PYQ Sourabh Raina Aldehyde Ketone and Carboxylic acid a a { Abdehde , ketones and Cosbonied. 7 Very short amsioer type qnesteovsl (Monts? oumcl” 4) G1 Waite He Tupac mame of He Comp (2ol4 -CtH | cu ce cH G . | ° - ‘ -2-One ee cae eu dbvoxy pena OT | ing CHy-GH -cHy | $ OM aut of He Sobeaningreatior (aor) Or Nate Be pro 5 @ ual CHC HE CHE © nH,0 Avs CHy- CHe CH“ CHOa3 = = — 22 7 ———s How Com you conat tHe foLhouneng Acetone ho e Avs Q : me S C2030? fobs : 1 nc | CHy- E-CHs ARMY, Cy cu-CUs HO" amp “2-1 | Prop exe gzore) propanca-0f Cy cke He . fam pene oi «Ne stuctue 4 com ounce A anh B y ©, cack of, following reartion gic ol : i = A Hs? B (2014) | Ans CuCHs cok CpoH i Iedurhol uot, (F | = | Potar,cum as potamivm 4, Bengotcadtet:(os Arrange te followin bn mnreaatng order 4 ie oT -y menbioneot HCO : © CH,COOH , (2CH,COOH, FCH, COOH CALS on te) @ cco, CH,CH,OH, ch,’ cH, CH, CBouting po root c F | } Wolf- kisGner nedution ® a sean Ans @ Wolfs: wishener seduction ~ aedels chad ng wont KOK im Righ woidin | ek wk ‘gag om | B got a als os le g HL NHe, ae cH, CH Cu e- 4 ne’ ad ae NN Ha E pie et pee chamal > eR O Conniz2 2 ann sean peotebyd es a oe H aton ouch ako and Keduho feabmenk We | undone s bh 2 | vance OBESE H | : jee cot See pede ko —> Hee | 4 ‘ i inetane 7 formeltelate acook Potassium feimateon Auount pr the fotbo y | Giz otfowen: OMe product: im the julbnotng reaction et cooNa (a0 +NaOK —ZB Oéave sumple test £0 disbinguthe bebateon gottowserg nich oon PRowe paws 4 compounds : Benzo a @) oona oo = ae ) 2Z +NaoH —_Z> 7 Decorbonytaton Benzene Ae diam itentnnate, solic n Cone | acalt Ho | cooH > - = co. co + NaHCs wo ELber esCeule | © Reackon Ww hero’. Phenol. +NahCo, >No aeaton BeySourabh Raina re ole A ceoumt hot. the following © CH,CHO & more seackve soarkion with HCN - Haan CH,COCHs, towards @olw) | © There one tao NI, qoups in semicorbaziole CANNHCONH,) Howey er only, one & myoluedk tw formation f rE AINE a1) j Ars Tue ele tron releasing mothyk yo in CH,COCHS, Rindes approaek of Nucteophale omc He se dule cle tnphibicity 4 conbong® gpomp- oF Ey G29 SNE @ Semécorba, the Bos fotlowin sogonante due to dledion wihkdraw eng patna of 08D gg. ae on Ni fain coryegabon i R ay = Lone Gi Lone P NAS CHR Seu Co gmp" soa NH, > Rogonamie oo. ee : e i ———— = Involvedk in fermen” ore aa eeePsi te Keoson fm the follastng staloment ) OBengote acto doesnot undergo pueda waft eation © Oxtclation of, aldehyde t Grater thom hak a keeone Czo» ancl. re cakalyse Ars O Canboxye qronp ts deakvatong etsbonded to cor boxy? aBumerium cRlacde Lewis 062099 goup- u coo ® p- c=0 pee R : cont Oum of wome carbon Gy dba, ee ediseke withonk Leanage Cannot be onthe -carbon honk. Thus onidotonh abehelesche & easter, thar \ Ketone - | | || Ao popaldeyde b> Les rcartite. Cham prepare es enucleopialy addition eartion : . @ Y-N swbenzore occ 4 a. stvonger acid Ham art ee Aw © The polasity of He coxhonge qowp Ry aeducer ww Aono hgte due fo, sexonomie 4 7 CHy-CH,> o=3. oH cy “Ta ben palaekade coulon 25 Con bon: the cs oe A GIS Cave season fea he fo Llowing staloment beLomes = i atarked 10 ber zoe in nature anc A Coo™ © Tn uenvtobenzod ack, Nog ncéck Gi is eedaon worchdsaustng Ciabline the tonngate boxe," gov Coo” | | | ‘DH = => : l - aut foie M = Nb3. haePea — ——s Ol6 i of He 4otlor O16 @ Waite product of the fabbowtng seaction. © (20lt) +HON @ ave cBomicak test sa ua between a -2-Ohe following por of compounds B Ans | (he = Ci. “pobenamove % conn hy len | ohexamone © Butanak Abela y pees cLikesont Dy Toblen's Rangkese CH,CHCHCHO vaca’ +00 2 | putonak CHSC - 1 ',CH,CH, Cod +2034 +2RO+NH, SBvrmninatIF pane Be follow ed @ Autgtation O pldolemndenaotion (OIE? se — Tao dturhion of, ace yh grauplts Ars © Acekylaton tegen acticy obviole: C = Fe cam be done by acct H,co)> Na + CMs wow > oc igh ands a tyes 1c Foxerg 2 a gets, One ne x 4 8s agteabi = pita dc ene 4 diknte ap! p Ryda kere ot ee Chet) >= con 2 rg dk Naow 9) oon Ch e-# ee at A ea os io oe ao ; é Aldel Cgc CHEMO But-2 ew es eeeSourabh Raina GIS How will you convert he foLlowtng im not anne tam Luo Step> - (aolp © Acetophenone te berets aa! phenone Ranote 008 O Etramote octet. #0 2- Ryauory “4 A Rc coona Vie An O aoe oe = Nook + 72. =) oe Fodofyer fy Aik acebopbenine Benzo ae © Ue, | Rec P cH Coo. Cy ee ke pinplaelsonatemse Etkomote ocfet a | Nao | Ou -CH,-C 00 lu | ae Ryans ethamore oud |1a Complete, He following tation. Oo 2CgHsCHO Conc kok (gold) CHO nos /H, S24 ® ee CJ trade HOH cook _donkoH , ° gy oe wo let Ben: sengitabatet Praia benpoa te oxaalyle CHo © cHo HNO, /H,SO4 = : 273-283k ae No, neNutio benzalleRde |‘ee ca 620 Draw He stuchure of, tee {ylloving - | © p- Moshe benzaldehyde | © Y-Meshytpent 5: en- Aone (20189 | ao cHoO | 2 pzmeth benpalceelrde CH, |; ° t CHy 6 AO e- GH3 - cH uchaeshyppead oe aor8eal Amsamge Le pol in prenige nder of How ce 5 ia for oO Ethamok, oS » opens ch os wane, l phahi Ou Nubobenzoie oor, Benzo oe 3" es y-methory benpole nck. eat son gh) g Ars CHy-cH,- EH 5 G2a ® How con you disiong akb a pana. L ne @ diaw shuctme of He following dainotwe fa etal of ethanok (0) Cyomoliydin of Ggdobrbowen’ WUeriac one, cle rent oe + _ oh” _.cuiccoe * 2A a | OW" _.cHy¢ zh Ch chase * 2cAgCNHsI . er 4 OUT NA HLS) oo go ou © cH e%2 + Cals? <— | 4 HON? a cH, DH | ¢ whoo 7° 0H ogrhob' ne cytobubomone i Hs | : Homfacekal of tkarel | Gyamobyasie- ™ - Ga4u Convert He followin (2022) O Benpote avid to benzaldehyde © Propamol to 2-bomopapanois nocd CHO @ Acetaldehade he brd-2- Arn © cGooH gee | _ sola, aw pa/ Basen pon aldeRyee Berpogp chlaide O cucr-cr,-0 wcities cnc — Sie CHa CH,-| u sue Oho . ae a DH O (g-bemn pO Cs 7 ® cut 2 eer ee” CH,-crH Heche H 9 Cu, Se Sinn Etkamol | fa CH-cH ech ~CHE : But-2-enakOas a alkene A wh wobeouLer frmula CcoHio on Cz0ne yb nes a mixture d Compounds Band C- Compound y B gives postive Febling test and ali veal with. Todune 1 amet NaOH 4o@udann. - Compound C dows mot give FeRben gobubion kost bre futon Lodo firm: Thentgy fre compo B anaic —Cgolad Ax Compound 5 > f Bling test 9 Ar, Compound B a o> To dof sim test chy Aeoeabachyp 0 t ° Compoimd <> No eee > cn t-cn, Aetore: Ww 3c + CH, CHO | cH ° 3 = CH- > | Tee cH CMs Zn on chy +2n0 gemetylnre-2-2ne faaB26 “Waite 7 shunctine tompo A, ; of “pr ound B amd C on Cok of © as Maldigelio a OO — oC | @Snh/He , en Boe Gop oe @ CH,CN Oo > A Ba an (Se Oe a = Ol Ah Ne Nao @ cHcn ees os CH,cHO om @ Hot CH,- Heo chy -CHo wold h \4 CH, CHeCH-CHD But-2 enc92% © WRek Ul undago foul nucleophile addition vention Acotab de : ‘ebarine mu eophihic. addition seation O Whot & composition of Fehbing's seagent: © Draw anger of te Berni conba one of Ofhamace (2022? Ars © chang cup riecn, ce on tents Bindernite ntdelyte use 60 Sr aD carbon mae jetrophhat. © wo seporate solution, pehling solution nA Aapeous Copper sub sulphate Aakolire sodisum Febhing rolution (37 2 pean Cnt Oe ° = ees WU, -C =N- NH-C— CH, = ay HN NHC MT cH, 4 NH-E-NUL. | Semicarbazore & ethanal Hu Etkomoh SemiconbazidleSourabh Raina 528 ete He main produ in he. Go blaring neartow © 2CcH, cow + (CH, CA © cH,ce,che ancy) [love Xt (gor) 1 CH 7 zor. © peonnsnet OE O° CH city Ce =, Art @ gcuycoe + (Cts! ie Peopanone ® ca cw- on zncig) Jeoneth CH, CHL cHs + He “emmenson-sotbattibr Propane ® yet eon <> ane Pecan borep ohm Clo Rercmnegaa Tio moles of organic compoumal Aon Aneakmrent | we Strong bose gives Luo connpounds Band. Compound B on deh dogenohion. we, Gr give DB whhe acideh cation Of c yi con bon ylie aciel ‘p wth owoeculor fanmule. of CH, 0,. Thontiby the compounds A By C and D am Wh alk heme cok seation inVvo aoa an mokecuter formula BP i CHO, , thus D's fuesteetieuy * ° ° 0. wa pt obtamed. by adaptation $°S Cooter geet) ate C2013) NaOH , CHoH + HCooNa, pmnsahe 2HCHO — Meth Sodium f Vo |» | HCHO - Formabdehyte eea 030 Yow tout Weal cyt the followin convesior | OR Sieh le i | ® = ne a Ppnawckophonone (2029) | © Benzere fm" H,CoDH dvs CH.OK che guien Fo AS oh, a O we : lee Phen re enol’ on a i: Hy S24 Cu-cH= CH Paopene TS GoCHs oCHs, CHscow HN, H, S04 i i (Dp) wanna leg NOw Benzene ome ndanacatnph enone |r B31 @ Waite stu cture 4 oxime of acetone © Thonkifg At d si _— CHcooH pes, 4 Me[Ph bass, p Sate e = | [eaeus” | aus Cy : oe Oo CB y=0 +t NH-OH | =o is ace | coe Hydawnefomite “"V° erie asters | (p Cl,coon pas, cxncoe eee cutew ane | Epromnit, Acct xpcbtaide abe CH CHCHOHK Propane | EthanekO32 ° 332 An Og amic compound A foxtng Hie mnoleculon fowmula CsHgo on theotment with Gu at ST3k give B. B doesnot seduce Feb Ging's gobuiion but give a yotbo prectpit ate & He compound ‘c’ wth Tz /Na ou . peduce He sbuctur ¢ A) amaC- CQ02> Ars ., A» Moeculor fomula Cee? aeons = Agdehade a ketone (B) 1 Treakment Wu Cu [Ss #3! Cabtobel> => B 7 Does not Kode Febhing splution 9 ketone — Todefom = cH) A> CH GH-CHs ow ae | See Naou!T, Ci CH-CH, area” cH, o-CH, NAOAT™S ChycooNa tCHIs ou ° Yeblos ppe033 Explain hy © canborye growp bn © Sodium pisnbpbate ts used in punfication of eae _ ZmMoxb> 4 Benzow oxtd. ts meta oliectin ArS & Resonance | Benzow ait £2, 0 as Lo O~.-0¥ ou,” ei c A i a 6 C3 eh | ie WW ( = eo | Coxbonybic. romp im bengote actol at as aking deativaking and mek dwocking groupy | O33 Explain thy O Corboryl gromp fe Benzore axtd is meta. olnrectin © Sodttinm bisnbp hike ts wsed: in icocbion. of aldehyde er prsinction toed 0 Ase 2Mone @ Noe 4Naso, = eat 080, 44 2 / 3°57 0H Bisuophite addition pres eatloe) the bisnlphate addtion product ts water solubhe - amd coun be conv ered back by Hoe whainak corbonye a avid babe torapo umd. by beating & Vth cbluke, rain nal O44 Therefore Mese OAL useful fr purficabion ¢ alchoFade aud ketoneO34 & hive ackomical Lest ustingulbhe betiseen ethama amd etkamote oof” 10) Why & Hen Aydnogen % aldehyde amd ketones = QoL acidic. im natue % C 2M onle) Ans © Sodium beconbonate 8° * Lthanote aot of ~ Babsk efpAvesconce of (0, gos does not sone with NaHCos Ch,covney + NaHCOs oo — CH, C00 Na Co4 +c Gt | +H,ple> Ethano£O34 & ive a homioak Lest t distinguish between ctamak andethamoic acted” OWhy t% He x Ay drogen o aldehyde and. ketones ov ackdic in nasne ®% C2M ols) Ans Op The x Ry olsogen of abdebyde amd kekone ane ackdic due t presence % Contonyl giovp Haak Kos a Strong efevaon withdrawing fps: | @ Resonane stabibsation o% the amkon aemoyal o, <- Rydogen ; 2 5 ey ee Seb ees co Conjugate boss homed aftr Ml a/ O25 An organic compound. A with, moleculer formula Cue Undergo oot ol Fy doolysis fo fom duo compourndl Bamdl c- oxttadion af C with actalepied. potassium. Db» permamgamads produce 6: Sodiiim &014 Bon Reating >Monls | DU soda Lime gives methane =" | OD Identify AB ama © : eee © ontg Banke week fos hago. boing pom tO Ars Ehamote atk - CH, cooNa Nanil , cHy tNa,Cos He _kisindue CH,CoDu CH, CHOH ©) Kt CH,CHLouW | CH, C00C, Hs + H,9 ———> cH,coot + CHs Lo Ete awkake A> CH, C000 He Eta? auctate Be CH Cook + Ethanol oud C7 CHOW > Ethaw?.3S An organic vorapounc A with, mnlecnLar formula Cute 0, Undergo occ ol bydoolysis fo fom tuo compound. Bande oxtolatan of C wth. ackolepiec potassium 2023 peamamgamate codute B. Sodium BOLE & Bon heaterg 2M onl Dh soda Lime gives methane © Tdonbify A,B om © ; ifetidlates © ont Bamae Bick Bos Righn boiling pom ron Ars BrEmomow acta Bos Rigbe. boiling point thom C CE ton) Likanote ack ck Fave mie extensive H- bonot = Most con bonybe ak exisc os dimer ba VO pour phase - oe zo- - HO | chy ce So tH, No H-~-o% toot