Professional Documents
Culture Documents
Electrochemistrybyme PDF
Electrochemistrybyme PDF
o At RY 3 A748 oa oe Given eattja =e > __£'e*"| 8 = —o-6v - ha _ 4 —Since__tuluction_Poantial _Q A1d Saale thon B 4D _ MA con oxide meana Rx ia }eosibre 2 Oue (an __u0e__Atoue __Ag 1003, ohn Cu Comtofnen given > fly = 0-80 V , Ets oes cHon . tg — - — Sine Teach iy Q Cu 1h quecten ther A jue ancons displo cerntn * A _____Rx+_ in Qeesiie Penee we Gn't stone Ay nO, Sal tin Gr Grieves A| J « Gar Give Elecbtochemical Rep merertt obion y Oxicletion ~ Reduchon Mal Rey Overall Rx ££ *eolt ee a ) Eng =F ontoy —_ cuMfeu = t0-34V Soli eee Since Reduction Potential Qe Ag is _queatet_thon Gu do —Ag acts as 44 Cothode 4 Gu acts as Anode, Aredei- Cuts) ——> _ eu** lay) +207 oxidetion Help &«: Gthede |-_Ag*toa) tem 3 Als) J x2 Reduction half Re» —— $$ ______ Oven || RE ——— —talg +2.A9¢a4) byt 2agts) a ——Cleciochemmi al Cit Rephexentohion als). } C70) |} AgTiag) fags) ——Stondard_£-m-F.) tll — — Elell_= _€tnode = Elanode 2) Ro ~ p-ay ogee Wt b lpia tg D> o-4ov- _ U)£ re] fe = obey ; Enctfal=-irly —_ So} eae ating fe 15 queated thoy _ | AL 40 Fe arts od £ A-AL acts ad ri” __ Amerie. Kista Anode. aoe Ase ic ALU ——> aly a0} xr. —Lathodet- fe 4ar——> Fe Tx | | I | || | rane 2A 3¢6"_——9 al +360 6) E0:F col 9 ee t R —Eonoole ts = Po + 2). a) Boy oo ererdohon ——alf_atton) |e? um) ff, if 9 PP DH= ) Detenat-ration — Q- Non _stondauel rel elechuoae tl t Eta f ———-“uaing_ Neunat 9.” a _ M. Coll . elect) eS Ratoduck Cone + Reactant Canc, oe awaday change a WF Redaxe C98 09 > > pT: — _ _ a _ ~ f= -E= 09-0591 log a - $a n a ~~ ~~ a a > wine electrode Pokntial Q 2m * i Br] POroImM 8 tt cn Em = -0-16 y- a _ S_2n" 426 —>» ants) _ _ M22) 3 ___f2n_=_E2n— 0-059) log n 2) -0-16 — 9-054) a Bey] = 2 2» >) =8-16 = 9-058 log _1 — 2 = 7 - — 2 moth 90 54) sabe oe = _ ee ea 2 ss) 0-92 Vv. oe a at ames E: PO - 0-054) “wh | u yo -o- 055). | tos lo ge 7 > bay = -RA fem as Wt er ww E+ £=q0sa) toy : : n ~ 2 O- 04054! by Be _ ! “te = 0-059) log e598 94 )=0:059) x3 —— Vv Non- Stondarnd — Clechtochernical cell £-1 rl 4 £Gu = flew ~ 2: -202 er fe ae Se os Eu oo. . ren . —____= Fall a-054 toy a (my 200) | ee ans ___&- Retewmine. ec Eeeit __ —Aypae * lore ee) my on fe*(o- mee ee z= Dal a agen ee ena — FZ?_feell 2 Even =0-052) log @ oe 7 etter ee 7 = (-o-e pl) - 9-054) 0g AC 4 a ore | | | + 203 205 (my foJ® oe eg 20-3 ~0-054) lay 10° _ “ $ F034 0059) x 6 5S 0-35 Vv - 7 _ 7O___Detev mination _}_Electuode Sota ertinteDoka pee : ee . C Ge2 oo x Aon a educde 0 Cee] Fe = fe2* +20" > Fe n=s2 —@__£,” € Fed Fe =9 Feit + ae-> > Fe mes —@ Fo 2 _ Ain @ =D + 2 Aga = Ab, + AG _ ais anf mgt - Mas = nee mey _ _ - OES etme — _ _ ng ee 2») _L£+24 _ = Pr 3 a _ - 2D Ge detsmine cell is — _ mM ___fe | fe (o-e1m) }] AL™* (0-001 m)] abo Lac} al 2 Mv _ ——— a fe fe = eS os _— Eeatt = £*= 9-954 log & n ee = - - +e _ ——— ¥ 7 _ —Conarlin G—— oe aa - mode £ Gtnode ~— ES Some aenetol dipped in Some_ ere es auth haved. if: Cone _ = ws, 2 Sa emiecnon J ic _ G4 Such cell (Call = 0) : ae Prete Cll J& — Tie ese - —& _ _ but gas hnvclued _ — i /orenP _* = & ‘Bes Fela} et tee fay Gl Reaction will & —be__Spontencowr if - A) R= 8) > — & atin D) fp =A = Latin 9 pipeee - oe 0 a — aa —2et =a lets) 20 2er ~ a _ saan » Gace net) Gihode EEE > 7 - _ wf = om =0-0 54 tap — yf Le T a oe o ef me ——— > - 2-0: 054 tog fh - 7 > = 20-958) ng > © oe ~ 3 a - > — F Relatfonshtp blw £-m-F 2 colt £ AG 3 AG = -ve Q use jal ood 7 a lene by dystere oo - 2 =electitcol took _ 2 - 3 =chanye. x Potentiel. dif ae —_ i > =nf x Evel _ 3 Ao_2_=nF feet} Ags -né eau _ _ > Relomtionship bj Evelt Lk (epuslonstont) 3 ar >= At’ +2: 303 £7 (09.6 — __{von't vei 4) _ So AG" = -2"303 eT log 2 fe Eval = £22303 RT og a a leg ks lela ee DP [og k= eit | > at age) — 4 6-059] 2 _oe - = ——+ — Cell a a \ — hich elt he nechauger — See ana wee Ta) e FP gt techlenche Gil sv) ge _ cen aprile sod Lo thodle ——— + 7 rt a har —£ _ T+ -| nist Paste e EE {4 tt Manse a | Ul _ aie eos a a eo —gapattine SA wens Gree Conteinen Se - OF nck anbyct & At fmede -2n_—3 Dpr?* +9¢- © At Cotmode © Mo, + 2NHit +0 Bro, t2NH3 +H,d = Dole Zn jon Combine sith Nia Jour 0 Complex [an imi T 2 —This_Cll_ do met Pradside_(ontont Voltage sterough out ie ros ——tine —hecoude electue lye Gone. chenge wot time e > HA _Cell _ecome dod aliet Some time even ft ie met —___In_use becouse Amonium chlowide al tole wwe ; Zinc. so se Use Fouous Popo lime to slow down © this Pua car, & 9 —Mlewy Call_o Bution Gall —-35v) _& - =fytephie Tet - & 7 * mmolat Ponte Ze for ere < Oy gO 2 ro, tape qT@ Date No. Page es ——but_ 08) £440. > Hy!) + 20n7 - 7s do _nert chonge—icith Hime “41 Quovider _Gnatont —Voltoge — though out Ue time.» tA mot Env Luamental | feted ce—ie$ Puerence * = — nest Canby es esi J ~~ Coser at cien — Poss (0a) 4) 2 fsou W) +20 - sere: zk Papal 50% ; + Ut 407 ——> Prsoy 2H, 0- ——__-_ Oy get So Speci pi Coll, ene ore Dict ee——_ Ghaaging) [Ext Voltage EmeE geal] — a _ CrectclyHe Gl Nechanisn cm _ ———dissolvtel to, 50, etc. 40 arte ad elechiolyte e 0 a 5 dine seachuity Q H 1A -Iras ton fe cay s 28 fo Ht get peductd ——$@. Angdy Femetal Cothede _r Fe —> fe? +r0- 2s bon 3 on - nx er 2H +10, 3 wo. a PT OHO DOs Angle a Sua feta & roa, o- e _ _ - pe. 4.0,-Mh0 fes0y-2HD: & be. clechuochemi al Setup tne Place aud Metal _ - ~ 3 enidised —_omeand Como ded p97 5 blFacto schich dedde fel Q Cautotion a > O Beoctvity og Mel yp _ — y Rate 2 Comuorio 3 a > get oxidised Metal 9 @_ Presence _Q Tnp sidiea te - = > Tin pure metal Comode ostiy. __ 7 —e “leas %achve elernent iP ies > 4 pn - a y® Presen line water) _ a _ Me Cea a Jouce metal to acta ot onede.. = Mlethed in Presont Cowintiog : a 2 Weapons ble fou. Cosmosion do not (ome in Corttoe-+ v0’ _ oem FS sesifiel orci a a Aetna § onal sity — —___In__oxidetion, __ ee @_falvenisetion — =P Bera _ © - nv Se SHoth- : B __2n_Coating on Fe. — AO, — z “Tn ning a an a “ark on toke Sn Gaaling “on m Ee ply 2S — st send sth atin Q joun ~ tte pace 4 _Fuel cell eT 7 * Fy « } md — #7 | | FT a 3 A device uohich Geoseereetebtoin convent Combustion enes crn into _elec-tticol eneugy ‘Sa _Feeg Hy Fuelcell (fart uacel in Apollo 4 tot = Se pra set) {t+ MgO + 2e- —3 9 ou Papen = Ho. | < ea oe « = aE | 7) oo +20n7- 20+ 20- 4 2 — Cle with Pt,eo — } = Adu anto; ye - oe > - en envi Hon mental Quiendly. _ » uy) High edticons Grex 8%) oe ~~ Didadventose_ a Se . — Costly. a Oo WO Efficreney g— puct call —— > ——- are a > 4 = elecbuicol enengy x loo _ ett enesigy a — = pee ~~ hh ee —_ Lg) yduogeaubon-0 pele a —_—_ (so Pone 92) N= ; = a > Gg “+ 6HyO —> atop ? Gada = Thations . _ a ae tations ave boatel on dha pick that dating dine. — f_tétuction » one Qe fons 18 Yepleted by the othe .now thee pod ze ions ilo tn theis_ionic Conduct vities which _ Yeault 4 Vay! ing Consluchity duniing Ao. Cowise Q tttelion . bo Conductometic ttuolions (on be — > Poi formiel in Schutiond whee te ions _hove digeen eth Conductivilies and | Se ee LS _-+20 e7 ae a — mo bilities we Gon hove _urttnest Canes fesolg- fens ined ad _boses ete, a 2 Song acid Vs Steong Be _ Consideved htuation @) HCL (Stony ccd) with Nodn Isto oy base) a AniNielly swith pure UCL —.the fonductonce vey. high due to 1ho highly ae al: . a oe Qnducing ions : wows One we stork adding rota fans mabey gp aue_xeptterd s0itn Net (slow mouirg) theueby dec toxivg Overell @nductonce. Bill dhe equivalence pomt. whew woe Kove only Macl i _oum cols Now pe futher add Noort then the sole stata hosing om excess C7 OH jong « ohich_inuteases the Conductivity + Hence if we plot a gusph Q— Conductonce Versus Volume Qwaon add tel | Ll ae