“Trermody namice —? Ceo
yolk mtemive and d Extensive, properties
tae propesties = ra tem? “stem Ko 8 pent me
oe did: Kone £€ Valve
chang: ho aye to Balenive
aus na clauge ho do Nohensive
x “Rabon Pa % Ratio of 9 -Bxtensive popes = Znfenic |
(&) = intensive «
eal
\ intensive papperties ts nok adel ihVe 117 nature
g y Edowive prperles axe acldve I nature
X work pHeak > not Mmt™ nor Ext. properbes
Go3 site Hanlin and path fadion
state funcho) > Ohly depend upon Dnibal ar) pha state
o} proceas-
paih_punet Funct”. —clepend upon both pnibal are firaltete
ard path e| prncess
xo Heak wick and Heat capaci toa _path funct” fund”,
aye! ofher propesBes to State Funchon
gpa dh 14S:
oy 1A) 5 sate Punch
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met >
on the pystern > | eK t ,
hy tha aystem > ears ASGN Thera) Preagy are} Enatalpy of Reachirn
ee eas i
Tes sun eo} att Yond | enesqy of aystero :
Te lu) = PEE + But Epyt —7 7
¥ State funchar
¥ Extensive paoperlea by per mole or pes gram Internal ence
tlennive
~¥ absolute Value > nok gacountable
x Senge Dy BB. (du) = acountable /
¥ Us f(T) > BE. ty tuneof tein ony forided ae,
i.e 3 say
e-
¥ Ue S(t, Pvc) Porseal ¢
yt ee af
Entralby s
¥ State func”
x Exersive prwperbes by but |
% Gbsolute value LH)es
Geet AN Une ofthe rans
phate | = F=f = Fox, (Vj-Vij
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dt=o
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eget] ,| [PRB] tena
=. ee
dv=o
clu= q+ =4, Wo
= Hear At Cont Volume
ip Called Infernal
¥ Heat a} Const volume-(4,=av) =state fuel
dP=0
clU= 4—Pexy dV
eae PR) 1-8.“
dv= qe =o
= book done of Adiabade
process Donte’
ie,
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H = UFPV
[— >=
No chemical 17 Chemica} nenocturs
No phe Uae pppoe Osun a
only temp cevge : =| :
Si 1) Ys
: Where >[drq= Folal mate of goocoutes Prachi
= tote) mole 4 geneous Rear}
1
du=dv dnsdu | cl (4m)
(9) Phase Fyansfer process
( Reversible |
(lo) EntwoPg ena in ape
of guid
ty Melb
ay Meee oer et
golid <2 guid
dc= Liev
af
n° , ds=0
ceo [stte func?)
ise +8-3032 08 loge ‘
on ve
d= 2.3032 nA i
ds = 2-3032 Mp gi
aie
els= 9.3032 Ny tog
¢
ve
des nGinley natn
- Ve
v
ds = neptnTeynRin
a
ds =< (OH) py
Temp: a) process
Bie (AH) yap.
Tb
ds= (OH) gus
TnErtnby Fosronla
wa) Entropy Chanse in
dy = [An (ay) rap 5
publimthon prvcern 4 as Gi au
% Tr
jfolid de
n, 0 lg? 7 Ps )
3) Entooby char 3 78 lg a
FY “Ghembat €Dyan= yg “CD
ae nd Rentant-
Cal Entsoby cha
by Ente chang 5 Abntvease
(ds Ami = @s) opt 45) sae
(AS) universe
Reversible prrcess
cy tic
sel Rev. lam) (RS Temipsotess
precess [4s),.=°
{ 8
(4) =0 Core ot Sin
(4), «7 Oe
7
bb) ong = o (4am Hace
: . "Ts
ids) 2+ dary Tey [eu 6)
(45 any. 7
Talit) Dbr