SOLUTIONS CLASS -

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Q-1 Multiple choice questions-

i. On mixing 20 ml of acetone with 30ml of chloroform the total volume of the solution is-
a. < 50 ml b. = 50 ml c. > 50 ml d. =10ml
ii. In the following diagram point ‘X’ represents-
a. Boiling point of solution
b.Freezing point of solvent
c. Boiling point of solvent
d. Freezing point of solution
Q-2 Ques/ Ans-
i. Identify which liquid will have a higher vapour pressure at 90℃ if the boiling point of two liquids A and B are 140℃ and 180℃
respectively.
ii. State Reoult’s law for a solution containing volatile components.What is the similarity between Reoult’s law and Henry’s law?
iii. Differentiate between ideal solution and Non-ideal solution.
iv. What is meant by positive deviations from Reoult’s law?Give an example what is the sign of ∆mix for positive deviation?
v. How is the vapour pressure of a solvent affected when a non-volatile solute is dissolved in it?
vi. A solution is prepared by dissolving 10 g of non-volatile solute in 200g of water.It has a vapour pressure of 31.84 mm Hg at
308 k. Calculate the molar mass of the solute.
vii. Vapour pressure of water at 293k is 17.536 mm Hg.Calculate the vapour pressure of aqueous solution when 20g of
glucose(molar mass=180g mol-1) is dissolved in 500 g of water.
viii. Calculate the ,ass of ascorbic acid (molar mass=176 g mol -1) to be dissolved in 75 g of acitic acid to lower its freezing point
by 1.5℃. (Kf =3.9 k kg mol-1)
ix. A 5% solution (by mass) of cane-sugar in water has freezing point of 271k. Calculate the freezing point of 5% solution(by
mass) of glucose in water if the freezing point of pure water is 273.15k.
(molecular masses: Glucose C6 H12 O6 : 180 amu ; cane-sugar C12 H22O11 : 342 amu)
x.Some ethylene glycol , HOCH2CH2OH is added to your car’s cooling system along with 5 kg of water.If the freezing point of
water glycol solution is 15.0℃ , what is the boiling point of the solution?
(Kh=0.52 k kg mol-1 and kf =1.86 k kg mol-1for water)
xi. For a 5& solution i=of urea(molar mass=60g/mol).Calculate the osmotic pressure at 300k. (R=0.0821l=L atm K-1 mol-1)
xii. Calculate the boiling point elevation for a solution prepared by adding 10g of CaCl 2 to 200 g of water.
(Kb for water=0.52 k kg mol-1 , molar mass of CaCl2 = 111g mol-1)
xiii. a)Why is boiling point of 1M NaCl solution more than that of 1M glucose solution?
b)A non-volatile solute X(Molar mass= 50g mol-1 ) when dissolved in 78 g of benzene reduced its vapour presure to 90%.
Calculate the mass of X dissolved in the solution.
c)Calculate the boiling point of elevation for a solution prepared by adding 10g or MgCl 2 to 200 g of water assuming MgCl2 is
completely dissociated.
(kb for water = 0.512 k kg mol-1 , molar mass Mgcl2 = 95 g mol-1)
xiv. 3.9 g of benzoic acid dissolved in 49g of benzene shows a depression in freezing point of 1.62 K. Calculate the Van’t Hoff
factor and predict the nature of solute (Associated or dissociated)
(Given : Molar mass of benzoic acid = 122 g/mole , Kf for benzene=4.9 k.kg/mole)
xv. a)Differentiate between Ideal and non-Ideal solution.
b) 30 g of Urea is dissolved in 850 gm of water calculate the vapour pressure of water for this solution. If vapour pressure of pure
water of 298k is 23.8 mm of Hg.
Questions – (UP board)
i.A sample of H2SO4 is 94% (w/v) and its density is 1.84 g/ml.Calculate the molality of this solution.
ii. At any temperature the vapour pressure of a solvent is 0.416 bar 0.5 g of a non volatile non-electrolyte solid was dissolved in
42 g solvent (molar mass=84g mol-1) the vapour pressure of the resultant solution was found to be 0.414bar.Calculate the molar
mass of the solid.
iii.The vapour pressure of two liquids P and Q are 80 mm and 60 mm respectively.Calculate the total pressure of a solution
obtained by mixing 3 moles of P and 2 moles of Q.
iv.The boiling point of pure acetone is 56.38℃.When 0.707 g of an organic compound is dissolved in 10g of acetone, there is
elevation upto 56.88℃ in boiling point.What is the molecular weight of the compound? Molecular elevation constant (kb) for

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acetone is 1.76 ° kg mol-1
v. A solution of glucose containing 0.45 g in 250 ml water was prepared at 0℃what is its osmotic pressure? R=0.0821 l
atm/k/mol.
vi. A solution of urea is 6% (by mass).Calculate the mole fraction of urea and water in the solution.
vii. Calculate the asmotic pressure of 5% aqueous urea solution (w/v) at 27℃ molecular weight of urea is 60 g/mole (R=0.821 L
atm K-1 mol -1 )
viii. Freezing point of a 5% (by mass) of sugar in water is 271 k calculate the freezing point of 5% (by mass) solution of glucose
in water , if freezing point of pure water is 273.15 k.
ix. Define Osmotic pressure. Establish a relationship between osmotic pressure and molar mass of solution.
or
What do you understand by osmosis and osmotic pressure?