15t Year Chemistry WNT Sia Guess Paper vet i Weide Chapter-1 &Short Questions 1. Define and explain the concept of Mole and Avogadro’s number with example. 2. Define limiting reactant, And how limiting reactant is identified? 3. What are isotopes and why the isotopes have the same chemical properties? 4, The atomic masses may be in fractions. Why? 5. Differentiate b/w actual & theoretical yield. 6. Give the reason to explain that actual yield is ( less than the theoretical yield? 7. Define molecular ion. How it is formed? eS 8. Define Yield. How is efficiency of a CH measured? Or (Percentage yield) 9. What is stoichiometry? Write fasstfyiptions, 10, Mg atom is twice heavier thysp.thaCof carbon atom. Justify the statenfeii 11, Calculate gram atoms in O:Ly of sodium: 12, Differentiate b/w empirical and molecular formula with examples. 13, Nz and CO have the same number of electrons protons and neutrons. Explain it. 14, No individual Neon atom in the sample of the element has a mass of 20.18 amu, why? 15, What is the justification of tworstrorg pegs in | > the mass spectrum for bromine, whi i ie only one peak at 127 amu is indicated? #rLong Questions ile Tor LL UE Gia drlobreSige asi zs bot poll Bas tsvsnv) Bo VL Me Whatis ference between actual yield -arfd tht theoretical yield? Why actual yield is less than theoretical yield? What is mass spectrometer? How is it used to determine the relative atomic masses of isotopes? Write dot 1s steps to calculate the empil ula of a Compound. 4. Défihestcichiometry. Give assumptions, mation any two important laws which _\a& to perform stoichiometric calculation. Ss reated and uploaded by taleemcity.com ) iY Chapter-2 #xShort Questions 1 Differentiate between st phase? Differentiate b/w adsorption & partition chromatography. Why is there a nced to crystallize the crude product? What is Ry value? Why it has no units? Define crystallization. Write the name of various steps. What is difference b/w qualitative and uantiyivelahalysis? ‘Write four properties of good solvent. How crystals are dried by reliable method? How undesired colours are removed from the crystals? nary and mobile we -u4ertaleem city 1* Year guess papers ,Google Alig tL Koh" Year10. Define distribution law. How it is helpful in solvent extraction? 11. Define sublimation with any two examples? 12, What is solvent extraction? Give its example & technique. 13, Define chromatography. Give its two uses and describe its importance. 14, Write uses of paper chromatography. Created and uploaded by taleemcity.com &Short Questions 1, Convert °C into °F and vice versa, 2. Define absolute zero, What is its value? 3. Explain Boyle’s law according to kinetic molecular theory of gases. 4, Calculate the value of R in SI units, 5. What do you mean by absolute zero temperature of gases? 6. Define Avogadro's law of gases? Differentiate b/w diffusion & effusion, 8. What are the faulty points in the Kinetic molecular theory of gase: 9. State Dalton’s Law of partial pressure/‘ oS] its two applications. ). Define critical temperature on by giving an example of ea State under what condit att real gases deviate from the ideal beh . What is plasma? How it is formed? Write four applications/ uses of plasma. . Lighter gases diffuse more rapidly than heavier gases. . Why water vapours do not behave ideally at 273K? $0> is non-ideal at 273 K but Hehay ps Hike pn | ideal gas at 327°C. Justify. .. What are isotherms? What happens to the positions of isotherms when they are plotted at high temperatures for a particular gas? Id Chapter-3~ |<) 4) |)” & @: 1 17, Do you think that the volume of any quantity of a gas becomes zero at - 273.16 °C.? Is it not against the law of conserva do you deduce the idea of absolute zero from this information? zLong Questions jon of mass? How Numerical Example? 3, 4, 5, 6,7 rergise Questions 18, 19,20, 21 and 23 Tayle ate Me nose important numerical and examples from this chapter. For better preparation, prepare all numerical type questions of this chapter wants floats on water? Or (Ice has less {enSity than liquid water. Why?) WhY boiling point of water varies from sea level to higher level? 3. Define molar heat of fusion with one example 4, Evaporation causes cooling. Explain. 5. Define (a) Anisotropy (b) Polymorphism (c) isomerism 6. Earthenware vessels keeps water cool. Explain, 7. The electrical conductivity of metals decreases with the increase in temperature, why? 8, Define lattice energy. Give examples. 9. Explain why ionic crystals are brittle? 10. Define transition temperature and give two examples, 11. What are crystallographic elements? Explain with diagram, 12. Why ionic solids do not conduct electricity? 113, Diamond is hard and an electrical insulator, Oduye 41 14, Define Hydrogen Bonding. Why H20 is liquid at room temperature but HpS is a gas 15, Define unit cell. Define crystallographic elements, -u4ertaleem city 1* Year guess papers ,Google A2Ligt. L681" Year16. Differentiate between isomorphism and polymorphism with suitable example. #Long Questions 5, Describe manometric method for determination of vapour pressure of a liquid with diagram. (vv imp) Classify solid on the basis of bonding. Tonic solid, covalent solids, metallic solid with its properties. (vv imp) Define liquid crystals and write their uses, (vv imp) reOSi ii What is H-bonding? Discuss H-bonding in biological compounds and ice. (imp) Write a note on three factors affecting London forces. (imp) Created and uploaded by taleemety.com Chapter-5 #Short Questions Why the nature of cathode rays is independent of the nature of gas used in discharge tube. 4 How it was inferred that cathode rays are SJ material particles? aS ‘What is nuclear reaction? Write sea the production of neutron. What happens when a neutroy Give products forme: 6 8 Write defects in mee neutron? Calculate the radius of n' orbit for hydrogen atom. Describe Zeeman's and Stark's effect? State Moseley's law. Give its mathematical expression. Differentiate between Atomic Emission Spectrum and Atomic Absorption Spectrank? | | 7] atomic model ). How does Bohr introduce Plank’s quantum theory in his model? Give its two postulates? . Differentiate between line spectrum and continuous spectrum? . What is de-Broglie's Equation and Heisenberg uncertainty principle? What is (n + J) rule? Define Pauli’s exclusion principle with example. Differentiate between frequency and wavelength? Define Hund's rule. Give an example. Give electronic configuration of 2aCt, 29C, 26Fe, 2gCC2 and Br. 13, 14. 16. 17, | WLbng Guléstions 1, Write down Millikan’s oil drop method for the measurement of charge of an electron. 2. Calculate radius ofa Bohr’s atom using Bohr’s sume maine SS 3. Give maip-pos s and defects of Bohr’s atomic nal) 4. DefirfeGuantum numbers. Discuss briefly myijial quantum number. a detailed note on X — rays. ted and uploaded by t Chapter-6 ‘¥Short Questions mcity.com yD 1, Define octet rule. Give two examples of compounds that do not obey this rule. Cationic radius is smaller than the parent atom, while anionic is larger than parent atom. Why? 3. Define ionization energy and electron affinity. Give its trend in periods and group of periodic tables? 2 4, Define electronegativity? How the electronegativity difference decides the nature of chemical bond? ifferentiate between covalent and [i ooudiatd dovaent bond 7. Explain the term bond order. 8, Why bonds are more diffused than sigma bonds? -u4ertaleem city 1* Year guess papers ,Google A2Ligt. L681" YearDefine covalent radii and atomic radii. Give example? ). Define Pi-bond and Sigma-bond, Why is Pi- bond weaker than Sigma bond? - Differentiate between bonding molecular orbitals and anti-bonding molecular orbitals. . Why the bond distance in the compromise distance between two atoms? Define bond order What is bond order of 037. Define atomic radius. How does it vary in groups and periods? jaa Why MOT is superior to VBT?’ Define dipole moment. The dipole moments of CO; and CS2 are zero but that of SO. is 1.61. 2nd ionization energy is greater than Ist Why? Why 2nd electron affinity shown with positive sign? #&Long Questions 13. 14. Sil 15. 16. 17, 18. 1. Write the main points of VSEPR theory and explain the structure of ammonia on the basis of this theory 2. Define hybridization and explain structure of _\{ water on its basis. S 3. Describe No and O» molecules on basiga SS MoT B (4) ) 4. Sp2 and Sp hybridization wine 5. Explain ionization energy ae J example. Also describe its period 6. Define electron affinity. Nane the factors affecting it. How does it vary in the periodic table? Chapte Short Questions 1. What is the First Law of Thermodynam with examples? Differentiate b/w spontaneous & non- spontaneous reactions. it Describe that burning of candle is a spontaneous process, Justify Define AH,” (enthalpy of reaction). Can it be negative? How? Explain what is Lattice energy? Give Example. Define enthalpy of formation and atomization with an example. Define standard enthalpy of combustion & solution with example of each. ine standard enthalpy of atomization with seataple | J Define internal energy, system, surrounding, state, and state function. Why is it necessary to mention the physical states of reatanpgand produets ina thermochemi ion? Apply, Hess’s law to justify sour Dil endotti ° Questions (eevee exothermic and What is fi that AE=qv Define Enthalpy and prove that gp=AH Describe bomb-calorimeter method for determination of enthalpy of reaction, 1 law of thermodynamics? Prove 4. Define and explain Hess’s law of constant heat summation with examples, 3. Define enthalpy of reaction, How is it measured by glass calorimeter? Chapter-8 frShort Questions Bw TL grate ety ofimass action 2. ‘Define Ke. How the value of Ke of a reaction helps to predict the direction of a reversible reaction? 3. How does catalyst effects reversible reactions? 4, Define Le-Chatelier’s principle. -u4ertaleem city 1* Year guess papers ,Google A2Ligt. L681" Year5. How does the change of pressure shift the 3. One molar solution of urea is more dilute than equilibrium position in the synthesis of NH3 ? one molar solution, Why? 6. Define pH and pOH. 4, Define upper consulate temperature with 7. Define PK, and PK; example. 8. What is common ion effect explain with the 5. Define mole fraction and parts per million example of NaCl 6. Sum of the mole fraction of components of 9. Differentiate b/w acidic buffers & basic solution n is always equal to unity, Justify buffers with example of each. How a basic 7. Differentiate between Ideal and non-Ideal buffer can be prepared? solutions? 10, Why the solubility of glucose increases on 8, What is ebullioscopic constant and eryoscopic increasing temperature? 4 poses with example? 11. Define solubility and solu y bites ‘b/w hydration & hydrolysis. solubility produet of PbCl2 & AgsCrOx. 10, What is solubility and solubility curve? Name 12, Define buffers and buffers capacity. Also its two types. explain their uses 13, What is Henderson equation for acids and 11. Differentiate bey eeu eration and buffers? hydrolysis, wean -xample each, 14, The change of volume disturbs the equilibrium 12, Boiling pofagS}eP the solvents inerease due to position for some of the gaseous phase the pres Noein Give reason. reactions but not the equilibrium constant, 13. me {yhter of crystallization? Give frLong Questions ee citi soluton temperature, Also give Ronan Numerical DSS Example# 2, 4, 5, 6,7 & i " 25> Exercise Question# 21, 22, 23, 24 and S 16 What are colligative properties? Colligative properties obeys when solutions are dilute. State reason? Define hydration energy. On what factors does ‘These are the most important m Ys it depends. examples from this chapter. For paration, ou (i prepare all numerical type quesifangNpthis chapter. ong Questions Created and uploaded by.teleemcity.com whup Chapter-! #&Short Questions a EMO LIC 1. NaCl and KNO; are used to lower the melting point of ice. Justify. 2. Differentiate b/w molarity & molality with I example of each. Also write formulas. Define colligative properties. Explain elevation of boiling point. Raoult’s law Solubility curves Depression of freezing point Azeotropic mixtures ~ Ghapte 10 ‘Short Questions Calculate oxidation number of Mn in (i) KMn0, (ii) KpMnO, (iii) NayMn0, -u4ertaleem city 1* Year guess papers ,Google A2Ligt. L681" YearDefine oxidation number and calculate the oxidation state of underlined element. a) HsPOr b) Ca(CrOs)> Impure copper can be purified by electrolytic process. Explain What is the use of salt bridge? A salt bridge maintains the electrical neutrality inthe cell, Explain with reason, SHE acts as an anode when connected with copper electrode but as cathode with zine electrode. Why? . What is electrochemical series iets! 2 | applications. Na*and K*can displace hydrogen from acids but Pt, pd, and cu cannot explain. Give discharging reaction of lead accurnulator. Explain the working of alkaline battery. How is Aluminum anodized in an electrolytic cell? Define terms, electrochemistry, electrolysis, oxidation, reduction, Voltic cell and electrolytic cell. . Explain the following with reasons. The standard oxidation potential of Zn is 0.76 V and its reduction potential is - 0.76 V 14, Rule for assigning oxidation number. 6 10. We ¥ Define the rate of reaction. Give its units. Differentiate biw instantaneous & average rate of reaction. What is pseudo first order reaction? What is half-life period? Give one example. What is effect of surface are on rate of a. reaction? How order of reaction can be calculated from half-life method? Differentiate b/w homogeneous catalysis & terggeneous catalysis with examples. \ofine ‘atdotatalysis with one example. Give two characteristi 's of enzyme catalysis. A finely divided catalyst may prove more effective. Give reason. fic in its action? How a catalyst i i What do yor activation energy? The radigagtive decay is always a first order ee ot Rate ofredction is an ever-changing aac: Give Reasons. u 12, 13, 14. oe on Questions Half Life method to determine the order of reaction 2. Activation Energy fLong Questions @ }) 3. Arhenius Equation @ 4. Catalysis and its types & any four 1. Voltaic or Galvanic eell characteristics of catalyst. 2. Electrochemical series oS 5. Define order of reaction and explain 2nd and applications ne zero order reactions. 3. Explain lead accumulator battery and its 6, What is meant by Enzyme Catalysis? Write discharging process. reaction showing the catalysis of urea. Also 4. Importance of electrolysis and electrolysis of write two characteristics of Enzyme Catalysis. fused and aqueous NaCl solution Note: © This guess paper consists of the most important Created and uploaded by taleemcity.com questions from exam's point of view. ) be _|4. # \ This does not mean that the entire paper will come ENE LID promi (1 Chapter-11 &Short Questions “These guess papers can help you pass the exam if you didn't prepare well. Prepare the complete syllabus along with it if you wish to secure high marks, -u4ertaleem city 1* Year guess papers ,Google A2Ligt. L681" Year