Electrochemistry = Previous Years’ CBSE Board Questions | 2.1 Electrochemical Cells Mm 1. Anelectrochemical cell behaves like an electrolytic cellwhen (2) Eet™Eesermt (0) Eas 0 (A) Exrternat < Ect (0 Exe Eat (2020)(8) | MMMM mts) 2 Give two. points of differences between _ electrochemical and electrolytic cells (2/5,2020)(30) 3. Define electrochemical cell. What happens. if | ‘external potential applied becomes greater than Ezy of electrochemical cell? (A12019, 2/5, A12016)(i7) 2.2 Galvanic Cells MM 4, The correct cell to represent the following reaction . Zn 2hg' 920?" +246 (a) 2Ag| Ag" Il Zn | Zn7* (b) Ag” | Agi 2n°* | Zn (©) AglAg' Zn] 2n* (4) Zn] Zn?" I] Ag? | Ag (2023) 5. Ifthe standard electrode potential of an electrode is sreater than zero, then we can infer that its (a) reduced form is more stable compared to | bydroren gas () oxidised form is hydrogen gas (@) reduced and oxidised forms are equally stable. (@) reduced form is less stable than the hyd: as. (2020), 2.3 Nernst Equation MIM 6 AGand Ee for a spontaneous reaction will be (a) positive, negative (b) negative, negative (2) negative, positive (d) positive, positive. (2023) 7. ting + © —>Agiy 2 = 40.80V Fejiyt 20° —> Fey: E°=-0.44V Find the Ey for : Feqy + 2ABlgy —? Feng + 2A (a) 16V (b) =146V () 204V (4) 124V (2023) more stable compared to | | & Consider the following standard electrode potential values Sa¥yg +2e"9Snyy E°=-0.14V Fe ag te Fey = 40.77 ‘What is the cell reaction and potential for the spontaneous reaction that occurs? (2) 2Fe ag + Sag > 2Fe™ ag Sg B=-091V (0) Fe p+ Sty)->2Fe™ ay +S =4091V (0) 2 y+ Sry Fag +S & =1091V (A) 2Fe aq + Sryg)—> 2Fe* aq) + Sn" = 44.68V (2023) MMM eos) ®% Caleulate the emf ofthe following cell at 298 K: Soe Hang [Hayy (1 bar), Phy 410, Caleulate A,G*for the cell reaction at 25°C: Zn|Zn** | Cd** Cd Given that : E*;,24/2»=-O.76V, Ecuaryeq* O/40V, 1F = 96500C mol? (2023) 1. Write the Nernst equation for the following cell reaction: M5) + Chg >: ria + Cuyy Ho wil RG, be tected when concentration ot ( Cur*ionsisincreased and Gil) 2n?* ions isincreased? (Term Il, 2021-22) 12, Foranelectrochemical cell (2023) +8 i —> Aba + Mat Oita tleprevetution fio write the Nerst SXitin for tiecbowecehae 2s. oz) 12, Chedapttmentet ia ebong at 25°C: ‘Aly IAIP* (0-001 M) |] Ni?*(0.1 M) [Nig Given: Hea ~025V sav tlog2 = 08040, 3-0-4771) (2019) (Er) 14, Calculate 4,G* for the reaction; May + Cufdy —> Mey + Cy Given E2_y = +2.71V, 1F = 96500C mol”® (2/3.M2014) (ig) 15. Equilibrium constant (K,) for the given cell reaction is 10.Caleulate E%qu. Ag+ Biay —Aiog + By (2/3 Foreign 2014) WMI (smarts) 16, Write the Nernst equation and calculate the emf of the following cell at 298 K: © semned ith nt Seamer47, 18, 19. 21. 22. 23. 24, Zn | Zn?" (0.001 M) || H* (0.01M)| Hag) (1 bar) | Pty, Given :E3n2*/2n™ O.TOV.E i, =008¥ [log 10= 1] | (Tem 1, 2021-22, Foreign 2015)( 6) Caleulate 4,G* and log K, for the following cell: Nig + 2AG jag —> Nigsy + 2880 Given that E2q4 = 1.05 V, 1F = 96,500C mol" (erm, 2021-22) | ah | Calculate the maximum work and logK for the given reaction at 298 K: Nig * 208 ag = NES Ghee 2 Veatng= #080 L 1F = 96500 mol"® (2020) or | For the cellreaction INMallA8 jaa ce contin at 256: How | much maximum work would be obtained by operation of this cell? Epa "70-25 Vand E54 =0.80V (9/5, Delhi 2015C) Calculate the e.m. ofthe following cell at 298K: Fey | Fe** (0.001 M) || H” (0.01 M)| Hayy (1 bar) | Pty Given that Etqy = +0.44V {log 2= 0.3010, log 3= 0.4771, log 10= 1} (Termt,2021-22)(@) oR Calculate emf ofthe following cell at 25°C: Fel Fe7"(0.001 MIIIH*(0.01 M)I Fite” -O4AV, Een * Ol Calculate AG for the reaction, Ziggy + Cu fag > 20g + Cy) Given: E8for Zn?*/Zn= =0.76V and for Cu /Cu=+0.34V R= 8.314) K! mol", 1F = 96500C mol". (3/5, 2020) (Phy (Delhi 2015) Calculate e.m of the following cell: daylay "maranag gotta (Given: Ey27y" -076\. Engng" +080V {Given log 10 1], Ceyen, “gape +2 2 Cat rete aaa eat Ent yin “0.763 V (Al 2019) (ip) Zinc rod is dipped in 0-01 M solution of zinc sulphate when temperature is 298 K. Calculate the electrode potential of zinc. (Given: E%,2/2n* * -0-76 Vs log 10 1) (2019C)(E) ‘Write the cell reaction and calculate the e.m.t of the foll cell at 298 K. ‘Snyq Sn" (0.004 M) || H"(0.020 M) | Haig (1 bar) | Ptyy (Given : Eym/sn = -0.14 V) For the reaction, (3/5, 2020) | (3/5,2018)(0) 2AgClyy + Hay (atm) > 2Agyg + 2H°(0.1 M) ‘nh +2Cr(01M) AG? = - 43600 Jat 25°C. Calculate the e:m.£of the cell. (log 10°" =~ n) (95,2018) Calculate emf. of the following cell at 298 K. Cr+ 3Fe?"(0.1M)—> 2Cr"(0.01M) + Given Efe = -O74V, Ehpa2rr = -O4 (Delhi 2016) Calculate Ey for the following reaction at 298 K. 2g + 3Cu?"(001M) + 2A"(001M) + 3Cuy, Given: Ey 198V (3512016) Calculate the standard cell potential of the galvanic cellin which the following reaction takes pace : Fein) + AB jag) ~? Fe'taay + AB Calculate the 4,6? and equilibrium constant of the reaction. 080565 5.077) (3/5, Dethi2015¢)(0) Calculate the emt of following cell at 298 K : Maya | Mg?*(0.1 M) || Cu2"(0.01 M)|Cug, [Given: Egy =+2.71V, 1F =96500C mot] (3/5, Dethi 2014) Estimate the minimum potential difference needed to reduce Al,O, at 500°C. The Gibbs energy change tothe decomposition reaction 2a $a is 960 kd. (F = 96500 C mol”) ee (3/5.Delhi 20140) 27. Ener | EEE 6 mars) 30. E* for the given redox reaction is 2.71 V. Mig +Cu?"(0.01N) > Mg"(0.001M+Cu4y, Calculate Ey for the reaction. Write the direction of flow of current when an external opposite potential appliedis (i) less than2.71V and (ii) greater than2.71V (Dethi 2019) 31. Calculate emf and AG for the following cell ‘Maggy Mg?" (0.001 M) I Cu?* (00001 M) | Cuyy Eagan) "237 VE gy @AO2AV (NCERT, Al 2015) is) 2.4 Conductance of Electrolytic Solutions MO 22, The unit of molar conductivity is fa) Sem” mol"! (b) Sem? mol"* () Sem? mol™* (¢) Scm*mol (2023) Assertion (A) : Conductivity of an electrolyte increases with decrease in concentration. Reason (R) : Number of ions per unit volume decreases on dilution. 33, © semned ith nt Seamer(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A). (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct ‘explanation of the Assertion (A). (€)_ Assertion (A) is correct, but Reason (R) is wrong statement. (d) Assertion (A) is wrong, but Reason (R)is correct statement. (2020)(fin) = [1 mark) | 24, Givereason: Conductivity of CHsCOOH decreases on dilution. (1/5,2018)(0) | Define limiting molar conductivity. Why conductivity of an electrolyte solution decreases with the 35. decrease in concentration? (1/2, Delhi 2015) OR Define the following term ; miting molar conductivity (5, Dehi2014) ‘36. State Kohirausch's law of independent migration of ions. Write its one application. (1/2, Foreign 2015) oR Define the following term ; 1 Kohlrausch's law of independent migration of ions. _ (1/5, Delhi 2015C)(f) 37. Define the following term : Molar conductivity (Ap) (1/5, Delhi 20150) WEN omar) 28. On diluting two electrolytes ‘A’ and 'B, then Aw of increases 25 times while that of ‘8 increases by 1.5 times. Which of the two electrolytes is strong? Justify your answer graphically. (2023) {State Kohlrausch's law of independent migration ofions. | (i) Calculate the degree of dissociation (a) of CH;COOH if Ay and Af, of CHgCOOH are 48 ‘Sem? mol" and 400 S em? mol" respectively. (Term it, 2021-22) | of 0.001 M acetic acid is 7.8 10" Sem”, Calculate its degree of dissociation if Ag, for acetic acid is 390 Sem? mol” (Term il, 2021-22)(ii) Ina plot of 4, against the square root of concentration (C1) for strong and weak electrolyte, the value of limiting molar conductivity of a weak electrolyte _ ‘cannot be obtained graphically. Suggest a way to obtain this value. Also state the related law, if ary. (Term ,2021-22)(@0) ‘Answer the following questions (Any two): {a)_ Define molar conductivity (Ay). i (0) Write the unit of Ay. | (@) How does Am vary with concentration? (Term 2021-22C) 39. a 42, 43. Answer the following questions (Any two): {a) Why is alternating current used instead of direct current for measuring resistance of an electrolytic solution ? (0) State Kohlrausch's law of independent migration of ion. (€) Depict the Galvanic cell in which the following ete Maya + CUR > Maiy + eS term, 2021-220) X and ¥ are two electrolytes. On dilution molar conductivity of °X increases 25 times while that Y increases 25 times. Which of the two is a weak electrolyte and why? (2/5, 2020) (i) In the plot of molar conductivity (Ay) vs square root of concentration (c¥/“)following curves are obtained for two electrolytes A and 8 ‘Answer the following: (Predict the nature of electrolytes A and B. What happens on extrapolation of Ap to concentration approaching zero for electrolytes ‘Aand 8? (2/5, Delhi 2019) (Ee) 46. Explain with a graph, the variation of molar ‘conductivity of a strong electrolyte with dilution. (2019) Caleulate the degree of dissociation (x) of acetic acid ifits molar conductivity (A,) is 39.05 Sem? mol", (Given: 2°(H*) = 349.68 S cm*mol™ and XNCHjCOO")=40.9Sem? mol) (Delhi 2017) Define the term degree of dissociation. Write an expression that relates the molar conductivity of a weak electrolyte to its degree of dissociation. (2/5, Dethi 20150)(6*) 49. Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration. (NCERT, 2/5,A12015) State Kohlrausch law of independent migration of ions. Why does the conductivity of a solution decrease with dilution? (a12014) Define the terms conductivity and molar conductivity for the solution of an electrolyte. Comment on thel Variation with temperature. (Delhi, Al 2014C); The resistance of 0.01 M NaCl solution at 25°C is 200 Q The cell constant of the conductivity cell Used is unity. Calculate the molar conductivity of the solution, (2/3,A12014C) WM omar) ‘5a. (a) The standard Gibbs energy (4c) for the following cell reaction is -300 kJ mol”? : yg + 2A ~» Zr + ZAG 47. 5. 52, © semned ith nt SeamerCalculate Et, for the reaction. (Given: 1F = 96500 C mo!) (b) Calculate 25, for MgCl, if A° values for Mg? _ jon and Ci" ion are 106 S cm? mol"? and 763 Sm? mol" respectively. (Term|, 2021-22) 54. The conductivity of 0.001 mol L* solution of (CHCOOH is 3.905 x 10°* Scm”* Calculate its molar ‘conductivity and degree of dissociation (a). [Given:2°(H") =349.6Scm? mol" and A°(CH3COO") = 40.9S.cm? mol”*] (Term tt, 2021-22C, 3/5, Al 2016) 55. Conductivity of 2 x 10°? M methanoic acid is ‘8x 10°° Scm"*. Calculate its molar conductivity and degree of dissociation if A, for methanoic acid is 4045 em? mol", (2020) 56. Out ofthe following pairs, predict with reason which pair wil allow greater conduction of electricity. (i) Silver wire at 30°C or silver wire at 60°C. ) 0.1 M CH,COOH solution or 1 M CH,COOH solution. (ii) KCI solution at 20 °C of KCI solution at 50 °C. (3/5, 2020) 57. The electrical resistance of a column of 005M KOH solution of length 50 cm and area of cross-section 0,625 cm? is 5 x 10° ohm. Calculate its resistivity, ‘conductivity and molar conductivity. (3/5, 2020) 58. (a) Following reaction takes place inthe cell: Zryg + AgsO jy + HzO —> Zeviny + 2AGiy + 2OH Gog, Calculate 4,G*of the reaction. [Given : Etz,2%/2q)" -0.76V, Engine)” 080 1F = 96,500 C mot} (b) How “tan you determine limiting molar conductivity, (Aj) for strong electrolyte and weak electrolyte? (2019) 59. The conductivity of 0.20 mol L"? solution of KCI is 2.48 x 10S cm"?, Calculate its molar conductivity and degree of dissociation (a). Given :2° (K*) = 73.5 Sem? mot" and # (Cr) = 76.5 Sem? mol". (2015) 60. Resistance of a conductivity cel filled with 0.1 mol "> KCI solution is 100 0. Ifthe resistance of the same cell when filled with 0.02 mol L" KCI solution is $20 2, calculate the conductivity and molar conductivity ‘of 0.02 mol L"? KCI solution. The conductivityot 0.1.mol L"* KCI solution is 1.29 10°20"? em (3/5,A12014)(%8) | MMU (4/5 marks) ‘61. Rahul set up an experiment to find resistance of aqueous KCI solution for different concentrations at 298 K using a conductivity cell connected to a Wheatstone bridge. He fed the Wheatstone bridge with ac. power in the audio frequency range 550 to 5000 cycles per second. Once the resistance was calculated from null point he also calculated the conductivity x and molar conductivity A,, and recorded his readings in tabular form. ‘Ag (Sem? mot?) a jus z 1290 Fe = Answer the following questions: (a) Why does conductivity increase though the ‘conductivity decrease with dilution? (b) If Ag of KCl is 150.0 S cm? mol"?, calculate the degree of dissociation of 0.01 MKC. (@) If Rahuthad used HClinsteadto KCI then would you ‘expect the A, values to be more or less than those perKClforagiven concentration Justify. (2023) 62, Read the passage given below and answer the ‘questions that follow: Oxidation-reduction reactions are commonly known asredox reactions. They involve transfer of electrons from one species to another. In a spontaneous reaction, energy is released which can be used to do useful work. The reaction is split into two half reactions. Two different containers are used and ‘a wire is used to drive the electrons from one side to the other and a voltaic/galvanic cell is created. It is an electrochemical cell that uses spontaneous redox reactions to generate electricity. A salt bridge also connects to the half cells. The reading of the voltmeter gives the cell yoltage or cell potential or electromotive force. If Erxy is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. One mole of electric ‘charge when passed through acell will discharge half a mole of a divalent metal ion such as Cu**. This was first formulated by Faraday in the form of laws of electrolysis. The conductance of material is the property of materials due to which a material allows the flow of ions through itself and thus conducts electricity. ‘Conductivity is represented by kand it depends upon natureand concentration of electrolyte, temperature etc. A more common term molar conductivity of a solution at a given concentration is conductance of the volume of solution containing one mole of electrolyte kept between two electrodes with the Unit area of cross-section and distance of unit length. Limiting molar conductivity of weak electrolytes cannot be obtained graphically. ey © semned ith nt Seamer(a) Issilver plate the anode or cathode ? (b) What will happen if the salt bridge is removed ? (ce) When does electrochemical cell behave like an electrolytic cell ? (4) (@ What will happen to the concentration of Zn’ and Ag’ when Exe ~ 0. | 69. Following reactions occur at cathode during the (i) Why does conductivity of a solution decreases with dilution? ‘OR (d) The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 $ cm? mol. Calculate the conductivity of this solution. (Term i, 2021-22) The electrical resistance of a column of 0-02 M NaOH solution of diameter 1-40 cm and a length 44 cm is 5-00 x 10° ohm. Calculate its | resistivity, conductivity and molar conductivity. a takes place: Nig + 2ABing > NiRSy +2ABi9 Further show : (i) Which of the electrodes is positively charged ? (ii) The carriers of the current in the outer circuit. (0-1) 2A}"* (0.01 M) + 3Nig Calculate its emt if E2qy= 1-41 V. {b) How does molar conductivity vary with increase inconcentration for strong electrolyte and weak Depict the galvanic cell in which the reaction 70. mn. electrolysis of aqueous silver chloride solution : AB‘ te AQ B= +0.80V Hay +e" Sta E°=000V (On the basis of their standard reduction electrode potential (E*) values, which reaction is feasible at the cathode and why? (Al 2017C, 1/2, Delhi 2015) How much charge is required for the reduction of Amol of Zn” to Zn? (Delhi 2015) Following reactions occur at cathode during the electrolysis of aqueous copper (I!) chloride solution : Cujty+2e"Cuy: B= +034V te ties : Hing Sa § (On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why? (1/2, Foreign 2015) (0) &=0.00V | 72. State the Faraday’s first law of electrolysis. a) Represent the cellin which the followingreaction | 7. electrolyte ? How can you obtain limiting molar | conductivity (A%,) for weak electrolyte? (2019) (Delhi 2015¢)(@) MEM camarks) (2021¢)() 73. (i) What should be the signs (positive/negative) 2.5 Electrolytic Cells and Electrolysis | |. Mm 65. Four half reactions | to IV are shown below: 1 2Cl—+Cl+ 26" I, 40H" +0, +2H,0+ 20" Wh, Nat ¢e"—9Na IV. 2H +20" +H, ‘Which two of these reactions are most likely to occur when concentrated brine is electrolysed? (a) and itt (b) landiV. (Wand i (@) Wandtv (2023) Ss ‘66. How much charge in terms of Faraday is required to reduce one mol of MnO; to Mn"? (2020) (&) 67. How many coulombs are required for the oxidation of Lmolof H,0to0;? {One word, 2020) 68. Give reason: 7%. n. On the basis of E* values, ©, gas should be liberated 7, at anode but it is Cl, gas which is liberated in the electrolysis of aqueous NaCl, (1/5, 2018)() for Efy and AG* for a spontaneous redox reaction ‘occurring under standard conditions? (il) State Faraday'sfirstlaw of electrolysis. (2023) Predict the products of electrolysis of an aqueous solution of CuCl, with platinum electrodes. (Given: E’cy2cy = +0.34 V, =+136V, Ev mgg = 0.00 V.E'20,n4,0)7 + 1.23V) (2/5,2020) |. Predict the products of electrolysis in each of the following : (a) Anaqueous solution of CuSO, with Ptelectrode (b) An aqueous solution of AgNO; with Pt electrode (20200) How many seconds does it require toreduce 3 moles of Fe™ to Fe”* with 2Acurrent? (Given :1F = 96500€ mol”) (2020¢) Following reactions may occur at cathode and anode during electrolysis of aqueous sodium chloride. What products will be held at anode and cathode? Use given E* values tojustify your answer, Cathode: Najag +6 Nay f=-271V Hag +e > 3 Hayy £*=0.00V hacer Cg sttigee” , Baetiuv 2H-Ojnq) > Orig) 4H" + de” E* = + 1-23V. (2019) (ip) Calculate the mass of Ag deposited at cathode when current of 2 ampere was passed through a solution of AgNO for 15 minutes. © semned ith nt Seamer(Given: Molar mass of Ag = 108 g mol"*, 1F = 96500C mol") (2/3, Delhi 2017) State Faraday’ first law of electrolysis. How much charge in terms of Faraday is required for the reduction of 1 mol of Cu" to Cu? (2/5, Delhi 2014) ‘A solution of Ni(NO)> is electrolysed between platinumelectrodes using acurrent of 5.0 ampere for 20 minutes. What mass of nickel will be deposited at the cathode? (Given :At. mass of Ni= 58.7 g mol, ‘IF = 96500 C mol") (Foreign 2014) Predict the products of electrolysis in each of the following: {) An aqueous solution of AgNO with platinum ‘electrodes. (il) An aqueous solution of H2SOs with platinum electrodes. WMI (mares) 182, When a steady current of 2A was passed through two electrolytic cells A and B containing electrolytes, ZnSO, and CuSO, connected in eries,2 gofCuwere deposited at the cathode of cell 8. How long did the ‘current flow ? ‘What mass of Zn was deposited at cathode of cell A? [Atomic mass: Cu = 63.5 gmol"?, Zn = 65 g mol”; 1F = 96500C mol} (2020)(E) ‘A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO, and ZnSO, until 28 g of Fe deposited at the cathode of cell X How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y. (Molar mass : Fe = 56 g mol”', Zn = 65.3 g mol”, 1F = 96500C mol”) Chromium metal is electroplated using an acidic aL a3. solution containing CrO3 according to the following ‘equation: CrO pq + 6H" + 66» Cry + HzO Calculate how many grams of chromium will be electroplated by 24,000 coulombs. How long will it take to electroplate 1.5 g chromium using 12.5 A current? [Atomic mass of Cr = 52.gmol"?, 1F = 96500C mot} | (ai2019) (a) The cell in which the following reaction occurs: DFO y+ 2a) —> FO ag + Ly has Ey = 0.236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given: 1F = 96,500C mol!) (NCERT intext) (b) How many electrons flow through a metallic | ‘if acurrent of 0.5 A is passed for 2 hours? (Given: 1 F = 96,500 mol!) (a12017) (2/5, Delhi 2014C) (3/5, Dethi 2019) _ WME (Smarts) 86. () State Kohlrausch’s law of independent migration of ions. Write an expression for the limiting molar Conductivity of acetic acid according to Kohilrausch’s law. (i) Calculate the maximum work and log K, for the siven reaction at 298 K: Nig + 2Ag {aq =—Nitog + 2ARig Given: Ena pg®-O25V. Engng ™ 1F = 96500C mol" 2.6 Batteries | ES mar 87. Define: Secondary batteries (1/5, Delhi 20150)(8)) WEEN e2arts) 88. Write the name of the cell which is generally used in hearing aids. Write the reactions taking place at the ‘anode andithe cathode of thiscell, (Al2017)(8] ‘Write the name of the cell which is generally used in inverters. Write the reactions taking place at the ‘anode and the cathode of this cel. (412017) ‘Write the name of the cell which is generally used in transistors. Write the reactions taking place at the ‘anode and the cathode of this cel. (412017) What type of battery is mercury cell? Why isit more ‘advantageous than dry cell? (2/5,A12015)(U)) HEE (5 marisy 92 (a) The conductivity of 0.001 mol L*? acetic acid is 495 x 10° S em" Calculate the dissociation constant if A®,, for acetic acid is +080V (2023) 290.5 Sem? mol"*. (b) Write Nernst equation for the reaction at 25°C : 2Aliy + 3Cujsay > ZANE + 3Cupy (c)_ What are secondary batteries? Give an example. (2019) | 2.7 Fuel Cells JM 99. Which of the following cell was used in Apolo space programme? (a) Mercury cell {b) Daniel cel (© Hz—OzFuelcell (4) Drycell (2023) SO ‘94. Name the cell use in hearing aids and watches. (2020)(7) 95. Name the type of cell which was used in Apollo space programme. (2020, 1/3, Al 2014) 96. Define: Fuel cell (Delhi 2017, 1/5, Delhi 2015C, 2014) © semned ith nt SeamerMMM emacs) 97. Give twoadvantagesoffuel cells. (2/5, 2020) 98. Define fuel cell and write its two advantages. (2/5,2018)(8) | 99. From the given cells : Lead storage cell, Mercury cell, Fuel cell and Dry cell ‘Answer the following : () Which cellis used in hearing aids? | (ii) Which cell was used in Apollo space programme? (ii) Which cells used in automobiles and inverters? {iv) Which cell does not have long life? | 100. Write two advantages of Ha—O2 fuel cell over ordinary cell. (2/3, Foreign 2014) 2.8 Corrosion | MBM mart) 104. Using the E° values of A and B predict which is better for coating the surface of iron E(t) 7-044] to prevent corrosion and why? Ease ay = 2.37 Vi Ege py 2-014 (Delhi 2016)(8) | (412016) (ia) beh) Bre) el oy 2.3 Nernst Equation i ‘SNo. Limiting: y a SS WM omer) t 396 1. Represent the cell in which the following reaction — 2 501 takes place. The value of E° for the cell is 1.260 V. | 7 ‘Whats the value of Ey? | 3 « 735 2Alg + 3Cd** (0.1 M) > 3Cdyy + 2AI?* (0.01M) | a 199.1 pana (a) 350Sem®mor® —(b) 375.3Scm* mol 2.4 Conductance of Electrolytic ere Get Solutions | eazy 1 Mm 2. Themolar conductivity of CHsCOOH at infinite dilution is 390Sem?/mol. Using the graph and given information, the molar conductivity of CH5COOK willbe i ie | as 40 | 2s Jas | 5 xsl 2 a5 Ker | a | x | OT Or OS | nae (a) 100cm?/mot (b) 115Scm7/mol j () 150Scm?/mot (d) 125Scm?/mol | (erm, 2028-22) | 3. Which of the following option will be the limiting molar conductivity of CH,COOH if the limiting ‘molar conductivity of CH;COONa is 91.S.cm? mol? Limiting molar conductivity for individual ions are _ given in the following table. i 4. Solutions of two electrolytes ‘A’ and ‘B' are diluted. ‘The Aw of ‘B' increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behaviour of ‘A’ and’B! (Term ll, 2024-22) 5. State Kohirausch law. Calculate the emf of the following cell at 298K: AliglAI** (0.15 M) |] Cu" (0.025 M) | Cus (Given Earn * ~1.66 V, Pcu2ezcy * 0.34 V, Jog 0.15 = =0.8239, log 0.025 = -1.6020) (2020-21) ‘On the basis of E® values identity which amongst the followingjis the strongest oxidising agent? Clg + 2e”— 2CI"; B= 41.36V, MnO," +8H" + 5e"—»Mn?* +4H,0;E"=+1.51V Cr0}% 14H" + 66" + 2Cr** +7H,0; ra+1.33V The following figure represents variation of (Ap) ¥5 4 for an electrolyte, Here, Ay is the ‘molar conductivity and Cis the concentration of theelectroiyte. O} © semned ith nt Seamer