- 2024

– 12 (Set A)

 lHkh iz'u gy djuk vfuok;Z gSA

 iz'u dzekad 1 ls 5 rd oLrqfu"B iz'u gSaA izR;sd iz'u ij 1 vad fu/kkZfjr gSA
 iz'u dzekad 6 ls 20 rd vkUrfjd fodYi fn;s x;s gSaA
 iz'u dzekad 6 ls 12 rd dqy 7 iz'u gSaA izR;sd iz'u ij 2 vad fu/kkZfjr gSaA ¼'kCn lhek 30 'kCn½
 iz'u dzekad 13 ls 16 rd dqy 4 iz'u gSaA izR;sd iz'u ij 3 vad fu/kkZfjr gSaA ¼'kCn lhek 75 'kCn½
 iz'u dzekad 17 ls 20 rd dqy 4 iz'u gSaA izR;sd iz'u ij 4 vad fu/kkZfjr gSaA ¼'kCn lhek 120 'kCn½
Instructions :-
 All questions are compulsory to attempt
 Q. No. 1 to 5 are Objective type questions. Each question carry 1 mark.
 Internal choices are given for Q. No. 6 to 20.
 Q. No. 6 to 12 total 7 questions. Each question carry 2 marks (word limit 30 words)
 Q. No. 13 to 16 total 4 questions. Each question carry 3 marks (word limit 75 words)
 Q. No. 17 to 20 total 4 questions. Each question carry 4 marks (word limit 120 words)

iz-1 lgh fodYi pqudj fyf[k,% (1x 6) = 6

Q.1Choose the correct option of the following-
1- fof'k"V pkydRo dh bdkbZ gS&
v- ohm-1 c- S cm-1 l- S cm n- ohm
1. Unit of specific conductance is –
a. ohm-1 b. S cm-1 c. S cm d. ohm
2- 'kwU; dksVh dh vfHkfØ;k ds fy;s osx fu;rkad dh bdkbZ&
v- mol , L-1 sec-1 c- sec-1 l- mol-1 L sec-1 n- bues ls dksbZ ugh
2. Unit of rate constant for zero order of reactant –
a. mol , L-1 sec-1 b. sec-1 c. mol-1 L sec-1 d. None of this
3- izFke laØ;.k Js.kh esa fdl rRo dk E0 dk eku /kukRed gksrk gS&
v- Zn c- Cu l- Cr n- Mn
3. Element of first transition series has positive E0-
a. Zn b. Cu c. Cr d. Mn
4- LQwjnhIrh ds :Ik esa fdldk mi;ksx fd;k tkrk gS&
v- ySaUFksukbM ds vkDlkbM c- ,fDVukbM ds vkDlkbM l- laØe.k /kkrq n- mijksDr esa ls dksbZ ugh
4. Which are used as Fluorescent?
a. oxide of Lanthanide b. oxide of Actinides c. Transition element d. None of this
5- ehjcsu dk rsy dgk tkrk gS&
v- ukbVªks cst
a hu c- Dyksjks cst
a hu l- Qsuksy n- ehFkkbZy ,ehu
5. Mirbane oil is also called as -
a. Nitro Benzene b. Chloro Benzene c. Phenol d. Methyl amine
6- gkWQeSu eLVMZ rsy vfHkfØ;k esa mRikn gS&
v- ,fYdy vkblks Fkk;ks lk;ukbM c- ØsVksfud ,flM
l- ,fYdy vkblks lk;ukbM n- ,fYdy vkblks Fkk;ks lk;usV
6. Product of Hoffmann Mustard oil reaction is –
a. Alkyl Iso thio cyanide b. Cratonic acid c. Alkyl Iso cyanide d. Alkyl Iso thio cyanate

iz-2 fjDr LFkkuksa dh iwfrZ dhft;s& (1x 6) = 6

Q.2 Fill in the blanks-
1- 0.9 % NaCl foy;u ,oa ekuo jDr dh dksf'kdkvksa dk nzo ----------------------------gSA
1. 0.9% NaCl solution and liquid of Human blood cell are …………. .
2- fll IysVhue ladqy dk mi;ksx-------------------ds bykt esa fd;k tkrk gSA
2. Cis platinum complex are used in treatment of ……………. .
3- ,sfYMgkbM ] izkFkfed ,sehu ls fØ;k djds -------------uked {kkj dk fuekZ.k djrs gSA
3. Aldehyde react with primary amine to form ……………base.
4- cky esa ----------------uked izkVs hu ik;k tkrk gSA
4. ………..protein is present in Hair.
5- tks vfHkfØ;k dsoy ,d in esa iw.kZ gksrh gS] mUgs --------------dgrs gSA
5. Reaction occurs in single step is also called …………… .
6- KMnO4 esa -------------------------ladj.k gksrk gSA
6. …………….Hybridisation is present KMnO4.
iz-3 lgh tksMh cukb,% (1x 5) = 5
v c
1- H2O2 & v- eksukslSdsjkbM
2- izFke dksVh dh vfHkØ;k & c- d/
3- QkLthu & l- ukbVªks csthu
4- lqØkst & n- bZa/ku lsy
5- fglcxZ vfHkdeZd & ;- csathu lYQksfuy DyksjkbM
& j- dkcksZfuy DyksjkbM
& y-- K = 3 x 10-1 S-1
Q.3 Match the pair correctly:
A B
1. H2O2 - a. Monosaccharide
2. First order of reaction - b. d/
 3. Phosgene - c. Nitrobenzene
4. Sucrose - d. Fuel cell
5. Hinsberg Reagent - e. Benzene sulphonyl Chloride
- f. Carbonyl Chloride
- g. K= 3 x 10-1 S-1
iz-4 ,d 'kCn @okD; esa mÙkj fyf[k,% (1x 5) = 5
Q.4 Answer in one word / sentence:
1- tks foy;u fLFkj rki ij fcuk la?kVu cnys mcyrs gS] os dgykrs gSA
1. The solution which boils at constant temperature without changing its composition are called.
2- vkghZfu;l lehdj.k fyf[k,A
2. Write Arrhenius equation.
3- K2[ Hg I4] dks dksu lk vfHkdeZd dgk tkrk gS\
3. K2[ Hg I4] Reagent is also known as.
4- QkLQksMkb,LVj ca/k fdls dgrs gS\
4. What is phosphodiester bond.

5- 2 RX + 2Na → RR + 2 Nax mijksDr vfHkØ;k dks D;k dgk tkrk gS\

5. 2 RX + 2Na → RR + 2 Nax , write the name of readion.

iz-5 lR; @ vlR; fyf[k,% (1x 6) = 6

Q.5 Write true and false.

1- RCN → RNC (T/F)

1. RCN → RNC. (T/F)

2- E.D.T.A ,d f}narqj fyxs.M gSA(T/F)
2. E.D.T.A is Bidentate ligand. (T/F)
3- fXyljkWy dk IUPAC uke ,Fksu &1 ] 2 & MkbvkWy gSA(T/F)
3. The IUPAC name of Glycerol is Ethane – 1 , 2 – diol. (T/F)
4- ,YMkWy la?kuu vfHkfØ;k esa flusfed vEy curk gSA (T/F)
4. Cinamic acid is formed in Aldol condensation reaction. (T/F)
5- foVkfeu & C dk jklk;fud uke jsfVukWy gSA (T/F)
5. Retinol is chemical name of vitamin A. (T/F)
6- izksVhu vehuks vEy dk cgqyd gSA (T/F)
6. Protein is polymer of amino acids. (T/F)
iz-6 izkVs hu dk fod`rhdj.k dh ifjHkk"kk fyf[k,\ 02
Q. 6 Define denaturation of protein?
Or
isIVkbM oa/k dh ifjHkk"kk fyf[k, \
Define peptide bond ?
iz-7 ,sehu {kkjh; gksrs gS D;ksa\ dkj.k fyf[k,A 02
Q.7 Amines are basic in nature why? Give reason.
Or
fuEu ifjorZu dh dsoy jklk;fud lehdj.k fyf[k;s CH3 NH2 ls C2H5 NH2
What is chemical reaction of following change? CH3 NH2 to C2H5 NH2
iz-8 fodkcksZfDlyhdj.k dh ifjHkk"kk o jklk;fud lehdj.k fyf[k, \ 02
Q.8 Define decarboxylation and give its chemical equation.
Or
lk;uksgkbMªhu ls vki D;k le>rs gS\ ,d mnkgj.k fyf[k,A
What is mean by cyanohydrins? Give an example.
iz-9 f}d yo.k ,oa ladqy yo.k esa dksbZ nks vUrj fyf[k;sA 02
Q.9 Write any two difference between Double salt and Complex salt.
Or
leUo; e.My dh ifjHkk"kk fyf[k, \
Define Coordination sphere.
iz-10 fuEufyf[kr milgla;ksth ;kSfxdksa ds IUPAC uke fyf[k;s& 02
[ Ni (CO)4] Na2[ Ni Cl6]
Q.10 Write IUPAC name of following co- ordination compound-
1. [ Ni (CO)4] 2. Na2[ Ni Cl6]
Or
fuEufyf[k milgla;ksth ;kSfxdksa ds lw= fyf[k;s%
1- VsVªk ,sehu Mkb ,sDok dksckYV (III) DyksjkbM
2- iksVsf'k;e gSDlk lk;fuMks QSjsV (III)
Write the formula of following co-ordination compound-
1. Tetra ammine di aqua cobatt (III) chloride
2. Potassium Hexa cyanido ferrate (III)
iz-11 'kq) ty dk dh eksyyrk Kkr dhft;sA 02
Q.11 Calculate Molality of pure water.
Or
izfrykse ijklj.k dks ifjHkkf"kr dhft, \
Define Reverse osmosis?
iz-12 ,sYdksgkWy dk DoFkukad laxr gkbMªksdkcZu ls mPp gksrk gS D;ksa\ dkj.k fyf[k,A 02
Q.12 The Boiling point of Alcohol is High than that of comparable hydrocarbon why? Give reason.
Or
QhukWy ls fuEu dks izkIr dhft;s% 1- fifØd vEy 2- Vªkb czkseks fQukWy ¼dsoy jklk;fud lehdj.k½
Following compound obtained from phenol- 1. Picric acid 2. Tri Bromo Phenol (Give only chemical
equation )
iz-13 vkn'kZ foy;u dks mnkgj.k ,oa xzkQ lfgr le>kb;sA
Q.13 Explain ideal solution with example and give suitable graph. 03
Or
,d inkFkZ ds 5 xzke dks 50 xzke cst
a hu esa ?kksyus ij foy;u dk fgekad vour gks tkrk gSA inkFkZ dk vkf.od
nzO;eku Kkr dhft,\ [KF =1.85 K Kg/mol]
On dissolving 5gm of substance in 50gm water, the depression in freezing point of the solution is 1.2 C.
Determine the molecular mass of the substance.
[KF =1.85 K Kg/mol]
iz-14 fufEufyf[kr ds vip;u ds fy;s fdrus vkos'k dh vko';drk gksxh\ 03
1- 1 eksy Al 3+ dks Al esaA 2- 1 eksy Cu 2+ dks Cu esaA 3- 1 eksy Zn 2+ dks Zn esaA
Q.14 How many charge is required for the following reaction:
1.1 mole of Al3+ to Al
2.1 mole of Cu 2+ to Cu
3.1 mole of Zn 2+ to Zn

0.025 mol L-1 esFksukWbd vEy dh pkydrk 46.1 S cm2 mol-1 gS bldh fo;kstu dh ek=k Kkr dhft;s\
[ H = 349.6 S cm2 mol-1 , CH3COO = 54.6 S cm2 mol-1

0.025 mol L-1 methanoic acid is 46.1 S cm2 mol-1 . Calculate the degree of Dissociation?
[ H = 349.6 S cm2 mol-1 , CH3COO = 54.6 S cm2 mol-1
iz-15 v)Z vk;qdky ifjHkkf"kr dhft,\ izFke dksVh dh vfHkfØ;k ds fy;s v)Z vk;qdky dh x.kuk dhft;sA 03
Q.15 Define Half life period? Calculate the Half life period for first order of reaction.
Or
,d izFke dksVh dh vfHkfØ;k 50 fefuV ij 90% iw.kZ gks tkrh gS rks blds fy;s v)Zvk;qdky dh x.kuk
dhft,\¼ ½
A first order of reaction is 90% completed in 50 minute, and then calculate Half life period of this
reaction. ( )
iz-16 QhukWy dks ok;q esa [kqyk j[kus ij xqykch jax dk gks tkrk gS D;ksa\ dkj.k fyf[k,A 03
Q.16Why is Phenol converted into pink in colour on kept in air?Give reason.
Or
,sFkhy ,sYdksgkWy ds futZyhdj.k dh fØ;kfof/k dks le>kb;sA
Write the mechanism of Dehydration of Ethyl Alcohol?
iz-17 la{kkj.k ifjHkkf"kr dhft, rFkk blds fo|qr jklk;fud fl)kUr dks le>kb;s\ 04
Q.17 Define is corrosion? Explain its electrochemical theory of corrosion.
 Or
NHE dks fp= ,oa lehdj.k fyf[k,\
Give NHE equation and diagram.
iz-18 laØe.k rRoksa ds fuEu xq.kksa dks le>kb;s& 04
1- ladqy ;kSfxd dk fuekZ.k 2- mRizsjdh; xq.k
Q.18 Explain following property of transition element-
1. Complex formation 2. Catalytic property.
Or
YkSUFksukbM fdls dgrs gS\ RkFkk bUgs i`Fkd djuk dfBu gksrk gS D;ksa\
What is Lanthanide? And it is difficult to separate them why?
iz-19 gSyks ,sYdsu dh rqyuk esa gSyks ,sjhu esa U;qfDy;ksfQfyd izfrLFkkiu dfBukbZ ls gksrk gS D;ksa\ dkj.k fyf[k,A 04
Q.19 Why is nucleophilic substitution more difficult in Haloarenes than in Haloalkanes? Give reason.
Or
foyksiu vfHkfØ;k fdls dgrs gS rFkk bl vfHkfØ;k ds fy;s lsVtSQ fu;e dks le>kb;sA
Write elimination reaction? Write Saytzeff’s Rule for Elimination reaction.
iz-20 1-,sfYMgkbM ds fy;s jtr niZ.k ijh{k.k lehdj.k lfgr fyf[k,A 1+3=4
2- QkeSfYMgkbM dh veksfu;k ls fØ;k dh lehdj.k fyf[k;s ] rFkk mRikn dh lajpuk cukdj bldk mi;ksx
fyf[k;sA
Q.20 1.Write silver mirror test for Aldehyde with equation?
2. Write an equation formaldehyde react with Ammonia and draw the structure of product and
write its uses.