Faculty of Science M.Sc. (Second Semester) EXAMINATION November/December, 2018 (CBCS Pattern)

C 6 E 9 A E
CC C50 0762 2E6 61E 7F8 819 BA FEE E3B B6D

7 1 7 1 B F
C5 507 62E E61 E7F F81 9B AF EE3 3B6 6D7 7FB
6 E 9 A E D F E
50 0762 2E6 61E 7F8 819B BA FEE E3B B6D 7F BE 57A
7 E 1 7 1 F 6 7 B 5
07 62E 61 E7 F81 9B AF EE 3B6 D7 FB E5 7A CC
62 61 E7 F8 9B AF EE 3B D FB E5 7A CC 50
62 E61 E7 F8 19B AF EE 3B 6D 7FB E5 7A CC 50 762
1 7
2E E61E E7F F81 9BA AFE EE3 3B6 6D7 7FB E57 7AC CC5 507 62E E61
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E 61 E7
1.
61 E7F 81 9B AF EE 3B6 D7 FB E5 7A CC 507 62E 61 E7 F81
A E 3 7 C 5 F
1E E7F 819 9BA FE E3 B6D D7F FBE E57 AC C5 076 62E 61E E7F 819 9BA
8 B A
7F 19 BA FE E3 6 7 BE 57 C C5 076 2E 61E 7F 81 BA FE
7F 819 BA FE E3 B6 D7 FBE 57 AC C5 076 2E 61E 7F 81 9BA FE E3
D F 9
(e)
(c)
N.B. :—
(b)
(a)
(d)
F8 819B BA FEE E3B B6D 7F BE 57A ACC C50 0762 2E6 61E 7F8 819 BA FE E3B B6D
19 A FE 3B 6D 7F BE 57 C 50 76 E 1E 7F 19 BA FE E3 6D 7F
BA FE E3 6 7 BE 57 AC C5 76 2E 61 7F 81 BA FE E3 B6 7 B
FE E3 B6 D7F FBE 57 AC C5 076 2E 61E E7F 819 9BA FE E3 B6 D7 FB E57
(ii)
(i)
(iii)
E3 B6 D7 B 57 AC C5 07 2E 61 7F 81 BA FE E3 B6 D7 FB E57 AC
B6 D7 FB E5 AC C5 07 62E 61 E7 81 9B F E B6 D7 FB E5 A C
Time—3 Hours
D7 FB E5 7A C 07 62 61 E7 F81 9B AF EE 3B D FB E5 7A CC 507
FB E5 7A CC 507 62 E61 E7 F81 9B AF EE 3B 6D 7FB E5 7A CC 50 62
shifts.
E5 7A CC 507 62 E61 E7 F8 9B AF EE 3B 6D 7FB E5 7A CC 50 762 E6
7A CC 50 62 E6 E7 F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6 1E
CC 50 762 E6 1E F8 19 A FEE 3B 6D 7F BE 57A CC 50 76 E6 1E 7F8
(Tuesday, 4-12-2018)
frequency.
50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19
76 E6 1E 7F 19 A FE 3 6D 7F BE 57 C 5 76 E 1E 7F 19 BA
2E 1E 7F 81 BA FE E3 B6 7 B 57 AC C5 07 2E 61 7F 81 B F
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E 61 E7 81 9B AF EE
E7 8 9B AF EE 3B D FB E5 7A CC 50 62 6 E7 F8 9B AF EE 3B
Constants :
F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6 1E F8 19 A E 3B 6D
c = 3 × 108 m/s
h = 6.626 × 10 –34 Js.

Attempt All questions.
Attempt any three of the following :

CHEMISTRY
Paper CH-424
This question paper contains 4 printed pages]
(CBCS Pattern)
AG—283—2018
FACULTY OF SCIENCE
(Principles of Spectroscopy)
6D7FBE57ACC50762E61E7F819BAFEE3B
Give the applications of ESCA spectroscopy.
NOVEMBER/DECEMBER, 2018
M.Sc. (Second Semester) EXAMINATION
Use of calculator or logarithmic table is allowed.
E3 B6 D7 B 57 AC C5 07 2E 61 7F 81 BA FE E3 B6 D7 FB E57 A
B6 D7 FB E5 AC C5 07 62E 61 E7 81 9B F E B6 D7 FB E5 A
D7 FB E5 7A C 07 62 61 E7 F81 9B AF EE 3B D FB E5 7A CC
FB E5 7A CC 507 62 E61 E7 F81 9B AF EE 3B 6D 7FB E5 7A CC
E5 7A CC 507 62 E61 E7 F8 9B AF EE 3B 6D 7FB E5 7A CC 5
Explain. Write a note on nuclear and electron spin interaction.

7A CC 50 62 E6 E7 F8 19B A EE 3B 6D 7F E 7A CC 50
Give an account of polarization and scattering of light radiation.
CC 50 762 E6 1E F8 19 A FEE 3B 6D 7F BE 57A CC 50 7
50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 76
15
Give an account of chemical shifts and factors affecting the chemical

The molecule H2 is microwave inactive while HCl is microwave active.
Time : 10.00 a.m. to 1.00 p.m.
Maximum Marks—75
P.T.O.
The force constant of H-Br molecule is 420 Nm –1. If the reduced
mass is 1.65 × 10–27 kg, determine the fundamental vibrational
76 E6 1E 7F 19 A FE 3 6D 7F BE 57 C 5 76
2E 1E 7F 81 BA FE E3 B6 7 B 57 AC C5 07 2E
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E
E7 8 9B AF EE 3B D FB E5 7A CC 50 62 6
F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6
19 A FE 3B 6D 7F BE 57 C 50 76 E 1
BA FE E3 6 7 BE 57 AC C5 76 2E 61
FE E3 B6 D7F FBE 57 AC C5 076 2E 61E E7
E3 B6 D7 B 57 AC C5 07 2E 61 7F
B6 D7 FB E5 AC C5 07 62E 61 E7
D7 FB E5 7A C 07 62 61 E7 F81
F E 7 C 50 6 E E F
C 6 E 9 A E
7 1 7 1 B F
6 E 9 A E D F E
7 E 1 7 1 F 6 7 B 5
1 7
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E 61 E7
4.
3.
2.
A E 3 7 C 5 F
WT
8 B A
D F 9
(e)
(c)
(a)
(b)
(a)
(b)
(a)
(d)
(i)
(i)
(ii)
(ii)
E5 7A CC 507 62 E61 E7 F8 9B AF EE 3B 6D 7FB E5 7A CC 50 762 E6 lines ?
Spectroscopy.
Answer the following :

the rotational constant.
charge transfer spectra.

using suitable diagram.
( 2
Or
Or
Or
Answer any three of the following :

)
force constant and bond energy.
Explain Spin Hamiltonian.

Explain spin-spin interaction.

Explain the energies of atomic orbitals.
Give an account of AMX splitting.

(A = 1.60 × 10–27 kg and B = 5.80 × 10–27 kg)
B6 D7 FB E5 AC C5 07 62E 61 E7 81 9B F E B6 D7 FB E5 A Explain the theory of NQR. Give the applications of NQRS.
What is Raman effect ? Explain pure rotational Raman spectrum.
Give an account of spin densities and McConell relationship.

7
8
8
7
8
15
Explain the break-down of Oppenheimer approximation. Show the P,

Q and R branches in rotational vibrational spectra of diatomic molecule
What are the main factors which determine the intensity of spectral
8
What are the conditions for vibrational spectra ? Give an account of
AG—283—2018
If the internuclear distance of AB molecule is 1.20 × 10 –10 m, calculate
Describe electronic transitions in electronic spectroscopy. Explain

Enumerate basic principles involved in Electron Spin Resonance
76 E6 1E 7F 19 A FE 3 6D 7F BE 57 C 5 76
2E 1E 7F 81 BA FE E3 B6 7 B 57 AC C5 07 2E
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E
E7 8 9B AF EE 3B D FB E5 7A CC 50 62 6
F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6
19 A FE 3B 6D 7F BE 57 C 50 76 E 1
BA FE E3 6 7 BE 57 AC C5 76 2E 61
E3 B6 D7 B 57 AC C5 07 2E 61 7F
B6 D7 FB E5 AC C5 07 62E 61 E7
D7 FB E5 7A C 07 62 61 E7 F81
F E 7 C 50 6 E E F
C 6 E 9 A E
7 1 7 1 B F
6 E 9 A E D F E
7 E 1 7 1 F 6 7 B 5
1 7
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E 61 E7
5.
A E 3 7 C 5 F
WT
8 B A
D F 9
(b)
(A)
(i)
(i)
(ii)
(ii)
(iv)
(iii)
(c)
(c)
(c)
(c)
(b)
(a)
(b)
(a)
(b)
(a)
(b)
(a)
(d)
(d)
(d)
(d)
FT NMR.
questions :
0
1
2
3
1
0
3/2
1/2
Symmetry
Asymmetry
( 3
Or

None of the above

)
distribution about the nucleus.

Symmetric top molecules have :

Spin in electron distribution

Explain mutual exclusion principle.
All moment of inertia are zero
Two moment of inertia are equal

All moment of inertia are different
13C and 19F have nuclear spin equal to :

All three moment of inertia are equal
Explain the vibration in polyatomic molecules.
The vibrational degree of freedom for O2 molecule is :

7
5
7
The electric field gradient arises from .................... in the electron
P.T.O.
Select the correct alternative for the following multiple choice
AG—283—2018
Explain the coupling constant ‘J’. Write down the advantages of
76 E6 1E 7F 19 A FE 3 6D 7F BE 57 C 5 76
2E 1E 7F 81 BA FE E3 B6 7 B 57 AC C5 07 2E
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E
E7 8 9B AF EE 3B D FB E5 7A CC 50 62 6
F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6
19 A FE 3B 6D 7F BE 57 C 50 76 E 1
BA FE E3 6 7 BE 57 AC C5 76 2E 61
E3 B6 D7 B 57 AC C5 07 2E 61 7F
B6 D7 FB E5 AC C5 07 62E 61 E7
D7 FB E5 7A C 07 62 61 E7 F81
F E 7 C 50 6 E E F
C 6 E 9 A E
7 1 7 1 B F
6 E 9 A E D F E
7 E 1 7 1 F 6 7 B 5
1 7
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E 61 E7
A E 3 7 C 5 F
WT
8 B A
D F 9
(B)
(c)
(v)
(b)
(a)
AG—283—2018
CC 50 762 E6 1E F8 19 A FEE 3B 6D 7F BE 57A CC 50 76 E6 1E 7F8 (c)
(b)
(a)
(d)
Stark Effect
Zero Spin
( 4
4
Both (a) and (b)

No Nuclear Spin
Franck-Condon Principle
None of the above
)
Write notes on any two of the following :
Zero field splitting and Kramer’s degeneracy.
10
C12 and O16 do not interact with electron because they have :
AG—283—2018
76 E6 1E 7F 19 A FE 3 6D 7F BE 57 C 5 76
2E 1E 7F 81 BA FE E3 B6 7 B 57 AC C5 07 2E
61 7F 81 9B F E B6 D7 FB E5 A C 07 62E
E7 8 9B AF EE 3B D FB E5 7A CC 50 62 6
F8 19B A EE 3B 6D 7F E 7A CC 50 762 E6
19 A FE 3B 6D 7F BE 57 C 50 76 E 1
BA FE E3 6 7 BE 57 AC C5 76 2E 61
E3 B6 D7 B 57 AC C5 07 2E 61 7F
B6 D7 FB E5 AC C5 07 62E 61 E7
D7 FB E5 7A C 07 62 61 E7 F81
F E 7 C 50 6 E E F

Faculty of Science M.Sc. (Second Semester) EXAMINATION November/December, 2018 (CBCS Pattern)

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Faculty of Science M.Sc. (Second Semester) EXAMINATION November/December, 2018 (CBCS Pattern)

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C 6 E 9 A E

CC C50 0762 2E6 61E 7F8 819 BA FEE E3B B6D

h = 6.626 × 10 –34 Js.

Attempt any three of the following :

FB E5 7A CC 507 62 E61 E7 F81 9B AF EE 3B 6D 7FB E5 7A CC 50 62

Explain. Write a note on nuclear and electron spin interaction.

Give an account of chemical shifts and factors affecting the chemical

Answer the following :

charge transfer spectra.

50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19

Explain Spin Hamiltonian.

Explain spin-spin interaction.

Give an account of AMX splitting.

CC 50 762 E6 1E F8 19 A FEE 3B 6D 7F BE 57A CC 50 7

Give an account of spin densities and McConell relationship.

Explain the break-down of Oppenheimer approximation. Show the P,

If the internuclear distance of AB molecule is 1.20 × 10 –10 m, calculate

Describe electronic transitions in electronic spectroscopy. Explain

50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19

50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19

None of the above

distribution about the nucleus.

FE E3 B6 D7F FBE 57 AC C5 076 2E 61E E7F 819 9BA FE E3 B6 D7 FB E57

Spin in electron distribution

CC 50 762 E6 1E F8 19 A FEE 3B 6D 7F BE 57A CC 50 76 E6 1E 7F8

50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19

13C and 19F have nuclear spin equal to :

FB E5 7A CC 507 62 E61 E7 F81 9B AF EE 3B 6D 7FB E5 7A CC

The electric field gradient arises from .................... in the electron

50 762 E6 1E 7F8 19B BA FEE 3B 6D 7F BE 57A CC 50 762 2E6 1E 7F8 19

FB E5 7A CC 507 62 E61 E7 F81 9B AF EE 3B 6D 7FB E5 7A CC 50 62

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