45. The frequency of B is 3% greater than A. The 48.

An increase in pressure of 20 kPa cause a certain

frequency of C is 2% less than that of A. If B and C volume of liquid decrease by 2 × 10–3 percentage
of initial volume. The speed of sound wave in
produce 7 beats/second, then the frequency of A is
 kg 
(1) 130 Hz liquid is nearly:  Density of liquid = 2 × 103 3 
 m 
(2) 135 Hz
(1) 500 m/s
(3) 160 Hz (2) 700 m/s
(4) 140 Hz (3) 850 m/s
(4) 920 m/s
46. Two soap bubbles of radius r1 and r2 coalesce to
49. A disc of radius R is pivoted at its rim. The period
form a single bubble under isothermal condition in for small oscillations about pivoted axis
vacuum. Find the radius of resulting bubble. perpendicular to the plane of disc is
(1) r1 + r2 R
(1) 2
r +r g
(2) 1 2
2 2R
(2) 2
(3) r12 + r22 g
2R
r12 + r22 (3) 2
(4) 3g
2
3R
(4) 2
2g
47. As length of a simple pendulum is increased
fourfold, the time period becomes 50. Young’s double-slit experiment establishes that:
(1) 3 times (1) Light consists of waves
(2) 4 times (2) Light consists of particle
(3) Light consists of both wave and particle
(3) Remains unchanged
(4) Light consists of neither particle nor waves
(4) 2 times

SECTION-II (CHEMISTRY)

SECTION - A (1) CH3CH2—Br

51. The reagents used for the following conversion
(A) & (B) are respectively (2)

(3) Br–CH2–CH2–CH2–CH2–CH2–CH2–Br

(1) LiAlH4 & soda lime (4)

(2) Zn(Hg)/HCl & Red P + Hl
(3) Red P + Hl & Soda lime
53. Which of the following is the correct set of
(4) Soda lime & Red P + Hl
52. Which of the following might form cyclohexane quantum numbers for last filled electron of 21Sc?
on reaction with dry Na in ether? (1) 3, 2, 0,  1/2 (2) 4, 0, 0,  1/2
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 (3) 3, 0, 0,  1/2 (4) 4, 0, –1,  1/2 quantity of the product formed (x) varies with
temperature (T) as given. Select correct statement:
54. Which of the following is not permissible
arrangement of quantum number for electrons in
an atom?
1
(1) n = 5, = 3, m = 0, s = +
2
1
(2) n = 3, = 2, m = −3, s = − (1) Stages I and III are endothermic but II is
2 exothermic
1
(3) n = 3, = 2, m = −2, s = − (2) Stages I and III are exothermic but II is
2 endothermic
1 (3) Stages II and III are exothermic but I is
(4) n = 4, = 0, m = 0, s = +
2 endothermic
(4) Stage I is exothermic but stages II and III are
55. The compound MX4 is tetrahedral. The number of endothermic
XMX angles in the compound is:
(1) Three 59. The first, second and third ionisation energies
(2) Four (E1, E2 and E3) for an element are 7 eV, 12.5 eV
(3) Five and 42.5 eV respectively. The most stable
(4) Six oxidation state of the element will be:
(1) + 1 (2) + 4
56. Number of S – S bond is H2SnO6 is : (3) + 3 (4) + 2
(1) n
(2) (n – 1) 60. Match the oxide given in column I. with its
(3) (n – 2) property given in Column II
(4) (n + 1) Column I Column II
(i) Na2O A. Neutral
57. The effect of temperature on equilibrium constant (ii) Al2O3 B. Basic
is expressed as (T2 > T1) (iii) N2O C. Acidic
K −ΔH  1 1  (iv) Cl2O7 D Amphoteric
log 2 =  −  Which of the following options has all correct
K1 2.303R  T2 T1 
pairs?
For endothermic reaction false statement is:
(1) (i) – B, (ii) – A, (iii) – D, (iv) - C
1 1
(1)  –  = Positive (2) (i) – C, (ii) – B, (iii) – A, (iv) - D
 T2 T1  (3) (i) – A, (ii) – D, (iii) – B, (iv) - C
(2) H = positive (4) (i) – B, (ii) – D, (iii) – A, (iv) - C
(3) log K2 > log K1
(4) K2 > K1 61. Small quantity of industrial toxic waste is
removed by
58. For the following reaction through stages I, II and III (1) Burning in open bins
A ⎯⎯
I
→ B ⎯⎯
II
→ C ⎯⎯
III
→D (2) Controlled incineration
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 (3) Burning in closed bins (2) 5.50 × 10–12
(4) Both (1) & (2) (3) 5.65 × 10–13
(4) 5.65 × 10–12
62. Which of the following compounds can exhibit
66. How many total number of substituents are
tautomerism? present in the following compound?
(1) C6H5CHO
O
||
(2) C6 H5 − C − CMe3
O O
|| ||
(3) C6 H5 − C − CH 2 − C − H
O
|| (1) 3
(4) C6 H5 − C − C6 H5 (2) 4
(3) 5
63. Among the following, the most stable isomer is: (4) 6

OMe 67. Graphite is a soft solid lubricant extremely

(1)
difficult to melt. The reason for this anomalous
OH behaviour is that graphite
OH (1) is an allotropic form of carbon.
(2) is a non-crystalline substance.
(2) OMe (3) has carbon atoms arranged in large plated
rings of strongly bonded carbon atoms with
OH weak inter plate bonds.
(4) has molecules of variable molecular masses
(3) OMe
OH like polymers.

OH OMe 68. Standard reduction potentials of the half reactions

are given below:
(4) F2(g) + 2e– → 2F–(aq) ; E° = +2.85 V
Cl2(g) + 2e– → 2Cl–(aq); E° = +1.36 V
Br2(l) + 2e– → 2Br–(aq) ; E° = +1.06 V
I2(s) + 2e– → 2I–(aq) ; E° = +0.53 V
64. Strength in volume of a solution containing 30.36
The strongest oxidizing and strongest reducing
g/L of H2O2 is
agents respectively are
(1) 10 volume
(1) F2 and I–
(2) 20 volume
(2) Br2 and Cl–
(3) 5 volume
(3) Cl2 and Br–
(4) 30.36 volume
(4) Cl2 and I2
65. The ionization constant of ammonium hydroxide is
1.77×10–5 at 298 K. Hydrolysis constant of 69. Initial setting of cement is mainly due to:
ammonium chloride is (1) Hydration and gel formation
(1) 5.65 × 10–10 (2) Dehydration and gel formation

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 (3) Hydration and hydrolysis 75. Phenol is treated with bromine water and shaken
(4) Dehydration and dehydrolysis well. The white precipitate formed during the
process is
70. Na2SO4 xH2O has approximately 50% H2O by (1) m-bromophenol
mass. Hence, x is (2) 2, 4-dibromophenol
(1) 4 (3) 2, 4, 6-tribromophenol
(2) 5 (4) A mixture of o- and p-bromophenol
(3) 6
(4) 8

71. How many grams of NaOH should be added to 76.

water to prepare 250 ml solution of 2 M NaOH?
(1) 9.6 × 103
(2) 2.4 × 103
The reaction is an example of:
(3) 20
(1) Nucleophilic addition
(4) 24
(2) Nucleophilic substitution
(3) Electrophilic addition
72. NH3 gas is liquefied more easily than N2. Hence
(4) Electrophilic substitution
(1) vanderwaals constants ‘a’ and ‘b’ of NH3 >
that of N2 PI
C2 H5OH ⎯⎯⎯
3 → A ⎯⎯⎯→ B ⎯⎯⎯⎯⎯ →(C),
KCN
Hydrolysis
77.
(2) vanderwaals constants ‘a’ and ‘b’ of NH3 <
that of N2 (C) is
(1) CH3–COOH
(3) a (NH3) > a (N2) but b (NH3) < b (N2)
(2) CH3—CH2—COOH
(4) a (NH3) < a (N2) but b (NH3) > b (N2)
(3) CH3—(CH2)2—COOH
(4) CH3H—COOH
73. A real gas most closely approaches the behaviour
of an ideal gas at 
78. CH3COOH ⎯⎯⎯
P O
→ X.
(1) 15 atm and 200 K 2 5
Identify X.
(2) 1 atm and 273 K
(1) CH3COCH3
(3) 0.5 atm and 500 K (2) CH3CHO
(4) 15 atm and 500 K (3) (CH3CO)2O
(4) CH4

74. Which is always correct at equilibrium? 79. In the given following diazonium salt which is
(1) G° = 0 more stable?
(2) G = 0 + −
(1) C2 H5 N 2 X
(3) Ssystem = 0 + −
(3) E = 0 (2) CH3 N 2 X
+ −
(3) C6 H5 N 2 X

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 + − (2) K3[Cu(CN)4]
(4) C6 H5CH 2 N 2 X
80. Amino acid /proteins with only activated benzene ring (3) CuF2
give only (4) [Cu(CH3CN)4]BF4
(1) Xanthoproteic test
(2) Benedict test
(3) Fehling’s test
(4) All of these

81. Nucleic acids are:

(1) Polymers of nucleotides
(2) Polymers of nucleosides
(3) Polymers of purine bases through phosphate ester
bonds
(4) Phosphate ester bonds

82. 75% of a first order reaction was found to

complete in 32 min. When will 50% of the same
reaction complete ?
(1) 24 min
(2) 16 min
(3) 8 min
(4) 4 min

83. The rate constant for a first order reaction whose

half-life is 480 sec is:
(1) 1.44 × 10–3 sec–1
(2) 1.44 × sec–1
(3) 0.72 × 10–3 sec–1
(4) 2.88 × 10–3 sec–1

84. Which is not true for a detergent molecule?

(1) It has a non-polar organic part and a polar
group
(2) It is not easily biodegraded
(3) It is a sodium salt of fatty acid
(4) It is a surface active reagent

85. Among the following, the coloured compound is

(1) CuCl
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 SECTION - B 91. Number of stereocenters present in
86. The -bonded organometallic compound which
is:
has ethene as one of its component is
(1) Zeise's salt (1) 0
(2) Ferrocene (2) 1
(3) Dibenzene Chromium (3) 2
(4) Tetraethyl tin (4) 3

87. Name the three lanthanides which show +2 92. Silica is added to roasted copper ore during
oxidation state also: extraction in order to remove:
(1) Sm,Tb,Gd (1) Cuprous sulphide
(2) Sm, Eu, Yb (2) Ferrous oxide
(3) Ferrous sulphide
(3) La,Gd, Lu
(4) Cuprous oxide
(4) Yb, Pm,Sm
93. Which factor is most responsible for the increase
88. In a solution of CuSO4 how much time will be in boiling points of noble gases from He to Xe?
required to precipitate 2 g copper by 0.5 ampere (1) Decrease in I.E.
current? (2) Monoatomic nature
(1) 12157.48 sec (3) Decrease in polarisability
(2) 102 sec (4) Increase in polarizability
(3) 510 sec
(4) 642 sec 94. XeF2 and XeF6 are separately hydrolysed then:
(1) Both give out O2
89. W g of copper is deposited in a copper (2) XeF6 gives O2 and XeF2 does not
voltameter when an electric current of 2 ampere (3) XeF2 alone gives O2
is passed for 2 hours. If one ampere of electric (4) Neither of them gives HF
current is passed for 4 hours in the same
voltameter, copper deposited will be 95. Which one among the following is a thermosetting
(1) W plastic?
(2) W/2 (1) PVC
(3) W/4 (2) PVA
(4) 2W (3) Bakelite
(4) Perspex
90. How many stereoisomers are possible for the
following?
BrCH2CH(CH3)CH2CH3
(1) 0
(2) 1
(3) 2
(4) 4

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96. The sulphide not soluble in hot dilute nitric acid is (2) Schottky defect
(1) CuS (3) Both (A) & (B)
(2) ZnS (4) None of these
(3) CdS
99. Which of the following will have the highest
(4) HgS
coagulating power for As2S3 colloid?
(1) Al3+
97. Atoms of the element 'A' form HCP and atoms of 2−
element 'C' occupy only two-third of octahedral (2) SO4
voids in it, then the general formula of the (3) Na+
compound is 3−
(4) PO4
(1) CA
(2) CA2
100. The gas which is expected to have maximum value
(3) C2A3
of KH will be
(4) C3A2
(1) BH3
(2) CO2
98. Which defect decreases density of the crystal?
(3) H2S
(1) Frenkel defect
(4) He

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