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ACHEMTCAL KINETICS 37 3 Rote oh reackton + : : Te | quantity ‘of reactant species consumed OY the quantity of product species Formed (9 unit of time cn a Chemical Teact? o cabled the vate OF tha yeattton 8 "3 Consider, a general wactton A—2B! With the parsage ‘of time’ the Conc oF A goo OM Aeereacing whyie as the Conc.’ eB gd-m Inexeasing / a f 3 duck cones Reactant time Roke eb reaction ,(7) = amt 66 A consumed dime daken nv ‘xb. amt of B produced Time taxon Typu of vate of reaction *- aa ty Average ats The vok of weaction measund oven g long ; dime Uterval & called omg vate - < Rate of react? + ~ Atay at -\ 7 scannet wnt CamScanner we 5 ay ae yy feat Aled mvyPl i Aten. VE STgN signitien thak daning the CONC, Ob, the meachants decreases with paunege| oy Ame" wht tue sign Signtgeas tak | (COME Oh the produck increarer with paprege ob tte hud Reaction (2) Tnstakoneow ” aide omen neat pb ada Tt UW debinecl ap tenn, Pp one CONC Of ang. one of the reactant oF oie Spectey ak that. porticulan Tnstank of FMe. 4 Roe 6e reactions —~ 4 CAT at: a sot IN rate joh meaction 2, dle] ne at : Dnt ob vate of reaction *- Me G). Sine. cone U generally enpressed, En mel/y - Hen nik: of rote y mot uit® mes ie: | mol ut! sed", mel ur nin etc! CH) Bn case oF’ gone us tuathon , cone ale? replaced by presswue Hence unit *t wake” =| oh veactim UW atm time! ov bar ma! da ~akm geo ; otm min), ban set! phe. | eal a -2 A Scanned with CamsScanner Factors abiecting the rake oy reaction a | 1) Ebreck ght gb _conc fe Crreokerr the Cone oF the neackant r greater wil ‘be tw intermolecular otlision ¢ and hence Qseatey will be the rote of -meaction ? : o4S cand. pining nema th ain (20% ayaa but bwins more brightly tn a jar ob OXYGEN (1007 02) duc to high céne- of ses Ww Nakww_o redictant * oa f 98h tre " reccichaints ark Tonic ‘specien then thal wade Ob reaction ty” tnstantond otis « 9 Th the reactants ore molecular cpecied then the vote of reaction & clow- TU the FLactants ane gmall cized species then wate of reaction % fast - "PA meaction wilt proceed “baster tb the meaclents One ‘mixed tothe Wquid. phase ov solution phase’ then wNonied out under, heterogenous’: cond’ provided. ithe conc; ale same - ! | eq 7 sx we, Star, “to. dissolve sugan quickty when two ate in Same state’. ) Temp . Temp har a@ moaked effect on the wate oF chemical reactions Tn most Ob the eases ha, ro of reaction betomes double or trip canned wi aamsocanner ) | ' t i ‘ “yor a lw erice iH emp. + i 7 The wako of Hoe rode sopFane doing oF WC. B~ Known, ay : deme coursiccent and. 4 ee, CQpal (0. 9-3- Wes : KER sein CoekhiCtent, = Kesto 37 5 4 : i , ,a ; a ySnrith ate aeastin = 3g v eens W 0) Sioa ad =p) Rate 6h reactton ncreass ti simarcat Swiyace arto. ok ridactants © eg Poa Coal burns briliently: then eryptak ~7 Powdan sugar dissolve wapidly tin om suger GW) Etrbect oF “oh, eataliph’- ae Rake of aneaction Mar be inoreaszel by adding a Suitabl cakolypt « The “Substance” which ‘glow down the Cotkctlyst action rd known oD poison ov inhibitor: a wt > TAd Substance ovhich Nereaa: The cate Vackivity i Krol &) " promotor ér acteleriter yA cakdlyst “take part tn’ the: -reachon’. “Pt Gs “tengumed one | ‘shap oe ‘een i tho: the wakes, oF certain “gpomtcal sreackeons as i Greatly inkluenced by taght tmadcation) + Absorption Light may excite onea.theng, melee bree times > tre molecules broken down tinto. more reactive , inter midialis * rth meactions’ brought “about by light creda “one cabted photochemical eacton « 24> photography ,photosyntreris ee.: ie Modo expression erate of NERO a tohon wake 6h reaction can be expr i 0 | 3 dipreunt way 1 { @ Low of mas action é { CW) Rode of appearence and: dic appearence 2 Wu). Rok law - i hal om of Mass acon .- : —— Lt stokes that the “robe ob which & Subsianw TEACH: - is ipropotional 10 th . motor concantredio, and tar Trak Of Chemical _penckten is dec + PR portional to, molwr, Lone of ractank. and Cath reactant te, raised to the : oom. to ds _Stochiomatry “co efficient . ‘ “Congadan a reaction inating. two: cae A ane 3. fea > ih ; : Scanned with Cam$canner PMA AB > pay duck Sey ao, Tae, pec’ +0? Tow! Sf Mags? action COL OF Traction of fa” x fe)” tok =k k tay" (a)? : ® rd : | sas ~ preporitenatity. ee oF wake Const: i ov Valo city const. . 607, valocty © co chyictent ov speahic reaction , mode os ° ChaRD CHT BAGS ot creda. constant | Cth Value yo difyownt por Ae cn) Te doesnot depend on Conc OF reactant WY) Crreedor the walur of & A qerakur B® the Tok. Of Teackon ». ; a ' Gv) Ets valu & _ eons ak fixed Rs Be ! Danaus : with change in tear - W)Rate a9: (Rate, lox) * Consider a genoras ue rt ht n As Product pr ioral daw, the rate of neackion fey an « [A] [oyé For a cionple meaction a = eM andy = =A. Tha main dipownce “b/w vate” law GAA lows A maw actin, 6 thak Low of mass” acken Ws theori te cad) obsewvat" Whee ay rake tow 3. exparimenta observa . rea] Scanned with CamScanner lary’ ° ea oh A aah Law covvespinds. 10 -Slowert. steps He tomaplax reaction Ae slots FSB: Oh the svat _detvceitingy TBR fo ocio dye ga ates ~ For a Sing Step iad” the low 6b: mang nckton and the vrais law e2aprusion ont Ha, Sore, + However. “bos the" mkt pla | Lomp tx ack Hue ork dibruuent + i when Ae Mabe on. forms of Law of MMe ari -OCACOM, and rab tow aa. game ' Mhur: reaction is cath to be i stmpe ; reaction Om Chimentovey TAL aLECO - WRoke of ap Hite ‘and * -Assappuanunie 3 de uy Consider » & gonuras neachonTe®§ ah +be wet £AD rake of reaction. = yak of disap peariencs: iy A = Toke of des cep pranonca 8 B pirat, 3 Appranenck “oy C v= rake 9 appranene oD. rok, of reaction, > AOD, tate Tad EU eh ts Fox example Nagy + BHeegy 2NM3 cap a " se ACN} aC) cacti) | at s BATE let g sap scanntcrwht CamScanner Fn Tn TE OS ; Scanned with CamScanner

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