10 Practice Question [3] (JEE-Mains & Advanced 2024) 1, Two liquids A and B form an ideal solution. The solution has a vapour pressure of 700 torr at 90°C. It is distilled till 2/3" of the solution is collected as condensate. The composition of the condensate is Xq' = 0.75 and that of the residue is Xq" = 0.3. If the vapour pressure of the residue at 90° is 600 torr, which of the following option is correct. (A) The composition of the original liquid was Xa = 0.6 (B) The composition of the original liquid was X4 = 0.4 © P= 2500 torr @) Ps = 500torr 2, A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Ozonolysis of Q leads to a dicarbonyl compound R. which undergoes intramolecular aldol reaction to give predominantly §. The structure of the product $ can be : PQ Sam RGSS HESS Oo ‘oO Me Mé “Me oO oO J Me oC CO Mi ‘Me 3, In the decay sequence, Bag Th Sgt Pa Zo Th X1. X2. X3 and x4 are particles/radiation emitted by the respective isotopes. The correct option(s) is (are) (A) x1 will deflect towards negatively charged plate (B) xis 8” (C) 33 is y-ray (D) Zis an isotope of uranium ‘Nirmal Academy for Science Education (NASE) 117/N/SS5 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 98896555564, Aniline reacts with mixed acid (cone. HNO3 and cone. H)SO,) at 288 K to give P (51 %). Q (47%) and R (2%). The major product of the following reaction sequence is : (Ac, 0.ppriding sen Q— 2B. GhCo Oba oceces9 GNM, HUTS EPO: GEOH Br Br Br Br Br Br (A) () © ©) Br Br Br Br Bi cd Br Br Br 5. For the given reaction sequence, select the CORRECT statement(s) : BRRo, neva H cH —| cere, OH» p) Otomo raetytnns, CoHs (A) Pis an organomettalic compound known as Grignard reagent. (B) Qis an optically active compound having two chiral centre. (C) PQ involves biomolecular nucleophilic substitution reaction. (D) Absolute configuration of compound P is ‘R’. 6. Which of the following reaction(s) will give 1° aleohol as major product : t t Zo-He HyPd (A) CH;-C-H 288, (B) CHy-CHr-C-H EE 5 Ny NaBH. @ Bis (©) cHy-c-c1 SR (D) CHy-CH=CH, OBB 7. Which of the following statements for crystals having Schottky defect is‘are CORRECT? (A) Schottky defect arises due to the absence of a cation or anion from the position which it is expected to occupy. (B) Schottky defects are more common in ionic compounds with high coordination numbers. (C) The density of the crystals having Schottky defect is larger than that of the perfect crystal. (D) The crystal having Schottky defect is electrical neutral as a whole. Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 98896555568. Degree of unsaturation of major organic product in following sequence is : CH; , @KMn0,,NaOH/A CHs (i) dil H,SO, (@ LAI, EO @) HA ()NaCn (O° (sii) BaO, 4 9, Among the following, how many acids will undergoes decarboxylation on strong heating ? () CH,(COOH)> (ii) Oxalic acid (iii) Mellitic acid Co(COsHe)s Gv) (CH ¢-CEr-CHs-€-OH wa He-(-CHr-¢-OH (vi) (OL (vii) CH;-CH(OH)COOH CO;H ‘COpH 10. Which of following pairs can’t be differentiate with given reagent. (1) Glucose & Fructose — (2) Sucrose & a-glucose — NH) = NH-CH3 @) & —> NE, OSe NB OO = I) (3) Ph-C-CH; & Ph-CHO — & LN or ‘OH OH cHycl cl M «& — (8) Phenol & Picric acid — Br) water Tollen’s reagent NaNO? + HC] CHCl; + KOH. A Fehling solution Victor mayer test Ag. AgNO ‘Na metal Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556