A

hending back bon ol

, Back- bting: Any oundl fo be
BF bond in Bl, oxpectecd
B Atrongu wd Ahorter han
eh brnliny h
To (xplain this, concopt of

5. backe lond.
Bf
CB=F
o-back bond struetumy
B.0 > e,uielant
all B-F boncly ave
Evpurimnanlay
Entent o Back - bonding
Resenane >BI
Htybrid B- CLpi-po
back
To fevm 4hrons - bordi, sige of orbital mwt bond)
)Dueto
be timilor (to inerase extento ever lap) n Bl3 atom
BBrs, eter terminad halogen ha a tamger p- erbital than Boren
wuich cleerass eatent of evlap Omel in tun lowers strengtn oh T-bon d.
A hew's aud

Trinchgl amine
Trisyl amne
(CHs), N (SiH)aN
Cyrgnida) (Trigona plamow atout Natem
pr-dr
backbonc
CH3
CHy CHs Sit3
q. what back- bonding,
Ocer omel wen oloes it
why odos it
Sits Thy pr- dT back
ocr ? Hasi bend is ddeloaled
St Hs in entre moleule
atons that hawe LoP (9.
halogen) to e (Tri_enai Planow)
oleficint atoms(tig Beron). IE ocer!
to gai stabiiy
For back bonding to take place both bonded ato nut be
-Qnd pmresent in
Period. One ol tu ato Ahd
pair wie n.o efw eyt hawe a(ouwvacant
Lying have a o
erbital /witn ow enrsy)
'Sio,, HAIAA, siye ethir, ete.
 ples Vawiouy
hybrillntion
C;o, (oahon suboxcle), Be Cl,ete.
(l- Be -Cl (9)

BE Bcl3, Alct, ote.

B-F

p'd /sp'd' sp
2PCL ,(o)’ PCL, Pc
Pel, (1) Cl

olos ste exiut bt not sel, (or sBrsr) ?

SBr cannot exist ue to tule

arounel's
Strecie hhorane: Repuoion atom within a mseue die to b'g
atom
Comparien e Bond Ange :
turmin atom Jone Cone pirs
are
ci hherent; MorL Lp cause mer
rpuin and reduees bend an gla.
!NH,

H sp hybridiatbn

H
H
 Contra

=) E N o central atom BiA.

(tN) >(EN), YE N),
NH P H3
)
towomd
As. Ruasoni Ahit f a' cloud
t.N elenenf
yntre

Drmge's
Nity
benal
angle PH Hz S
Drago's rula applus:
3rd and hiyher parlood einath PRon when
tAsta H, Se atta che o to ueer term'nal atom o low
Te E N. 42,5, Ctr H) ther 1 no
hybd" biybridi
Jatien o) central atom i (entral atom has me m7e o P.

poyatomie beus. n 4uch casu, pure 'p' br bitalo

atom form bonol wtta termin al ateny (H ov c)
(ntral atom terminal atom
diljerut =)
(Eyeert n tae y p' trminad oatom wber ENu
sp3
deuioing gactor)
Br Bv
Cempre blw tHoa anol Dfz.
/Pue to laye sige, stui
Convur
cloushom

Ei pectd: O9°28
than ep' L' od t09.5°?
kra Back -
boroliuy d' blw LP of
and valant
ateins Cp+- do orbital o] C
Double bond chorobach bond)
ctey in O-C
loond case ratr
reduced