Prof.DrNagesh Kalvanka KALYANKAR aa oNFET[SEE Vee, = CHEMISTRY TOPIC NAME: ( S- BLOCK ELEMENT ) CLASSES ‘Vashwant Cotlege Rood. Lied, } KO, —= Pale Yellow REO, = Urhght Vettow C0, a OFange kK +o, Rh +0; Be + 0; ——— eo Uno) gives My) Q,———__- 4. Lie 8 (UA iteide) So, Li Readed with Air sii ON 1S Group=2 clementg. . . with 5 Frag a > Mix, ail sd al Misy Be.Mg Ca, St, Ba i © ux +g0——\+ tion > ut. Metal G10 4,0 -—— rome, 6 = 24M +110 ——— ot Ha" with Hydrogen te G1 eM | 1y;——————e it | 10 U0, 2 iiaeco, Paramaqnel | NCO 6 CaCO tae ree) Blue colewr | Trick, | Met canbnste 2 aeteie 060, Best Reducer V1 Me Oy to HaCO,———2 stata onic 60, # heconcertrabion- | | 3. BeSO, ta HS, —-——* Metal ovide #806 Oy (Ms Nak tn,.09) Tei NO,), to fa (NO) —————* 10+ Oe O; 18. {NCO} Preparation by Solvey Prncess jum carbonate {, ————* Ammonis —————* [Jrine Sotution FTN"6. NxiCO}S10;-—$-nassio,+ 0)" ; Page — 3 MCL NaC, ay Nac + CO;+0, 18. Nat. prepared by “Ciataee hellner Celt” Se Sro aad exadlojeigo (Disprepernation Ret) Ss S401 vacls sadio «10 ( DigpROPORRA ER RE") aca, . * \ + NaOlt ———* nach + saci 1,0(, . =a ; . + 3 32 Besson santo, Fa, OD ispropomaien: RX) 3. y+ S40 sar sons tho 128 Fy+ Ns0H—-sar- 0,+ 10 |26.€0, +Na01t——— Na €0, «11,0, $8a,0,05:10110—— =» Na) 5 natiogstt0y,34. BN +10 —nom,ennt Myo, ——_ "sano, “1,0 160" eA 411,10, ——————-.11,0,+311,0 RS) 4 wt B,0, + 31,0 2440, ————_- 37) Red Hot 384 43LIAN————+ 20 TTA ILICL + SAIC : ether a jy, e2Namn; angst ny . 450K : 40, 2BF, +6Nall = BU, + 6NaF at. 8,11, + 30, ————= 8.0, « 31,0 120° | 241,11, +2N1) —————> 21 200°C | 2 BR = iN), + att; } rages DyNsH, (Borazole) Inorganic > graphaite53. Reaction of G— 14 clements: Page-5 Cy + HO, —————* C0 FaHvaawea, wae Gia Ong # Nagy ————* C0 +N Ratiom Dew rraducer san €aCO, + E+ C0110 0004 Clay +Ony Se co,,, eo CalOl) «©, + a6," = 11,0 ‘Milky _ SiO, + 4HF———+ iF, 20 Sik, + 2HF ———— Ht si, 2) SIREN NITYashwant College Road, | TOPICNAME : (REACTION OF Greta w19 + CLASSES NaCl+N,+21,0 Ny+Cr,0y+2H;0+ 41,0 % NH,NO,; —USt _- N,0#2H,0 07, 2NaNO)+2FeSO,+3H,SO,—— Fe,(SO,)+ "B= 2NsO5 ite itoroti 8. 2NO+N,O, 28 — < 2Pb(NOy); —“238 —~ 2PHOHINOS+02 t 10. 2NO;> ~ NOs) HLAHNOs#P O10 12. NaNOy+H,S0, HHSO+2NO+2HO SOct4 HPO, ISO,+1INOy 13. 4NH3(2)+50x(2) 4NO+611,0 IM, 2NO(g)+0,(g) . 3NO:(2)+ 00) 2HNOs+NO HINO, (ag) +11,0( ————— 1,0" +NO 3Cu +811 NO\(diL) 3Cu(NO3):#2NOHIO Cut4HNO,(cone.) Cu(NO5)+2NOy#2H,0 4Zn + LOHNO (dil) utc 4Zn(NOy),+N,O +5110 Zn +4HNO3(cone.) ————— Zn(‘NO});42NO2#2H,O 1, + 1OHNOs 2H10,+10NO;+411,0 C+4HNOs CO,;+4NO;4211;0 Sq+4811NO; = 81,0, +48NOy+1611,0 » +20TINOs(cone.) 4HjPO,+20NO;+41,0 @® NO} 43Fe"*+4H'————+ NO + 3Fe""211,0es w co 29, ee wt Sarees = 38, 40. 43. Ad. 45. 46. 47. 48. 49. [Fe(Hz0),/"+NO [Fe(I,0)+NOP* +110 cenowyen (Brown) 3Nall,POy+PHy Paget {Sodium hy pophosphite) P450;———+PiOy 5 Ty-+302—> PWD CaP +6H,0 + 3Ca(OH),42PHy Py+ 3NaQOH + 31,0 Ca,P;4+6HCI 3CaCl,+2PHy PH3t+HI PHI PH,I + KOH PHs+KI+H;0 3CuSO,+2PHy CuyP t+ 3H S04 3HgCl,+2P Hy HP 6HICL PH +11 Br,-—- PH, Br~ P+6C], —————- 4 : Py+8SOCl, + 4P C1, 4480 ;428,Ch; P-Cly+31 0 —————+ 1, PO+311C1 3CHyCOOH+PC],———+ 3CH ,COCI+H POs 3C; HOH + PC1, + SCI Cl + HPO P,+10C], —————~ 4PCls Py+10SO,;C1—————~ 4P C1. + 1080; PC1¢H,0 ———- POC, #211C1 POCIy+3 yO ———— 1 P0,4311C1 PCI, "+ P14 Cs CyHOH+P.C1l,k ————~ C HCH POC HHICI CH,COOH +PCIs CH,COCHPOCL+HCIL 2Ag +PCly ———— 2AgC 1 +PCly Sn+2PClk—— Sal +2P Cl 3 4AgNOy O+HsP! 4Ag+4HNO;t+H;PO, re) NH,CONH,+2H,0: (NH .):;CO;==2NHy+H,04CO, ZnSO4+2NU,OH—— Zn(OW) 34 (NH):804 FeCly+3NH,OH Fe(OH)s+3NH,Cl Cur" #(aq) IN; —_——$ CaN) een ie Heat Ca(OH);+2NHL,C1L——— CaCl,+2NHj+2H,0 ©e-& GROUP 16 . faq 58. 2NaOH +(NIL):80, ial Na,SO#2NII3+2H,0 ScClyt 38e 59 2Se:Cly = Catalyst GY akci0,>| 7 2KCI+30; 61, 2Ag,0(s) 4 AgO(s)+O.(g) 62. MeO(sy 2y(J+02(2) 63. 2H,02(aq) ————— 21,0 (+0; 64. 4A1+30, 2AL05 65. 2ZnS + 30; 27nO0+3S80, B roro, HCl+0 ‘G8. SOs+H1,0 69, CaO +H,0 HSOs Ca(OH); 70) Al;Ox(s) + GHCI(aq)+9 HOC) ————+ 2] AN(H,0) 1° +6CL_ Al,Oy(s) + 6NaOH (ag) #311,0() ———+ Na AMON) (aq) PbS(s) + 405(g) —————- PbSO, + 40; 13. 21 (ag) + H,0(/) + Ox(g) 20H + 1(s) + Ox(2) 74. NO(e) + Os() 75. SOs*(aq) + 21 (uq) 76. 4FeS;(ag) +1102(g) 77. 2NaOH + SO; 78. Naz:SQs + H,0 + SO; 79. SOx(g)+Cl,(aq) 30. 2Fe*’ +S0,+211,0 NO;+0, H,0 +80; 2Fe:05 + 880; Na,SO.+ 11,0 2NaHSO, SO;Ch) 2Fe"+ SO, + 4H? 11, 580; +2MnQ, +2H,0 580," +41 + 2Mne* 2, SO;+H,O0SO, H,S,0, 3. H,SO,(ag) + H,0() H,O°+HSO, 4, 2MX+H,SO,—————> M80, + 2HX (X= F, Cl, NOs) H,SO, 3. CrH2On 12C +11H,0 ; Cu + 2H,S0; CuSO,+ SO, +2H,0oo -9 37, S + 2H,SO,(conc.) ————+ 380 #2110 Peat C + 211,80 ,(cone.) ————+ CO) + 280) #210 39. CaF,+H,SO, CaSO, 2NF 90. SO; +H,0 H,SO4 GROUP 17 a) FN $2 +x, [X's Br, CLT % Ch2x $21 +X, [Nis Br Tt] Vv oy Bra? P28 +1, 94. 2E,(g) + 2H;0() ———- 4" +4F +0; 95. Xq(g) + H,O() ————+ HX+HOX(aq)[X=CLBC] ml 96. 41 (ug) +4 (aq) +08) 21;+2H,0. 97. Mg(s) + Br,(f) —————+ MgBr; 98, MnO, +4HCI MnCl, +2H,0 + Cl; _. 4NaCl+ MnOy+4H,SO, 100. 2KMnO,+16HCI 101. 2A1+3C1 102. P6Cls 103. S,+4Cl; 104. H+ Ch 105. H:S+Ch; 2HCI+S 106. Ciotlis + 8Cly IGHCI + 10C N H,Cl+ N;! e 2NaOH + Cl; ——+ NaCl + NaClO + H:0 MnCl; + 4NallSO,+2H,0+Cl, 2KCI+2MnCl; + 5Ch, + SH,0 AICI APCh Ch Sun lig 2HCI (coi e ai 6NaOH +3Cl; ———* SNaCl + NaCl0) + 31130 (hot & cone.) {Gy 202/01 +24 —$+ca(0CH 3+ Cacl+ 2140 i a ena ch CHCl + HCI‘14. 2FeSO; + H,SO, + Cl, 11S. NaySO,+ Ch, + 1,0 Na2SO4 + 2H1CI 116, SO; +2H,0 + Cl, $O,+2HCI 1 + 6H;0 + SCl; ——> 2HI0, + 10HCI Cl; + 10 ——+ 2H1C1 +10] Coloured substance + [0] colourless, 119. NaCl + HyS0, ——"* ___ Nanso, + HCI 120, NalSO, + NaCl = Na,SO, + HCI 121. HCKg) + HO) Ho+cr 122. NIL, + HCI NILCI 123. Au + 41 + NOs +41 ——. AnCly + NO +21,0 3PL+ 16H + 4NOy + 18C1) ——- 3MC12 +4NO+ SHO fercens) 129, 1; + Cl; ———- 21C1 130. 1, +3Cl, ——- 21C1, 131, Br; +3F; ——+ 2BrF, 132, Br, + SF, —— 2BrF, 133. Ag + Cl + AgCl AgGl + 2NHs(aq) ——+ [Ag (NH5):1C1 * GROUP 18 135,:Xe + F; —Z8 1. xepy(s) = 7 © Struchtume 136. Xe + 2F; Thar XeF,(s) P © “Toko! No. of Lene pain: 573K 137. Xe +3F; 60-70 bar XeF,(s) Fe; (SO,)5 + 2HCI Fag» U(s) +3CIF, » XeF, +O, F, UF, 43C1F Nek, +0; 2NeF (8) + 211 ,0(f) ——+ 2NeHHHF 40; [ASL Nek, +PEy [XeF] IPE.) . XeF;+ ME M'[XeF-] [M=Na K.Rb ar Cs] “6NEF, #12 ;0 Xe + 2NCO 24 F330, 0 2 ACOLEY W472, Ne + Pt, ——+ | Ne] PU 148. NePy + She —$——+| NeF | + [SEALtar (04 IES THEORY. NET. NUL CET.APE (Maine & Ads anced Ss Prof.Dr.Nagesh Kalyankar Sir's KALYANKAR |Sere ‘Sint CLASSES | Yess Root TOPIC NAME : (REACTONS OF D= BLOCK) Shyam Nagar, NANDED Reaction of D-Block lem 01. MnO, + KOH + oO; K,Mn0,+H1,0 | jack) (Green) Ch KMn0,+ KCI A (Purple) 02. KMnO,——*__. K,Mn0,+ MnO, + O; cea eee: SemMewala eilium) 04\KMn0j + H,0 494 MnO;+KOH+Samnevsote, os MnO, + KOI Wales K;Mn0,+H1,0 + Samne wala ms oxidakien 4 Bast eaium 6) KMinO, +1;SO,+KIe K;S0,+MnSO,+H,041; (Acidic medium) +t ah, ab +3 @ kan04+n1,80,+%S0,——__- K,SO.+MuSO,H10+F (S04), (Acidic medit ee @ kmnocensoen,00, ——~x;soamasoanjosto, “(Acidic medium) 09, KMROMEKTE HO 4\ % (Neutral Medium) aS 10. KMn0j#1;+10 ——~ H10;#Mn0;+14,0 (Neutral Medium) Ss KT0y+Mn0;+H;0Pag eA \cidic Mediun a 0 KI Ip +3 +4 H,C,0, co; 2 0 HS g +4 +6 SO, SO; 3! 0 | KX TTT eK (X+ CLBr,1) 42 9 Na,S,0,. —————__>—_ S+ Na SO, ‘ ies = HNO, §_.—————]————_ no, +2 +3 | FeCl, FeCl +2 ‘4 SnCk =————_——————— snc, l oO H,0 a 8, K2S04+ MnSO4+ H20 ; QFoe 198 HS THFORY, NFP T MICE TATE (Maine & Advanced 5 2 r a rol.Dr.Nagesh Kalyankai cuss Joee KALYANI R | sewer MISTRY CLASSES Yael teal, | TOPIC NAME ‘sostmorco al vaerosin.oncc\ cae Na,Cr;0;+Na,SO,+H1,0 K,Cr,0;+NaCl Cr,0;+O; (y ‘ellow) (Green) deems (to AB ent Ky SogcesSOqeIKO* SE, 1. i)FeO. rOPNacont ii) Na,CrO,+H,SO, iii) Na,Cr,0, + KCI 207+H,SOs+H30;—-K;SO4¢CrO4H,0+CrO;—-Cr303+O; K:Cr:0;+H2SO,+FeSOy SOstCry(SO,)s+H1,0+Fe(SO.)s @3.K,Cr,0,+H;S0,+K1—- K Cry(SO4)s+H, 041; 08.K,Cr;0;+H;S0,+H,S —- K;SO¢Cry(SO,)s+H,0+S +HS0,+NaC1—- KHSO,+NallSO+Cr0;Cl;+H30 i (Red Brown) 2 CrO,Ch- m0 W,CrO4HCl “Their Chloride do not Reacted with KyCr30; \ (Oxalic acid) 11. AgNO + NaS,;0;—- AgiS;Os(white) 25 [Ag(S205)2]" (Black) into Thiosulphate @* CuSO.5H;0: ——-Blue victriol * 2nSO4, 71:0 ——+ white vietriol orrosive substance © Wg.Cl ——- Calomel < use asa electrode: ° —votiow * (KHgl+KOW) ite — Nessler’s Reagent [Mn** ——~ Pink ‘KMn0,—- Purple K,Cr;0; —- Orange K,CrO,——- Yellow Ce Green | CrO;——- Biue ‘CrO;Cl,—- Red Brown, ‘NO;—— Red Brown | | Br—- Red Brown BenProf.Dr.Nagesh Kalyankar Sir's cuass KALYANKAR | sic CLASSES Yashwant College Road, TOPIC NAME: Shyam Nagar, NANDED ‘REACTIONS OF IFSBLOCK ELEMENTS: «Rage 1) REACTION WITH HYDROGEN: Ly > Lowthanaigs os 2Ln+3H; ————+ 2a, SS ; 2) REACTION OF CARBON: ang oxideins @) 3La+C ————+ LajC Lathanide earbideX~7 3) REACTION WITILH,O Ln + 34,0 ———~ En (ON) #314 NOTE: La(OH) CeO PP(OW) Herren PL MONI: adii of Lanthani died Lontiuatsl ag La rer * Covalent Characterfed) + Fonte Characterfes-C) . Basie Charecter{es) 4 S 4. REACTION WITH OXYGEN : . din + 2Ln,0s+H;0 ————~ 2Li(OM)s 5. REACTION V NITROGEN: 2Ln +.N; ————> 2LnN “Lanthanide Nitride; 6. REACTION WITH HCI: | tun 6c aLnci3i,t NOTE: a —_ -Migeh Metal ———+ La Fe + Trances of C,S,Ca,Al; ‘Used manufacture . Of bullets and Shells ;ww ewe wee Tearagfecanieuecars FL Learning Tectalgue cart {i} ff IMPORTANT STRUCTURES IMPORTANT STRUCTURES: 1 Coavarian SiC, wo Saicom Leorgnic benzene (or) Horesione "y { " a aS cr MI {oy Morale (8%, learganic graphite Calciumcacblde Gacy Ry GEN cit eda tere Cerberus 4 silanes 2 Uydeasas Hysremic Retam NU [peremagmeti jes mememer 15,0055 IMPORTANT STRUCTURES erie RSME) Meee ed sot tue colour mm a [rmagmen, colenurtens) LM, LOY He are Ny Aly pe wite mes ae Sat i Nout a, «80, ta 80, 1 SOC paereeyt cbternde 12 Myerryt Ameer 115,00," C1aberaphate boa(Memes 1H omang seipheriy TNeetiasen's olptherie ool Merhatrs went Comet Dithienate tow, manne oe Tetrathienate be Pretnth iments inn ‘Thine! rhberiee IMPORTANT STRUCTURES 22 Wypepbenptar mee acd 1 FU, o Mester mt [mde eo recy agent 0380-0 -ieo eo 38 ist foto ot val jeri wid Feretediatph \ on NE y i r Me Senaphenpene oe oon mee o . Perevemeardnalpoors ard Wa on a o xs os oy ite of ON ea we" aid “i Fe fa io“ © 0 ols a 7 0 o Sarre oost d 8 ko 7 cs - o Sa. Fereyphenpierts acti HPO)tr IMPORTANT STRUCTURES Ch, Mat eee beet s - M0, WL 40, Cyebe Trmer [Vapeort Hie) Soran mat DEMO, = Ayu fareee RPe LDL ea g 0) =a) 145. HMO, fll wf sterdetl SS eee Ce RIEO uu tetiss te Sa, at. we, SLO $1 Cath, 1Catehom Cyaanibtey GN Cen ce ep \EOM . 7 lt ia we] “ee” Pn Se & Se ae! ao NaIMPORTANT STRUCTURES IMPORTANT STRUCTURESHogce BCeoAooOHNeaRoa B