naomi ye ea ns | ‘Example 20 ib ase ve bw Br a | ee bang menastonic have wask dsperon | — School/Board Examinations | = ee SECTION-&, | ‘Epa 8 ino ha oF, wa mA seer ele ofa es ‘ean: pass gaa oH NE, ‘SchootBourd Exam. Type Qestons eSchegweno onc, a ‘omen nn aan Fay stp or maa ep » "MW sham used in cing appara? bidoke Bate etree tga dee ko | rin ogo een of Coat conan HD, mom gn Tonigepearonse awa ae HHA Bhp, " nha eae ee! 8 yen. iernpon, HO,» Heo, > HOO, Satay Bom ove amen qe PT.8 Cong Exe ep ne 6 lang 8? ate Bnd nF asl ay ar oe fatton + PO hse ‘spiseo ran Feo Ho i Fo? fee Nn A p sei 18000) No epaamesenk 9, Ps tone om woos Dus ran 5) 0 Ps ot P-P (69. MHP,D er teas Sn i re cman og. tephra A invoner ‘apo, 1 apo, + Phy 7. Bans ange hw er banat cP ony hcg hh stg Mi tin. en 4 Wateper weno tere 8 hand he Mae ell mn ape viene ager ge dees AN mata co A490) + THO + HPO —s Akg + AD, + HPO, | | 8 Wahine wien? heer Them. cds ins © gh Ha nti hey of ci 10, wroteon recent Pha ae Cy Hao aid wh cnn 0H em eae ad cae Ey Th 1 at i a PO _ hte h Seen minpogambmeontocretine | |e mtg te Sat mateewenenee ace ae ees P+ 7a re a ct, as en 1 Noe Poa o> Oreeneierad — ne evmtnwnee nner frauen 2 att noe eon ies Bes [cant 7 Wy ee Phos mtag Seton: FO, © 340 why + ae Fn ae ee 10 eee ou how Das i Pves on aE\ 54 The piock Elements 6 3. Which ofthe following halides of group 15 isnot hydrolysed? ‘02 (1) NF QM, Oe: © PF (4) Both (1) & (3) 4. Brown ring tests sed forthe identification of () Pog @) Nos @) sof (4) Hoos 5. White phosphorus occurs as discrete P, units, where P atoms lie atthe comers of a regular tetra, The PPP bond ange is () 0 @ 09-26" @ & @ 0 8. Onhophosphonis acid on heating gives (1) Hypophosphorus ac (2) Orhophosphore acid (2) Phosphene gas (4) Both (2) & (9) 7. Which ofthe following is correct? (1) HPO, is ibasie and recucing ) H,P0, is dibasic and non-reducing (8) HPO, is tibasie and reducing (4) #,PO, is tibasic and non-edueing a ‘The comtect order of decreasing acidic strongth of oxyacds of group 15 element is (1) HNO, > H,StO, > HAsO, > HPO, @) HPO, > H,As0, > H,SBO,> HNO, (8) HNO, > H,PO, > HyASO, > H,S60, (4) HNO, > H,AGO, > H,Po, H,800, 8. The bond angle is maximum in @ PH, © Ast, soe, 10. When excess of NH,(aq) Is added to @ blue solution containing Cu ons (1) Soliton un 4 ut formation of Cu" ons ) Soliton becomes red de to frmaton of [Cu (2) Sctiton become deep blue de to formation of [CuNH J (0 Scluton becomes colours due to excess coloutss NH, GROUP 16 ELEMENTS cede eee en electron canaraton ra oh men cee ca JPrvor metas Seleriam (80) Towra (cro Meas Folorium (,Po|-+ Redioctve metal tale 12.8 day) Group 16 known as chaleogens, means oe fonring elements such as oxides and sulphides. i Corporate Office Aakash Tow 8, Puss Road, New Delhi-110005, Phone /o11-47629458 Sylar es J68 The p-Block Elements Board & Competitive Exams | Example 11: Name the radioactive element of Group 16. Solution: Polonium, Example 12 : Elements of Group 16 show lower value of 1st ionization enthalpy compared to Group 15, why> Solution : Due to extra stable haltfilled p orbitals of Group 15, larger amount of energy is required to remo, electron as compared to group 16. Example 13 : H,Sis less acidic than H,Te, why? Solution : "Down the group, E-H bond dissociation enthalpy decreases and hence acidic character increase, Example 14 : Give hybridisation and structure of SF, Solution : _sp%a, tigonal bipyramidal geometry and see-saw structure, ——_ Try Yourself 13. List important sources of sulphur. 14. Why is H,O a liquid and H,S a gas? 15. Write order of thermal stability of Group 16 hydrides. 16. Write properties to show anomalous behaviour of oxygen.kL 76) api Sens ses of Sulphur Ait ‘ramp 15 Wc eben orog botara7? Exon 1 Ht pve wer foerao1 se, Saws a01= 0, feaeranoeh fans rie no*s Tae reat cement hee ee ie * (Laie Mowry HO, +180, ver naaa, 2 80,9 On, sean nom psi hapa vaoyshpo. 2 a0, 21 poncho, 2 R80, $280, “icon por util eal as ed may ties, sr we ae fb rare esi sm, ont oie 1 Forte marsase tran () nsonge bats ot aos (A nay et 1 ovcsn (ony ea tn ere sete) ‘rari nro a has wo ra lern ns eta e , {8 Compete toma mada NANT FO cat + 20, — ows 3 19. Why cos 0; apm ge 20, Howls esa gutta? 21 hat bogben wen she Sate loch mse dn Ft eat | com ino Onn ee 2. How ponent 0, ca? "2 Menon Wes ae ee $0 yn Wiens cars mans yt 0b Ct i? Wy ay << hi rH? Te comet det cy ie fon ay co ote tin OMorisenses He fa woens NS? HT naan anne pom lant lo ‘tang 17: Ges aap et ote Ee Anpha odara Oates Om + 148%, — cat + ae (35 + Ho — 14804 Ot Kane oe Hee Tle eo {) Ste taper a tan 1 Seis ere xcoon ee + 040876 1 O asa dome ues Sm rr wene =n Zeon vovene mie) Souter: Aedes = 80 (0 Shae mare earnest mesa hc oth oer ptr morc) Dy 80, ea Neanious 0 oo oe ian Coarse Aakash Tove, Pie Read, how Dana 4 eS Pea oH ATES aBoard & Competiive Exams |) 78 Te pBlock Elements 14, Which ofthe folowing compounds does not exis? () SF, @ scl, 15, 0, molecules @ resonance hybrid ofthe to structure i PY >, ZN, Se (4) S08, and “The te oxygen-onygen bond lengts in ozone molecule are (0) ential (2) Sight aiferent (©) Largely diferent (@) Cannot be measured due to resonance 16. S,ring of bat hombic sulphur and menocinc sulphur has crown shaped structure, The S — S - $ bond i I'S fing is | () 10028" @ ur @) 108 120" 17. In the contact process of manufacturing of H,SO,, the catalyst used is (9 PQs 2) V0, yy ©) Ra ) NO 18. Number ofS = © bonds in pyrosuphurie acid are (1) Two @) Four @) Fre e ) Sb 19. H,S0, In aqueous medium lonises in two steps, H,SO, (aq) + H,0 ®) —+ HyO* 66) + 80," (ag), Ky, = x ok, HS0¥ (ag) + H,0 (| —+ Hy0* (aq) + SO K,, = y Whats relation between x and y? Mxsy @ } @xry @ xy 20, Whats the product wien Mg react with SO, 7 (1) go 2) Mgs0, ©) Mas 4) Both (1) & (3) GROUP 17 ELEMENTS s ‘General electronic configuration: net gas] ne2ag Fluorine (GF Chane (7): Bromine (8 ldine () Astatine (asl) > Racioactive element Collectively known as halogens (100k hao means sa ‘are highly reactive non-metal ere 7 ‘and gones means boen ie. ' lements. Great simlariy among ¢ ee eee : ty among Group 17 elements observed. orporate Offi Aakash Tower, 8, P sh Tower, 8, Pusa Road, New Deli-110005 Phan i 01447623458h ‘compe Exams (Level ‘The p-Block Elements 83 Fe i Why do halogens have maximum negative elecion gain enthy i the espetve porads Fe] perl abe? Halegens have the smallest size and high effective nuclear charge in theit respective periods. Thus ‘they ready accept one electron to have noble gas configuration, ‘pe 20; Alliough 44H of fluorine is less negative than that of chlorine, but fone Isa Stonger oxcisng | ‘agent than chlorine, wy? jon: This due to (0) Low bond dissociation enthalpy of F-F bond, (i)_High hydration enthapy of tle 21 : Fluwvine exhibits only =1 oxidation slato whereas alr halogens show +1, 3, +5 and +7 oxidation | Staes also. Explain, Jon : Fluorine being the most electronagative element cannot have positive oxidation state. Other halogens: have d ofbitals, therefore can expand their octet apie 22 : Give correct order of boiling point of hydride of group 17. Won: _HCL< HBr < HI < HE ‘Considering parameters as bond dissaciaton enthalpy, AH, and hydration enthalpy, compare ‘oxidising power of F and Cl Give two examples to show anomalous behaviour of fuorne ‘Sea is greatest eource of some halogens, comment ‘aration ) By heaing manganese dioxide with cone. HCl ing mange tno, + 4HCI 4 MnCl, + Oh + 240 ‘Nso, ANaCl + MnO, + 44,80, ——? MnCl + 4NaHSO, + 24,0 + cH (By the action of HCI on KMnO, 2Nnd, + 1GHC! ——> 2KCI + 2MnGh + BHO + So}, Corporate Once: Aakash Tower, 8, Puse Road, New DelNi-110008, Phone :017.47623456 nee Ro tetas_ #& 7 . .. © mepecngees Bett comet | esate ty 2 SE EEE] ’ wrewel Sp Bee aaA NN 3X. Nor te oe a ab 3 entre rn tn 3 ee ened nd or oan 2 Re cane nee EASA ASN ipeansareemennntennt SIS woke eo a (exes) 0 een om iy bg ae i ne & Recere wrregemret fe rye be nem te pester uF menttett werarort ve +250 — w+ SFO jycinreaeet icone fw cis tertee ee ee a Gow on co OT erm oe? ae cena: 3 + OUCH ——+ Be } HOD, + HO To an ne ow NGO = 1,614 9, 58a 7 in mr by a gen (yond @-ho tase 5 ony=1 1 om 2 Fan ent wl 10, po crest and A. Nec rer, Enact: Gooey Season!) tnentng CO, DOT, 8G oe, @ Sears orerse (0 oom Bop -| ine 0 08 (Elsewhere ray pons rn Hb rcs arte sw J Fens wit, fo frm OF, Of, WH He sae: Fe 8 Fat + (1 ggen mses eee srr ern tr 1 Artie HOF 9 oon8 5 Tn at waty ft oer 82 as, 0, 1 " ‘Bamps ts mr op BF, oe aa EPR oy ‘Seuten: Ths wo ee ae oy ca ge ore aman ttn, sala ‘Seem ope eso Ostemew ayer 8 woney wun a acne este ant "80, [CS en sane ae eas os [Fcenu covet Oh oe Pa ed 29 anno90 The p-Block Elements Board & Competitive Exams (Loy . atc. is 27. Aqua regia, which is used for dissolving noble metals like gold and platinum et 29. 30. (1) 1:3 mixture of cone. HCI and conc. HNO, (2) 3:1 mixture of cone. HC! and conc. HNO, (3) 1:1 mixture of cone, HCI and conc. HNO, (4) 3:1 mixture of dil, HCI and cone. HNO, Halogens react with oxygen to form many oxoacids, commonly named as hypohalous acid, halous acid, hej, acid and perhalic acid. The halogen(s) which form(s) halous acid is/are (1) @ a, (3) Cl, Br, and |, (4) F,, Cl, and Bry The number of peroxide linkages in perchloric acid is (1) Zero (2) One @) Two (4) Four Which is the correct order of bond length? (1) F,< Cl,
ara depatonatan eit oreclon (mc + NaNO, —9 2 The pea ames $7 soma oer 15 an a OHO, 2+ 7 mano + HS, —> 7 eos pine prepa tom tap oe fon at or manag srr an we on iy 0 nan cakzoun phen danas ane my? Gv ng ow al a ‘Symone eanien ‘rp 1 50 te thing and eng apr SO, ry et 2 Onn hws coin af me le ue Hoe oes 1 attain en? (0 $0, easoteaints0,7 Paes cae hast? Hots rte wm 0, pee HC? Osan peptone gv ts 4 EE 19 Wy yt aro ne atts 8 1 Wn equon wna ans ru oan NM aa sow cccurans ea 17 soe at ae nye nde? Ge wag a ns * care wacton 1 cao, + 0 —* tone yee a se? Boy voy eo ancora me ——en otro (0 Reese! 2h in, 2) Ren cas ie wn 4, (©) Reson un pose wth ett jgsscommmetemten upturn 8 see noe i oe wreech 8, Bre dexatenapy (oy PH, Har = sry 6) HHO, HOY MY: Baten ors HIRES? Gi hye ete How do Pr wh eg he cast nn nil ecto ae mire tg yh ea ofan ow Fa ‘erreoes eect secre cravat ot gap 1 waar tn tant rs ree oy jeg mt re + I wey I (6 yay «ne 7 © 1h +o? ‘tc, yn , er, secnoN-8 et Tee P20 ime Sor Anam Type Questo tt {Siento ron oar ‘any to uns tien as owt atcandse tenn vcunateros Copan oe ati a ee100 pone Coron Cuceton 4S a mucha Conor Wh te omg ern NO, oan aie mo, Ps hansen hag fect ae (Psp atin terreno tortie (Paes od poo 8 (0 Peon pos 2 aoerecinanetnaeas tone Fas Saeee once satain a oman, oe | sree | — (8) Boh encore ace ne nn ec IPETON PS ag portant (8) ern and ee oe to eh creeper t, (6) Asan 8 es, san 8 wy IT (0) Aen (erg tt en) cos se 5 A: Flamer an R: PP ard iy wee Dn N= Nn 1 ASH ie ei eto my wih i Aare tye ego fy eas oon gp Ans Folens Geen 8. Gvetomstbcensvomadin tome ernie 10 Ramet abr ‘Sat Anime Type Ouest: 11. Gta engin arma eh 1, Sxlantow nur show et eos. 14 as tcrsonsmnts poate tong ane Tp Gertn ee 15 Comat aire 0) cosh 0) Ce at — ep OAS STP Ra a exh ora scone) martin eH, $0 by ent gn Gi cnn exh sos cesengnd cya poe. hs sexorhincosegorrancherentrecs | gu stone i | | | (9 Ha, 10, HO, HOD Ae 1 FCs Bonddeestonspy PH Aa Se, ten pw econ [porate OMmce *aakaah Too PST= esas (Lav = ) ee (G8 1 me peg caret 9 ie tg 8 0 Re St Mc wn oy rats of 9 Sing POET A 0 te (0) Ona SECTION an 8 wae femme (8 atom | ome yo ste Sammi tet me bom gi NN (ome eee 390 cen noe acne 2c any 3 Ho, oreo annoy OER om 10, stoma | 2 OVOP oe Oe ® 8 Sn en te on] HOE, sense on © me Nepean —— lamp engeonsens 7 oe osphorus which ssohmare 12 Cengncanbe men ae, tact er | De ose eernnan a, aca a ° poss min an aa os ca } ow ee eegeese ht pene oy tee | (Ae cnten a 9 pga aoa 2 an semnae 2 messes oon tenant ne ®ve fhe fotaming N-N bond is nat) Crhophospnerc acd 1B My NONE NO, | Pyrophosphoric acid (6) NON, NPS omaeee a No 2 Otero st NNO canter 4. enol tn maces tan oy A erent mei ns eee 6 0, 1]? Sxstinan pore ras tate OT eg 1 eminer —AM«a40 +040, nore toe nen a parma] Rt hens cece tate —# Ba 6 ) nO. a] 83 eusie au 2 8004» 3 a “e PRET ase exo mge 6 ashe a [] a a ora 19 ee N, scr ah eae ns PMsan & Campsie Ee Bester tr ig aes he se nn we eemotaipecncr om amore Ye aml POR et arts otra be an a 22. Form of sulphur which sont nana aronsionn im hearer a re — Square pyramidal (1 52 gal sya peers FOO Ostia ore Sor ra oe pr 1) 6M By H>Her>HOI> HF: csc anegy | yr, DetHS 1) echere ea > Bry lpi Bond de 120, Bont T shape 16) 0 iar S HO Ber hi Banta, hobo mae enthalpy of HOF, omy represen by 9 Motte gen taemeets ae me tote act | 2. twang aon ae md ns “ee wae cn ear | Fetnponn (a HE A> He > Hs Bot pie Wheaten | 10 40, 2 Chevestnh es ,a 2 ie oy | a9, mar i Saas | as, 2 Nee © yy ts pw ersten of mat £0, wh ptm Wl ee | % Seven peso estar? ON Sinicetimmarerad | ino, ders 1. Chen radion wih cad ard dhe Nao erg nn | Garey nace 4 Game tase CERT. tH Ductemenee, Ef (1 m00 arco, | a | © mao; . ihe falcon! AP AL | Beanery io sate mpi pe ene os preps "Pea ons, ol Dh temmmanan 7 (EY nso, see ceorars Oe Siecmmene BS a 8.0, 1 Lor tnwnnain imei ms, ame ® Sscojooanrs 5 Oa peme Smita soteny OTe 5. mown ema mpeg eee (eran monet sel paar ae 1) Wo, + Heo +6, «140 22. The concer of aes sora om a8.) as 1 rn 2 HAE, +0,” worn nee oO ae 8) Hots 0; 82 cH 6 Ho 2) H00,> Hea,» 40, ‘SECTION -6 aw ch toy «90, a « payed sah i cape Brno See arti « Noam mes 2 27. The clu sown by hoe icant hen, Mot tace es cannes © & 53, Tec win smu ong ae ve oe (0 Foe (9 pec o ae aca 2 chan at AI an Ret 8) Chore acid ‘9 ye (6 Pato ss ae oA Tn PE4106) The p-Biock Elements 1 10. [Al ofthe given etatoments ae comect except INCERT Pg. 197] cease ag (2) Fluorine has higher electronegatvty than oxygen {@) Elements of group 16 have higher ionisation ‘enthalpy than elements of group 15 (4) On moving down the group, the atomic size generally increases ‘Consider the given action, Ps —X-+ PosO, ‘and X's a thermadynamically unstable compound then Xis INCERT Pg. 191], o @o% oy so, “The shape of XeOF, is (1) Pyramidal (2) Square pyramidal @) Tevahedtal (@) Octahoral “The compound in which nitrogen exhibits lowest oxidation state is INCERT Pg. 172] a) NA 2) NH, NH (4) NH,OH INCERT Pg. 210] a 1 2 43, 4 6 a Boat & Conpative Exams, he eorect order ofthe reducing sr manne pe (1) PH, ORE 1 Boh Sten ar ver a ne 47am (6 otto cot saertine — © Sp ADy + S059 Aa feeachinocner rayon reresaomng © WNW" B0y Ng 300M Soumer Meera) Za NO + yO 1 wey @Hn cron em) (ein BH HH) Bam eMeateHI HO fa aio) HIN aC EHO ti ec era day ‘Soe teansPo EI, Th HB4>F> cy sn camped gn Column Inston and shoe penn tne ao es per, ‘nae ome, (Dire tes x0, 0) Saixe one (emer, 1 Pym me, 1) Syren om @ ow om ow. » PRS a0 Ww Mw oom mw ow mo he wrt the bg aso ‘ales inte overt Hs fs He sin haher nig prt ner ea 1 Me nd any of He moo 8 ‘bomen an 2) Meet tne wen ‘nts wth poeuce pee 0 ne nem ‘entra cements ne of (© Thee eran bond te povFis toon wih OK Op aout here G40, Ha ane of poche a (royeata sent J, so ere DW LHP, ne (Rear (9 Mor oan st of rsteis sre 0 -OH QOD a on PH Os (9 Peres fo Fa rd P= (4 Hane gh ert rst } casita ag DMS 8,>4:outiegsrem | 9 Soe a Q)M>ve> Hote Aman] 9 Melee an Or rchr ens acngnay | Yet Graces -bodacoataus|? Maenpraen ogress nee 6 © made nines srceewnin:| Geaswond ea mot | ena 0) Nica 66 Leos kate nyrogen hai sc, BSF 2) Metron | we 9 pop 9m 9 oy ve 4 hatnteettoingmaaieaeten | Dein oe a Pevins* | Mtogen fom, but phosphors does nt om we Se ane ee anne ow, re 1 Treetops coat anton eitecarea to | OF -porg ea ca 4 wich of te ftoning compounds (2) bm praonding is #000 1900, °H0 ‘tbe Wp onan eal? (thigetone tence (a c0+c0, +40 ye (2) neo hen ecton i a ai? a. chancaltomsn cea om omy Base, aces ne % Wet ot tne aoming aces "|B ae tt santos 00, eee ae 20+ ce, ; ay © ao var, sant 10, ig 000 a oe Movie, vai +0, ne TE Ne Den0005 ha vo. ar8204 aa ones na RE eel122. The p-Block Elements 68. Pb + conc. HNO, gives (1) PbINO,), + NO, @) PbNO, + N,O @) Pb(NO,), + NO, @) PbINO,), +N,O 69. Which has ability to release bromine from KBr? mb 2) Br, @F, ) so, 70. Which of the following has P-P linkage? (1) H,P,0, 2) H,P,0, (6) HPO, 4) H,Po, m1 73, NEET (Leva Bonds present in N,O, are (1) Only covalent 2) Only ionic (@) Covalent and coordinate @) Covalent and ionic Which of the following dissolves in water but does Not gives any oxyacid solution? () so, @) oF, @) scl, ) so, (8) Molten KH, (4) NH