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Be Larbi 2016
Be Larbi 2016
com
ScienceDirect
Solar Energy 127 (2016) 206–215
www.elsevier.com/locate/solener
Received 30 November 2015; received in revised form 3 January 2016; accepted 12 January 2016
Abstract
Simulation models of interdigitated back contact silicon heterojunction (IBC-SiHJ) solar cells, not only help in understanding the cell
behavior in line with the experimental results but also help further in predicting the cell performance, adding to the cost effectiveness in
the cell processing.
IBC-SiHJ solar cells that combine the hydrogenated amorphous silicon/crystalline silicon (a-Si:H/c-Si) heterojunction and interdig-
itated back contact (IBC) concepts are very promising in order to reach the highest one-junction efficiency (g). In this paper, we have
studied these solar cells by two dimensional modeling using Silvaco Tcad Atlas software which has recently extended its capability to
simulate these devices and given accurate bulk and interface complex defect models and allowed special specification of transport physics
for the hetero-interface. The study has been done on the IBC-SiHJ structure based on n-type crystalline silicon (c-Si) by introducing a
very thin intrinsic hydrogenated amorphous silicon (i-a-Si:H) layer between the c-Si base and the doped a-Si:H layers and varying the
values of the following parameters: c-Si substrate and back-surface field (BSF) doping concentration, thickness of i-a-Si:H layer (Thi-a-Si)
and rear side geometry. The impact of these parameters has been tested by generating the current–voltage characteristics under illumi-
nation. It is shown that the open circuit voltage (VOC) and g of IBC-SiHJ solar cells increase with decreasing i-a-Si:H thickness. The g
improves further with the increase of p-type emitter width (2Wp), the decrease of n-type BSF width (2Wn) and gap width (Wg) which are
explained by the simulation. The S-shaped J–V curves with low fill factor (FF) observed previously in experiments are confirmed by sim-
ulation. To improve FF, Thi-a-Si and Wg should decrease. Results indicate that to achieve high g, c-Si substrate and BSF doping concen-
tration must be optimized. The Wg (spacing between BSF and the emitter) must be kept as small as possible to avoid recombination of
minority carriers in the base. The optimum geometry corresponds to a minimum size BSF region and a maximum size emitter region.
With these optimizations, an enhanced g 23.20% is demonstrated by the simulation.
Ó 2016 Elsevier Ltd. All rights reserved.
Keywords: Silicon solar cells; Interdigitated back contact; Amorphous-silicon; IBC-SiHJ; Atlas software
⇑ Corresponding author.
E-mail address: wbelarbi@yahoo.fr (M. Belarbi).
http://dx.doi.org/10.1016/j.solener.2016.01.020
0038-092X/Ó 2016 Elsevier Ltd. All rights reserved.
M. Belarbi et al. / Solar Energy 127 (2016) 206–215 207
Fig. 1. Schematic picture of IBC-SHJ solar cell: (a) cross sectional view and (b) bottom view.
2.2. Physical models Quantum Potential for quantum correction. Fermi model
and recombination models (Shockley–Read–Hall (SRH),
Modeling of IBC-SiHJ solar cell is a matter of some dif- Auger and surface recombination) were also included into
ficulty caused by the necessity of treating 2-dimensional the simulation. The radiative recombination is not
currents, the presence of amorphous materials with included, because in silicon, band to band generation/
ambiguous parameters some of which are difficult to obtain recombination is insignificant. The carrier mobility was
from experiment, complex transport mechanisms, modified taken dependent on the doping concentration. Recombina-
light generation profile and so on. Neither of conventional tion of carriers through SRH and Auger mechanisms were
programs used in photovoltaic (e.g. PC1D, AFORS-HET, also modeled as a function of doping concentration (Lu
PC2D, . . .) are suitable. However, Silvaco ATLAS et al., 2009).
supports all these requirements. In this paper, the work
presented is a step toward understanding the IBC-SiHJ
2.3. Recombination models applied to c-Si
cells with simulation performed using Silvaco ATLAS,
which has recently extended its capability to support
2.3.1. SRH recombination
heterojunctions, midgap and interface traps for these types
The SRH recombination is modeled as follows:
of solar cells (Atlas, 2013). The paper focuses on the
behavioral trends in the cell electrical parameters viz. pn n2ie
JSC, VOC, FF and g, with variations in IBC-SiHJ RSRH ¼ h D Ei h D Ei
sp n þ nie exp Ekt E i
þ s n p þ n ie exp Ei Et
geometrical parameters and c-Si substrate and back-surface B T k B T
1E21 1E21
Acceptor tail state density
Acceptor tail state density
Donor tail state density
Donor tail state density
1E20 Acceptor mid-gap defects 1E20 Acceptor mid-gap defects
Donor mid-gap defects
Donor mid-gap defects
-1
)
)
1E19
-1
1E19
Defect levels (cm -3 .eV
1E17 1E17
1E16 1E16
1E15 1E15
0,0 0,2 0,4 0,6 0,8 1,0 1,2 1,4 1,6 1,8 0,0 0,2 0,4 0,6 0,8 1,0 1,2 1,4 1,6 1,8
Energy (eV) Energy (eV)
Defect density levels in p-type amorphous layer Defect density levels in n-type amorphous layer
1E16 1E16
Defect levels (cm- 3.eV - 1 )
1E15
1E14 1E15
1E11
1E10 1E13
0,0 0,2 0,4 0,6 0,8 1,0 1,2 1,4 1,6 1,8 0,0 0,2 0,4 0,6 0,8 1,0
Energy (eV) Energy ( eV )
Defect density levels in intrinsic amorphous layer Defect density levels in c -Si defective layer
Fig. 2. Density of states (DOS) in a-Si:H p-type, a-Si:H n-type, i-a-Si:H and defect region layer respectively.
5 1018 cm3 has a significant influence on the JSC, but For doping concentrations below 1016 cm3 (which cor-
not on the VOC. responds to NSRH), the SRH recombination mechanism is
the predominant one. The lifetime is mainly determined by
3.1. Sensitivity on c-Si substrate doping the SRH process as seen in Fig. 6. The Auger recombina-
tion becomes significant when concentrations are above
A set of simulation is performed in order to estimate the 1016 cm3 and even becomes the dominant recombination
sensitivity of cell performance to different bulk dopings, process for Nd > 5 1016 cm3.
which is varied within the range 2 1016–3.5 1016 cm3. When the doping concentration increases, the JSC
This sensitivity was evaluated while keeping the total decreases as we observe in Fig. 7. This is due to the lifetime
device parameters fixed, with front surface recombination of carriers and their mobility which decrease with higher
velocity (SRV) 10 cm/s derived from lifetime measurements doping concentration and the Auger recombinations
(Lu et al., 2009), which gives good passivation at the front becomes stronger. The impact of c-Si substrate doping on
and rear surfaces and low recombining a-Si:H/c-Si inter- VOC is negligible.
faces. The bulk lifetime is defined as: By increasing the c-Si doping concentration, the FF is
1=sbulk ¼ 1=sSRH þ 1=sAug improved, see Fig. 7. This improvement is related to the
decrease of the resistivity of the c-Si substrate.
It is determined by SRH and Auger recombination pro- The parameters JSC and FF do not evolve in the same
cess and these processes depend on the doping concentra- direction when the doping concentration varies. These var-
tions. sbulk is depicted in Fig. 6. ious changes result in the existence of an optimum c-Si
M. Belarbi et al. / Solar Energy 127 (2016) 206–215 211
Table 1
List of modeling parameters and defect distributions used in the simulations.
Material Interface c-Si n-Type a-Si:H Buffer a-Si:H p-Type a-Si:H
defects
Bulk lifetime (s) 2 103 2 1012 2 1012 2 1012
Band gap (eV) 1.17 1.17 1.70 1.70 1.65
Electron affinity (eV) 4.05 3.9 3.9 3.9
Effective conduction band DOS (cm3) 2.89 1019 2.5 1020 2.5 1020 2.5 1020
Effective valence band DOS (cm3) 3.14 1019 2.5 1020 2.5 1020 2.5 1020
Conduction tail states Nctail A (cm3) 0 n/a 1021 1018 1021
Ectail A (eV) 0.07 n/a 0.12 0.09 0.07
Valence tail states NVtail D 0 n/a 1021 1018 1021
(cm3)
EVtail D (eV) 0.12 n/a 0.12 0.09 0.12
3
Acceptor-like (A) dangling bond states db
N A (cm ) 2.4 10 16
n/a 1019
10 16
1019
Edb A (eV) 0.5 n/a 0.7 1.1 1.3
rdb A (eV) 0.2 n/a 0.2 0.15 0.2
Donor-like (D) dangling bond states Ndb D (cm3) 2.4 1016 n/a 1019 1016 1019
Edb D (eV) 0.5 n/a 0.45 0.9 1.1
rdb D (eV) 0.2 n/a 0.2 0.15 0.2
Electron mobility (cm2 V/s) 1417 1417 2.03 2.03 2.03
Hole mobility (cm2 V/s) 470 470
40
30
Current density (mA.cm-2 )
0.002 μm
20
0.006 μm
0.010 μm
0.015 μm
0.020 μm
10
0
0,0 0,1 0,2 0,3 0,4 0,5 0,6 0,7
Fig. 3. Meshing of elementary IBC-SiHJ solar cell structure. Voltage ( V )
15 -3
3.3.1. Effect of Thi-a-Si
5x10 ( cm ) The aim of including an intrinsic a-Si:H layer is to pas-
10 16 -3
5x10 ( cm ) sivate the dangling bonds on the c-Si surface. As a result,
17 -3
5x10 ( cm ) the a-Si:H/c-Si interface defect-state density is significantly
18 -3
1x10 ( cm ) reduced. Applying an emitter and BSF buffer layer, 726 mV
18 -3
0 5x10 ( cm ) is reached (Table 2) due to the relatively low recombination
0,0 0,1 0,2 0,3 0,4 0,5 0,6 0,7 rate at the a-Si:H/c-Si interface.
Voltage ( V ) Table 2 shows a slight increase of VOC from 720 to
726 mV when the Thi-a-Si increases from 3 to 17 nm. This
Fig. 5. J–V curves as function of n-BSF doping. enhancement of the VOC is due to low defective i-a-Si:H
layers. However, the FF reduces drastically from 83.44%
to 74.60% with increasing i-layer thickness. The impact of
Thi-a-Si on JSC is negligible, as we observe in Table 2. These
predicted trends are qualitatively consistent with the results
of other authors e.g. in references Lu et al. (2009) and
Diouf et al. (2011). We found an optimum Thi-a-Si = 6 nm,
which leads to a highest g.
38,4 84,0
23,18
Jsc
0,723
83,8
38,3 23,16
Voc ( V )
Jsc (mA.cm -2)
η (%)
FF (%)
83,6 η 23,14
38,2 Voc
0,722
FF
83,4 23,12
38,1
83,2 23,10
38,0 0,721
2,0E16 2,4E16 2,8E16 3,2E16 2,0E16 2,4E16 2,8E16 3,2E16
Fig. 7. IBC-SiHJ solar cell key figure of merits as a function of c-Si doping concentration.
38,378
83,65 23,20
0,724
83,60
23,19
Jsc (mA.cm )
-2
Jsc 83,55
FF (%)
23,18
η(%)
38,377
Voc (V)
η
83,50
0,722 FF 23,17
Voc 83,45
23,16
83,40
chances to recombine. Increasing the Wn from 80 to Increasing Wg results in a decrease of JSC, FF and g, but
450 lm results in a slightly decrease of JSC as we can see the VOC remains constant. The Wg will be taken as short
in Table 2. Wn variation has no influence on VOC. The as possible with good surface passivation to avoid recombi-
BSF should be taken as narrow as possible to reach best nation of minority carriers in the bulk c-Si and damage of
JSC values, but narrow n-strip can cause electrical shading the cell performance. To remove this gap region would be
effects. From the other side wide n-strip can increase series an attractive solution but this would lead to internal cell
resistance to majority carriers current. Thus Wn should be short circuit, thus making this solution is unsuited. Smaller
optimized. The optimum value which corresponds to the gap (between emitter and BSF region) was effective to
highest g is 180 lm. increase g and thus, we assumed a suitable value of
In Table 2, the smaller the Wg, the higher the efficiency 50 lm in order to eliminate the possibility of shunting.
is, because the recombination of minority carriers on the With these optimizations, a conversion g 23.20% is
surface between emitter and BSF is smaller. As for the reached.
BSF region, increased Wg corresponds to an additional lat-
eral distance to travel for minority carriers photogenerated 4. Conclusion
in c-Si above the BSF region. This additional distance
increases their chances to recombine before reaching the The simulation has provided an initiative to help
emitter. In addition, the interface with the c-Si substrate understand and obtain a detailed analysis of IBC-SiHJ cell
and the gap region can also be recombining. The impact characteristics. 2D numerical simulations for IBC-SiHJ solar
of the Wg on JSC, on FF and g is shown in Table 2. cells have been studied by using the software SILVACO
214 M. Belarbi et al. / Solar Energy 127 (2016) 206–215
Table 2
Summary of device performance of IBC-SiHJ solar cell.
Thi-a-Si (lm) JSC (mA cm2) VOC (mV) FF (%) g (%) Wp (lm) JSC (mA cm2) VOC (mV) FF (%) g (%)
0.003 38.4646 720 83.44 23.14 400 35.09 722 84.05 21.34
0.004 38.4647 721 83.40 23.17 500 36.08 722 84.02 21.94
0.006 38.4646 723 83.25 23.20 600 36.83 722 83.97 22.38
0.008 38.4645 724 83.06 23.16 700 37.48 722 83.91 22.76
0.010 38.4643 725 82.81 23.12 800 37.93 723 83.81 23.01
0.012 38.4641 725 82.47 23.05 900 38.27 723 83.64 23.16
0.015 38.4636 726 81.75 22.87 950 38.38 723 83.50 23.20
0.017 38.4632 726 80.60 22.54 1000 38.46 723 83.23 23.17
0.020 38.4625 724 74.60 20.80 1050 38.52 723 82.69 23.06
Wn (lm) JSC (mA cm2) VOC (mV) FF (%) g (%) Wg (lm) JSC (mA cm2) VOC (mV) FF (%) g (%)
080 38.52 723 82.71 23.07 30 38.41 723 83.52 23.22
110 38.48 723 83.12 23.16 40 38.39 723 83.51 23.21
130 38.46 723 83.26 23.18 50 38.37 723 83.50 23.20
180 38.37 723 83.51 23.20 60 38.35 723 83.49 23.18
250 38.21 723 83.68 23.14 70 38.33 723 83.48 23.16
300 38.03 723 83.77 23.06 80 38.31 723 83.47 23.15
350 37.84 723 83.83 22.96 90 38.29 723 83.46 23.13
400 37.62 723 83.88 22.83 100 38.27 723 83.45 23.12
450 37.32 723 83.92 22.67 110 35.25 723 83.44 23.11
Values in bold correspond to the maximum efficiency.
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