5 @ ) 6 @ M-psit Write down the symmetric and antisymmetric combinations of spin functions of a two electron system. Setup the antisymmetric wave function for ‘ground state and any excited state of helium atom, 9 Measurements on the line spectrum of a certain atom show that the separations between adjacent energy levels of increasing energy in a multiplet are in ratio 3:5. Use Lande assign the quantum numbers L, $ and 3 to these levels 6 terval rule to Unie The value of anharmonicity constant and equilibrium frequeney for OH molecule in ground electronic state are 123.3 emr! and $602.81 cm’, Find the number of vibrational energy levels below the dissociation limit and the dissociation energy 5 No of Printed Pages : 06 Rall No. DSI B. Sc./M. Sc. Dual Degree EXAMINATION, 2022 (Fourth: Semester) (Main & Re-appear) Phy,, BT DPH202 Atomic and Molecular Theory Time : 3 Hours) [Maximum Marks : 75 Before answering the question-paper candidates should ensure that they have been supplied to correct and complete question-paper, No complaint regard, will be entertained after the examination. inthis Note : Attempt Five questions in all, selecting one question from each Unit. Q. No. 1 is ‘compulsory All questions carry equal marks. os) M-DSIL Pro.L @ ) © @ © 0 ©) M-psit (Compulsory Question) Explain Space Quantization ? 3 Why is 4D, term not split in a magnetic field ? Explain 2 Why water cannot be used as a solvent for infrared spectroscopy 2 Explain, why for a state with given ultiplicity the level having largest L have lowest energy. 2 Explain, what information about the structure of a molecule can be obtained from the analysis of Raman spectra. 3 What is. the basic requirement for a molecule to show IR spectra ? Which type of spectroscopy would one observe the pure rotational spectra of Hy? 3 Unit What is normal and anomalous Zeeman effects ? Discuss the Zeeman pattern of the resonance (D1, D2) lines of sodium. 9 Show by actual transitions the Stark-effect components of H., line of hydrogen. 6 2 3% @) © © 4 (@) o Calculate the energy difference between electrons whose spins are parallel and antiparallel tothe field, when a beam of clectrons enters in a uniform magnetic field of 4.2 » 10° gauss 6 Explain, how magnetic dipole behaves in an extemal magnetic field ? Calculate angle berween L and $ verotos in ?P3» state of one electron atom. 5 Caleulate the possible orientation of the total angular tum vector corresponding to ) ~ 5/2 with respect to 4 magnetic field along the nis, 4 Unit Discuss the spectrum of Helium atom with appropriate energy” level diagam. Explain, why ortho and para combination of He is not possible ? 9 Find the spectral term for Ti atom, Also find its grows state 6 core MDS 3 Pro.CO) %. @ O) © M-psit ‘The far inffared rotational absorption spectrum of diatomic molecule shows equidistant lines with spacing 20 en! Find the positon of the first stoke lines in the Raman rotational spectrum of the molecule 6 What do you mean by Raman seatering ? Explain why Raman stokes are more intense than Raman antistokes Tines. 6 The vibrational constant oy and wy of HCI are 2937.5 em! and $1.6 emt Find the wavenumber at which the first Raman stokes line will be observed at Go em") 5 Explain the advantages and disadvantages of Raman spectroscopy. 4 6 (b) Discuss the fine structure of infra-red bands of diatomic molecule 7 (©) Discuss the effect of isotope substitution of the vibrational spectra of anharmonic oscillator, 3 7. (a) Obiain an expession for the vibrational energy level of a diatomic molecule taking it as anharmonic oscillator. Discuss its spectrum and the relevant selection rule, 9 (©) At what temeprature would the number of HCI molecules in the first excited vibrational state be equal to about 37% fof the number in the ground vibrational stale? What fraction will be found in the first excited vibrational state at 700 K ? Take om, = 2881.3 om! and ignore 6%, 6 Unie tv 8. (@)_ Explain the principal, construction and working of Raman spectrometer. 9 vst» Mest s Pro,