Q4) A glass cylinder with internal diameter of 2em and high of 30cm is filled with CO (A) and H; (8) ata total pressure of 2.5 atm at 0°C. The diffusion coefficient of these system under these conditions 4s 0.265 cm/sec. If the partial pressure of CO is 1.8 atm at one end of the cylinder and 0.65 atm at De® to] 2-P ] so nl oe OD a Bae oe rene a) equimolar counter diffusion (Na = - Na) b) counter diffusion where No = -0.65 Na, and 2 0.65 = 10S m/s (LI atm) €) diffusion of CO through stagnant H2 (Ne = 0) | | the other end, find the diffusion rate for (30 marks): | Inanacteee + 488150883 »10% [Re 8.208 +10"* manele: ot * 4. 6¢ «10% nol /mts fe 2.5 .atm OC 1a De O.2650mY/5 © 2.68 a10"%my area % Pay © O-CS eter 8 ny +B (ParPa,) , 205 yooh ls (19-068) 064 ATR) 8205-10 iaagh fe K CBA") = 4.5350u109g 0°? mol/at s | Na = 4.64 910°" ol fn* § Ka Bae B+ Be (Me 0-05 Kd) [amas she BB co.9s)ut, Nev ossnu(B). Be Za Bg [xe (t-oss ES) +B 2 |MPa> “See (ea |Ne(@az,) « “Bek (dase 20-35 Pay | P0388 Nes DooPr 1 [i p-0-3S Pas RY (2) 7 0-085 Pa | | | 2.65 10 “Sars (2-5 ofA) ——|n 2:5-0.35 (0.68) | 8-208 +10°S *opfr|m K (275K) (0.8m) (0-3)b 25 -0-3S(+). # SHANLUTA «io°8 #5.4q «10 moal/m*sQ5) A vertical tube of 2.5 mm In diameter is filled with toluene to a depth of 15 mm from the top open-end. After 300 hrs at 39.4 °C and a total pressure of 759 mmHg, the level has dropped to 75 mm from the top. Calculate the value of diffusivity (15 marks). Data: ®s,« vapor pressure of toluene at 39.4°C = 7.64 kN /m?, A = density of liquid toluene = 850 kg/m? « 830.000 gf? HA » Molecular weight of toluene = 92 g/mot (Co He CHs) Za # 75am * 0.075 ZistSams d.o1sm RE S314 mPa K Cio afl woes Fe TS mig 2 1O1K2 Po, T StU FSI. Pas 7-H KN/m? # 740 Pa at Oe Das «4 (Zee zs" Her (20) Pe Io(-S) £7. 552080908 x10 m* /s 27-85 «lon /sfusion rate of Propanol at 25 °C under steady state conditions in a water film with '5 cm. The concentrations of Propanol at each sides of the film are, 15% and 5% of Propanol by weight, respectively. The diffusivity of Propanol in water solution is. The densities of 15% and 5% Propanol solutions at 25 *C are 0.968 and 0.985 g/ml, respectively. Molecular weight of Propanol (CsHe0) and water aye 60gnd 18 &/mol, respectively (25 marks) ( ae Tao! 8,4 15cm 10-0015 m Neem YS. Dag 25°57 10" em '/peee Tease 229k mh," ta) SSO *oYs vey ous/ 60 ginetd Kart & S/O gimol)s C3s7ie gin) Xa * erae TE heen so wiegv on , +8370 gimet)+ (O-4S/ re yheml) “reves oe Hove 5 0-0802% $206/ , 0.050 * esheo girei)e(o-essit gine!) = a _____. , rees2gug 742 Ie. * (¥S760 gimA)oloAs Ne ginot) 749186 G/eok > +Ce Cpe MRO ge” eiy.g8201 mel/m3 #4 Count EEE # SOMS-17271 en? A 2 29-784 + 20-12 g/erol 20+ $/nel Cas 1ScogIe? . gogis.o184 mol/n? FCS GImcd Xan? Xer-Xe Uo Xa:)-G-%) (1-0-0580) (0. tint Xeoke 4 (ex) M4) ((00°050)- (0-010) 5 see aooan ink. tn f ro-ose ee [; 0.967 (0.0015 m) = 6-805 765% mel/m' +s = GSI mol/m?s