p+ For Resewee Lebrany ‘ D.\. Levellow . ChE 258 Process Safety \ 11) Es FI uu @ ‘timate the flash point of a solution of 50 mole % water ani 50 mole % methanol. From Table @-! Medhanel has a flash pomd of Sor, Flash pod occuvs when the partial pressure of methanol 1S Cage +o th vapor pressune of pore methanol at the flash -hempevature. SWF = 12,109G. = 28S,S- °K From Appendiv Z sak 8 WP = A - TF L InP“. igserx - 2o268S 34.29 4285.5 sok. P= 63, Fmmtly @ Aash Point Pachat Pressuat is given by RavoottS Lau Re xi PO X= BO aes (spe a p= izzy In(7.4) = 188870 - Beze.S5T VY “B4244TT 0S “Ts 248.2°K =6) Estimate the LFL and UFL of the following mixtures: Allin volume % Combest g EL #UFL basis Hexane os (Ml 0.28 Methane WS ‘s 0150 Ethylene 05S 27 36 0.25 Acetone o £2 a Ethyl Ether 00 14 Bee 8 Total combustibles 2.0 Air 98.0 From Table 6.1 gk LFL ¢ UPL, dake Calevlale mrvfore properti2s osiing Le’ Chadelier eguadion UF Lin = Pay a combuehen base URL, \ UFUmy = = 13.6% me By Sy BE — VW is 36 LeLm% = ! sy eo Ll bet . = 2,38 on = Ss fs Estimate the LFL and UFL of Problem 6-3a at 50°C, 75°C, and 100°C. Procedure for estimeling @ different pressure / thm. Q Comect Sev temo Covmect Lu Prassare @_ De mivtore calculation For Temperature correction 6-3, 6-4 appl UFLT= UFlag Fi+ as (T-2S8/bie ” 1 LFL, = UFlas[ I 75(7-25)/dte] a & vee 1c From Peery's Handles (ene wolfe | 9 | LAL | SZ5 | BRe U¥caYmeyS hexane Ss ae 2S fooz.st Methane wo [50] s is | anaes, Ethylene 3S S| 2% 36 B34.23y Ave 8 —_ Totud Combis] 2.0 LELeg Utre | LL Ice UFL ee [URL 25 | UFLion Heexane | 1094] 1054 | 1038 eo [7.704 | 7,920 Methane | 4559] 4,4 [3,678 1.320} 12,043 | 18165 Ettylene | 2,550! 2,400 | 2.250 B,00%! 40,00B' 42,005 Now cpply Le Chuther's Prinegle —1_—_—____ LAL, 2 2S Ue Snes 1.06% ee Trova * 4.354 * Je50 = LFlmy,7s = 2.17% LFLmy,t0o = 2,054 UFlimy, 26 = 44,3 to UFLmy co = [447% VFL ime,75 = [Sel loc 5) Estimate the UFL of Problem 6-3a at 1 atm, 5 atm, 10 atm, and 20 atm of pressure. Pressure has no effect on CFL, om UFL UFlp = UFLaty 4 20.6 CloyP4t) Pe mesa Paseae absolute ‘Species mol% ) Qe UFLahy rane Ss tS 7S Methane 10 1SO Is Ethylene s a 36 Ave 98 Toledo | Bu (loadn ( 1o15.4h) eae, one (Coatmy A eres a) = 2,026 Mee (s atm U1, = 01705 MPa CEO AL CF 2146S) UF lv, sams 3b +145 = “~e UFlmy, toatm © 16 + ZOFZ = 343% UF Lamy Zone = Be + 264T = 40,5 %yVC EA Estimate the MOC of propane, hydrogen, and methane. Mees (Fees mamas) (Maage S) = tre ( wetede A) Propane Cag +50, —> 440 + 300 Table 6-\ CFL = 2.1% MOLs (21% SS = (oS ele L 8) tydregen 2H 4402 > Heo Table 6-1 LFLE 4.0% (4.0%)(4)= 2.0% O) Methane CHy + 20. = Zuo + Co, Table 6-1 LFL= S% Moet = (S.0%)(2) = 10%ChE ZS5E De Wilkow 6-13. A set of experiments are run on a flammable gas in a spherical vessel. The following data are obtained for two different vessel volumes. Estimate the value of K, for this combustible gas. V=im v= 20m Time (sec) (bar) Time (sec) ——~P (bar) 0.0 0.0 00 00 on 02 02 ous 02 0s 03 0.35 03 12 04 0.6 0.35 16 05 09 0.40 32 06 14 0.425 47 07 22 0.450 65 08 41 0.475 69 0.85 5.0 0.500 7 0.90 6.2 0.550 14 0.95 1 0.600 13 1.00 70 0.650 20 1.05 12 0.700 64 1.10 67 0.750 6.1 1s 6.25 0.800 5.7 1.20 5.90 0.900 SA 1.30 5.40 1.000 47 1.40 5.00 1.50 5.60 note Find slope at maze 42) ys. sna BS AP. GS-44. 72 tor be 195 - 42S tes For second deta set AP 2 62-50 = 24 bar t 40-.8S s Ks (2 ber\( 1 m5 = 72 bao 72 +65.2 Zz t= (28g) (aonI= 66.2 bee =| 68.6 bare 3Use Table 6.@ far Thevmodynamre olata- synce Hembelty energy ret avalable assowe 4G 44 Cale + SOz —> 3Co, * 4hko AGy (eat (mol Cre = ~S.614 Cop = -44, OO Q = @ Hos -St.036 M6 = ZO pat — Ei reactants = 3(-FAL60) + 4(-SH.e86) - 16 -S.6r4) +500) = 495,71 kat /mod AG = f4as,71 Keal\\( mute ( 45823 (som = 256,000 Keals amet DN A4 9 tb a enersy releatect TNT Eqpwatent (2oe.eo0 keot)( jo get (ST . fo ye ae 22 B,0009 71 00. bm \ ( © 3 Tor) (atic) = S02,95 lbmTH1 Eq O-1S to get scaled dutdrce 0044 = 12,584#/lbm* Ze PO qor'3 (502.45 ibn) c Ustne, Figame G1 — Oveepressuve 35 2B by hn Table GF —Non-remforee coneele or cinta walle Rammaged,/ 4 You coud inteprefeate Hore decheyed” te (psy mm Table 6-7 Men Figo GIL qwes 238 St /y ily Eg 61s = fp NS loo S 5 eee () . SSA's) = 24,6 lbm Thos = OVCE Wty = ZF Clbin re 1341. ma\(4ay a ao ; “total, 6-16. A VCE with methangWestroyed a house structure 100 feet away from the ignition ¥ source. Estimate the amount of methane released. CHy + 20. > Coz t2ro Aesume AA * AG Table 6-8 to Saar of Cully =~ 12,140 Cog = -A4: 20 KO = -S4,636 AG = Products - Reactants F442 60-4S4.636)4 12.140 = 144,282 Lead/mod AG = (ianaae eat mol see 5426 beak VU “mo A Teg Tom From. Table 6.4 Over pressuye 18 10 esis From Figune ot AD ccalech distance = 7B + fy Eg 6s | i 2 ots = Ze DME cy Oost a 46% ibm. Mya &) = ( Fein) = 1ISB2 tom tor Assominy scene ont Ze of ype te owe pretsone | Come lr). — Wt = 1953 sre 2 ise Ba a Ou mecas tom) sey usaeedy iit nt Pie \=Ve / , Yor coud intepretete thre decheyed” to psig m Table 6-7 Then Figue 6b gwes 3 $4 /iyatts Eg GIs . : 100. . Mae Fe Bans} = 22,6 lbm “Aes os Oe WT = ZREI— = 1aq] hm TUT Va 1391) [oy ur 4235859) ( (tzocet\{ tb Meth (‘2h ‘Soke (3 w)( (esse (SI cee 22 |