Safety Data Sheet in accordance with - ARCHROMA,.” Regulation (EU) No.453/2010 ete Trefix MSW fla Page (9) ‘Substance key: HOE33. . Revision Date: 24. 05.2015, Version: 2-07 EU Date of printing: 24.02.2016 aarees otherwise in wilting. Any existing intellectualindustral property rights must be observed. Ov to possible changes in our products and applicable nationa) ang international regulations and laws, the tus of our products could change. Material Safety Data Sheets providing safety precautions, that Skbuld be observed when handling or storing Archroma prodvcts, Ae ‘available upon request and are provided in compliance with applicable law, You ‘Should obtain’ and review the applicable Material Betaty Data Sheet information before handling any of these products. For additional information, please contact Archroma. .a ~ Safety Data Sheet in accordance with Regulation (EU) No.453/2010 Lire ewwaweee : Trefix MSW fla 7 Page 10) SUT Version 2-070 Revision Dale 23052015 Date of printing: 24.02.2016 SECTION 1: Identification of the si comanvancenanaa ubstance/mixturé and of the 1.1, Product identifier Trade name Trefix MSW fla Material number: 155335 1.2. Relevant identified! uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture Industry sector : Textile processing industry Type of use Textile auxiliary 1.3. Details of the supplior of the safety data sheet Identification of the company ‘Archroma Management GmbH. Neuhofstrasse 11 : 4163 Reinach, Switzerland Telephone no. : +41 61 716 3401 Information about the substance/mixture Product Stewardship +41 61 716 401 e-mail: PS.MSDS-Europe@archroma.com 1.4, Emergency telephone number +49 69 2222 5285, +33 17211 0003, +39 0236042 884 (24 h) SECTION 2: Hazards identification 2.4, Classification of the substance or mixture Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended) Not a hazardous substance or mixture. Classification according EC Directive (67/548/EEC or 1999/45IEC, as amended) “The product is net classified as dangerous according to EC directivesithe relevant national laws. . 2.2. Label elements CLP regulation (Regulation (EC) No. 1272/2008, as amended) Oe oo ig substance or mintue, The product does not require classication and labelling as hazardous according to CLP/GHS. 2.3. Other hazards No additional hazards are known except those derived from the labelling.ce _ Safety Data Sheet in accordance with ARGHROMA, ~ Regulation (EU) No.453/2010 ve tanace SO Trefix MSW fla Page 2(9) ‘Substance key: HOESS Version: OT EU Revision Date: 24.05.2015 Date of printing : 24.02.2016 SECTION 3: Composi nlinformation on ingredients 3.2. Mixtures Chemical characterization castor oil derivative 7 nonionic fatty-acid polyglycolesters Mixture SECTION 4: First aid measures 4.1. Description of first aid measures General information 5 Remove/Take off immediately all contaminated clothing, After inhalation If inhaled, remove to fresh air. After contact witht skin : In case of contact, immediately flush skin with plenty of water. After contact with eyes In case of contact, immediately flush eyes with plenty of water for atleast 15 minutes, After ingestion In the case of accident ér if you feel unwell, seek medical advice immediately (show the label where possible). 4.2. Most important symptoms and effects, both acute and delayed ‘Symptoms ‘No symptoms known currently. . Hazards" No hazards known at this time. 4.3. Indication of any immediate medical attention and special treatment needed Treatment . ‘Treat symptomatically SECTION 5: Firefighting measures i 5.1. Extinguishing media Suitable extinguishing me ‘Water spray jet Foam Carbon dioxide (CO2) Dry powder 6.2. Special hazards arising from the substance or mixtureSafety Data Sheet in accordance with ARCHROMA;: > Regulation (EU) No.453/2010 : eee Trefix MSW fla, Page 3(9) Subse oy HOESS = Revision Date: 24.052015 jersion:2-01 5 Date of printing = 24.02.2016 Carbon oxides 5.3. Advice for firefighters Special protective equipment for firefighting in case of fire: Wear respiratory protection, SECTION 6: Accidental release measures > 6.1, Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. ‘Wear suitable protective clothing, 6.2. Environmental precautions ‘Do not allow to enter drains or waterways | 6.3. Methods and material for containment and cleaning up “Take up mechanically and dispose of iter processing, clean all equipment with the following: Water : 6.4, Reference to other sections” ‘Additional information Tiormation regarding Safe handling, see chapter 7 SECTION 7: Handling and storage 7.4, Precautions for safe handling : ‘Advice on safe handling ip special measures necessary f stored and handled as prescribed. Hygiene measures 7 ‘Wyach hands before breaks and at the end of workday, Use protective skin cream before handling t= product. Tee off immediately all contaminated clothing ‘and wash it before reuse. : ‘Advice on protection against fire and explosion 'No special measures necessary. \ 7.2, Conditions for safe storage, including any incompatibi ies Further information on storage conditions Keep containers tightly closed in a cool ‘well-ventilated place, Handle and open container with care. Keep away sources of ignition. 7.3. Specific end use(s) No further recommendations.Safety Data Sheet in accordance wi ~ : e with Al MA. Regulation (EU) No.453/2010 a ROM ea Trefix MSW fla Pegs 4) age ‘Substance Key: HOESS CoE E Revision Date: 24,05 2015 = Dale of printing 24.02.2016 SECTION 8: Exposure controls/personal protection 8.1. Control parameters e Exposure it values are not available. DNELIDMEL values z DNEL/DMEL values are not available. PNEC values PNEC values are not available, 8.2. Exposure controls . General protective measures ‘Avoid contact with skin and eyes. : Respiratory protection : Wear dust mask when.handling large quantities Hand protection : Chemical resistant gloves : ‘Take note of the information given by the producer concerning permeability and break through times, and of special ‘workplace conditions (mechanical strain, duration of contact). Eye protection : Safety glasses : Body protection : working clothes SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: solid : Form : : pellets Particle size : not tested. d Colour: yellow Odour: characteristic ‘Odour threshold : + nottested. pH value : 5 (20°C, 50 gf) Melting point approx. 50°C* Flash point : not applicable Evaporation rate : not tested Combustion number : not tested. Minimum ignition energy: —_ not tested. ; Vapour pressure : not applicable Solubility in water : dispersible meING Safety Data Sheet in accordance with * ARCGHROMA, 2 Regulation (EU) No.453/2010 mie eee STE ~refix MSW fla : Page 5(9) : ~dubstance Ke 3 3 i wy HOESS Revision Date: 24.05.2015 “version: 2= 07 EU a Date of printing : 24.02.2018 ~ octanotiwater partition not determined "coefficient (og Pow) : Ignition temperature : not tested ; Self-ignition temperature: not tested. , Thermal decomposition: No decomposition i used as rected . Viscosity (dynamic): not applicable 9.2. Other information Donsit : 0,920 gfems (60 °C) Bulk density not tested, SECTION 10: Stability and reactivity 10.1, Reactivity See section 10.3. "Possibility of hazardous reactions" 10.2. Chemical stability Stable under normal conditions. 7 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 40.4, Conditions to avoid Strong oxidizing agents 10.5, Incompatible materials not known 10.6, Hazardous decomposition products No hazardous decomposition products if stored and handled as prescribed SECTION 11: Toxicological information 44.1. Information on toxicological effects = Information related to the product itself: L050. > 2.000 mgikg (rat) Method : Evaluated according to GHS (Globally Harm: ‘System) criteria not tested. Acute oral toxici ‘Acute dermal toxicity : ‘Acute inhalation toxicity :" not tested.ety Data Sheet in accordance with * | ARCGHROMA, sulation (EU) No.453/2010 rere ix MSW fla ; Page 6(9) tance key: HOES3. . : Revision Date: 24.05.2015 yon: 2-O/ EU : Date of printing : 24.02.2016 Irritant offect on skin : No skin irritation (rabbit) Method : Evaluated according to GHS (Globally Harmonized System) criteria Irritant effect on eyes : No eye iritation (rabbit eye) . Method : Evaluated according to GHS (Globally Harmonized : System) criteria Sensitization : not tested. Repeated dose toxicity: nottested. * Genetic toxicity in vitro : not tested. : Assessment of mutagenicity : No information avallable Assessment of No information available. carcinogenicity : Assessment of toxicity to No information available. reproduction : SECTION 12: Ecological information 12.4. Toxicity Information related to the product itself: Fish toxicity: LC50 > 100 mgf (96 h) Method ; Evaluated according to GHS (Globally Harmonized System) criteria Daphnia toxicity : not tested, Algae toxicity not tested, ; Bacteria toxicity + + E50 > 100 mg/l Gh, activated sludge) Method : Evaluated according to GHS (Globally Harmonized System) criteria 42.2, Persistence and degradabillty 7 Information related to the product itself: tity + prox. 90 % Blodagradabiity arMhod : OECD Test Guideline 3028 i endemand 2.130 mg/g ; goo ee Method : DIN 38409-H-41 i J oxygen demand 1.080 mg/g mona mika Method : DIN 38409-H51 42.3, Bioaccumulative potential a ‘Information related to the product itself: Bioaccumulation: not tested, 42.4, Mobility in soil *Safety Data Sheet in accordance with ARCHROMA, Regulation (EU) No.453/2010 tire enwamern = Trefix MSW fla Page 7(9) 5 Suastance key. HOES Revision Date: 24,05,2015, Date of printing : 24.02.2016 Information related to the product itself: Behaviour in environmental compartments no data available 12.8. Results of PBT and vPVB assessment Information related to the product itself: no data available 12.6, Other adverse effects. Information related to the product itself: ‘ Additional ecotoxicological remarks Product dos not contain any organic bound Halogens which could lead fo AOX-values’ SECTION 13: Disposal considerations 13.1, Waste treatment methods . Product : In accordance with local authority regulations, take to special waste incineration plant Uncleaned packaging Consider recycling. Composition cH; 0 SECTION 14: Transport information Section 14.1. to 14.5. ADR hnot restricted 5 ADN not restricted RID 7 not restricted IATA not restricted ‘ imps not restricted 414.6, Special precautions for user : See sections 6 to 8 of this Safely Data Sheet. 14:7. Transport in bulk according to Annex I of MARPOL3/78 and the IBC Code (International Bulk Chemicals Code) No transport as bulk according IBC - Code.&) > Safety Data Sheet in a : IMAL ¢ CC i Regulation (EU) Noase/sne — ARGHERIMAt Trefix MSW fla ; ; Page (9) Substance key HOES Substance rer 0 mae PAE TTS Date of printing : 24.02.2016 Other regulations Apart from the data/res ¢gulations specified in this concerning Sealy. heath and envvonnentl piecing, ns oman Bamlaie 45.2. Chemical safety assessment No Chemical Safety Assessmas nt (CSA) is yet avail st Component subsancescontaveanimpeaicl ener SECTION 16: Other information Product should be stored, handled and used in accordance with good industrial hygiene practices : informity with legal regulgtions. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. it should therefor not be construed as garanteeing specific properties. Legend ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous ° Goods by Road ° ‘AOX ‘Adsorbable organic bound halogens cas Chemical Abstracts Service DMEL Derived Minimal Effect Level (genotoxic substances) NEL Derived No Effect Level _* C50 Half maximal effective concentration GHS Globally Harmonized System IATA Intemational Air Transport Association IMDS international Maritime Dangerous Goods cso Lethal Concentration 50% L050 Lethal Dose 50% MARPOL ternational Convention forthe Prevention of Pollution From Ships NOAEC No Observed Adverse Effect Concentration NOAEL No Observed Adverse Effect Level NOEC Non Observed Effect Concentration OEL Occupational Exposure Limit PBT Persistent, Bioaccumulative, Toxic PEC Predicted Environmental Concent icted No Effect Concentration REACH Region, Etuetion, Authorisation and Restriction of Chemicals RID Regi nal Rule for Transport of Dangerous Substances DY Railway SVHC + Substances of Very High Concern vPvB very Persistent and very Bioaccumulatve i Tf our knowledge and is intended as a genera) This information corresponds to the present state of ; doce of ou roduets i 4 their possible applications. Archrome makes no warrants ets oF implied, as to the information's accuracy Or cumcy, sufficiency of freedom from defect Tet revtabilty in connection with any use Of this information ay 7 C4 products responsi i ? articular re sutoay of Newer Hoste Sa onan Sal, eh conte Ma information waives any of Archroma's Gen