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General Chemistry 10th Edition Ebbing Test Bank
General Chemistry 10th Edition Ebbing Test Bank
Test Bank
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Chapter 8 - Electron Configurations and Periodicity
2. What is the maximum number of electrons that can occupy one p orbital?
A) 14
B) 2
C) 10
D) 1
E) 6
ANS: B PTS: 1 DIF: easy REF: 8.1
OBJ: State the Pauli exclusion principle.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | Pauli exclusion principle MSC: general chemistry
3. What is the maximum number of electrons that can be accommodated in the n = 2 shell?
A) 8
B) 4
C) 16
D) 22
E) 24
ANS: A PTS: 1 DIF: easy REF: 8.1
OBJ: State the Pauli exclusion principle.
TOP: atomic theory | electronic structure of atoms
6. What is the maximum number of electrons in an atom that have the set of quantum numbers
n= 1 and l= 0?
A) 6
B) 14
C) 10
D) 18
E) 2
ANS: E PTS: 1 DIF: easy REF: 8.1
OBJ: Apply the Pauli exclusion principle. (Example 8.1)
TOP: atomic theory | electronic structure of atoms
7. Which of the following orbital diagrams violates the Pauli exclusion principle?
1s 2s 2p
A)
B)
C)
D)
E)
8. Which principle or rule is violated by the following orbital diagram of an atom in its ground
state?
1s 2s 2p
10. Which of the following statements is true concerning the electron configuration [Kr]5p2?
A) This configuration cannot be the ground-state electron configuration for a Sr atom
because it violates the Pauli exclusion principle.
B) This configuration cannot be the ground-state electron configuration for a Sr atom
because it violates Hund's rule.
C) This configuration is the ground-state electron configuration for a Sr atom.
D) This configuration cannot be the ground-state electron configuration for a Sr atom
because it violates the Heisenberg uncertainty principle.
E) This configuration cannot be the ground-state electron configuration for a Sr atom
because it violates the Aufbau principle.
ANS: E PTS: 1 DIF: moderate REF: 8.2
OBJ: Define building-up principle.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | aufbau principle MSC: general chemistry
12. Which principle or rule is violated by the following orbital diagram of an atom in its ground
state?
1s 2s 2p
13. Which of the following electron configurations represents an excited state of the indicated
atom?
A) Ne: 1s2 2s2 2p6
B) N: 1s2 2s2 2p3
C) P: 1s2 2s2 2p6 3s2 3p2 4s1
D) Na: 1s2 2s2 2p6 3s2 3p2 3s1
E) He: 1s2
ANS: C PTS: 1 DIF: moderate REF: 8.2
OBJ: Define building-up principle.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | aufbau principle MSC: general chemistry
14. Which of the following have one or more filled d subshells in their ground state electron
configuration?
A) Ga
B) Cl
C) Si
D) He
E) Ar
ANS: A PTS: 1 DIF: easy REF: 8.2
OBJ: Define noble-gas core, pseudo-noble-gas core, and valence electron.
TOP: atomic theory | electronic structure of atoms
15. Two elements that have the same ground-state valence shell configuration of ns2np2 are
A) K and Mg.
B) O and Se.
C) Al and Ga.
D) Ge and Pb.
E) Mg and Ca.
ANS: D PTS: 1 DIF: easy REF: 8.2
OBJ: Define noble-gas core, pseudo-noble-gas core, and valence electron.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table MSC: general chemistry
17. According to the building-up principle or aufbau principle, which subshell is typically filled
next after the 3d subshell?
A) 4p
B) 5f
C) 6p
D) 5d
E) 1s
ANS: A PTS: 1 DIF: easy REF: 8.2
OBJ: Define building-up principle.
TOP: atomic theory | electronic structure of atoms
18. Which of the following electron configurations corresponds to the ground state of an atom
of a transition element?
A) 1s22s22p5
B) 1s22s22p63s23p63d104s24p2
C) 1s22s22p63s23p63d64s2
D) 1s22s22p63s23p64s2
E) 1s22s22p63s23p4
ANS: C PTS: 1 DIF: easy REF: 8.2
OBJ: Define main-group element and (d-block and f-block) transition element.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table MSC: general chemistry
23. Which of the following statements is true concerning the electron configuration [Ne]3s13p1?
A) It may represent a ground-state electron configuration of a Al+ cation.
B) It may represent an excited-state electron configuration of a Mg atom.
C) It may represent an excited-state electron configuration of a Ne– anion.
D) It may represent a ground-state electron configuration of a Mg+ cation.
E) It may represent a ground-state electron configuration of a Na+ cation.
ANS: B PTS: 1 DIF: difficult REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table | writing electron configurations using
the periodic table MSC: general chemistry
24. Which of the following may represent an excited-state electron configuration for a cobalt
atom?
A) [Ar]3d54s1
B) [Ar]3d64s2
C) [Ar]3d84s1
D) [Ar]3d64s1
E) [Ar]3d74s2
ANS: C PTS: 1 DIF: difficult REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table | writing electron configurations using
the periodic table MSC: general chemistry
25. All of the following ground-state electron configurations are correct except
A) .
B) .
C) .
D) .
E) .
ANS: A PTS: 1 DIF: moderate REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table MSC: general chemistry
26. What is the total number of electrons in p orbitals in a ground-state vanadium atom?
A) 6
B) 18
C) 12
D) 24
E) 30
ANS: C PTS: 1 DIF: moderate REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
29. Which of the following sets of four quantum numbers (n, l, ml, ms) correctly describes one of
the valence electrons in a ground-state radium atom?
A) 7 1 0
B) 6 1 1
C) 7 2 0
D) 7 2 0
E) 7 0 0 +
33. What noble gas core would be used when writing the ground state electron configuration for
tungsten (W)?
A) [Xe]
B) [Rn]
C) [Kr]
D) [Ar]
E) [Ne]
ANS: A PTS: 1 DIF: easy REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
34. If the electron could have a third spin state (that is, , – , and 0), what would be the
ground-state electron configuration of carbon?
A) 1s22s4
B) 1s22s32p1
C) 1s32s3
D) 1s22s22p2
E) 1s32s22p1
ANS: C PTS: 1 DIF: difficult REF: 8.3
OBJ: Determine the configuration of an atom using the building-up principle. (Example
8.2) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration MSC: general chemistry
35. The elements that are filling the 5f subshell are called
A) alkali metals.
B) transition elements.
C) lanthanides.
D) actinides.
E) main-group elements.
ANS: D PTS: 1 DIF: easy REF: 8.3
OBJ: Determine the configuration of an atom using the period and group numbers.
(Example 8.3) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table | writing electron configurations using
the periodic table MSC: general chemistry
36. The quantum numbers of an atom's highest-energy valence electrons are n = 5 and l = 1.
The element to which this atom belongs could be a
A) inner transition metal.
B) alkali metal.
C) s-block main-group element.
D) transition metal.
E) p-block main-group element.
ANS: E PTS: 1 DIF: moderate REF: 8.3
OBJ: Determine the configuration of an atom using the period and group numbers.
(Example 8.3) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table MSC: general chemistry
37. The angular momentum quantum number of the two highest-energy valence electrons in an
atom of germanium is
A) 4.
B) 0.
C) 1.
D) 2.
E) 3.
ANS: C PTS: 1 DIF: difficult REF: 8.3
OBJ: Determine the configuration of an atom using the period and group numbers.
(Example 8.3) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table MSC: general chemistry
38. Which of the following sets of four quantum numbers (n, l, ml, ms) correctly describes an
electron occupying a d orbital of an element in the third row of the transition metals?
A) 4 2 2 +
B) 5 2 1 –
C) 5 3 –1
D) 4 1 0 –
E) 5 0 0 –
39. An element that has the same ground state valence-shell electron configuration as indium is
A) boron.
B) silicon.
C) krypton.
D) lithium.
E) barium.
ANS: A PTS: 1 DIF: easy REF: 8.3
OBJ: Determine the configuration of an atom using the period and group numbers.
(Example 8.3) TOP: atomic theory | electronic structure of atoms
40. What is the valence-shell electron configuration for the fourth-period element in Group VA?
A)
B)
C)
D)
E)
ANS: C PTS: 1 DIF: easy REF: 8.3
OBJ: Determine the configuration of an atom using the period and group numbers.
(Example 8.3) TOP: atomic theory | electronic structure of atoms
KEY: electron configuration and the periodic table | writing electron configurations using
the periodic table MSC: general chemistry
41. The statement that "the lowest-energy configuration for an atom is the one having the
maximum number of unpaired electrons allowed by the Pauli principle in a particular set of
degenerate orbitals" is known as
A) the aufbau principle.
B) Hund's rule.
C) the Pauli exclusion principle.
D) Heisenberg uncertainty principle.
E) the quantum model.
ANS: B PTS: 1 DIF: easy REF: 8.4
OBJ: State Hund’s rule.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | Hund's rule MSC: general chemistry
42. Which principle or rule is violated by the following orbital diagram of an atom in its ground
state?
1s 2s 2p
43. The element whose atoms in the ground state have two half-filled orbitals is
A) Na.
B) Be.
C) Tl.
D) Po.
E) Sb.
ANS: D PTS: 1 DIF: easy REF: 8.4
OBJ: Apply Hund’s rule. (Example 8.4)
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | Hund's rule MSC: general chemistry
44. How many unpaired electrons are found in the ground state electron configuration of
selenium (Se)?
A) 2
B) 3
C) 5
D) 0
E) 1
ANS: A PTS: 1 DIF: easy REF: 8.4
OBJ: Apply Hund’s rule. (Example 8.4)
TOP: atomic theory | electronic structure of atoms
46. An atom of which of the following elements is not diamagnetic in the ground state?
A) Ca
B) Rn
C) All are diamagnetic.
D) Cd
E) Pt
ANS: E PTS: 1 DIF: easy REF: 8.4
OBJ: Define paramagnetic substance and diamagnetic substance.
TOP: atomic theory | electronic structure of atoms
KEY: electron configuration | magnetic properties of atoms MSC: general chemistry
A) 3 only
B) 2 and 3
C) 1 only
D) 1 and 2
E) 2 only
ANS: B PTS: 1 DIF: easy REF: 8.4
OBJ: Define paramagnetic substance and diamagnetic substance.
TOP: atomic theory | electronic structure of atoms
52. Who was the first chemist to recognize patterns in chemical properties of the elements?
A) Bohr
B) Dobereiner
C) Meyer
D) Mendeleev
E) Newlands
ANS: B PTS: 1 DIF: easy REF: 8.5
OBJ: Describe how Mendeleev predicted the properties of undiscovered elements.
TOP: atomic theory | periodicity of the elements
KEY: Mendeleev's predictions MSC: general chemistry
53. Which of the following statements concerning the periodic table is incorrect?
A) The elements in a given group or family have similar chemical properties.
B) The chemical characteristics of the elements are periodic functions of their atomic
numbers.
C) All the elements are arranged in order of increasing atomic weight.
D) Mendeleev left spaces in his periodic table for undiscovered elements.
E) Mendeleev received most of the credit for the early development of the periodic
table.
ANS: C PTS: 1 DIF: easy REF: 8.5
OBJ: Describe how Mendeleev predicted the properties of undiscovered elements.
TOP: atomic theory | periodicity of the elements
KEY: Mendeleev's predictions MSC: general chemistry
54. Which of the following species would be expected to have chemical properties most similar
to those of the nitrogen atom?
A) nitride ion
B) nitrite ion
C) phosphate ion
D) phosphide ion
E) phosphorus atom
ANS: E PTS: 1 DIF: easy REF: 8.6
OBJ: State the periodic law.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group VA elements MSC: general chemistry
55. Which of the following elements would be expected to have chemical and physical
properties most similar to those of the bromine (Br)?
A) chlorine (Cl)
B) neon (Ne)
C) gallium (Ga)
D) calcium (Ca)
E) lead (Pb)
ANS: A PTS: 1 DIF: easy REF: 8.5
OBJ: State the periodic law.
TOP: atomic theory | periodicity of the elements
56. When arranged in order of increasing atomic number, the elements exhibit periodicity for all
the following properties except
A) electron affinity.
B) color.
C) ionization energy.
D) electron configuration.
E) atomic radius.
ANS: B PTS: 1 DIF: easy REF: 8.6
OBJ: State the periodic law.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties MSC: general chemistry
59. A section of the periodic table with all identification features removed is shown below.
V W X
Y Z
Which element has the smallest atomic radius?
A) W
B) Y
C) X
D) Z
E) V
ANS: C PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
60. An atom of which of the following elements has the smallest atomic radius?
A) Sb
B) I
C) Te
D) Rb
E) Sn
ANS: B PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
61. An atom of which of the following elements has the largest atomic radius?
A) Cl
B) P
C) Na
D) S
E) Si
ANS: C PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
62. An atom of which of the following elements has the smallest atomic radius?
A) At
B) F
C) I
D) Br
E) Cl
ANS: B PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
63. An atom of which of the following elements has the largest atomic radius?
A) As
B) Sb
C) P
D) Bi
E) N
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
64. An atom of which of the following elements has the smallest atomic radius?
A) Cl
B) Rb
C) Ca
D) Si
E) As
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
65. An atom of which of the following elements has the largest atomic radius?
A) Ge
B) K
C) Cl
D) Ca
E) As
ANS: B PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
66. In which of the series of elements listed below would the elements have most nearly the
same atomic radius?
A) Na, K, Rb, Cs
B) F, Cl, Br, I
C) Na, Mg, Al, Si
D) Sc, Ti, V, Cr
E) B, Si, As, Te
ANS: D PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | atomic radius MSC: general chemistry
67. Rank the following atoms in order of the largest to smallest atomic radius: Al, P, Cl, K.
A) K > Al > P > Cl
B) Al > K > P > Cl
C) P > Al > K > Cl
D) Al > P > Cl > K
E) K > P > Al > Cl
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative atomic sizes from periodic trends. (Example 8.5)
TOP: atomic theory | periodicity of the elements
68. Below are data on the first four ionization energies for a fictitious element X.
First ionization energy = 500 kJ/mol
Second ionization energy = 2000 kJ/mol
Third ionization energy = 3500 kJ/mol
Fourth ionization energy = 25000 kJ/mol
From the data, which of the following statements is incorrect?
A) The third ionization energy is greater than the second ionization energy because
X2+ has a bigger charge than X+.
B) X could belong to Group IIIA.
C) X could belong to Group IIIB.
D) X could belong to group VA.
E) The fourth ionization energy is much greater than the third ionization energy
because X3+ consists of a noble-gas core or a pseudo-noble-gas core.
ANS: D PTS: 1 DIF: difficult REF: 8.6
OBJ: State the general periodic trends in ionization energy.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
69. Which of the following properties, in general, increases from left to right across a period in
the periodic table?
A) ionic charge
B) atomic radius
C) density
D) ionization energy
E) metallic character
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: State the general periodic trends in ionization energy.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
70. The statement that the first ionization energy for an oxygen atom is lower than the first
ionization energy for a nitrogen atom is
A) inconsistent with the general trend relating changes in ionization energy across a
period from left to right and due to the fact that oxygen has one doubly occupied
2p orbital and nitrogen does not.
B) consistent with the general trend relating changes in ionization energy across a
period from left to right because it is harder to take an electron from an oxygen
atom than from a nitrogen atom.
C) consistent with the general trend relating changes in ionization energy across a
period from left to right because it is easier to take an electron from an oxygen
atom than from a nitrogen atom.
D) incorrect.
E) inconsistent with the general trend relating changes in ionization energy across a
period from left to right and due to the fact that the oxygen atom has two doubly
occupied 2p orbitals and nitrogen has only one.
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: State the general periodic trends in ionization energy.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
71. The change in energy for which of the following processes corresponds to the first
ionization energy of calcium?
A)
B)
C)
D)
E)
72. The change in energy for which of the following processes represents the first ionization
energy of bromine?
A)
B)
C)
D)
E)
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: Define first ionization energy.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
73. The change in energy for which of the following processes corresponds to the second
ionization energy of barium?
A)
B)
C)
D)
E)
74. An atom of which of the following elements has the highest fourth ionization energy?
A) Al
B) Se
C) Si
D) Ga
E) As
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
75. An atom of which of the following elements has the smallest ionization energy?
A) I
B) Sb
C) Sn
D) Rb
E) Te
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
76. An atom of which of the following elements has the largest ionization energy?
A) Te
B) Sn
C) Sb
D) I
E) Rb
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
77. An atom of which of the following elements has the smallest first ionization energy?
A) Sn
B) Pb
C) Ge
D) C
E) Si
ANS: B PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
78. An atom of which of the following elements has the largest first ionization energy?
A) N
B) Sb
C) As
D) P
E) Bi
ANS: A PTS: 1 DIF: easy REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
79. An atom of which of the following elements has the smallest first ionization energy?
A) Rb
B) Si
C) F
D) As
E) Ca
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
80. An atom of which of the following elements has the largest first ionization energy?
A) Ca
B) Rb
C) Ge
D) Cl
E) P
ANS: D PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
81. An atom of which of the following elements has the largest second ionization energy?
A) Na
B) Cl
C) S
D) Si
E) Mg
ANS: A PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
82. Which of the following ground-state electron configurations corresponds to an atom having
the largest ionization energy?
A) [Ar]3d104s24p3
B) [Ne]3s23p3
C) [Ne]3s23p2
D) [Kr]4d105s25p3
E) [Xe]4f145d106s26p3
ANS: B PTS: 1 DIF: moderate REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
83. Rank the following ions in order of increasing first ionization energy: O2–, Mg2+, F–, Na+.
A) Mg2+ < Na+ < F– < O2–
B) Mg2+ < O2– < Na+ < F–
C) O2– < F– < Mg2+ < Na+
D) O2– < F– < Na+ < Mg2+
E) O2– < Mg2+ < F– < Na+
ANS: D PTS: 1 DIF: difficult REF: 8.6
OBJ: Determine relative ionization energies from periodic trends. (Example 8.6)
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | ionization energy MSC: general chemistry
84. The electron affinity value expected for the process would be
A) a small negative number.
B) a large positive number.
C) a small positive number.
D) a large negative number.
E) zero.
ANS: D PTS: 1 DIF: easy REF: 8.6
OBJ: Define electron affinity.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | electron affinity MSC: general chemistry
85. The change in energy for which of the following processes corresponds to the electron
affinity of iodine?
A)
B)
C)
D)
E)
86. Which of the following statements is true about the ionization energy of Mg+?
A) It will be equal to and opposite in sign to the electron affinity of Mg+.
B) It will be equal to and opposite in sign to the electron affinity of Mg.
C) It will be equal to and opposite in sign to the electron affinity of Mg2+.
D) It will be equal to the ionization energy of Li.
E) none of the above
ANS: C PTS: 1 DIF: moderate REF: 8.6
OBJ: Define electron affinity.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | electron affinity MSC: general chemistry
87. An atom of which of the following elements has the most negative electron affinity?
A) Rb
B) As
C) Cl
D) Br
E) Se
ANS: C PTS: 1 DIF: easy REF: 8.6
OBJ: State the broad general trend in electron affinity across any period.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | electron affinity MSC: general chemistry
88. According to the general trend in electron affinities, which group (or family) of elements
tend to form the most stable anions in the gas phase?
A) noble gases
B) halogens
C) transition metals
D) alkaline earth metals
E) alkali metals
ANS: B PTS: 1 DIF: easy REF: 8.6
OBJ: State the broad general trend in electron affinity across any period.
TOP: atomic theory | periodicity of the elements
89. Which of the following forms the most stable anion in the gas phase?
A) Br (electron affinity = -325 kJ/mol)
B) I (electron affinity = -295 kJ/mol)
C) Te (electron affinity = -190 kJ/mol)
D) C (electron affinity = -122 kJ/mol)
E) As (electron affinity = -77 kJ/mol)
ANS: A PTS: 1 DIF: easy REF: 8.6
OBJ: State the broad general trend in electron affinity across any period.
TOP: atomic theory | periodicity of the elements
90. Which of the following ground-state electron configurations corresponds to an atom that has
the most negative value of the electron affinity?
A) 1s22s22p63s1
B) 1s22s22p63s23p5
C) 1s22s22p63s23p2
D) 1s22s22p63s23p63d54s2
E) 1s22s22p6
ANS: B PTS: 1 DIF: moderate REF: 8.6
OBJ: State the broad general trend in electron affinity across any period.
TOP: atomic theory | periodicity of the elements
KEY: periodic properties | electron affinity MSC: general chemistry
91. Which of the following statements is true concerning a concentrated solution of lithium
oxide in water?
A) The resulting solution is strongly basic.
B) The resulting solution is weakly acidic.
C) The resulting solution is neither acidic nor basic.
D) The resulting solution is weakly basic.
E) The resulting solution is strongly acidic.
ANS: A PTS: 1 DIF: easy REF: 8.7
OBJ: Define basic oxide, acidic oxide, and amphoteric oxide.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group IA elements MSC: general chemistry
93. Sodium and potassium have similar chemical and physical properties. This is best explained
by the fact that both elements
A) have the same ground-state valence-electron configuration.
B) have low relative atomic masses.
C) are in Period 1 of the periodic table.
D) have relatively low first ionization energies.
E) are active metals.
ANS: A PTS: 1 DIF: moderate REF: 8.7
OBJ: Describe the change in metallic/nonmetallic character (or reactivities) in going
through any main group of elements.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group IA elements MSC: general chemistry
95. A few atoms of the new element 113 were created in 2004 by a team of Russian and
American scientists. It has been given the temporary name "ununtrium" and the temporary
symbol "Uut." Based on ununtrium's position on the periodic table, what type of oxide(s)
should it form?
A) Ununtrium should form a basic oxide with the formula Uut2O3.
B) Ununtrium should form an amphoteric oxide with the formula UutO.
C) Ununtrium should form an acidic oxide with the formula Uut2O3.
D) Ununtrium should form two acidic oxides having the formulas Uut2O and Uut2O3.
E) Ununtrium should form two basic oxides having the formulas Uut2O and Uut2O3.
ANS: E PTS: 1 DIF: easy REF: 8.7
OBJ: Describe the change in metallic/nonmetallic character (or reactivities) in going
through any main group of elements.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group IIIA elements MSC: general chemistry
96. The element antimony is in the same group as phosphorus. Which of the following is the
formula of antimonous acid?
A)
B)
C)
D)
E)
ANS: D PTS: 1 DIF: moderate REF: 8.7
OBJ: Describe the change in metallic/nonmetallic character (or reactivities) in going
through any main group of elements.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group VA elements MSC: general chemistry
97. The element selenium is in the same group as sulfur. Which of the following is the formula
of selenous acid?
A)
B)
C)
D)
E)
ANS: C PTS: 1 DIF: moderate REF: 8.7
OBJ: Describe the change in metallic/nonmetallic character (or reactivities) in going
through any main group of elements.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group VIA elements MSC: general chemistry
98. An unknown element, X, reacts with oxygen to form two oxides with the general formula
X2O3 and X2O5. The pure element is strongly paramagnetic, and the oxides are amphoteric.
Which of the following elements could be represented by X?
A) Sc
B) Na
C) Bi
D) S
E) Sb
ANS: E PTS: 1 DIF: moderate REF: 8.7
OBJ: Describe the change in metallic/nonmetallic character (or reactivities) in going
through any main group of elements.
TOP: atomic theory | periodicity of the elements
KEY: periodicity in main group elements | group VA elements MSC: general chemistry