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“Trermody namice —? Ceo yolk mtemive and d Extensive, properties tae propesties = ra tem? “stem Ko 8 pent me oe did: Kone £€ Valve chang: ho aye to Balenive aus na clauge ho do Nohensive x “Rabon Pa % Ratio of 9 -Bxtensive popes = Znfenic | (&) = intensive « eal \ intensive papperties ts nok adel ihVe 117 nature g y Edowive prperles axe acldve I nature X work pHeak > not Mmt™ nor Ext. properbes Go3 site Hanlin and path fadion state funcho) > Ohly depend upon Dnibal ar) pha state o} proceas- paih_punet Funct”. —clepend upon both pnibal are firaltete ard path e| prncess xo Heak wick and Heat capaci toa _path funct” fund”, aye! ofher propesBes to State Funchon gpa dh 14S: oy 1A) 5 sate Punch G P Cm | ee ) Aue H Ayscand sures Ke btch _ wrk and Rent he a met > on the pystern > | eK t , hy tha aystem > ears AS GN Thera) Preagy are} Enatalpy of Reachirn ee eas i Tes sun eo} att Yond | enesqy of aystero : Te lu) = PEE + But Epyt —7 7 ¥ State funchar ¥ Extensive paoperlea by per mole or pes gram Internal ence tlennive ~¥ absolute Value > nok gacountable x Senge Dy BB. (du) = acountable / ¥ Us f(T) > BE. ty tuneof tein ony forided ae, i.e 3 say e- ¥ Ue S(t, Pvc) Porseal ¢ yt ee af Entralby s ¥ State func” x Exersive prwperbes by but | % Gbsolute value LH) es Geet AN Une ofthe rans phate | = F=f = Fox, (Vj-Vij [normal proceaa)> teen dt=o 0 = qno - dvso aati eget] ,| [PRB] tena =. ee dv=o clu= q+ =4, Wo = Hear At Cont Volume ip Called Infernal ¥ Heat a} Const volume-(4,=av) =state fuel dP=0 clU= 4—Pexy dV eae PR) 1-8.“ dv= qe =o = book done of Adiabade process Donte’ ie, duzo > shite funck” » Cop=6 Pnthalpy charge of aystern (dn) H = UFPV [— >= No chemical 17 Chemica} nenocturs No phe Uae pppoe Osun a only temp cevge : =| : Si 1) Ys : Where >[drq= Folal mate of goocoutes Prachi = tote) mole 4 geneous Rear} 1 du=dv dnsdu | cl (4m) (9) Phase Fyansfer process ( Reversible | (lo) EntwoPg ena in ape of guid ty Melb ay Meee oer et golid <2 guid dc= Liev af n° , ds=0 ceo [stte func?) ise +8-3032 08 loge ‘ on ve d= 2.3032 nA i ds = 2-3032 Mp gi aie els= 9.3032 Ny tog ¢ ve des nGinley natn - Ve v ds = neptnTeynRin a ds =< (OH) py Temp: a) process Bie (AH) yap. Tb ds= (OH) gus Tn Ertnby Fosronla wa) Entropy Chanse in dy = [An (ay) rap 5 publimthon prvcern 4 as Gi au % Tr jfolid de n, 0 lg? 7 Ps ) 3) Entooby char 3 78 lg a FY “Ghembat €Dyan= yg “CD ae nd Rentant- Cal Entsoby cha by Ente chang 5 Abntvease (ds Ami = @s) opt 45) sae (AS) universe Reversible prrcess cy tic sel Rev. lam) (RS Temipsotess precess [4s),.=° { 8 (4) =0 Core ot Sin (4), «7 Oe 7 bb) ong = o (4am Hace : . "Ts ids) 2+ dary Tey [eu 6) (45 any. 7 Ta lit) Dbr

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