Safety Data Sheet Page: 1/9 Japan Chemical Industies Safety: Preparation / Revision Date : 29 October 2010 Product: TOYOTA Injector Cleaner especialy for D-4 series petroleum engin 1. IDENTIFICATION Trade name Manufacturer Company Name Address Telephone Number Facsimile Number Person In Charge ‘deta sheet according TOYOTA Injector Cleaner JOL-MSDS-603141 (Pin:08813-00830 especially for D-4 series petroleum engine Japan Chemical Industries co.,Lté 813, Kikkawa, Shimizu-ku, Shizuoka, 424-8568 Japan +81(64)345-3476 +81(64)347-6865 8,Ogura(Prepared by M.Matsunaga) Emergency Telephone Number: +81 (64)345-3476 2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Explosives Flammable gases Flammable aerosols ‘Oxidizing gases Gases under pressure Flammable liquids Flammable solids Self-reactive substances and mixtures Pyrophoric liquids Pyrophoric solids Self-heating substances and mixturés ‘Substance and mixtures which, in contact with water, emits flammable liquids Oxidizing iquids Oxidizing solids Organic peroxides Corrosive to metals HEALTH HAZARDS Acute toxicity (Oral) Acute toxicity (Dermal) Acute toxicity (Inhalation: gas) ‘Acute toxicity (Inhalation: Vapor) Acute toxicity (Inhalation: Dust) Acute toxicity (Inhalation: Mist) Skin corrosioniiritation Serious eye damage/eye irritation Respiratory Skin sensitization Germ call mutagenicity Not appiicable Not applicable Not applicable Not applicable Not applicable Category 4 Not applicable Classification not possible Not classified Not applicable Classification not possible Classification not possible Classification not possible Not applicable Not applicable Classification not possible Not classified Category 6 Not applicable Classification not possible Not applicable Classification not possible Category 2 Category 2A Classification not possible Catagory 4 Classification not possibleSafety Data Sheet Page: 2/9 ‘Japan Chemical Industies Safety deta sheet according JQLMSDS-50314 Preparation / Revision Date : 29 October 2010 Product, TOYOTA Injector Gleaner especially for D4 series potroloum ongine P/N:08813-00630 Carcinogenicity Category 2 Reproductive toxity Classification not possible Specific target organ toxlity-Single exposure Category 1.2.3, Specific target organ tovicty-Repeated exposure Category 1,2 Aspiration hazard Category 1 ENVIRONMENTAL HAZARDS Hazardous to the aquatic environ ment—Acute hazard Category 2 Hazardous to the aquatic environment—Chronic hazard Category 2 Pictogram Signal word Danger Hazard statement Combustible liquid May be harmful in contact with skin Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction ‘Suspected of causing cancer ‘Causes damage to organs May cause damage to organs May cause respiratory iritation; or May cause drowsiness and dizziness. ‘Cause damage to organs through prolonged or repeated exposure May cause damage fo organs through prolonged or repeated exposure Toxic to aquatic ite Toxic to aquatic ife with long lasting effects Precautionary statement [A safety measure] Wear protective gloves and eye/fece protection. Keep away from flames and hot surfaces. ‘Wash hands thoroughly after handling, Avoid breathing mist vapours. Contaminated work olothing should not be alowed out of the workplace. Obtain special instructions before use. Do not handie until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, dtink or smoke when using this product. Do not breathe mistvapours. Use only outdoors or in well-ventilated area. Avoid release to the environment. [First-aid measures}Safety Data Sheet Page: 3/9 Japan Chemical Industies Safety deta sheet according JOLMSDS-60314 Preparation / Revision Date : 29 October 2010 Product TOYOTA Injector Gleaner especially for D4 series petroleum engine PIN:08819-00630, In the case of fire, use carbon dioxide / powder extinguishant / sprinkling / ‘alochol-tesistant-related fire foam for fie extinguishing, The stick flooding adds to danger. Call a POISON CENTERidoctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap end water. ‘Take of contaminated clothing and wash before re-use, If skin iritation or rash ocoure, seek medical advice/attention, IF IN EYES: Rinse cautiously with water more than 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing, if eye irritation persists, get medical advice/attention Wash contaminated clothing before reuse. IF exposed or concerned: Get medical attention/advioe. IF exposed: Call a POISON CENTER or doctor/physician, Call a POISON CENTER or doctoriphysician if exposed or you feel unwell IF INHALED: Remove to fresh ait and keep at rest in a position comfortable for breathing. Get medical attention/advice if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctoriphysician. Do NOT induce vomiting, Collect spillage. [Handling and storage] ‘Store locked up, Store conlainer tightly closed in coolwell-ventilated place. Keep out of reach of children, [Disposal considerations} Inthe case of the disposal, please confirm local disposal regulation concerned by all means. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical nature Polyether amine in solvent naphtha ‘Composition ingredients Component wis, CASNo,__ EINECS No Poyether amine 70.0~80.0 Confideniial + ‘Solvent naphtha, heavy aroma, 20.0~30.0 @4742-94-5 265-1985 Hazardous Components Chemical name Wi% __CAS No,_EINECS No__Hazard symbol _ R-phase Payether amine 70.0~80.0 Confident * N R563 Sdlvent naphtha 20.0~90.0 G4742-045 265-198-5 XN R5AN53,R65 REGRET 4,24-Timethyl benzene 0.8~1.3 95-63-6 —202-436-9-XnN RIOR2ORIEII7IOB, 4,3,5-Tiimethyl benzene <1 108-67-8 203-6044 XN RIORI7RSA53 Naphthalene 18~2.7 91-20-38 202-048-5 nN R22RAO.RSOISS * :Polyether amine is in compliance with the EC Seventh amendment Directive 92/32/EEC, The wording of the hazard symbols and R-phrases Is specified in chapter 16 if dangerous Ingredients are mentioned. 4, FIRST AID MEASURES General advice:Safety Data Sheet Page: 4/9 Japan Chemical Industies Safety data sheet according JQI-MSDS-6031-4 Preparation / Revision Date : 28 October 2010 Product TOYOTA Injector Cleaner ospecially for D-4 sories potroleum engine P/N:08813-00830 Immediately remove contaminated clothing. If inhaled: If dificulties occur after vapor has been inhaled, remove to fresh air and seek medical attention, ‘Skin contact: ‘Wash thoroughly with soap and water. Get medical attention if irritation develops. Contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. IFinitation persists, get medical attention. On ingestion: DO NOT INDUCE VOMITING. If conscious, attention, ive 2 glasses of water. Get immediate medical Note to physiciant Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 6. FIRE-FIGHTING MEASURES Flash point: 66 degrees Celsius Suitable extinguishing media: CO,, dry chemical, or foam. Water can be used to cool and protect exposed material, Unsuitable extinguishing med water jet for safety reasons Firefighting Procedures: Wear full protective fire-fighting gear including self-conlaining breathing apparatus operated In the positive pressure mode with full-ace coat, pants, gloves and boots, Water may cause spiattering Unusual Fire & Explosion Hazards: Toxic fumes, gases of vapors may evolve on buring 6, ACCIDENTAL RELEASE MEASURES Personal precautions: Personal protective equipment must be wor, see Personal Protection Section for Personal protective equipment recommendations. \Ventilate area if spilled in confined space or other poorly ventilated areas. Environmental precautions: Contain contaminated water waters/groundwater. Methods for clearing up or taking up: For large amounts: Pump off product.Safety Data Sheet Page: 5/9 Jopan Chemical Industies Safety data sheet according JOL-MSDS-6034-4 Preparation Revision Date : 29 October 2010 Product: TOYOTA Injector Cleaner especialy for D4 ries petroleum engine PIN:08813-00830 For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. HANDLING AND STORAGE Handling if No special measures necessary provided product is used correctly DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. ‘Take precautionary measures against static discharges. Keep containers closed when not in use. Do not discharge into drains or the environment, dispose to an authorized waste collection point. Use appropriate containment to avold environmental contamination. Wash thoroughly after handling. Storage Further Information on storage conditions: Store ina cool piace. Protect from direct sunlight 8, EXPOSURE CONTROLS/PERSONAL PROTECTION 3 Other Exposure See Hazardous Ingredients Section for any applicable exposure mits for components. Ventilation Procedures: Use local exhaust ventilation to control mists or vapors. Additional ventilation or exhaust may be required to maintain air concentrations below recommended exposure limits. Personal Protective equipment Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) - 0.7 mm coating thickness Polyethylene-Laminate (PE laminate) - ca, 0.1 mm coating thickness Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 20 minutes of permeation time according to EN 374) nitrile rubber (NBR) - 0.4 mm coating thickness Manufacturer's directions for use should be observed because of great diversity of types. Eye Protection: Safely glasses with side-shields (frame goggles) (EN 166) Respiratory Protection: Respiratory protection in case of vapor/aerosol release. Body protection: Body protection must be chosen depending on activity and possible exposure, 9. apron, protecting boots, chemical-protection suit (according to DIN-EN 485).Safety Data Sheet Page: 6/9 Japan Chemical Industries Safety data sheot according JOLMSOS-5031-1 Preparetion / Revision Date : 29 October 2010 Product TOYOTA Injector Gleaner especially for 0-4 serlas petroleum engine PIN:08613-00630 General safety and hygiene measur Hardie in accordance with good industrial hygiene and safety practice, Wearing of closed work clothing is required additionally to the stated personal protection equipment, 9. PHYSICAL AND CHEMICAL PROPERTIES Form liquid Color yellowish-brown Odor ‘ammonia pH Not determined. Botting point 2180 degrees Celsius (at Solvent naphtha) Melting point Not determined. Flash point 66 degroes Celsius ‘Autoignition temperature > 400 degrees Celsius (at Solvent naphtha) Explosive limit in air between 0.6 and 7 vol% (at Solvent naphtha) Vapor pressure Not determined, Density 0,042 glam? (16 degrees Celsius) Solubilty in water insoluble Viscosity approx. 63 x 10 m’/s (25 degrees Celsius) 10, STABILITY AND REACTIVITY Stability Material is normally stable at moderately elevated temperatures and pressures. Decomposition Temperature: Not determined, Incompatib Strong acids. Strong oxidizing agents Polymerization: Will not occur ‘Thermal Decomposition: ‘Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete ‘combustion. Ammonia may be formed on burning in limited air supply. Propylamine, polyalkylglycols, and aliphatic alcohols may also be released. 11, TOXICOLOGICAL INFORMATION Acute Exposure Oral Toxélty: ‘The LDS0 in rats is >6000 mg/kg at Polyether amine). Based on data from components or similar materials, ‘Swallowing this material causes severe initation of the mouth, esophagus and stomach. Eye Iritation: May cause eye irritation, but will not injure eye tissue. Skin Irfitation: Not expected to bs a primary skin iritant. Based on actual data.Safety Data Sheet Page: 7/0 ‘Japan Chemical Industios Safoty data sheat according JOLMSDS-6034-4 Prepavation | Revision Data : 29 October 2010 Product TOYOTA Injector Cleaner especially for D- series petroleum engine PIN: 13-0830 Dermal Toxicity: The LDso In rabbits Is > 2000 mg/Kg (at Polyether amine). Based on data from components or similar materials, Inhalation Toxicity No data available to indicate product or components may be a tonic inhalation hazard. Respiratory Iritation: May cause nose, throat and lung iritation. Based on data from similar materials. 12, ECOLOGICAL INFORMATION Environm 4 Freshwater Fish Toxicity: ‘The acute LC5O Is 1 - 10 mg/L. based on actual data (at Polyether amino). Freshwater: Not determined. Invertebrates Toxicity Algal Inhibition: The acute E050 is 10 - 100 mg/l. based on actual data(at Polyether amine). Saltwater Fish Toxécity: Not determined. Saltwater Invertebrates Toxicity: Not determined, Bacteria Toxicity: Not determined, Miscellaneous Toxicity: Not determined. Biodegradation: This product shows limited biodegradation based on QEOD 301-type test data for similar products Bioaccumulation: This material displays no potential to bloconcentrate. Soil Mobility: Not determined, 43. DISPOSAL CONSIDERATIONS Must be dumped or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packs can be re-used.Safety Data Sheet Page: 8/9 Japan Chemical Industries Sofety data sheot according JOLMSDS-6031-4 Preparation / Revision Date : 29 October 2010 Product, TOYOTA Injector Cleaner especially for D4 ries potroloum engine PIN:08813-00830 Packs that cannot be cleaned should be disposed of in the same manner as the contents, 14. TRANSPORT INFORMATION Land and inland navigation transport (ADRIRID) UN No. 3082 Transport document name ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID.N.O.S Class 9 Packing Group m Marine transport (IMDG) UN-No. 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID.N.OS . Class 9 Packing Group 1 Marine Pollutant applicable Air transport (ICAOJIATA) Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID.NO.S. UN No, 3082 Class 8 Packing Group 0 48. REGULATORY INFORMATION Regulations of the European union (Labeling) / National legislation / Regutations Directive 1999/45/EEC (Preparation Directive’): Hazard symbol(s) Xn Harmful N Dangerous for the environment Rephrase(s) R37 Iritating to respiratory system. R653 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmfut may cause lung damage if swallowed. ROS Harmfut may cause lung damage If swallowed. R87 Vapors may cause drowsiness and dizziness, S:phrase(s) $23 Do not breathe gas/fumes/vaporispray. 824 ‘Avoid contact with skin. ‘836/37 Wear suitable protective clothing and gloves. Bt ‘Avoid release to the environment. Refer to special instructions/Safely data sheets. S62 IF swallowed, do not induce vomiting ; seek medical advice immediately and show this container or label Global Chemical Inventories EU ‘All components on EINECS. USA All components on TSCA Inventory or exemptSafety Data Sheet Page: 9/9 Jepan Chemical Industies Safely data sheet according JOL-MSDS-6034-1 Preparation / Revision Date : 29 October 2010 Product: TOYOTA Injector Cleat ally for D-4 series petroleum engine PIN:08613-00830 Canada All components on DSL. Japan All components METI. Australia All components on NICNAS. Korea All components on ECL. Philippines All components on PICS. China All components IECSC. 16. OTHER INFORMATION Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 2: Rephrase(s) Rio Flammeble R20 Harmful by inhalation, R22 Harmful if swallowed. R96/37/38 Irritating to eyes, respiratory system and skin, Rao Limited evidence of a carcinogenic effect. RAS May cause cancer. R46 May cause heritable genetic damage. REO/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. ‘The information contained herein is based on the present state of our knowledge and does not therefore guarantee certain properties. Recipients of our product must take responsibilty for observing existing laws and regulations.