—~S 4) @l4s 21 v A
gy #3 F f
) AN al;
xperir Observation Result
| = _ aa
. Take asmall quantity of | No reaction. | Dilute acid
given powder in a test | radicals absent.
tube, add dil. H,SO,. |
. | L.Take a little quantity of |Colourless gas with | Cl- of strong
given powder ina test | pungent smell HCI | acid radical
tube now add conc. |(Hydrogen chlo- | group may be
H)SO, in it. ride) gas is evolved.| present.
2.Bring a glass rod dip- _| Formation of dense| Cl- (Chloride)
ped in NH,OH or amm; white fumes due to| is present.
onia solution with the |NH,Cl(Ammonium|
contact of evolved gas.| chloride).
Shemical reactions ;
2NH,Cl+H,S0, —4-»2HCIT +(NH,),SO,
Inorganic salt (Conc.)
HCl+NH,OH——NH,Cl
(Dense white fumes)
(B) Tests for basic radicals :
fo] Experiment__[ Observation | Revit]
Take a small quantity | Colourless gas with! NHj{ (Ammo-
of given powder in a| pungent smell of | nium) may be
test.tube, add NaOH | NH; isevolved. | present.
solution and warm it.
Bring the glass rod Dense white fumes | NH,* (Ammoni-|
dipped in HCI with the} are formed due to | um) is present.
contact of gas. formation of NH,Cl
(Ammonium chlo:
ride).
hemical reactions :
NH,Cl+ NaOH —4 5 NH, 7 +NaCI + H,0 s
Ammonia
NH, + HCI—>NH,Cl
Ammonium chloride
(Dark white fumes) c
Result : In given inorganic powder Fe; akong thea)
Acidic radical: Cr 7”¢ 7°
Basic /Alkaline radical: NH @Fe-present.