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C X
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[(CH3)3CCH2Br]
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Common and IUPAC names of some Halides Common and IUPAC names of some Halides
Structure IUPAC Name Common Name Structure IUPAC Name Common Name
H Cl
Cl
Chloroethene Vinyl Chloride
H H H C Cl Trichloromethane Chloroform
(CH2=CHCl) Cl
(CHCl3)
H
Br Br
H H H C Br Tribromoethane
3-Bromoethene Allyl bromide Bromoform
(CH2=CHCH2Br)
Br
Cl (CHBr3)
H C H Cl
Dichloromethane Methylene Chloride Tetrachloromethane
Cl H C Cl Carbon tetrachloride
(CH2Cl2)
Cl
9 (CCl4) 10
H H
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Uses of Alkyl Halides: Fire extinguishing Uses of Alkyl Halides: Fire extinguishing
• For example, Bromotrifluoromethane (Halon • Carbon dioxide can cause severe distress at
1301, CBrF3) total flooding systems are typically concentrations of 3 to 6%, and has caused
used at concentrations no higher than 7% volume death by respiratory paralysis in a few minutes
per volume (v/v) in air, and can suppress many at 10% concentration.
fires at 2.9% v/v. • Bromotrifluoromethane (Halon 1301 ) causes
• By contrast, carbon dioxide fire suppression flood only slight giddiness at its effective
systems are operated from 34% concentration by concentration of 5%, and even at 15% persons
volume (surface-only combustion of liquid fuels) remain conscious but impaired and suffer no
up to 75% (dust traps). long term effects.
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