wi GGo sygasHEd, AH SCorgQashSb wWeiGss CuanGd. uma umpusye Queda UwenGsgaub Instructions: (1) Check the question paper for fairness of printing, If there is any lack of fairness, inform the Hall Supervisor immediately. (2) Use Black or Blue ink to write and underline and pencil to draw diagrams. uy: Coenauiren Bi ssl ULw euenggs sndrun@sener crugais. yt Cp 8 wi Note: Draw diagrams and write equations wherever necessary. UGH) -1/PART-1 GLY: () genensg Menrssepsqb Slenwehlsseyid. 30x1=30 . (i) sflurer Aoows CaibIsOSs) oripgis. Note: (i) Answer all the questions (i) Choose and write the correct answer. 1. pl Crr Catomsd st amped perelmada oer Benen yihdipg) (21) @flonearus (24) mencsorus (Q) (2) pp (24) (mF) apeflenenrus nitro compounds behave as acids in presence of strong alkali. (@) Primary (b) Secondary (©) @)and b) (a) Tertiary { Sq@iys / Tum overSEP 2016 6233 2 2. Galt srZeriGuLyuId GeflreAciumenrs UWsMG Gainoid (21) BépréA Qusréér (93) F6TdA mECEer (Q) BaaréhA BsCper (i) 6pnéA Qucnér is used as a refrigerant in refrigerator. (a) Methoxy benzene (b) Ethoxy ethane (c) Methoxy methane (@)_ Ethoxy benzene 3. Gyné serum ge, ‘x’ craigs : (31) Gordaaflen creinenflésens (4) SteusmL Gor erate (Q) Geuneim_tb crein (=) oAOprahinGer Lg, In the Bragg’s equation for diffraction of X-rays, ’n’ represents : (@) The number of moles (©) Avogadro number (©) A quantum number (@ Order of reflection 4. cr@sLpmatlesr Were wens seim logout : (1) smbeen (2) q-GsGor (GQ) PASaen (mF) ggeneiner ‘The charge of an electron is determined by : (a) Thomson (©) de-Broglie (Milliken (@)_ Einstein 5. ap Adler Acnerdsrd PL, aid Heong: an@rugy : (1) ICH,CH,I (%) CH,=CH, (Q) CH,=CHI—() ICH=CHT The reaction of ethylene glycol with Pl, gives : (a) ICH,CH,I (®) CH=CH, () CH,=CHI (a) ICH=CHI 6. anpseenQsctler Qungieren asAggGonpn Slane : (st) +2 (—) +1 (Q) +3 (mr) +4 The most common oxidation state of Lanthanides is : (@) +2 ) +1 ( +3 @ +43 6233 SEP 2016 Epssamaupmyar orGld IG 2-crengy? (21) doLmiéa: (2) sali creitGemis (Q) srouy eroirQornis () QutieL@ Which of the following contains a lipid ? (a) starch (b) mineral oil (2) edible oil (a) peptide 8G Galiub@srér soma AeenIe T, wpg T, AaucuPeoosafe sioflone wompleSlacr Ky wibgpnd K, cra Geuciuglene T, ayengy T, snes oS wdisors QGsei Gung (1, >T,) (2) Ky K (Q) =k () Ky #K An equilibrium reaction is endothermic if K, and K, are the equilibrium constants at T, and T, temperatures respectively and if T, is greater than T, then : @ K owafluder senwdy (21) Brengpd) (3) egu7gomb (Q) waCaremd () ereimgpdl The geometry of [Ni(CN),]?~ is : (a) Tetrahedral (b) Square planar (Triangular (4) Octahedral { Sgtiys / Turn over1. 12. 13. 14. 15. SEP 2016 4 B-giser Oyptiy eTeNLIBHE swid. (81) GG YGomiimer PsA . (2) G Superga Dyovy (Q) (=) wn (es) (*) orbs wmppeph Bedoma Loss of a B-particle is equivalent to (a) _ Increase of one proton only (b) Decrease of one neutron only (oc) Both (a) and (b) (a) No change phloem s8er QeweduGw oflgid (1) ras grén seutsrentl (<4) gram (Q) gn9 sorb (F) af epdy Primary amine acts as : (a) electrophile (b) Lewis base (©) Lewis acid (a) free radical morshd rasan Aasiusie Labs sre (91) HI (<4) KMnO, (Q) NaOH (F) HO Diethyl ether can be decomposed with : (a) HI (&) KMnO, (©) NaOH (@ HO ssCyrAd G@sGerad, [HpsCLrEid Denomdsculy GUE)? (2) Gy (4) G-Q (Q) G-C (fF) G-Ce Sucrose contains glucose and fructose linked by : @ G-q &) C,-Cy © G-cy @) Gy -Cy SWAULITEGL wyboedler auflens : (a) s p> d>f (Q) s>a>p>f (m) sprd>f () s>d>p>f (d) s (21) Qantiisglene (2) mes (Q) eumysaoflen getran0 () Updys SAG GumBere ‘The magnitude of gaseous adsorption does not depend upon : (a) temperature (b) pressure (c) nature of the gas (d) amount of the adsorbent26. a7: 28. SEP 2016 a 6233 Bsords sWlagos slob sobs KMn0, Ho ys gQGanppw Aeron __ AenenGars wonpfuwrs GewouGpgs. (31) KMnO, (<4) (COOH), (Q) Mnso, (mF) KO, is the catalyst in the oxidation of oxalic acid with acidified KMnO,. (a) KMnO, (&) (COOH), (3) Mnso, (@) KS0, arev_eng $58 HC] Hcnalmaule SrmHUSsSSo Aenemudlesr Alenansucns (si) Qyeimimd asens eleven (2) Leyes aucns aSlenen (Q) Cured pga ans ener ——() (pga auenss eBlenen Hydrolysis of an ester by dilute HCI is an example for : (a) second order reaction (b) zero order reaction (c) pseudo first order reaction (@) first order reaction Spssar_apger og Qusse AvnéeiAub sCurm_GOrer Cetpg Yao AyL Ld Bosanroads GanGsGw? (1) HCHO (<%) CH,CHO (Q) CH,COCH, — () CO, From which of the following, tertiary butyl alcohol is obtained by the action of Methyl magnesium iodide ? (a) HCHO () CHCHO () CH,COCH, (@) CO, aposgiacseréanan qamcd Denarollpes smramb : (1) Berson Q@tusra (2) aaheFigpa (Q) eof 2 DGasa () gel Mose The Tyndall's effect associated with colloidal particle is due to : (a) _ presence of charge (b) scattering of light (©) absorption of light (a) _ reflection of light [ BqGiys / Tum over* 295 30. SEP 2016 Csiomad cogs Garang Gee Gumigs Ppepcror swellsoer 2 Gang Mannan. (21) Oyler cast prenacr (94) sas crams prereset (Q) sefiés Cama crosLoncrsdt (m) (1) wg (Q) Formation of coloured ions is possible when compound contains (a) paired electrons (®) unpaired electrons (©) _ lone pair of electrons (a) (@) and () =-34.84 crafld n a Aly : (<3) 3 (Q)2 (F)1 if the value of E, = —34.84 to which value ‘n’ corresponds ? &) 3 () 2 (d 1 UGS) - I / PART - I SHwY: @ gGsqud uslmemigs lennsaeps6 cSonwel 15x3=45 @) GAGargG Aanaped gery Hoag) Oren cussed Beo_waf Note: (i) Answer any fifteen questions. 31. $2, (i) Each answer should be in one or two sentences. He, gan agpaunseSéraner? Why He, is not formed ? BiAgoen AL yesMér os owaUns sid axoperw Guppirangy. een? The ionisation energy of fluorine is greater than oxygen. Why ?33. 34, 35. 36. 37. 38. 39. 40. SEP 2016 9 6233 urevidr pi Apis POEL sraa crénuiong Bley. Show that phosphine is a very good reducing agent. Gund Liney Ugennbd eraueungy sumastiuiGSng1? How is Potash Alum prepared ? @psGrmb 2Gonss samanden ssi Danwy wim wwer wings? ‘What is the percentage composition and use of Nichrome ? SGoreflur saps Ade oglGpe. unis sHesgier yfluid onerous 8O% Give the reaction of ammoniacal silver nitrate with Formic acid. GeraGd 28g Dererserar yids Gas : @ N¥ pa)... 3) NB? (8) nee Gi) 9K @ 4). Complete the following nuclear reactions : @ ANFea (i) Ne (a, 8) Gi) 19K? (ed) - aCarsb Gmpuy GMpURG crénprd créren? crHSgssT_O BOS. What is metal deficiency defect ? Give an example CHC, ot GanGiflnw 615°C craflé 215) Pood 4s gereniould CsusduGed Gung igen Gorant acSlungd Gautiisenss somd8@ The boiling point of CHCI, is 61.5°C. Calculate the molar heat of vapourisation of the liquid, assuming ideal behaviour. LGargd sflora wnpP\SsGw, Alene wmpPAsGwd octet Qgm_iy eréron? BG THSHS 5D SES. What is the relationship between formation equilibrium constant and dissociation constant ? Give one example. [ Segue / Tum over4. 42. 43. 44. 45. 46. 47. 48, 49. 50. 51. SEP 2016 10 TAA Donen crenpra crénon? e+ HSHSSTLO BOS. What is opposing reaction ? Give an example. YEO aims Aneadg weary «+ Osgisar Oacr 5655. Give three examples for first order reaction. safl mipslér Oilers Slrweno, Glee ema yuan GHUIDS. Saf MpPUSHHS TOSSESTLD SOS. Give the dispersed phase and dispersion medium for a gel. Give example for gel. Candqney AGeou cucopwgy Define Kohlraush’s law. girériy sienwLiLy, Adv sonotienu! AL Hoounensrs Qepshingy. gen? Trans isomers are more stable than cis-isomers. Why ? SansSer ysalnGondn Aeaaus 555. Give the oxidation reaction of phenol. lear sosanrgesrar Dt Cowit Gengonenenus orapgss. Write the Victor Meyer's test for secondary alcohol. Fapsd Slane pgs. Write Knoevenagal reaction. Lombgy cre prs Ese crenprd crénen? HS SEEM OS BGS. What is trans esterification ? Give example. CHSN créngyb posag amicum@ew (A) tem sdese sider, srtuevler Sener G 2LUC@ (B) g s@slpg. Geo (B) LiAIH, aa aOsad OL b5 (OC) B SGApg. Gairomuscr (A), (B) wHmd (C) B sani. An alkylamine (A) molecular formula CH;N undergoes carbylamine reaction to give (B). When (B) is reduced with LiAIH, gives (C). Identify (A), (B) and (C). sors sOLuuer crénpred crénen? TOSHESTLD SHS. What is antiseptic ? Give an example.SEP 2016 uw 6233 UGH - UI / PART - IT SHY : GAMATG AAA GSgb GODASLLsb DE Senrdseer CoisAsOSai Quis sb ap Aenrssie55e oSlon_wat 7x8=35; Note: Answer any seven questions choosing at least two questions from each section. 52. 53. 54, 55. 56. 58. ifley - 9) / SECTION - A PBI SE anasergs Bendes Explain the shape of p-orbitals. giiGent Gaiu @G4s Yeneud UL aapig, Aedes. Explain Aluminothermic process with neat diagram. GorGarrosl. vemdA Gg onsen crauany ISAsOssiUGdng!? Describe the extraction of lanthanides from monazite sand. SdDsG po CaMIude GCornGprASer uwG wg? wiser Gewaur@asmor GAUIGs. How is chlorophyll important in environmental chemistry ? Mention its functions. 1Sflay - 4, / SECTION -B cent Gprduder ADLAUdLYEE9r 5—5: Give the characteristics of entropy. K, wig K, 5 Dor Guwner gman args. Derive the relation between K, and K,. crofius wigud Aésorer Ares erse QorGu 2 crer Gayun@scr wrenas? What are the differences between simple and complex reactions ? [ Agius / Turn over59. 60. 61. 62. 63. SEP 2016 12 @G Zn Bléneumts 0.01 M ZnSO, sengede 25°C & erevdsuGCwwreane, Qser Kopem Ber sysssa5s SemsAQ E=0.763 V. What is the potential of a half cell consisting of zinc electrode in 0.01 M ZnSO, solution Wifey - @ / SECTION -C SpasamL syenfisner or cSHa mst ccuany Aenenyng? () ait HS, (i) firég H.SO, (ii) -HI How does diethyl ether reacts with the following reagents ? @ Con. H,S0, (i) dil. H,S0, (i) HI SALLIOR MANE, GudteTdgcgne uy CupuGsss. Differentiate acetaldehyde from benzaldehyde srOAAE ord YCMMguLeér Ylud Deron uPepenperns aordgs: Explain the reaction mechanism of bromine with salicylic acid. sem Cag iGurgiasc UidA Angi eerqe Write short notes on chemicals in food. gs) -1V / PART-1V SHAY: @) Gworssb prong Aenrésieneg Sloowel 4x10=40 64. (i) enn cree 70 6G SL LouwIs Aocwléssud GudrOs Bsqpdrar Aenrésahe oCsgobd epenpy Aennssepse Slen_wefl () Answer four questions in all. (Question number 70 is compulsory and answer any three from the remaining questions. (21) Swehumigd aonenars UMBsGw anporiscrer cords. (9) UrepfeMer oMQULL Leimysoner Mens gs, (a) Describe the factors influencing the ionisation energy. (6) Explain the anamalous behaviour of fluorine.65. 66. 67. 68. SEP 2016 13 6233 (21) SipSaeir_aybenp alo (rel (ii) aienemrey cre (3) oGsgas HeoMId sAfluss gCenC_miysolr Uudrscans SOR (a) Explain the following : @ Ligand (ii) Coordination number (b) Give the uses of radioactive isotopes in medicine (21) Gord HpArawreh cpapew Aerses (<2) AonerCaus wrbpssér UpiyssautsA Gancransenus auf (a) Explain Brage’s spectrometer method. (b) Write briefly about the adsorption theory of catalysis. (81) alo, snd Apder4 UGH GuIGorrennsG Genérensnu efleut. (24) gt Bart Ddrsws Ser Opie 1 sinerLimLe euggell (a) Explain the quinonoid theory of acid-base indicator. (b) Derive Nernst equation of a reversible cell reaction. (2) LmiLiThés oWassar gal aphA ombGugens eu. (3) sé4aMé Ward Sipdscim_auonon creicunsy MeremsuGApgs? @) NaOH (i) NH, (ii) PCL; (a) Explain the optical activity of Tartaric acid (b) How do succinic acid reacts with the following ? @) NaOH (i) NH, (ii) PCs { Agus / Turn overSEP 2016 14 69. (51) QuerSer oLuCsrofud GCorranty SG Hg Spscin Coitisencr erévoungy sumftsuumis? @ mpl Gyn Queardein @) @ComGyr Queen, (i) Aenend nam Sen (2) GuiLeOLG Gerowniiy xem agero sid Oren lensEs. (@) How do you prepare the following compounds from benzene diazonium chloride ? (@ _ Nitrobenzene (i) Chlorobenzene (iil) Phenyl hydrazine (b) Show the formation of a peptide bond with an equation. 70. (81) CHO crenp gparsaagy aumiicim@eocus (A) crenp sflosGainos CH,Mgl 2a Benoryhig (B) crénp sflwé Coivsngss s@dingi. Bg) 2 Cons Gsrnwsgier naniggeer AacfiGupmibd. Getiowb (B) st H,SO, Ysaloaule 410K Gatuplauvle FF FSswerrpg CyH,9O cramp Yosag amisuT@orw (C) gs SGADs. (A), (B) WOM (C) BS Sam_Hlg1 Deronseror ers 5 5. (B)‘A’ orenp Caio wldgissb cep smpsstuGdng. GUMS oooverr Piss H,SO, o songsgy ‘A’ owes GUM “pyuyt 20°C Gaudu fleose Ag GOUGSHb GumQH 'B’ cremp Apopp Csinsass SGADE.'A’ S615 SIo18j NH,OH 2.4 Bonen yAgy 'C orénp sronamays GCeinosengé sms). ‘A’ a,ong) HS 0.1 ar Alenenyfigy‘D’ crenp a Geno Ap Spunmas seams. ‘A’, B,/C,‘D' cenucraudenns seinO.I4 55) Slenensoner cMGTES, AVS! (Q) (A) (CgHO) stem g@ sfws GCstob sGurGLruminbd AomsgGuG Ang. HMustsssomai wg Lt HCl a4 (A) BOSs 0058) (B) (CsHyq) BS SGFDg). (A) YGomBlgy_et gfe 273 K Qautirsflerauer Benen Aig (C) (CgH,OBr) ps Sepdlg (A), B) wow © g sam flag) Aerarsonor endg, (FF) Ba(OH), ergy aidlenw WE eriGali crafld 0.02 M Ba(OH), &Aus seomsdlén pH g sandalQ.(@) © (a) 15 ‘An organic compound (A) molecular formula CH,O reacts with CH,Mgl to give compound (B). Compound (B) liberates Hydrogen with metallic sodium. Compound (B) in the presence of Con. H,SO, at 410 K on dehydration to give compound (C) molecular formula C,H,)0. Identify (A), (B) and (C). Explain the above reactions. Compound (A) also known as blue vitriol can be prepared by dissolving Cupric oxide in dil. H,SO,. A on heating to 230°C gives compound B which is colourless. A reacts with excess of NH,OH and gives C which is a complex salt. A also reacts with H,S and gives compound D, a precipitate which is black in colour. Find out A,B, Cand D. Explain the reactions. OR An organic compound ‘A’ (CsH,O) undergoes iodoform test. When reduced with Zinc amalgam and HCl it gives B (CsHyo). A with Br, in Ether at 273 K gives ‘C’ (CjH,OBr). Identify A,B and C. Explain the reactions. Calculate the pH of 0.02 M Ba(OH), aqueous solution assuming Ba(OH), as a strong electrolyte. -000- 6233,