No. of pages - 16 (M) COMMON PRE-BOARD SCHOOL EXAMINATION (2022-23) CLASS : XII SUBJECT: CHEMISTRY (043) Time Allowed : 3 hours Maximum Marks : 70 ama: 3a aifaenta aia - 70 ward Freer frafataa Feet at aga araurt a oie : a wa ws 4 via vel a fafa fom 2 - wa, 0, 7 we SI ea ea 35 oe aah we atari @1 (2) wave ‘a Hoya Wen a 1g WH aes WER SOT Bude wer 1 ae a2! G) are ‘a' Bower dem 19 3 25 we fe ay outta ven Swe al woe we 2 tat wel (4) wave ‘1 3 wet Gem 26 8 30 TH M-Sat VaR Swe El welw we 3 sisi Fz (s) que 'a Yow den 31 ait 32 aTesa ana sit wehw we 4 sist a eI (6) ave Si wer dem 33 8 35 oe St sata we Swe 1 de eT iat a OO) wea va Haid oom fares Te A cent arian fares fog AE ZI (8) Seqpdex ote ain antral Sweet at arqta ae 21 General Instructic Read the following instructions carefully : (1) This paper is divided into five sections A, B,C, D and E. There are 35 questions in this paper. All questions are compulsory. (2) Section A - Question no. 1 to 18 are objective type questions. Carrying 1 mark each. (3) Section B - Question no. 19 to 25 are very short answer questions. Carrying 2 marks each. (4) Section C - Question no. 26 to 30 are short answer questions. Carrying 3 marks each. (5) Section D - Question no, 31 and 32 passage/case study based questions carrying 4 marks each (6) Section E — Question no. 33 to 35 are long answer questions carrying 5 marks each. (1) There is no overall choice. However, internal choices have been provided (8) Use of calculators and log tables is not permitted. 1 XII-CHEMISTRY-MwWUs-& (Section-A, preofettan mefeedia wea &, far ew we Tee eh eee TET 1 oe aT di ga aus H aig artafta famed Tete Following are multiple choice questions with one correct an swer, Each question caries 1 mark. There is no internal choice in this section. we an feria a gad fet aot & (a) afafrar st sitter (b) afafern at afar Sat (c) aifafarar at aife ae (d) afafen & a We The unit of rate constant depends upon the = _A4sf§ molecularity of the reaction (b) activation energy of the reaction (c) _ order of the reaction (d) _ temperature of the reaction wpa getaiiaers (arefeai-0) sraree (ill) #1 Ha @ - The formula of the complex triamminetri (nitrito-O) cobalt (II) is : _(ay~ [Co(ONO);(NH3)s3] (b) — [Co(NO2)3(NH3)s] (©) [Co(ONO>)3(NHs)s] (a) [Co(NO2)(NHs3)3] frafafad 4a ar setae 8? (@) Tea 6) =H (©) aaa (@) wet Which of the following is a disaccharide? (a) Glucose (b) Starch (c) Cellulose \ ~ Lactose fed wate afefea Xoy 4 ae wa wa fe wa ‘x’ at Wea aR TH ae 7 at oftfra a an at on at va x’ se ofa offer st wife @1 In a chemical reaction X—>Y, it is found that the rate of reaction doubles when then concentration of X is increased four times. The order of the reaction with respect to X is : (a) 1 (b) 0 (cY 2 wr 12 XII-CHEMISTRY-M5. frafafad ¥ a FH AgNO, BT afafra Hea Thy sada ST? Which of the following will give a white precipitate upon reacting with AgNOs? (a) K,[Pt(en),Cé,] (b) [CO(NH,),Cé,] oy [CHCH,O), ICC, (d) [Fe(H,0),Cé,] 6 KCU,K,SO, aon after B fare ave ete aa hI A HAR: B - The values of Van’t Hoff factor for KC¢,K,SO, and urea respectively are : (a) 2,3,2 (b) 2,13 92.3.1 (1,23 7 aa a a Sree view tees Syl after & fore af coat a aafafarar aa 3? Which of the following alkyl halide will undergo Sw! reaction most readily? (a) (CHs);-C-F \(6)(CHs)s-C-I (©) CH}-CHe1 (d) CHy-CHy-F 3. fafatad gai aa sem gH Tam aren wae 2? Which of the following pairs has the same size? (a) SY \ (by Zr, HE (c) Se, La (d) Se, Zr 9. feafafaa 2a sa ayer Trend vet 2? (a) WR =A (b) aT Ta BT STATA (c) ar aa a anaes rad) Fae A Gag Which of the following is not a colligative property? (a) _Osmotic pressure Lowering in vapour pressure (c) _ Relative lowering in vapour pressure (d) _ Elevation in boiling point 3 ‘XII-CHEMISTRY-M10. ie 13. 14, wet facet 4 frafetiad Fa yacr ae - Out of the following the strongest base in aqueous solution is : (a) CH;NH; \ (b)~ (CH3),NH (c) (CHy)3N (a) Ure (Aniline) frafatad 4 9 farad grr sitteront wen vet fen ort 2? Todoform test is not given by : (a) CH,CHO (b) CH,CH,OH oO Oo © CH, - be, —CH, —CH, Oe CH, _cn, -b-cH, —CH, fofetad aeied Fa ue tia HCC ak Fit Znce,F wea TH A fafa eat @ (a) 2-3yeater (vb) 2-faenge wrta-2-s9eT (c) 2-faenger ga-1-siet (d) 1-3ReaIet Amongst the following alcohols the one that would react fastest with conc. HCE and anhydrous ZnCé, is : (a) 2-Butanol oy 2-Methyl propan-2-ol (c) 2-Methy! propan-1-ol (a) 1-Butanol feat afrata 21 Hinsberg’s reagent is : Br C800 (b) soce, (c) C,H,COC/ @ (COCE), frafatad vfafen a wpe sere e - The major product of following reaction is : oe i CH, —-CH-~cH (a) CH,CH,CH,OH | ° wr CH, —CH— = (©) CH,CH,CH,CH,OH (4) = CH, ~ CH; OHprofiad Wer (wer Wem 15 8 18) A ww sifrme ger aT a He aT aati frafafan faaeat F a wet Ta HI PT (a) (b) (c) @ afirmes alt arr aei aa Se @ SIR aE oifrRe at at cae a afer ait er esi wet Hert Bed SN afaes Ht aet oAeT wa 21 saferrers wat sera 2 veg FTO Te FH 2h afro Tea wom & veg Bre we HH ZI In the following (Q.No. 15 to 18) a statement of assertion followed by a statement of rason is given. Choose the correct answer out of following choices. (a) (b) (©) (b) 15. Assertion and reason both are correct statements and Reason is the correct explanation of Assertion. ‘Assertion and reason both are correct statements, but Reason is not the correct explanation of Assertion. Assertion is a correct statement but Reason is a wrong statement. Assertion is a wrong statement but Reason is a correct statement. afirnorm ert A C-O-C ara wl aEEReaTa BITS waa safes zl ru 2 bat a a tfeaa api S ate sited serie & Fre ‘Assertion : The C-O-C bond angle in ethers is slightly more than tetrahedral angle. Reason : Due to the repulsive interaction between the two alkyl groups in ethers. safer < Prafafans wfafiren et ommferrar 2 21 H, +Br, > 2HBr were: ofafaren wT HA 3/2 ZI Assertion : The molecularity of the following reaction is2: H, +Br > 2HBr Reason : The order of reaction is 3/2. 5 XII-CHEMISTRY-Msfaeen Unfer wise sre vlan 8 aet TSKa z1 RO : UAT HI NH, Wye area aM afafoeen aA aH fee ACCC, Ae afatra aa 21 Assertion : Aniline does not undergo friedel crafts reaction. Reason : NH2 group of aniline reacts with A@C0,to give acid base reaction. arrest SAT UT We Mat a wala HT 21 RT : HHA wT A ns (nd Sa HS dra wH aS Had Hae ata @1 Assertion : Transition metals show variable valency. Reason : Transition metals have a large energy difference between the ns and (n—1)d electrons. WVS-G (Section-B Prafatad wet (wet Wem 19 A 25) wy sata we = sik Wel UT 2 vet ct 21 The following questions (Question No. 19 to 25) are short answer type and carry 2 marks each. 19, 20. ue yam aife st srrses afferan 30% armed & fare 40 fie a aH ert 21 cat fee ty. FI URReM sf) (aT 100-2, aT 70-1.8451, ait 30 = 1.4771) A first order decomposition reaction takes 40 minutes for 30% decomoposition. Calculate its t),.-value. (log 100=2, log 70=1.8451, log 30 = 1.4771). Frefafad 4 ae fear + fee waratre weit a fatten — () Ufsetfesees otk aatfesers F Gi) WA ait giorfer A Give chemical tests to distinguish between : (i) Acetaldehyde and benzaldehyde (ii) Propanone and propanol XII-CHEMISTRY-M21. 22. 23. 24. fefatad & fa fava rien difsre : @ DNAS @ wae wan TE aa, wey THER Sys ae eh (i) TRRTe 2 4S. Tham Tet ea Give the plausible explanation for the following: (i) The two strands in DNA are not identical but are complementary. (ii) Glucose doesn’t give 2,4-DNP test. fe sindaai Ta wee I east. (UPA) am fafa - Write down the IUPAC name of the following complexes: (i) [Co(NH,),C¢JC, (ii) _K,[Fe(CN),] aaTaVOR freq aiedaa are 2 a wee F yas geet st dot anfaa sifse : Draw the structure of optical isomers of the following complex ions : [PtC¢,(en), *.[Cr(NH,),C¢,(en)]* (a) Ue afafea A+B > sere & fer a7 fram Rate =k [A]! [BP @ fea a 1 afafea at rife sar 3? For a reaction A+B —> product the rate law is given by Rate = k [A]! [BJ] what is the order of the reaction. (>) fata aife sfaforen a fore an fraci —ce : ce w AA! weaVOR = A\A/ aawav/OR fra afaferat at gol eifae Complete the following reaction equation : () € >—oH+ soce,— * CH,OH (ii) Ly + HCe—— HO WvS-T (Section-C) Frafataa wert (wt dem 26 8 30) aR sate wea # ait ues 3 vel ar 21 The following questions (Question No. 26 to 30) are short answer type and carry:3 marks each: 26. wee & fee we Sa sem ta ee fr afifeens ai yefeia aifsa: (i) fst Sfrengs dec fol a Gi) itera afaferen Gi) ara sags Freie afafra Illustrate the following reaction giving suitable example of each case: (i) Gabriel phthalimide synthesis (ii) Carbylamine reaction (iii) Haffmann bromamide degradation reaction AtaVOR 8 XII-CHEMISTRY-M27. 28. 29. fre afatrasi FA, Bae Cat aert Sam - Write the structure of A, B and C in the following reactions: (i) CH CH,Ce—#o AAs, B—L_C (i) ~CH,COOH—2>A aia B—Lts2c_C (a) frafataa de afatnen & fire Aire fred sat -300 kd mot! & - The standard Gibbs energy (ArG°) for the following cell reaction is 300 kJ mol Zn,, + 2Ag*,, > Zn™* (aq) + 2Ag(s) aftr & fa E, #1 ofemer afm Calculate E°,, for the reaction (given If = 96500 ¢ mot’) (ob) MgCe, @ fore A’ at Uitmert wife afe Mg” aA TH Cem arr & fe \°S AM FAT: 106s cm’mol”! Ta 76.3 s cm’mol' Calculate A°, for MgC, if \° values for Mg” ion and Cé~ ion are 106 s cm’mol"! and 76.3 s cm*mol' respectively. frafafad dpe S daw wa Gaeta cat fafa - Write the hybridisation and magnetic character of the following complexes: @ — [NiCe, (i) [Co(NH,),}* (iii) [FeR,P [SRAM], HATH (Atomic number) : Ni= 28, Co = 27, Fe = 26] ean ern a (Terabe aifefarand Sf) - (i) Afefafer ama at (CH,CO),O/H*S are afaferar st wet & (i) WHat Na,Cr0,/H'a ataetga et 21 Gil) fra F CH,ce Prt ALCL Ae afafere et aA 9 XH-CHEMISTRY-M30. 31. What happens when? (Write chemical reactions) (i) Salicyclic acid is treated with (CH,CO),0/H* (ii) Phenol is oxidised with Na,Cr,O, /H* (iii) Anisole is treated with CHC? / Anhydrous AlCE, frefetad wae afifrn & yer sere a ea waeT - Draw the iuotures of major products of following reactions: CH CH,-CH, NO, (ii) (CH,),C - Br + KOH" (iii) O +Br, Aes, WUS-F (Section-D) Frefefad sede at ofan sit A feu ae wei Fo a Sf we aga vere da é st aa: waft teae ofits ai fre sere aq seat ae 21 ue wad Fonda ah stem 2 areata a oasis Aa cies a aa fava a da Saga ae we wee Sak Ey, cree @ at ftom ea: owatia ok et den aaah Ses ea 4 sfeafian fer aim @1 aga semua at fart werd & fqn BRI ameed By A sfeafad fear ara 3 Ag’ (aq) Ein, = —0.76V Eis igy = 0:80V XII-CHEMISTRY-M@) Rem aa s Tie Gi Sets TT : (b) ea eh aa cam-ag FF ea fem Te? 1 (©) aqa warts da aa dee aoe ae a sie ore wear #22 (i) Fa Ey =0 8 A Zn” ait Ag’ vrai a aixar wt eH eT? (ii) face #1 area aya Sere Fai edt 2? 31. Read the given passage and answer the questions that follow: ‘A electrochemical cell is the device that uses spontaneous redox reactions to generate electricity. A salt bridge also connects the half cells. The reading of the voltmeter gives the cell voltage or cell potential or electromotive force. If E%, is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. Silver plate Salt bridge Zn** (aq) Ag’ (aq) Es... = —0-76V Eggs ag = 0-80V (a) which electrodes going to act as anode and cathode in given above cell? 1 (b) What will happen if the salt bridge is removed? 1 (c) When does in electrochemical cell behaves like an electrolytic cell? 2 (i) What will happen to the concentration of Zn’*and Ag* when Ecen = 0. (ii) Why does conductivity of a solution decreases with dilution? | Ml XII-CHEMISTRY-M32. 32. fefatad apd at ute atk ara faq ae wet a sax —coona wowc (iii) CH=CH, —CH; ~CN—S284_, HO" feafafa a sat after at afufeasl @ wa aed afufearican & wa A orafeerd aifere : CH,COCH,, HCHO, CH,CHo, ( 0 >—cocH, oO cu,-b-cn, Write the products formed when benzaldehyde reacts with the following reagents: (i) CHCHO in presence of dilute NaOH (ii) H:N-NH <0» (iii) Conc. NaOH Distinguish between following : (i) | CH,-CH=CH-CO-CH, and CH, —CH, ~CO-CH=CH, CHO COOH . @ 24-30. eH at OT ARTI (ii) and OR 15 XII-CHEMISTRY-M(a) (b) © Write the final products in the following : CH, 5 Zn/H @ \ -9 sue, J Conc.HCé CH, a Co >—coona onc Gi) CH=CH, — CH, — CNB, Arrange the following in the increasing order of their reactivity towards Nucleophilic addition reaction : CH,COCH,, HCHO, CH,CHO, Coo cons Draw the structure of 2, 4 DNP derivative of 1 = C=cHt 6 XI cor.