“uuu OF ae the correct option(s) in the following questions, al specoet TUPAC name for CH, = CHCH, NHCH, * iy allyimetnytamine (©) 2-amino-4-pentene INCERT Bsempar @ 4-aminopent--ene @ N-methylprop-2-en-1-amine norder to prepare a 1° amine from an alkyl halide with simultaneous addition of one CI 2 earbon chain, the reagent used as source of nitrogen is ne CH, group in . Wyn tates (NCERT E; (a Sodium amide, NaH () Sodium azide, NaN, semplar} (@) Potassium cyanide, KCN (@) Potassium phthalimide, CgH,(CO),N-K* The best reagent for converting 2-phenylpropanamide into 2-phenylpropanamine i (NCERT Exemplar (excess Hy (B) Bry in aqueous NaOH ip (0 iodine in the presence of red phosphorus (d) LiAlH, in ether + Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine? INCERT Exemplar] (Hy (excess\/Pt_ (6) LiAIH, inether___(c) Fe and HCI (@ Snand HCI Amongst the given set of reactants, the most appropriate for preparing 2° amine is__- INCERT Exemplar] w (@) 2 R-Br+NH; (b) 2 R-Br + NaCN followed by Hy/Pt (0 1° R-NH, + RCHO followed by Hy/Pt @) 1° R—Br 2 mol) + potassium phthalimide followed by HO*/heat ‘The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is _______- ing, 2-phenylprop: INCERT Exemplar (@) excess H/Pt (6) NaOH/Br, (©) NaBH,/methanol —_ (@) LiAlH,/ether a organic compound ‘A’ on treatment with NH gives ‘B’ which on heating gives “C.°C when ‘eated with Br, in the presence of KOH produces ethylamine. Compound ‘A’ is © CH,~cH,—ch,—cooH GCHEODE © ch,— ¢H—coon (@) CHy—CH,—COOH cH. & 3 7 ie Source of nitrogen in Gabriel synthesis of amines is . [NCERT Exemplar] © Bae fide, NaN, (b) Sodium nitrite, NaNO ; Outen am yanide, KCN (a) Potassium phthalimide, CaCO aims (@) yuit® following, the strongest base in aqueous solution is [CBSE On, nine (6) Dimethylamine te i timethylamine @ Aniline se cH ‘ i CERT Exem (a cline following, the strongest base in aqueous medium is _____— [Ne CH. (6) NCCH,NH, (0) (CH).NH (@) CoHlsNHCHsi 12. 13. 14, 15. 16. 17. 18. 19. 20. 2. 22, ; 2 INCE, “Which of the following is the weakest Brinsted base’ (NCERT Exemplar NH) NH; CH,NI ot hw ( eH of) (@ CH.NH, ‘The correct increasing order of basic strength for the following compounds is ——_. (NCERT, Exemplar, NH, NH) NH, ( y] O NO> CH oO a «a @URI>RC1(®) RI>RBr>RCL_ (©) RCI>RBr>RI_— @) RI> RCL> Br Benzylamine may be alkylated as shown in the following equation: C,H,CH,NH, + R-X — C,H,CH,NHR Which of the following alkylhalides is best suited for this reaction through Sy1 mechanism? INCERT Exemplar] (@) CH,Br (®) CoHsBr (© CHsCH.Br @ CHB CH,—NH, on heating with CHCl; and alcoholic KOH gives foul smell of [CBSE 2020 (56/91)} @ O-cu0on © Or-cune © ()-cxen @ O-cuc Which of the following compounds will dissolve i i i action with Hlinsberg's reagent? ein an alkali solution after it undergoes Fé (a) (CHs)3N (b) CH,NH,, © (C.H,),NH (d) CgHsNHCgHs Methylamine reacts with HNO, to form . [NCERT Exemplar] @ CH;—O-N =0 (6)CH;—O—CH; — (c) CH,OH (@ CH,CHO In the nitration of benzene using a mixture of conc. H,SO, and cone. HNO, the species which initiates the reaction is . a INCERT Exel? (@) NO, () No* (© No? (@) NO; 2 2 ‘Which of the following will be most stable diazonium salt RNaX? (@ CHSCHN2X ——(b) CoHsN,X (© CHN,X @ CeHsCHANK Red it i eduction of nitrobenzene by which of the following reagent gives aniline? [NCERT Een?! al @ Sac ( Fenici (c) Hy-Pd Sn/NH,OH Which of the followin, J @ 4 ot) (@) Chlorobenzene Gy Brana ereeared by Sandmeyer's reaction? [CERT Been? 0) (0) Bromobenzene _(c) Todobenzene (@ Fluorobenzen?3. (Competency Based Question} (@ (CH,CH,),NH + CHjCH,Br A. CHyCONHC. (i) (CH,CO),0 + CH.NH, B. CcHgNC (ii) CH,CH,NH, + HONO C. (CHCH,),N (i) CgHNH, + CHC! + KOH D. CH,CH,OH @ @—A, (ii) —C, (iii) —D, (iv) —B © —B. Gi) —A, Gi) —C, (iv) —D Complete the following analogy: [Competency Based Question] Nitrating mixture : A :: Schiff's base : B (@ A:conc. HNO, + cone. H,SO, ; B: RN=CHR (®) A: dil. HNO, + conc. H,SO, ; B:R,N= CHR (© A:cone. HNO; + cone. H,SO,; B : NaBH, (@ A: dil. HNO, + dil. HS0, ; B:RN=CHR 6) O—C, i) —A, Gi) —D, i) —B @ @—D, Wi) —C, (ii) —A, i) —B '. Which of the following analogy is correct? [Competency Based Question] (@) Gabriel phthalimide reaction : Primary amine :: Hoffmann bromamide degradation of 1° amide : CgHsNH, (6) Ethanamine : Positive azodye test :: Aniline : Hibermann nitroso reaction (©) Hinsberg reagent : (CH;CO),O and pyridine :: Sulphanilic acid : Zwitter ion (@ N-methylaniline + Nitrous acid : Methy! anilin , N-dimethyl aniline : p-nitroso -N, N-dimethylaniline