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Revision nr.

01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 1 / 7

weber PU 2A Safety Data Sheet


1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Code ........

Product name weber PU 2A

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use Chemicial fixing

1.3. Details of the supplier of the safety data sheet

Name Saint-Gobain Weber Yapı Kim. San. ve Tic. A.Ş.


Full Address Ansızca Köyü Ansızca İç Kısım Sanayi Sokak No: 284
District and Country 35730 Kemalpaşa / İzmir
Turkey
tel. +902323970700
faks +902323970800
e-mail address of the competent person
responsible for the Safety Data Sheet ozgur.icli@weber.com.tr

1.4. Emergency telephone number

For urgent inquiries refer to +902323970713

2. Hazards identification.

2.1. Classification of the mixture


Classification according to Regulation (EC) No 1272/2008

This product is classified as dangerous /irritant according to EU Directives- (EC) No. 1272/2008.
Eye Irrit. 2
Skin Irrit. 2
Acute Tox. 4

2.2. Labeling Elements


Labeling according to Regulation EC No 1272/2008 (CLP)

Contains isocyanates. May produce an allergic reaction


Hazard statements:
H332: Harmful if inhaled
H319: Causes serious eye irritation
H315: Causes skin irritation
H302:Harmful if swallowed.
H312:Harmful in contact with skin

Precautionary Statements
P102:Keep out of reach of children.
P280:Wear protective gloves and eye protection/face protection.
P271: Use only outdoors or in a well-ventilated area P305+351+338:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
P337+313: If eye irritation persists get medical advice/attention
P501:Dispose of contents/container to manufacturer/competent authority
P362: Take off contaminated clothing and wash before reuse P301+330+331:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 2 / 7

3. Composition/information on ingredients.
3.1. Chemical structure: Polyurethane Sealant
According to EU Directives- (EC) No. 1272/2008:

Chemical REACH Concent


EINECS/ELI Registration Classification in Mixture
Name CAS No.
NCS No. Number (%w/w)

– 0,1 –
Diphenylmethane-4,4'-diisocyanate 101–68–8 202–966–0

Xylene 1330–20–7 215-235-7 1-5 Eye irrit 2,H 319 / Skin irrit 2 H315 /
01-2119488216-32-0007 Acute Tox. 4 H312 H332-302
– irrit 2 H315 /
Eye irrit 2,H 319 / Skin
Ethylebenzene 100–41–4 202–849–4 01-2119488216-32-0007 1-5
Acute Tox. 4 H312 H332-302
Calcium oxide 1305–78–8 215–138–9 01-2119475325-36-0000 1-5 Eye irrit 2,H 319 / Skin irrit 2 H315

Distillate Petroleum Light 64742–47–8 265–149–8 01-2119456377-30-0001 1-5 Acute Tox. 4 H312 H332-302
3-glycidyloxypropyl-
2530–83–8 219–784–2 – 0-1 Eye irrit 2,H 319 /
rimethoxysilane

*For the full text of the H-Statements mentioned in this Section, see Section 16.

4. First aid measures.

4.1. In case of eye contact:


Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes)
Seek medical advice.

4.2. In case of skin contact:


Wipe off. Wash affected areas with soap and plenty of water.
If irritation persists, seek medical advice.

4.3. If swallowed:
Do not induce the patient to vomit. Rinse mouth.
Give victim two glasses of water.
Never give anything by mouth to an unconscious person.
Seek medical advice.

4.4. If inhaled:
Take the person into the fresh air.
Seek medical advice.

5. Fire fighting measures.

5.1. Special protective equipment/procedures:


A self –contained respirator and protective clothing should be worn.
Mask and chemical resistant personal protective equipment should be used.
Determine the need to evacuate or isolate the area according to your local emergency plan.

5.2. Hazards during fire fighting


No data available.

5.3. Suitable extinguishing media:


Water fog ( if unavailable fine water spray), foam, dry chemical or carbon dioxide can be used.

5.4. Unsuitable extinguishing media:


No data available.

5.5. Hazards combustion products:


No data available.
Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 3 / 7

6. Accidental release measures.

6.1. Spill / Leak:


Avoid contact with.
Ventilate the area with fresh air.
Stop the leak if there is no risk.

6.2. Personal precautions:


Use personal protective equipment (protective gloves, work clothes and glasses)

6.3. Methods for cleaning up:


Clean away leakage mechanically; Cover leakage with damp absorbent material ( eg: sawdust, sand ).
After 1 hour, collect in a waste container.
Do not close ( it develops carbon dioxide).
Keep humid and leave for many days in the open air, in a controlled area.
Further disposal by incineration in accordance with local laws in force.

6.4. Environment related measures:


Collect the resulting residue containing solution.
Place in a closed container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.
Prevent the spilled material to leak and contact with garbage, canals and sewage
If the product has caused environmental pollution (sewers, waterways, soil or air),inform the relevant authorities.

7. Handling and storage.

7.1. Usage:
Avoid contact with eyes and skin.
Wear appropriate personal protective equipment.
Avoid breathing of vapors.
While using this product do not eat, drink or smoke.
Ensure good ventilation.
Keep in original container, tightly close the container used.
Do not burn the product container.

7.2. Storage:
Store in accordance with local regulations.
Store away from heat sources and foodstuffs, beverages and food.
Keep container tightly closed.
Store in a cool, dry place. ( between +5ºC ve +28ºC )

8. Exposure controls/personal protection

8.1. C Engineering Controls:


No data available for the mixture

Time Welghted Time Welghted


Short Time Short Time
Substance CAS No. Basis / Country Average Exposure Average Exposure
Value Value
Limit Limit

mg / m2 ppm-Calculated mg / m3 -8 h ppm-Calculated

Ethylebenzene 100–414 Spain/ VLA-ED 884 200 441 100

Xylene 1330–20–7 Spain/ VLA-ED 442 100 221 50

Distillate Petroleum Light 64742–47–8 Germany/ DFG 280 40 140 20

8.2. Personal Protection Equipment


Eyes: Avoid eye contact. Safety glasses should be worn.
Skin: Avoid skin contact.
Chemical resistant gloves should be worn.
Recommended: Butyl rubber / nitrile rubber gloves.
.
Respiratory: Avoid breathing of vapors. Respiratory protection should be used.
In case of long-term interactions, fresh air mask should be used.
Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 4 / 7

8.3. Hygiene Measures:


Avoid contact with eyes.
Especially in confined places, make sure you have proper ventilation.
Follow good industrial hygiene and safety practice.
Especially before eating, drinking or smoking, wash hands.
While using the product, do not drink, eat or smoke.

8.4. Environmental exposure controls:


Refer to section 6 and 12.

9. Physical and chemical properties.

9.1. Appearance: Paste

9.2. Odor: Characteristic


Color: White, Grey, Black and various colors
Important Health, Safety and Environmental Information:
Specific Gravity: 1,15 ± 0,03 gr/cm3
Boiling Point: no data available
Melting Point: no data available
Vapor Pressure: no data available
Inflammation: no data available
Water Solubility: insoluble ,reacts with water
The above information is not intended for use in preparing product specifications.

10. Stability and reactivity.

10.1. Chemical Stability:


Stable under normal usage conditions.

10.2. Materials to avoid:


Cures in10.2.
Reacts with alcohols and amines. Reacts with water forming carbon dioxide.

10.3. Hazardous Polymerization:


Hazardous polymerization will not occur

11. Toxicological information.


No data available for the mixture

11.1. In case of Inhalation:

Substance CAS No. Exposure Type Parameter Method Value Exposure Time Species Value Determination

Dermal LD50 >5000 mg/kg rat Literature/Supplier


Ethylebenzene 100–41–4 3
Oral LD50 3500mg/m rat Literature/Supplier

Dermal 1700mg/kg rat Literature/Supplier


Xylene 1330–20–7
Inhalation >5000 mg/kg 4 hr rat Literature/Supplier

Dermal LD50 >5000 mg/kg rat Literature/Supplier


Distillate Petroleum
Light 64742-47-8
Oral LD50 >5000 mg/kg rat Literature/Supplier

11.2. In case of eye coontact:


Corrosion / Irritation
Substance CAS No. Exposure Type Result Method Exposure Time Species Value Determination

Ethylebenzene 100–41– Skin Not irritating rat Literature/Supplier


4–1330
Xylene Eyes Not irritating rabbit Literature/Supplier
20–7

Distillate Petroleum Skin İrritating 72 rabbit Literature/Supplier


64742-47-8
Light Eyes Not irritating rabbit Literature/Supplier
Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 5 / 7

11.3. In case of skin coontact:


Sensitization
Substance CAS No. Exposure Type Result Method Exposure Time Species Value Determination

Distillate Petroleum
64742-47-8 Skin Not sensitizing Ginea Pig Literature/Supplier
Light

11.4. In case of ingestion


No data available

11.5. Mutagenicity
Genotoxicity (in vitro)
Substance CAS No. Result Method Exposure Time Species Organ Value Determination

not mutagenic Bacteria Literature/Supplier


Distillate Petroleum
64742-47-8
Light not mutagenic Mammalian-Animal Literature/Supplier

11.6. Carcinogenicity
Genotoxicity (in vitro)
Substance CAS No. Result Method Exposure Time Species Organ Value Determination

Ethylebenzene / 100-41- 5 days in103 Literature/Supplier


Xylene 4/1330–20–7 <75 ppm Inhalation weeks Rat

11.7. STOT-SE

Substance CAS No. Result Method Value Determination

Ethylebenzene / Category 3-
100-41- respiratory Inhalation Literature/Supplier
Xylene 4/1330–20–7 çirritation

11.8. Other Information


Reproductive Toxicity:
This product does not contain any known or suspected reproductive hazards.
Fully cured PU sealant (at least 24 hours) is not toxic or irritating.

12. Ecological information.


No test data available on the mixture.

12.1. Ecotoxicity Effects:

Substance CAS No. Method Parameter Result Duration Species Value Sourace
EC50 >1000 mg/l 72 Algea
Distillate Petroleum LC50 >10000 mg/l 48 Daphnia Manga Literature/Supplier
Light 64742–47–8
LC50 >84,444 mg/l 96 Fish Literature/Supplier

NOEC 21 days Fish Literature/Supplier

LC50 8500 48 Palaemonetes pugio Literature/Supplier


Xlene 1330-20-7
EC50 3300 96 Fish Literature/Supplier

EC50 2930,4400 48 Daphnia Manga Literature/Supplier

LC50 > 5200 48 Americamysis bahia Literature/Supplier


Ethylebenzene 100–41–4
LC50 4200 ug/L 96 Oncorhynchus mykiss Literature/Supplier
NOEC 6800 ug/L 48 Daphnia Manga Literature/Supplier

NOEC 3300 ug/L 96 Menidia menidia Literature/Supplier


Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 6 / 7

12.2. Persistence and degradability:


Persistence and Degradability

Substance CAS No. Mathod Result Duration Value Sourace


% Day
Distillate Petroleum 64742-47-8
Light Literature/Supplier
50 70

12.3. Bioaccumulation:

Bio-accumulation
Substance CAS No. Parameter Log Pow Duration Potantial Value Sourace

Xylene 1330-20-7 BCF-29 3,12- Bala Literature/Supplier

13. Disposal considerations.


13.1. Product Disposal:
Dispose of in accordance with local regulations.

13.2. Packing Disposal:


Dispose of in accordance with local regulations.

14. Transport information.

14.1. Road /Rail (ADR/RID):


Not subject to ADR/RID

14.2. Sea Transport (IMDG):


Not subject to IMDG

14.3. Air Transport (IATA):


Not subject to IATA

15. Regulatory information.

15.1. Labeling:
Irritating

15.2. National Legislation/Regulations:

16. Other information.

16.1. Information Sources:


This SDS is prepared based on the information received from the suppliers.

16.2. Full text of H-phrases referred to under sections 3

H332: Harmful if inhaled


H319: Causes serious eye irritation
H315: Causes skin irritation
H302: Harmful if swallowed.
H312: Harmful in contact with skin

16.3. Additional Information


The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

It is the responsibility of persons in receipt of this Product Safety Data Sheet to ensure that the information contained herein is properly read and
understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produces a
formulation containing the product, it is the recipient’s sole responsibility to ensure the transfer of all relevant information from the Product Safety Data Sheet
to their own Product Safety Data Sheet.
Revision nr.01 EN
Saint-Gobain Weber Yap› Kim. San. ve Tic. A.fi.
Dated 30/05/2016
Printed on 30/05/2016
weber PU 2A Page n 7 / 7

All information and instructions provided in this Safety Data Sheet (SDS) are based on the current state of scientific and technical knowledge at the date
indicated on the present SDS.

As stated above, this Safety Data Sheet has been prepared in compliance with applicable European law. If you purchase this material outside Europe,
where compliance laws may differ, you should receive from your local supplier a SDS applicable to the country in which the product is sold and intended to
be used. Please note that the appearance and content of the SDS may vary –even for the same product –between different countries, reflecting the different
compliance requirements.

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