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A Quantum Mechanics Questions Latest Quantum Mechanics MC@ Objective Ques! & oe SESE ae aise Start Complete Exam Preparation Penton Practice moa kJ ars Creeoeot og Question 1: View this Question Online > i The density of a quantum system with two microstates is given by ( correct option. 1, @)=-10)=2 oi Answer (Detailed Solution'Below) Option 3: (7) = 42. a 1 Recaro tra ). Choose the coaching govt. exams Under One Roof FREE oc ad Quantum Mechanics Question 1 Detailed Solution Concept: Ina square matrix, the sum of elements of the principal diagonal is called the ‘trace of the matrix’ Explanation: (21 Density is givenby?= \y 1 trace of density is 7") = 2+1=3 2 1 Now, normalised function of density is ( 1 =Tr(p7,) ~ = 1(2)=2 <0, >=Tr(po,) = gcrr(( “) = 3(2-1)=3 Hence, the correct answer is (72) = 32 (72) & India’s #1 Learning Platform Start Complete Exam Pr OR Geo aE cert ee Pinar Sh Irs hele Coed Rea Jownload App Question 2: View this Question Online > A particle of mass m is trapped in an infinite, quantum well of width L. The expectation value of its momentum in the third excited state is 1. Intinity 3. Zero ave Answer (Detailed Solution’ BoW) Option 3 : Zero Quantum Mechanics Question 2 Detailed Solution Concept: ro amr) ee ee eee ee : = ,/Esi For third excited state ¥(@) = Vzsin( 2) + Momentum operation is given byP a te + Expectation value of momentum operator can be written as \( =<\psi**)hat plipsi=\) Explanation: Expectation value of momentum is \C =\int_OMU(isqrt{\fraci2HU}Sin(\frac{3\pi x{L)(\hat p)(\sqrt{\frac{2}{Ly}Sin(\frac{3\pi xH{L)).dx\) \C =\int_O{L)(sqrt{\fraci2HL})Sin(\trac{3\pi x}{L})(-i\hbar \frac{d}{dx})(\sqrt{\frac{2HL)Sin(\irac{3\pi x} {U).dx\) \ =\frac{-2i\hbar}{L\int_O*{L}Sin(\frac{3\pi x{L))\frac{d}{dsySin(\frac{3\pi x}{L)).dx\) © . G ( e =\frac{-2i\times3\pi\hbar}{L\times L)\int_0*{L}Sin(\frac3\pi x}{L))Cos(\frac{3\pi ¢ wey ane ander — Convert limit from 0 to Lt0 Oto, put = = —> 3 =du \ \ =\frac{-2i\times3\pi\hbar}{L\times L)\int_0“{\pi}Sin wn Bebra NG =\frac{-2i\times\hbar}(L}\int_0* (\pi}si .. \ =\frac{-2i\times\hbar}(2L\int_0“{\pi}2Sin(u)Cos(uldu\) \C =\frac{-2i\times\hbar}2L)\int_0“{\pi}Sin(2u)du\) \C =\fracfi\times\hbar}{2L}[Cos(2u)|_0*(\pi)\) MC =\frac{i\times\hbar}{2L}|Cos(2\pi)-Cos(0)|=\fracti\times\hbar}{2L\(1-1)=0\) \Qimplies =0\) Hence, the correct answer is Option-3-Zero. ra India's #1 Learning Platform Start Complete Exam Preparation Rear eo ic Paid pipet er i) ri aos Question 3: View this Question Online > Five non-interacting identical spin 2 Particles are in the one-dimensional harmonic = Lmwa’ oscillator potential 2 The ground state energy of the system is pho Shw 22 a 3 ane ~% Answer (Detailed Solution Below) 2 Option 1: 37 Quantum Mechanics Question 3 Detailed Solution Concept: + For harmonic oscillator, 2("%2My) = (Mz + 3 )Pudy + (ny + 3 )hey Given: Vv Sapte? bmw’ Explanation: W, Wy = = Denali , V(z) = Amore using As, #y = 0, Elz) = (m+ Aho, « Bln.) =(n, + 3 )hw (58) =2841 + Multiplicity 2x3 Aa 3 . Due to spin 2, maximum of four OM, cn filled in one energy level. Energies of two lowest energy levels are “z = %1 0,Ey = (0+ 1)hw = Liu For Mx For": = 1H, =(1+ 3)hw = hw Total energy of the system is 2 =(3h4) = 4+ (3 hw) x 1 B= thot 3hw = Tho E =7 Hence, the correct answer is Option-1-" ~ 2 a India’s #1 Learning Platform 1,86,00,449+ Student: Alam CM CMe rte Licey )) Daily Live ented moar eto et Go cri Jownload App Question 4: View this Question Online > A particle of mass m is in the ground state of a 1d-harmonic oscillator potential of angular frequency w. The entire system is placed in the centre of a 1d-box of length Th am. The ground state energy 1, decreases. 2. increases. 3. remains ate XG... levels. ‘Answer (Detailed Solution Below) Option 2: increases. Quantum Mechanics Question 4 Detailed Solution Concept: The harmonic oscillator Hamiltonian is given as =F lka2 +H= Ft phe which makes the Schrodinger equation for energy eigen states as du lkou = «ot ae + pko'u = Eu Ve a Loi ceed pati Hamittonian becomes = py + 37702 Classical Oscillator frequency ‘The erieigy:eigeri value fora harmonicosallatwr become == Explanation: Noe siven:! = VE eo Squaring both sides, we get, \ P= hk =p w= kh om mt Substitute this value of angular frequency in energy state formula, =(net . By = (n+ 3 haw =ariye 2B, = (nt 1) =i Initially ground state energy is 2o = 3h | Brain Finally, ground state energy, 40 = 2 m= So, “0 ~ 0, energy increases. Hence, the correct answer is Option-2-increases. Pad ean cn aarti) Start Complete Exam Preparation RCO cece red Practice acs occa ree necro Ex hice Download App Question 5: View this Question Online > Consider a one dimensional free particle, for which the Hamiltonian commutes with the momentum operator. Which of the following statements is false? 1. All energy eigenfunctions are eigenfunctions of momentum téo, 2. All momentum eigenfunctions are eigenfunations of Hamiltonian too. 3. The position operator daes\not.commute with the Hamiltonian. 4. The position Uncertainty of a momentum eigenfunction is infinite. 4% Answer (Detailed Solution Below) Option 1 : All energy eigenfunctions are eigenfunctions of momentum too. Quantum Mechanics Question 5 Detailed Solution Concept: The Commutator of two operators A.B is the operator C=[A,8] such that AB-BA. Two Operators A and B commute if and only if their commutator [4,8] vanishes . [A.B] =AB-BA=0 = A,B commute Explanation: Consider Hamiltonian Operator for a single particle in one dimension =F += F+V(2) where ™ is position operator, p is momentum operator. wand P have a commutator (ep]= ih So, H,#] 4 0,[H,p] #0 {All momentum eigenfunctions are eigenfunctions of Hamiltonian too and the position operator does not commute with the Hamiltoy So, statement 2 and 3 are correct, A The uncertainty of position is infinite and the uncertainty of momentum is zero. This account of a free particle is consistent with Heisenberg's uncertainty principle. So, statement 4 is correct. =-k Ve)= > If there is a potential, then the energy eigen states are definitely not momentum eigenstates. So, statement 1 is false. Hence, the correct answer is Option-1-Alll energy eigenfunctions are eigenfunctions of momentum too. Top Quantum Mechanics MGQ Objective Questions a ie aPC Rael) RCE eer Start Complete Exam Preparation Cit I (ieee Cle ‘Question 6 \View this Question Online > Let * and poate position and momentum operators obeying the commutation relation %P} = ih. If jx) denotes an eigenstate of * corresponding to the eigenvalue x, uy .. elab/h |p) 1, an eigenstate of * corresponding to the eigenvalue x 2. an .“ of * corresponding to the eigenvalue (x + a) 3. an eigenstate of * corresponding to the eigenvalue (x — a) 4, notan eigenstate of ® Answer (Detailed Solution Below) Option 3: an eigenstate of © corresponding to the eigenvalue (x - a) Quantum Mechanics Question 6 Detailed Solution Concep' The momentum operator is given by p=-ih de where his the Plank constant. Calculation: Hp y = Puno (SE) Jp> 22 AUP a 2 = pe = aV p> + 2 (VY) fx> ». = rae Xpea> = (x-a)pera> The correct answer is an option (3). Pee ae LY aie Came MLC Ma) CR ee cer (ee caer bead Jee rere as D> Download App Eh ‘Question 7 View this Question Online > The generator of the infinitesimal canonical transformation q — q =(1-©)pis (1 + €)qand p= p 1.q+p an % Ber) 4, (P+P?) Answer (Detailed Solution Below) Option 2: gp Quantum Mechanics Question 7 Detailed Solution Concept! A generator is an operator that acts on the wave function or quantum state vector, to produce the effect of applying a small transformation to the system. Calculation: qoq=(1+4q p-p'=(1-e)p IfG is the generator then p-p= 6p) =e or ga 2S ag ~ehe 2ep Now G = qp ~¢S =-ep=6p eB =-€q=5q The correct answer is option (2). & India’s #1 Learning Platform CORE eeu Start Complete Exam Preparation Clee. ed eh aa Ces coe oresieocoag Exeltie2) Download App Question 3 View this Question Online > A particle of mass m is confined to a box of unit length in one dimension. It is described we by the wavefunction w(x) = i 5 sin Te (1 + cos 10) for. $x <1, and zero outside this interval. The expectation value of energy in this state is a 1. Se? Answer (Detailed Solution Below) 5 2e? 2 Option 3: ar Quantum Mechanics Question 8 Detailed Solution CONCEPT. The particle in a box model (also known as the infinite potential well or the infinite square well) describes a particle free to move in a small space surrounded by impenetrable barriers, Schrodinger’s equation for the same is given as: =(-¥ # % % HW >= (-E # + V(2))0 >, % the expectation value of the energy can be found using the expression: \(= Wracint.0 OAL BSi*"00 H \psi ()H\int_0“! \psi**09 \psi 00} \) CALCULATION: ie We are given with p00) = vi sin rex (1 + cos x) for 0 2.240 0 2 IPs) the ex ms ae (Fl) and the variance of H in the state I") - Aa (iDiy + 103) PO) ae ~ 4/3and 1/3 2. 4/3 and 2/3 Let the normalized eigenstates of the Hamiltonian H = Mi 20 J be !¥1), [Y2) and 0 3. 2and 2/3 4. 2and1 Answer (Detailed Solution Below) Option 3: 2.and 2/3 Quantum Mechanics Question 9 Detailed Solution Concept: Normalized eigenvector is nothing but an eigenvector having unit length. It can be found by simply dividing each component of the vector by the length of the vector. Calculation: 210 wih 2 ol \o 0 2 2-12 1 0 0 Eigenvalue= 1 = » a 1 ‘ [> = ys b> +1Y2>-ilya>) (2-2-4)? - 1) = 0 M=2M=1A 1 PE =2)= rer = 3, 1 PE=1)= 4, 1 PE=3)=3 11 ‘i (AB)? = 2> - The correct answer is option (3) Oe ee ae Rac iiiy Pela me CCM bcm e Le Lela) er aurs Lat Ca Che Download App ‘Question 10 & Quizzes CR oo ar kon View this Quastion Online > The wavefunction of a particle of mass m, constrained to move on a circle of unit radius centered at the origin in the xy-plane, is described by () = A cos? $, where ¢ is the aziamuthal angle. All the possible outcomes of measurements of the z-component of the — Lzin this state, in units of h, are ando 4, +2and0 Answer (Detailed Solution Below) Option 4: +2 and 0 Quantum Mechanics Question 10 Detailed Solution Concept: In quantum mechanics, angular momentum is"@)vettot operator of which the three components have well-defined commutation relati rs, This operator is the quantum Paige of the classical angular momentum vector. Calculation: Vid) = Acos?6 = (cos 26 + 1) A(abems % m8 2A (ee + eins) Thus the value of m = 2, -2 and 0. The correct answer is option (4). a c India’s #1 Learning Platform Start Complete Exam Preparation ORC Lark eon Peary ood ape UJ Mastercl es meter) VOownioad App Question 11 View this Question Online > The Hamiltonian of two interacting particles/one with spin 1 and the other with spin 2, is given by H = AS; - Sp + B (Six + $2, where S; and $2 denote the spin operators of the first and second particles, respectively, and A and B are positive constants. The largest eigenvalue of this Hamiltonian is ~ + 38h) 2, 3Ah? + Bh 1 3. 2(3Ah? + Bh) 4. Ah? + 3Bh Answer (Detailed Solution Below) Option 1: (Ah? + 38h) Quantum Mechanics Question 11 Detailed Solution Concept Aspin operator, which by convention here we will take as the total atomic angular momentum H, is P a vector operator (dimension h ) associated with the quantum number H a Calculation: H=AS; +S +B (Six + Sa) - winere Sand S: denote the spin operators ofthe first and second particles, respectively)” and A and Bare positive constants. 3,1 Sy=15)=25=3°2 Hag SORESE 0 (Ste + Soe) & 5 ; For the largest eigenvalue S = > a a3 = 3(3+Dpe ISP = 2h? 2 [S:)? = th* b Sty =h and So¢= 2 1p22na—3 ha Heat a yp lht §) 1 = 2(Ah? + 3Bh) The correct answer is option (1). India’s #1 Learning Platform Start Complete Exam Preparation Rt ti Practice aes Clits Efren a Ga I Question 12 ‘View this Quastion Online > The energy eigenvalues of a particle of mass m, confined to a rigid one-dimensional box of width L, are E, (n = 1,2, ..)- If the walls of the box are moved very slowly toward dE: each other, the rate of change of time-dependent energy a= of the first excited state is Ey aL Answer (Detailed Solution Below) —a et Option 3: ~ “3 ar Quantum Mechanics Question 12 Detailed Solution Concept: Energy in a one-dimensional infinite potential well of width L is given by thts? E> mr where, nis the energy ‘evel Bai, Calculation: nth? £2 = oma ae, anh? ab Sat = -2 aman te dE, 2B, dh foie = te The correct answer is option (3). Ed Ie APC Rael) Start Complete Exam Pre Po (liteet sees Download App Question 13, GORE Ss ecosont ca View this Question Online > Two spin 2 fermions of mass mare confined to move ina one-dimensional infinite potential well of width L. Ifthe particles are known to be ina spin triplet state, the ground state energy of the system (in units of 2mE=) is ke?” ‘Answer (Detailed Solution Below) Option 4:5 Quantum Mechanics Question 13 Detailed Solution Concept: Energy in a one-dimensional infinite potential well of width L is given by wns? E= om where nis the energy level band, Solution: If probabil in triplet state means Oo see dnsae eo” As it has been given that the two spin pe spin-triplet state then, 2s+1 =3, where s is the total spin. Now solving it we get: total spin s=1. So for that one electron is in the n = 1 state and another in the n = 2 state. So ground state energy of configuration is (12-422) Bea? hn? The correct answer is an option (4). od India’s #1 Learning Platform Start Complete Exam Preparation Rea Rott a ee Sl Ores re Download App Cees Practice Question 14 View this Question Online > The normalized wavefunction of a particle in three dimensions is given by Yes y, 2) = Nzexp[-abe + ¥? + 27)) where a is a positive constant and Nis a normalization constafit. If L is the angular momentum operator, the eigenvalues of L? and L,, respectively, are 1, ah? andh 2. h? andio he gle and gh Answer (Detailed Solution Below) Option 3: 2h? and oO Quantum Mechanics Question 14 Detailed Solution CONCEPT: The Angular momentum operator L? ,L,, in spherical coordinates are given by: R 1 (sing2)+ 1 2) a Mo a L, =—ih. io CALCULATION: The normalized wavefunction of a particle in three dimensions is.given by, WK J 2)= Nzexp[-a oe + +24) Writing the above wavefunction in spherical polat cOordinates we get: U(r, 0,4) = Nr-cos Be~ar? “—/*, z= 1c0s0,x = rsinO cos $,y ing Now operating the angular momentum operators on the above-transformed wave function, we get: Lay =f? (1, 2 (sin €Nre-e* x —sin®))_ Simplifying it a bit by taking the derivative again with respect to 9 we get: D2) — he For the Lz the derivative is respect to ®,, hence its eigenvalue will be 0. The correct answer Is option (3). Ca CER ae Rell Start Complete Exam Pr COR Ss ecosot ca Daa faa Cai ee eran Jownload App Question 15: View this Question Online > The sate vector ofa one-iasinle harmonic onilator of angular frequency, at time t = 0, is given by (WO) = Fy [10) + 12)], where !®) and |2) are the normalized ground state and the'Second excited state, respectively. The minimum time t after which the y N IO) is orthogonal to 1¥()), is 1. ao on Option 1: 27 Quantum Mechanics Question 15 < (¥(0) = (10) + 12] = fh |v). 2 Pea + © Ey = M+ (W(0)8 | Ye)) 03 t= phy cos-t(—1) ‘Answer (Detailed Solution Below) Nee t= 8 cost(-1)_ hora es = amp2" a

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