n mn tin ng dng

Nhm 6

N MN TIN CHUYN NGNH

PH LC
M U............................................................................................................................2
CHNG 1: C S L THUYT.....................................................................................3
1.1 Mc ch...................................................................................................................3
1.2 ngha.....................................................................................................................3
1.3 C s l thuyt v S cng ngh .........................................................................3
1.3.1 qu trnh x l sn phm sau khi ln men tinh bt sn xut ethanol [2]............3
1.3.2 qu trnh chng chit ethanol s dng mi monoethylenglycol (MEG).............5
CHNG 2: THIT K, TI U HA QU TRNH V TNH TON THIT B...........7
2.1 C s thit k trong chng luyn hn hp ng ph.................................................7
2.2 C s vic ti u ha qu trnh chng chit hn hp ng ph ethanol-nc..........8
2.3 Tnh ton thit b......................................................................................................8
CHNG 3: M PHNG QU TRNH CNG NGH.................................................10
3.1 M phng qu trnh x l sn phm ca qu trnh ln men tinh bt sn xut ru
Ethanol.........................................................................................................................10
3.1.1 qu trnh m phng..........................................................................................10
3.1.2 Kt qu m phng............................................................................................11
3.2 M phng qu trnh chng chit ethanol s dng dung mi MEG.........................11
3.2.1 Qu trnh m phng chng chit ethanol ........................................................11
3.2.2 Kt qu m phng qu trnh............................................................................13
3.2.3 Kt qu ti u ca qu trnh............................................................................14
CHNG 4: PH LC..................................................................................................18
4.1 Bng ph lc ca cc dng v thit b trong qu trnh m phng tinh luyn ethanol
s dng dung mi MEG................................................................................................18
4.2 Bng ph lc ca cc dng v thit b trong qu trnh m phng x l sn phm
sau khi ln men tinh bt................................................................................................21
TI LIU THAM KHO..................................................................................................27

Lp Lc Ha Du K52

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Nhm 6

M U
Nh chng ta bit, nhin liu ha thch v ang ng vai tr ht sc quan
trng. Bn cnh nhng u im vt tri, nhin liu ha thch ngy cng bc l nhiu
im hn ch: khng c kh nng ti sinh, nhim mi trng v vic ph thuc qu
nhiu vo loi nhin liu ny ang gy ra nhng bt n v kinh t, chnh tr. Thc t t
ra nhu cu cp thit cn phi tm ngun nhin liu thay th cho nhin liu ha thch. Rt
nhiu nghin cu c tin hnh v a ra c nhiu ngun nhin liu mi. Trong
, nhin liu c ngun gc sinh hc ang c u tin nghin cu v s dng.
V vy vic tm ra ngun nng lng mi c kh nng ti to v thn thin vi mi
trng l iu rt quan trng v cn thit. Bn cnh vic s dng cc ngun nng lng
nh nng lng thy in, nng lng nguyn t, nng lng mt tri, nng lng gi,
nng lng thy triuTh nng lng c ngun gc sinh hc ang rt c quan tm.
Ethanol l nhin liu i t ngun gc sinh hc ang c c th gii quan tm. V hin
nay Ethanol c s dng lm nguyn liu cho mt s qu trnh v c bit ethanol
nh mt ph gia pha xng to thnh mt loi nhin liu c gi l gasohol hay
gasoline alcohol gip tng ch s ON v gim thiu nhim mi trng. Nc ta l mt
nc c nn kinh t nng nghip vi th mnh l cc ngnh trng trt. Vic sn xut
Ethanol t cc ph phm ca sn xut nng nghip Vit Nam l rt kh thi.

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Nhm 6

V nhng l do trn chng em chn bi Tm hiu, m phng cc thit b trong

2 qu trnh: sn xut ethanol x l sn phm sau khi ln men v qu trnh tinh luyn
ethanol. V ti u mt phn cc thit b ca cng on cui cng ca qu trnh sn xut
ethanol khan
Chng em xin chn thnh cm n thy on Vn Hun ngi trc tip ging dy
mn hc v hng dn chng em hon thnh n ny.

CHNG 1: C S L THUYT
1.1 Mc ch
Tm hiu thit k v m phng cc thit b trong 2 qu trnh: sn xut ethanol l
x l sn phm sau khi ln men v tinh luyn ethanol sn xut ethanol khan. Ti u
mt phn cc thit b ca cng on cui cng ca dy chuyn sn xut ethanol khan n
c nh hng ln n cht lng ca loi nhin liu pha xng ny.
1.2 ngha
1.3 C s l thuyt v S cng ngh
1.3.1 qu trnh x l sn phm sau khi ln men tinh bt sn xut ethanol [2]
Tng quan qu trnh sn xut Ethanol bng ln men tinh bt:

Nguyn liu:

Lp Lc Ha Du K52

 n mn tin ng dng

Tinh bt
(%)

Nhm 6

La M

La
mch

La
mch
en

Bp

La min La go

C sn

60

63.2

56-58

62.6

58-63

55-65

69.2

Cc vi sinh vt tham gia qu trnh ln men

Vi sinh vt
Tc dng

Nm mc
Nm men
Vi khun lactic
hy phn tinh bt Thy phn dch ng thnh Axit ha dch
thnh ng.

ru.

ng trc khi ln
men.

Giai on qu trnh ln men

1.ng Ha
Tinh bt

ng

Ru

Cc phng php ng ha
Dng axit

Tc nhn
ng ha

2.Ln men

-HCl
810%
-H2SO4
25%

Men thuc
bc
Nm mc
t nhin
trong thuc
bc

Maltase

Amylo

Myco-malt

-Malt
-Cc loi
thc ny
mm

Amylomyces
rouxii,
mucor hoc
Rhizopus
cy trc tip

Enzymeamylase
ca:
-Asp. Oryzae
-Asp. Niger
-Asp. Awamori

Qu trnh ln men

Glucose v
cht dinh
dng

Hp th qua b mt
t bo nm men ri
thm thu qua mng
bn thm vo t bo

Ru v CO2

Phng trnh tng qut qu trnh ln men.

C6H12O6 = 2C2H5OH + 2 CO2 + 2ATP

Cc tp cht sn phm ph ca qu trnh ln men

Lp Lc Ha Du K52

Qua mng t bo
cht, Khuch tn
v tan vo mi
trng xung
quanh

 n mn tin ng dng

Nhm 6

Tp cht u
Thnh phn

Aldehyde acetic,
ethy
lacetate,
methyl
acetate,
ru metanol
si thp hn
ru etanol
c ly ra giai
on u ca qu
trnh tinh ch
S cng ngh
CO2

Nc

Tp cht trung
gian
Ethyl isobutyrate,
ethyl
isovalerianate.
Ty thuc, nng
ru v tnh
cht vt l ca tp
cht.

Tp cht cui
Ru cao phn t:
isoamylic,
isobutylic
Nhit si cao
hn etanol , kh
bay hi, t ha tan
trong nc

Dng CO2

Etanol t qt
ln men
Thp
tch CO2

Thp ra
CO2
Etanol a li
thp ln men

Beer

Light vent

Ethanol

Rect Feed

1stprod
Thp loi
Metanol

Thp c
c
Etanol

Thp tinh
ch

Fusel

Hi nc
(Steam)
Stillage A

Stillage B
To Rect

Hnh 1.1: S khi qu trnh x l sn phm sau khi ln men

1.3.2 qu trnh chng chit ethanol s dng mi monoethylenglycol (MEG)

C s l thuyt:

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Nhm 6

Ethanol thu c sau qu trnh ln men r ng, tinh bt hoc xenllulo c nng
khong 10%V 12%V. thu c cn c nng ln hn nng ti im ng
ph thng thng phi tri qua cc giai on chnh sau:
Giai on 1: S dng cc phng php chng ct thng thng nng cao
cn ti gn im ng ph (96,4%V)
Giai on 2: S dng cc phng php c bit khc tinh ch, lm khan cn.
lm khan cn hin nay ngi ta thng s dng cc phng php:
+Chng luyn:
-Chng luyn ng ph
-Trch ly mui rn
+Phng php bay hi thm thu qua mng
+Phng php hp ph
Phng php chng luyn ng ph c s dng nhiu do c u im l

thit k ban u n gin chi ph khng qu t.

S khi ca qu trnh

Hydrous ethanol
MEG

Lp Lc Ha Du K52

Thp Extractive

Thp Recycle
6

Pure
water

 n mn tin ng dng

Nhm 6

Anhydrous
ethanol

Solvent

Hnh 1.2: s khi qu trnh chng luyn ethanol

CHNG 2: THIT K, TI U HA QU TRNH V TNH

TON THIT B
2.1 C s thit k trong chng luyn hn hp ng ph
i vi cc hn hp gm cc cu t c nhit si ging nhau hoc rt gn nhau
hay to thnh dung dch ng ph, khng th dng phng php chng luyn thng
thng tch cc cu t ra dng nguyn cht, d thp v cng cao vi lng hi lu rt
ln. tch hn hp ngi ta phi c phng php c bit l trch ly hay cn gi
l phng php ng ph, ty thuc vo bay hi ca cu t thm vo (cu t phn ly).
A

R b sung

AR

R(A)

R
A

BR

AB

R
A

AB

R ti sinh

a)

b)

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Nhm 6

Hnh 2.1:
a) h thng chng luyn trch ly ( cu t phn ly c bay hi b)
b) h thng chng luyn ng ph (cu t phn ly c bay hi ln)
Cu t phn ly c tc dng lm tng bay hi tng i ca mt cu t trong
hn hp. Nu cu t phn ly c bay hi b khi thm vo nh thp s to thnh mt
hn hp gm cu t phn ly R v cu t B c bay hi b, cn cu t A c bay hi
ln. hn hp mi R v B c bay hi khc nhau nn d dng tch theo phng php
chng luyn thng thng (hnh 2.1). Phng php ny c s dng trong bi m
phng do c u im chng luyn trch ly khng cn bc hi cu t phn ly nn lng
hi t s t tit kim nng lng hn. Nu cu t phn ly R c bay hi ln hn cc
cu t trong hn hp khi thm n vo s kt hp vi mt cu t A trong hn hp to
thnh dung dch ng ph c bay hi ln.kt qu chng luyn sn phm nh s l hn
hp ng ph sn phm y l cu t B kh bay hi. V khi thm cu t phn ly vo s
to ra dung dch ng ph nn gi l phng php chng luyn ng ph.
2.2 C s vic ti u ha qu trnh chng chit hn hp ng ph ethanolnc
- Ti u nhit , p sut dng MEG, HYDROUS ETHANOL trc khi vo thp
m bo thp hot ng tt nhit , p sut khng nh hn hay ln hn nhit , p
sut ti a np liu.
- Ti u lu lng dng dung mi MEG khi c nh dng nguyn liu ethanol.
- Ti u Distillate Rate hay ti u lu lng dng ra nh thp.
- Ti u ch s hi lu ca thp Extractive.
2.3 Tnh ton thit b
Tnh ton cc thng s c bn ca thp CO2 wash, thp hot ng tch CO2 v
hp th tt c cc ru.
o
Bc 1: C th ha 2 dng wash H2O v to co2 wash u vo (chi tit xem
bng 4.12 v 4.18 ph lc)
Hm lng ethanol trong kh u ra l : 0.000001 phn mol. Cht hp th l dng
nc.
o
Bc 2: Tnh p sut lm vic ca thp hp th
p sut lm vic ca thp hp th : P Pethanol/b
Trong :

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Nhm 6

Pethanol l p sut hi ring phn ca ethanol trong dung dch nc ti nhit lm

vic ca thp. C th c tnh theo phng trnh Antoine:
Lg Pethanol = A B/(T+C)
T l nhit lm vic ca thp l 30oC. A,B,C l 3 h s ca phng trnh tng
ng vi H2O [5]
A
B
C
Tmin
Tmax
Water
8.071331
1730.63
233.426
1
100
Water
8.14019
1710.94
244.485
99
374
Ethanol
8.20417
1642.89
230.300
-57
80
ethanol
7.68177
1332.04
199.200
77
243

Pethanol = 31.740167 mmHg

b l hm lng ca ethanol cn li trong kh u ra (ppm) l 0,0001% = 1 ppm
P Pethanol/b = 31.740167 mmHg = 0.04176338 atm
Vy ta chn p sut lm vic ca thp nh l 1 atm v y l 1 atm
o
Bc 3: tnh lu lng dng to_ferm i ra y thp

methanol trong dng to_ferm = methanol hp th = methanol dng to co2 wash - methanol ra nh
mto_ferm = mwash water+ methanol(hp th) + m(Methanol, 1-propanol, 2-propanol, 1-butanol, 1-butanol, 3-M-1-C4ol, 2pentanol, co2 b hp th) mnc b cun theo ln dng nh
Trong : nethanol(h.th) + n(Methanol, 1-propanol, 2-propanol, 1-butanol, 1-butanol, 3-M-1-C4ol, 2-pentanol,co2 b hp th) nnc b cun theo ln dng nh = nethanol(to co2 wash) + n(Methanol, 1-propanol, 2-propanol, 1-butanol, 1-butanol, 3-M-1-C4ol, 2-pentanol, co2
dng to co2 wash) nethanol(kh ra nh) - n(Methanol, 1-propanol, 2-propanol, 1-butanol, 1-butanol, 3-M-1-C4ol, 2-pentanol, co2 nh) - n
(nc cun theo nh)

methanol trong dng to_ferm= mETHANOL(to co2 wash) - mETHANOL(kh ra nh) = 1.1276653x46
kg/h = 51.8726038 [kg/h]
Lu lng khi lng thnh phn ethanol trong hysys tnh l 51.8915052 [kg/h]

kt qu m phng ph hp vi tnh ton bng tay

o

Bc 4: tnh lu lng ca dng ethanol ra nh thp

m(ethanol trong dng kh ra nh) = m(ethanol dng to co2 wash) methanol(h.th) = 2.976x10-3 [kg/h]
Lu lng khi lng ca ethanol trong dng nh co2_stream m hysys tnh l
2.997712x10-3 [kg/h]
kt qu m phng ph hp vi tnh ton bng tay

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 n mn tin ng dng

Nhm 6

CHNG 3: M PHNG QU TRNH CNG NGH

3.1 M phng qu trnh x l sn phm ca qu trnh ln men tinh bt sn
xut ru Ethanol
3.1.1 qu trnh m phng
Sau qu trnh ln men, sn phm Ethanol chng ta thu c ch yu l nc v
Ethanol v nhiu nhng tp cht nh: Metanol, 1-Propanol, 2-Propanol, Axit axetic, 1Butanol, 3-metyl-butanol-1, 2-Pentanol v CO2. Trong qu trnh x l ny chng ta cn
loi b cc tp cht thu c sn phm hn hp ng ph ca Ethanol v nc. Qu
trnh thit lp m phng bng Hysys cho qu trnh x l ny bao bm nhng bc sau:
u tin chng ta chn m hnh cho qu trnh m phng ny l NRTL. Nhp 3
dng nguyn liu l dng nc, hi nc v dng sn phm ca qu trnh sau khi ln
men sn xut ethanol iu kin mi trng [2] (chi tt xem ph lc 4.12). Dng sn
phm nh ca thp tch CO2 thnh phn chnh l CO2.
Ethanol
0.016966
CO2
0.942106
H2O
0.040875
c a cng vi dng nc sch vo thp CO2 wash loi chit CO2 v thu
hi lng ethanol b cun theo bng thp ra CO2 (hp th ethanol). Thnh phn chnh
dng sn phm nh v y ca thp ny l: (chi tit xem ph lc 4.19)
Beer
Ethanol 0.027183

To_ferm
0.00859

Co2_stream
0.000001

0.99094

0.033305

0.00046

0.966690

5
H2 O

0.972206
9

CO2

0.000521

8
Dng Beer sn phm y ca thp loi CO2 c a cng vi dng hi nc
stream vo thp loi Methanol y l mt thp quan trong. Thp ny thc hin cng vic
loi b tt c Methanol trong dng sn phm ca qu trnh ln men. L mt thp hp th
s dng dng hi li cun cu t cn tch ln trong lng. Dng sn phm nh ca
thp T-100 c a ti thp tinh ch Main TS, thp Main TS c tc dng tinh ch loi
b sn phm nh, ethanol thu c th c ti sinh tr li thit b ln men. Dng sn
phm y ca thp Main TS cng vi dng sn phm sn Rect_feed c a ti thp
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Nhm 6

tinh ct T-101.(chi tit iu kin v thnh phn dng xem ph lc 4.22). Thp T- 101
l thit b c c nhm thu c hn hp ng ph ethano nc. Fusel l mt hn hp
ca cc Propanol, Butanol v Pentanol; n c gi tr cao hn Ethanol. S tch ly ca
Fusel oil trong thp tinh ch l nguyn nhn dn n s hnh thnh ca pha lng th hai
iu ny lm nh hng xu n hiu sut lm vic ca cc a trong thp. gii quyt
vn ny th Fusel oil cn phi c ly ra t cc a sn ca thp.
Rect_vap Rect_dist

1stprod
Fusel
stillage B
Mole Fractions
Ethanol 0.8917
0.892
0.889
0.690
0.0034
8
7
8
H2O
0.1022
0.105
0.109
0.305
0.9962
0
2
6
(chi tit iu kin cc dng sn phm v thp xem ph lc 4.22 v 4.17)
3.1.2 Kt qu m phng

Hnh 3.1: Qu trnh m phng x l sn phm ca qu trnh ln men tinh bt

3.2 M phng qu trnh chng chit ethanol s dng dung mi MEG
3.2.1 Qu trnh m phng chng chit ethanol
Qu trnh bt u t dng nguyn liu Hydrous ethanol v dng mono
ethylenglycol (MEG), c i qua thit b thp chng chit Extractive tch ethanol thu
c ethanol khan c tnh khit cao ri qua thp Recycle thu hi dung mi MEG
ti sinh li thp Extractive dng hi lu ny c i qua cc thit b nh bm, thit b gia
nhit mc ch m bo p sut v nhit hi lu li thp Extractive.
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Hydrous ethanol
MEG

Thp Extractive

Thp Recycle

Anhydrous
ethanol

Pure
Water

Solvent

Hnh 3.2: Quy trnh m phng

Qu trnh m phng s dng m hnh Peng-Robinson. Nguyn liu ethanol v
MEG i vo nhit 25oC, p sut 1 atm, lu lng ln lt l 50 v 100 kmole/h vi
thnh phn dng HYDROUS ETHANOL ethanol chim 95% cn li l nc. Dng
MEG c thnh phn Eglycol chim 99% cn li l nc (xem bng 4.1 v bng 4.2 phn
ph lc).
conditions
Name
HYDROUS ETHANOL
MEG
o
Nhit [ C]
94.35
88.50
p sut [Kpa]
160
112.0
Tc dng [kgmole/h]
100
79.86
composition
Phn mol
Ethanol
0.95
0.00
H2O
0.05
0.01
MEG
0.00
0.99
Dng MEG c a vo a s 3, dng HYDROUS ETHANOL vo a 12 ca
thp Extractive [4]. Thp Extractive c thit lp 20 a vi ch s hi lu l R=1.9, lu
lng dng sn phm nh l 100 kmole/h, p sut nh v y ca thp Extractive ln
lt l 101.3 v 202.6 kpa. (xem bng 4.10 phn ph lc).
Name Column
Number of stage

Inlets
Condenser Pressure[kpa]
Lp Lc Ha Du K52

EXTRACTIVE
20
Name
MEG
HYDROUS
ETHANOL
Pressure Profire
101.3
12

Inlet stage
3
12

 n mn tin ng dng

Nhm 6

Reboiler Pressure [kpa]

202.6
specifications
Reflux Ratio
1.9
Liquid Rate [Kgmole/h]
100
Dng ANHYDROUS ETHANOL l dng sn phm ethanol khan, dng
BOTTOMS dng sn phm y ca thp Extractive thnh phn gm c c H2O, ethanol
v Eglycol c a n thp RECYCLE thp ti sinh dung mi Eglycol. Dng PURE
WATER sn phm nh ca thp thnh phn chnh l nc, dng dung mi SOLVENT
c thnh phn chnh l eglycol l sn phm y ca thp c ti sinh tr li thp
Extractive. (xem bng 4.11 phn ph lc)
Name Column
Number of stage
Inlets

RECYCLE
10
Name
BOTTOMS
Pressure Profire
Condenser Pressure[kpa]
101.3
Reboiler Pressure [kpa]
101.3
specifications
Reflux Ratio
0.30
Liquid Rate [Kgmole/h]
14.02
3.2.2 Kt qu m phng qu trnh

Inlet stage
5

Hnh 3.3: s m phng c qu trnh chng chit ethanol

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Nhm 6

Kt qu dng sn phm nh ca thp Extractive

Worksheet/composition
Phn mol
Ethanol
0.995446
Eglycol
0.000025
H2O
0.004529
3.2.3 Kt qu ti u ca qu trnh
Kt qu ti u nhit c th hin hnh 3.3. nhit , p sut dng
HYDROUS ETHANOL vo thp EXTRACTIVE l 88.5 oC v p sut 160 kpa.

Hnh 3.4 : ti u nhit dng HYDROUS ETHANOL

Nhit , p sut dng MEG l 88.5 oC v 112.0 kpa ( xem bng 4.2 phn ph
lc). Nhit dng MEG khng nh hng n nng ethanol thu c nh ngc
li dng HYDROUS ETHANOL c nh hng n nng ethanol nh l do nhit
dng nguyn liu ny nh hng n bay hi, ngng t ethanol ti a np liu.
Kt qu ti u lu lng dng MEG, lu lng dng dung mi MEG c nh
hng n phn mol ethanol sn phm nh do Eglycol l dung mi c tc dng li ko
cu t nc gip ph im ng ph ca hn hp ethanol nc.

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Nhm 6

Hnh 3.5: Ti u lu lng dng dung mi MEG

Da vo th ta chn lu lng dng MEG l 85 kmol/h. lu lng dng
HYDROUS ETHANOL l c nh 100 kmol/h. (xem bng 4.1 phn ph lc)
Kt qu ti u t s hi lu ca thp Extractive, t s hi lu nh hng n phn
mol ethanol ca dng sn phm nh quyt nh tnh khit ca dng sn phm nh.
Reflux Ratio (R)
1.0
1.2
1.3
1.4
1.5
1.6

Mole Fractions
ethanol
0.994812
0.994872
0.994998
0.995446
0.995162
0.995214

Bng 3.1 : phn mol ca ethanol ph thuc vo ch s hi lu

T kt qu trn ta c th gi ch s hi lu v phn mol ca ethanol trong dng
sn phm nh.

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Moler Fractions ethanol

0.9955
0.9954
0.9953
0.9952
0.9951

Series1

0.995
0.9949
0.9948
0.9947
0

0.5

1.5

Reflux

Hnh 3.6: Ti u ch s hi lu ca thp Extractive

Da vo th ta thy ch s hi lu ti u l R= 1.4
Kt qu ti u lu lng dng nh ca thp Extractive dng sn phm ethanol
t tinh khit l ethanol khan.
Distillate Rate (thp Extractive)
Mole Fractions (ethanol)
70
0.994559
75
0.994603
80
0.994620
85
0.994611
86
0.994606
90
0.994579
95
0.994514
100
0.950017
Bng 3.2: Phn mol ethanol ph thuc vo lu lng dng nh
Qua bng ta c th

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Mole Fractions ethanol

1
0.99
0.98
0.97

Series1

0.96
0.95
0.94
0

20

40

60

80

100

120

Distillate Rate

Hnh 3.7: phn mol ethanol dng sn phm ph thuc lu lng dng sn
phm nh
Qua th ta thy ti v tr lu lng t 86 kmol/h th nng ethanol t tinh
khit cao. (xem bng 4.3 ph lc)
Worksheet/composition
Phn mol
Ethanol
0.995446
Eglycol
0.000025
H2 O
0.004529
Kt qu ti u ch s hi lu ca thp Recycle, thu c dng dung mi
Eglycol c tinh khit cao ti sinh tr li thp Extractive th ta ti u ch s hi lu
ca thp Recycle ngoi ra C th ti u s a, a np liu cng nh lu lng dng ra
nhng thng s ny c ti u bng thit b shortcut column trc. Thp Recycel c
10 a, a np liu l 5, lu lng dng nh l 14.02 kmol/h v ch s hi lu l 0.3 kt
qu thu c dng sn phm y.
Worksheet/composition
Ethanol
Eglycol
H2 O

Lp Lc Ha Du K52

17

Phn mol
0.000001
0.992196
0.007803

 n mn tin ng dng

Nhm 6

CHNG 4: PH LC
4.1 Bng ph lc ca cc dng v thit b trong qu trnh m phng tinh
luyn ethanol s dng dung mi MEG
Ph lc 4.1: thnh phn dng nguyn liu Ethanol
conditions
Name
Nhit [oC]
p sut [Kpa]
Tc dng [kgmole/h]
composition
Ethanol
H2O
MEG
Ph lc 4.2: Thnh phn dng dung mi MEG
conditions

HYDROUS ETHANOL
94.35
160
100
Phn mol
0.95
0.05
0.00

Name
MEG
o
Nhit [ C]
88.50
p sut [Kpa]
112.0
Tc dng [kgmole/h]
79.86
composition
Phn mol
Ethanol
0.00
H2O
0.01
MEG
0.99
Ph lc 4.3: Thnh phn dng sn phm ANHYDROUS ETHANOL
conditions
Name
ANHYDROUS ETHANOL
o
Nhit [ C]
78.15
p sut [Kpa]
101.3
Tc dng [kgmole/h]
85.97
composition
Phn mol
Ethanol
0.995446
H2O
0.004529
MEG
0.000025
Ph lc 4.4: Thnh phn dng sn phm y BOTTOMS ca thp Extractive
conditions

Lp Lc Ha Du K52

18

 n mn tin ng dng

Nhm 6

Name
BOTTOMS
o
Nhit [ C]
143.4
p sut [Kpa]
202.6
Tc dng [kgmole/h]
93.82
composition
Phn mol
Ethanol
0.100396
H2O
0.055658
Eglycol
0.843946
Ph lc 4.5: thnh phn dng PURE WATER
conditions
Name
PURE WATER
o
Nhit [ C]
78.68
p sut [Kpa]
101.3
Tc dng [kgmole/h]
14.02
composition
Phn mol
Ethanol
0.672054
H2O
0.327918
MEG
0.000029
Ph lc 4.6: thnh phn dng SOLVENT sn phm y ca thp Recycle
conditions
Name
SOLVENT
o
Nhit [ C]
193.8
p sut [Kpa]
101.3
Tc dng [kgmole/h]
79.80
composition
Phn mol
Ethanol
0.000001
H2O
0.007802
MEG
0.992196
Ph lc 4.7: Thng s thit b bm P-100
Design/connections
Design/Parameters
Name
P-100
Adiabbatic Efficiency
75%
Inlet
SOLVENT
Worksheet/Conditions/To E-100
Outlet
To E-100
Vapour
0.0
Energy
Q-P100
Pressure[kPa]
112.0
Fluid Package
Basis-1
Ph lc 4.8: Thng s thit b lm lnh E-100
Design/Connections
Name
E-100
Lp Lc Ha Du K52

19

 n mn tin ng dng

Nhm 6

Inlets
Energy
Outlet
Fluid Package

To E-100
QR-E100
COLED SOLVENT
Basis-1
Work sheet/conditions/Feed-M4
Pressure(kPa)
0.0
Ph lc 4.9: Thng s thit b RCY-1
Connections/Connections
Workshet/composition
Name
RCY-1
Ethanol
0.0000
Inlet
COLED
Eglycol
0.9923
SOLVENT
Outlet
MEG
H2O
0.0077
Fluid Package
Basis-1
Workshet/conditions/RCY1
Temperature[C]
88.5
Pressure[kPa]
112.0
Molar Flow[kmol/h]
79.80
Ph lc 4.10: Thng s thp Extractive
Design/Connections
Name Column
EXTRACTIVE
Number of stage
20
Inlets
Name
Inlet stage
MEG
3
HYDROUS
12
ETHANOL
Condenser
Total
Stage Numbering
Top Down
Ovhd Liquid Outlet
ANHYDROUS ETHANOL
Bottoms Liquid Outlet
BOTTOMS
Condenser Energy stream
QC1
Reboiler Energy stream
QR1
Pressure Profire
Condenser Pressure[kpa]
101.3
Reboiler Pressure [kpa]
202.6
Condenser Pressure Drop
specifications
Reflux Ratio
1.4
Liquid Rate [Kgmole/h]
86
Ph lc 4.11: Thng s thp RECYCLE

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20

 n mn tin ng dng

Nhm 6

Design/Connections
Name Column
RECYCLE
Number of stage
10
Inlets
Name
BOTTOMS
Condenser
Total
Stage Numbering
Top Down
Ovhd Liquid Outlet
PURE WATER
Bottoms Liquid Outlet
SOLVENT
Condenser Energy stream
QC2
Reboiler Energy stream
QR2
Pressure Profire
Condenser Pressure[kpa]
101.4
Reboiler Pressure [kpa]
101.4
Condenser Pressure Drop
0.000
specifications
Reflux Ratio
0.30
Liquid Rate [Kgmole/h]
14.02

Inlet stage
5

4.2 Bng ph lc ca cc dng v thit b trong qu trnh m phng x l sn

phm sau khi ln men tinh bt
Ph lc 4.12 : bng thnh phn dng nguyn liu u vo
Streams name
Temperature [oC]
Pressure [kPa]
Molar flow [kmol/h]

Wash_H2
O
25

FromFer

StreamA

30

140

101.325
130

101.325
2400

101.325

Mass flow [kg/h]

Ethanol
H2O
CO2
Methanol
Acetic acid
1-Propanol
2-Propanol
Lp Lc Ha Du K52

11000
Worksheet/composition
0
0.0269
1
0.9464
0
0.0266
0
2.693e-5
0
3.326e-6
0
9.077e-6
0
9.096e-6
21

0
1
0
0
0
0
0

 n mn tin ng dng

Nhm 6

1-Butanol
3-M-1-C4ol
2-Pentanol
Glycerol
Ph lc 4.13:Thp tch CO2

0
0
0
0

6.578e-6
2.148e-5
5.426e-6
6.64e-6

0
0
0
0

Design/Connections
CO2_vent
FromFer
Vapour outlet
To_CO2Wash
Liquid outlet
Beer

Name
Inlets
Outlets
Ph lc 4.14: Thp x l kh CO2
Name
Design/connection
s

Pressure profile

CO2 Wash
No. of stage
10
Inlet
stream Wash_H20 (top stage)
(stage)
To_CO2Wash
(bottom
stage)
Overhead vapour
CO2_Stream
Bottoms liquid
To_Ferm
Stage 1
101.235 kPa
Stage 10
101.325 kPa

Ph lc 4.15: Thp loi b hon ton Methanol

T-100
Connections

Name
Design/Connections
No. of stage
Feed stream (stage)
Overhead vapour
Bottoms liquid
Side draw vapour(stage)

Presure Profile
Temperature Estimate
Specifications

Lp Lc Ha Du K52

Condenser
reboiler

17
Beer

(top stage)

Stream A (bottom stage)

To_light
Stillage A
Rect_feed (stage 6)

Condenser temperature

101.325 kPa
102.325 kPa
90 C

Reboiler temperature
1.Comp recovery

110 C
Active

22

 n mn tin ng dng

Nhm 6

- Draw
Rect feed
- Spec Value
0,95
Design [specs]
- Component
Ethanol
2.Draw rate 1
Estimate
- Draw
React feed
- Flow basis
Mass
- Spec value
5000 kg/h
3.Draw rate 2
Estimate
- Draw
To_light
- Flow basis
Molar
- Spec value
1000 kmol/h
Ph lc 4.16 : Thp tnh ch ti y cc thnh phn nh c loi b b Ethanol thu
c (2nd EtOH)
Name
Connections

Presure profile
Design [Specs]

Lp Lc Ha Du K52

Main TS
Design/Connections
No. of stage
5
Inlet stream (stage) To_light (bottom stage)
Condenser type
Partial
Overhead vapour
Light_Vent
Over head liquid
2ndEtOH
Bottom liquid
To_Rect
Cond.energy
CondDuty
Condenser presure
101.325 kPa
Reboiler presure
101.325 kPa
Design/Specs
1.Vap Prod Rate
Active
Draw
Light_Vent
Flow basis
Molar
Spec value
1,6 kmol/h
2.Comp fraction
Active
Stage
Condenser
Flow basis
Mass fraction
Phase
Liquid
Spec value
0,88
Component
ethanol
3.Reflux ratio
Estimate
23

 n mn tin ng dng

Nhm 6

Stage
Condenser
Flow basis
Molar
Spec value
5.00
Distillate rate
Estimate
Draw
2ndEtOH
Flow basis
Molar
Spec value
2,1 kmol/h
Ph lc 4.17: Thp tinh ct (sn phm ca qu trnh ny l hn hp ng ph ethanol
nc)
Name

T-101
Design/Connections

Connections

No. of stage
Inlet stream (stage)
Condenser type
Overhead vapour
Overhead liquid
Reboiler duty
Condenser duty
Side draw liquid (stage)

Presure profile

Condenser presure
Reboiler presure
Condenser temperature
Reboiler temperature

29
To_Rect
(19)
Rect_Feed (22)
Partial
Rect_Vap
Rect_Dist
Stillage B
Rect_Reb Q
Rect_cond Q
1stProd (2)
Fusel (20)
101.325 kPa
101.325 kPa
79oC
100oC

Design/Specs
1. Reflux ratio
Stage
Flow basis
Spec value
2. Ovhd Vap Rate
Draw
Flow basis
Spec value
3.Distillate Rate
Lp Lc Ha Du K52

24

Active
Condenser
Molar
7100
Active
Rect_Vap
Molar
0.100 kmol/h
Active

 n mn tin ng dng

Nhm 6

Draw
Rect_Dist
Flow basis
Mass
Spec value
2.0 kg/h
Design/specs
4. Comp fraction
Active
State
2_main TS
Flow basis
Mass fraction
Phase
Liquid
Spec value
0.95
Component
Ethanol
5. Fusel draw rate
Active
Draw
Fusel
Flow basis
Mass
Spec value
3 kg/h
6. 1stProd Draw Rate
Estimat
Draw
1stProd
Flow basis
Molar
Spec value
68 kmol/h
Parameters/solver Damping factor (enable)
0.25
Ezeotrope check
ON
Ph lc 4.18: bng hai dng sn phm ca thp tach CO2
Beer
To CO2 wash
o
Temperature [ C]
30
30
Pressure [Kpa]
101.3
101.3
Molar Flow [kgmole/h]
2334
66.47
Mole Fractions
Ethanol
0.027183
0.016966
H2O
0.972206
0.040875
CO2
0.000521
0.942106
Methanol
0.000027
0.000013
Aceticacid
0.000003
0.000000
1-Propanol
0.000009
0.000010
2-Propanol
0.000009
0.000009
1-Butanol
0.000007
0.000006
3-M-1-C4ol
0.000022
0.000008
2-pentanol
0.000005
0.000007
Glycerol
0.000007
0.000000
Ph lc bng 4.19: bng 2 dng sn phm ca thp CO2 wash

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25

 n mn tin ng dng

Nhm 6

Co2_stream
To_ferm
Temperature [ C]
26.06
33.34
Pressure [Kpa]
101.3
101.3
Molar Flow [kgmole/h]
64.72
131.8
Mole Fractions
Ethanol
0.0000
0.0086
H2O
0.0333
0.9909
CO2
0.9667
0.0005
Methanol
0.0000
0.0000
Aceticacid
0.0000
0.0000
1-Propanol
0.0000
0.0000
2-Propanol
0.0000
0.0000
1-Butanol
0.0000
0.0000
3-M-1-C4ol
0.0000
0.0000
2-pentanol
0.0000
0.0000
Glycerol
0.0000
0.0000
Ph lc 4.20: bng dng sn phm ca thp T-100
To_light
rect_feed
o
Temperature [ C]
85.88
94.81
Pressure [Kpa]
101.3
101.6
Molar Flow
10.03
316.7
[kgmole/h]
Mole Fractions
Ethanol
0.316430
0.190280
H2O
0.560985
0.809175
CO2
0.121216
0.000000
Methanol
0.000164
0.000196
Aceticacid
0.000002
0.000003
1-Propanol
0.000319
0.000057
2-Propanol
0.000310
0.000057
1-Butanol
0.000148
0.000044
3-M-1-C4ol
0.000127
0.000157
2-pentanol
0.000300
0.000030
Glycerol
0.000000
0.000000
Ph lc 4.21: Ba dng sn phm ca thp Main TS
light_vent thu duoc ethanol
o
Temperature [ C]
46.35
46.35
Pressure [Kpa]
101.3
101.3
Molar Flow
1.600
2.101
[kgmole/h]
o

Lp Lc Ha Du K52

26

Stillage a
100.3
102.3
2617

0.000000
0.999991
0.000000
0.000000
0.000003
0.000000
0.000000
0.000000
0.000000
0.000000
0.000006
To_rect
79.71
101.3
6.332

 n mn tin ng dng

Nhm 6

Mole Fractions
Ethanol
0.191630
0.761541
H2O
0.049114
0.236087
CO2
0.758876
0.000736
Methanol
0.000158
0.000378
Aceticacid
0.000000
0.000000
1-Propanol
0.000046
0.000395
2-Propanol
0.000175
0.000828
1-Butanol
0.000000
0.000006
3-M-1-C4ol
0.000000
0.000000
2-pentanol
0.000001
0.000028
Glycerol
0.000000
0.000000
Ph lc 4.22: kt qu 5 dng sn phm ca thp T-101
Rect_vap
Rect_dist
1stprod
Temperature [oC]
77.99
77.99
96.16
Pressure [Kpa]
101.3
101.3
199.0
Molar Flow
9.997e-2
4.640e-2
67.97
[kgmole/h]
Mole Fractions
Ethanol
0.8917
0.8928
0.8897
H2O
0.1022
0.1050
0.1092
CO2
0.0029
0.0000
0.0000
Methanol
0.0030
0.0020
0.0009
Aceticacid
0.0000
0.0000
0.0000
1-Propanol
0.0002
0.0000
0.0000
2-Propanol
0.0000
0.0000
0.0003
1-Butanol
0.0000
0.0000
0.0000
3-M-1-C4ol
0.0000
0.0000
0.0000
2-pentanol
0.0000
0.0000
0.0000
Glycerol
0.0000
0.0000
0.0000

0.200251
0.798170
.0000046
0.000094
0.000003
0.000362
0.000172
0.000233
0.000201
0.000466
0.000000
Fusel
85.88
133.9
7.985e-2

0.6908
0.3056
0.0000
0.0001
0.0026
0.0009
0.0000
0.0000
0.0000
0.0000
0.0000

stillage B
98.79
101.3
254.8

0.0034
0.9962
0.0000
0.0000
0.0000
0.0001
0.0000
0.0001
0.0002
0.0000
0.0000

TI LIU THAM KHO

1. CC QU TRNH, THIT B TRONG CNG NGH HA CHT V THC
PHM Tp 4. GS.TSKH. Nguyn Bin
2. M.A.S.S. Ravagnani a,* , M.H.M. Reis a, R. Maciel Filho b, M.R. WolfMacuelb .Anhydrous ethanol production by extractive distillation: A solvent case

Lp Lc Ha Du K52

27

 n mn tin ng dng

Nhm 6

study 2009 The institution of chemical Engieers. published by Elsevier B.V.All

rights reserved.
3. HYSYS 2004.2 Tutorials and Applications 1981-2005 by Aspen Technology,
Inc. All rights reserved. (File hng dn s dng trong phn mm aspen hysys)
4. I.D. Gil1*, A.M. Uyan1, J.L. Aguliar1, G. Rodriguez1. L.A. Caicedo1. 1Department
of Chemical Engineering - National University of Colombia. SIMULATION OF
ETHANOL EXTRACTIVE DISTILLATION WITH A GLYCOLS MIXTURE
AS ENTRAINER
5. http://en.wikipedia.org/wiki/Antoine_equation

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