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SAFETY DATA SHEET

MEKP 808
SECTION 1 - PRODUCT IDENTIFICATION
NAME OF CHEMICAL Methyl Ethyl Ketone
Peroxide (MEKP)
is organic peroxide.

SECTION 2 – INGREDIENTS/INGREDIENTS INFORMATION

Ingredient Cas No %
Methyl Ethyl Ketones
1338-23-4 34
Peroxide
Dimethyl Phthalate 131-11-3 43
2,2,4-Trimethyl-1,3-
6846-50-0 20
pentanediol diisobutyrate

Hydrogen Peroxide 7722-84-1 01

Methyl Ethyl Ketone 78-93-3 02

Water 7732-18-5 01

SECTION 3 – HARZARD IDENTIFICATION

Health risks Intense itching
Limit exposure The ACGIH Ceiling STEL standard is 1.5
mg/m3(0.2 ppm) for Methyl Ethyl Ketone Peroxide.
Exposure route

Skin contact Intense itching of the skin, causing red, burning

spots and blisters.

Eye contact Causes serious eye damage and can cause

blindness

Dietary route Causes consequences on the entire body:

changes in structure or function of the throat,
causing dizziness, nausea, vomiting and other
intestinal and digestive effects.

Respiratory Mild poisoning through inhalation.

 Exceed mucous membranes and causes dizziness. No
more serious symptoms have been recorded by
medical science following exposure.

SECTION 4 - FIRST AID MEASURES

Skin:
Immediately remove contaminated clothing. Wash the
infected area completely with soap and plenty of clean water
for at least 15 minutes. If itching or worsening symptoms
continue to develop, seek medical help.

Immediately remove contact lenses (if worn). Rinse your eyes

Eye
with clean water for at least 15 minutes. Make sure you rinse
your eyes well by using your fingers to separate the eyelids. If
itching or more serious symptoms appear, seek medical help

Gastrointestinal Contact your doctor, hospital or Poison Control Center

immediately. Do not attempt to induce vomiting in an exposed

person.

Respiratory Seek exposure to fresh air. If coughing, breathing becomes

difficult, itching or other symptoms develop, seek medical
helpimmediately, even if these symptoms appear. several
hours after exposure.

SECTION 5 - FIRE FIGHTING MEASURES

Flash point: (COC) > 200ºF

Fire limit: Not yet noted or understood
How to use a fire Spray water from a safe distance – preferably using a spray nozzle.
extinguisher In the case of a very small fire, other means such as CO2
cylinders, gas fire extinguishers or dry chemicals can be very
useful. Dry chemicals combined with MEKP formulations can
cause re- ignition. Certain special domestic additives may be
particularly effective in extinguishing fires caused by MEKP
Special firefighting Firefighters should wear special protective clothing. In case of fire
procedures near the warehouse, refrigerate chemical containers with water
spray. If dry chemicals are used to extinguish a fire caused by
MEKP, the area must be thoroughly wetted with cool water to
prevent re-ignition.
Abnormal risk of fire The heat of the decomposition of peroxides increases the heat of
and explosion the fire

SECTION 6 - ACCIDENT REDUCE MEASURES

Steps to be taken in Need to build partitions to prevent chemicals from flowing down
into sewers and rivers and streams. Spilled chemicals should be swept up
Clean up with thinner such as perlite, vermiculite, or sand,
and place in a clean polyethylene bin or bucket. Wet the
barrel or bucket with water before sealing it.

SECTION 7 - HANDLING AND STORAGE

Handling and storage Cover the tank tightly to avoid contaminating the surrounding
area. Rotate inventory according to the oldest inventory first
priority (FIFO) principle. MEKP's performance and stability are
directly related to cargo handling and storage temperature history.
Refrigeration at 80°F (27°C) or lower is recommended for longer
shelf life and stability. Long-term storage at temperatures up to
100°F (38 degrees C) or higher will cause the product to deteriorate,
vaporize, and potentially cause the container to rupture leading to
fire and/or explosion. .

Other notes MEKP should never be added to hot solvents or monomers as

decomposition/violent reaction will occur. When using spray
equipment, never spray raw MEKP intocuring or raw plastic or
air ducts. MEKP should be stored in its original container. DO
NOT STORE WITH FOOD OR DRINKS. DO NOT USE MEKP
CLOSE
 FOOD OR DRINKS.
This is a substance that should not be mixed with other
substances other than its intended use. The remainder after use
must be returned at the end of the day to a container capable
of containing peroxides or, preferably, its original container.

SECTION 8 – EXPOSURE CONTROL/PERSONAL PROTECTIVE CARE .

Protect the airway If the concentration of toxic substances in the air reaches an
unsafe level,
you must protect yourself with anti-toxic clothing or a mask

Fan Active electric fan.

Protect eyes Wear protective glasses and wash your eyes after work.

Hand protection. Use rubber gloves

Other ways. You should wash your body and face a lot under running water
when the problem
becomes too big

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Boiling point ºF unclear density 1.1
Pressure (in mercury unclear (Water=1) unclear
vapor) mm Hg. % evaporation
>1
by volume
Vapor density (Air=1)
Solubility in A little evaporation speed unclear.
water. bit
Landscape of colors Slightly odorous white liquid.
andsmells

SECTION 10 – STABILITY AND ACTIVITY

Incompatible (Materials Dimethylaniline, cobalt napthenate and other promoters, promoted

to avoid) resin, resin promoter, dipping agent, strong. Acids, alkalis, metals,
metal salts, sulfur compounds, amines and other hot materials.

Stable Store well in a sealed container, away from sunlight and in a place not
exceeding 27 degrees Celsius

Risk of decomposition This substance has a fire hazard when decomposed.. creating tear gas
causing danger and toxic gases.
SECTION 11 - TOXICOLOGICAL STUDY RESULTS

Methyl Ethyl Ketone Peroxide

Toxicity:
Inhalation: LC mice50 :200 ppm/4 hr, harmful to lungs and respiratory tract. In

when with mouse --LC50: 170 ppm/4 hr,

Five internal organs: mice --LD50: lethal dose 65 mg/kg, loss of self-
control, behavior, muscle weakness, behavioral disorders.
Oral: mice :--LD50: 484 mg/kg; mouse--LD50: 470 mg/kg; — TD person

worry toxic dose: 480 mg/kg, dysfunction. causes damage to the

gastrointestinal tract, esophagus, nausea or vomiting

Skin: Rabbit Rabbit--LD50: 500 mg.

Dimethyl Phthalate
Toxicity:
Inhalation : cat --LCWorry:9300
mg/m23/6.5 hours. Eye, peritoneum:
mouse --LD50: 1380 mg/kg.
Oral: rat and cat: --LD50: 6800 mg/kg, causes fatigue, nutrient withdrawal and
total metabolism, weight loss or weight loss in dogs: --LD: >1400 mg/kg;
rabbit -- LD50: 4400 uL/kg.
Cutaneous toxicity: rats --LDWorry: 6500 mg/kg, difficulty breathing, chest tightness,
respiration, or cyanosis.
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate
Toxicity:
Oral: rat --LD50: >3200 mg/kgHydrogen
Peroxide
Toxicity:
Inhalation: rat --LCWorry: 227 ppm; mice—TCWorry: 67 ppm/6hr/6W-1,
dermatitis, skin irritation
Eye, peritoneum: mouse --LD50: 880 mg/kg.
Vein: rabbit--LD50: 15 gm/kg,. The body has convulsions, cannot control
the body, and brain damage.
Oral route: mice --LD50: 376 mg/kg, ingestion, hemoperitonitis, pigmented
or nucleated red blood cells; chromosome disorder. mouse --LD50: 2mg/kg.
Dermal toxicity: mice --LD50: 620 mg/kg; mouse --LD50: 1072 mg/kg.
Skin: Rat--LD50: 4060 mg/kg, affects the lungs, throat, respiration, lung
 congestion, effusion; rabbit--LDWorry: 500 mg/kg,. The body has
convulsions, cannot control the body, and brain damage

Methyl Ethyl Ketone

Toxicity:
Eye :: human 350 ppm.
Inhalation: mice --LC50: 23500 mg/m3/8hr.
Mouse eye, peritoneum--LD50: 607 mg/kg; mouse--LD50: 616 mg/kg.
Oral route: mice --LD50: 2737 mg/kg; mouse --LD50: 4050 mg/kg.
Skin: rabbit--LD50: 6480 mg/kg. Severe skin irritation, may cause redness, blistering
and edema.
May be harmful if absorbed through the skin. causes blindness. Toxic if swallowed
or inhaled. mucous membranes and dizziness.Toxic to the eyes, may cause mild to
severe damage. Prolonged inhalation of vapor may cause irritation

SECTION 12 – ECOLOGICAL ENVIRONMENTAL IMPACT INFORMATION

Environmentally toxic : Methyl ethyl ketone peroxide: EC50(small fish), 44.2 mg/L/96 hr; EC50

(algae), 42,700 ug/L/96 hr.

Environmental consequences: Methyl ethyl ketone peroxide (MEKP) has been measured
for its rate of decomposition in a closed environment and is found to be easily decomposable.

SECTION 13 – REMOVAL AND HANDLING

Prevent material from entering drains, sewers, streams,etc.

Follow local waste disposal regulations.

SECTION 14 - SHIPPING INFORMATION

Name of goods when shipped: ORGANIC PEROXIDE TYPE D, LIQUID (METHYL
ETHYL KETONE PEROXIDE,< 45%) 5.2
DOT Hazard Class:
UN/NA ID No.: UN3105
DOT Packing Group: PG II
DOT RQ RQ

2000 ERG GUIDE NO.: 145

SECTION 15 – FURTHER INFORMATION ACCORDING TO STATE

MANAGEMENT REGULATIONS
Chemical Name CASNumber %
Dimethyl Phthalate 131-11-3 43
Methyl Ethyl Ketone 78-93-3 02
 SECTION 16 – OTHER INFORMATION
NFPA 432 Organic Peroxide Classification Class III

NFPA 704 Rating HMIS Rating

Health Flammability Reactivity Health Flammability Reactivity

3 2 2 3 2 2

DISCLAIMER

The information in the MSDS is collected from sources, which we believe to be reliable.
However, the information is provided without any warranty, expressed or implied, as to its
correctness.

The conditions or methods of handling, use, storage and disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons, we
assumes no responsibility and assumes no liability for damages, losses or expenses
arising out of or in any way connected with the handling, storage, use, or disposal of the
product.

This MSDS has been prepared and is to be used only for this product. If the product is used
as an ingredient in another product, this MSDS information may not be applicable.