CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 1 Name (please print): Amo ve¥2 S Student Number: NSID, Signature: Check correct section: Q Stevens (Section 02; TTh) O Bowles (Section 04; MWF) University of Saskatchewan Department of Chemistry Chemistry 115 Midterm Exam (Term Il 2019-20) Time: 120 minutes Feb 28, 2020 READ THIS FIRST! 1. This is a closed-book examination. A data-sheet is attached to the back of this paper; you may detach this and keep it 2. This paper has 9 pages, including the data sheet. Check that you have a complete copy. 3. There are 30 multiple-choice questions worth 2 marks each. Marks are awarded for correct answers only. Total marks: 60. ‘Answer all multiple choice questions by circling a response on this paper, and by coding the corresponding response in HB pencil on the blue optical scan sheet. 4. If you change your mind, indicate this clearly on this paper, thoroughly erase the original response on the opscan sheet and replace with your revised answer. Multiple answers will be treated as no answer! In the event of a discrepancy, the response on the opscan sheet will count. 5. When you have finished fill out the top of this paper, and write your name (legibly!) and code your student number on the opscan sheet in HB pencil. Place the opscan sheet on top of this paper and hand in both together. 6. Only course approved calculators are allowed. Personal digital assistants, wireless devices, cell phones, laptop computers and music players are not allowed. [For marker use onl | Total MarksCHEMISTRY 115 MIDTERM EXAM (Term I! 2019-20) Page 2 MULTIPLE CHOICE QUESTIONS = (WORTH 2 MARKS EACH) 1. Given 30.0 g of Cu20 and 12.0 g of Hz, how many grams of copper are produced for this unbalanced chemical reaction? Cu20(s) + Ha(g) 2Cu(s) + H20(/) A. 10.79 B. 757g C. 378g © 26.69 E. 47.99 " average atomic mass of bromine is 79.9091 amu, what is the natural abundance of the heavier isotope? A 49.59% - yma fi-x)m B. 49.6% om ( ina C. 50.41% = Xm + My — KMD D. 50.4% Mong = A [77 4 ¥ (ry, —my 47 | 7 Go (moi m2) fay-m2) = BO eat 3 hs @Bwhat is the final concentration when 10.00 mL of solvent is added to 2.40 mL of a 4 fee iy solution? Cen AANA ory — FEWER coe, A. 0.100 uM B. 12.5uM C. 16.0 uM © 0.800 pm E. 1.00 pM 4. What is the balanced equation for: A[CH,] _ _14[02] _ 14[H,0] _ A[CO2] at" 2 at 2 At Ae Rate = A. CHs + 402 —» Y6H120 + COz P B. YH20+CO2—CHy +402. CM + 2 On ©. HzO + 2602+ CHs + 202 D. 2H:0 + CO2—+ CHs + 202 @)CH: + 202 2H20 + CO2 —= 2,0 4+COg 5. Which of the following factors will not affect reaction rates? ® Stoichiometric coefficients in the overall chemical equation B. Reactant concentrations C. Presence of a catalyst D. Temperature E. Collisions between molecules 6. What is the overall reaction order of the generic reaction below, when given the following information? A plot of In[A] vs time yields a straight line with a slope of -k. The units of the rate constant are M's", A+2B>C A= er der r=CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 3 7. Given the results of a series of experiments, what is the rate law for the formation of phosphene gas by the reaction of carbon monoxide with chlorine? 2 Experiment | Initial [CO] (M) | Initial [Cl] (M) | Initial rate (M/s) i 1.00 0.10 1.29 x 10% 2 0.10 0.10 1.33 x 10% 3 0.10 1.00 1.30 x 1079 4 0.10 0.01 1.32 x 107 22, 4 OD A. Rate =Kcoyjciyo [CP Ares & B. Rate = k{CO][Ci]"? - -\ © Rate = k{CO][Ciz] p er D. Rate = k[CO][Cl2]* . a E. Rate = k{Co]'? SS ete a 10, Pe Eh - 8. Given the following rate law, how does thé rate of reaction change ifthe concentration of A \0- remains constant but the concentration of B is doubled? Rate = KAP Lf ‘A. The rate of reaction will increase by a factor of 8. fi u = ©) The rate of reaction will increase by a factor of 16. 'b C. The rate of reaction will ncrease by a factor of 4. D. The rate of reaction will increase by a factor of 2 E. The rate of reaction will not change. 9. What is the collisional frequency factor if the temperature is 339.9 K, the activation energy is 18.0 kJ/mol, and the rate constant is 1.04 x 10° cm? molecule” "7 A. 1.05 x 10" cm®/(molecule.s) be Aen *” B. 1.78 x 10-7 cm®/(molecule.s) ©. 1.27 om?/(molecule.s) ( 6.07 x 10°? cm*(molecule.s) E. 1.48 x 10 om°/(molecule.s) 10. Determine whether the following statements are true (T) or false (F). = 6 © (a) The halt-lfe is the time it takes for the rate constant to drop by half. (b) Ina reaction mechanism, activated complexes are species that form during one elementary step and are consumed in the next elementary step. (c) The rate-determining step is the slowest elementary step in a reaction. A TET SFT B. TTF Giiguu D.TFF (FFT 11. The rate constant of the decomposition of PH3 was found to be 0.0705 s~ at 100°C. If the reaction is begun with an initial PHa concentration of 0.95 M, what will the concentration of PHs be after 11.00 s? 4 Ber reek @® 044M B. 017M 5 . kt C. 0.55M Lf kt => [A.-M D. 2.0x 105M ( ( > orgs lly E. 0.06M = 045m O-437M ~ oulCHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 4 12. The rate constant of a reaction at 38.0°C is 1.00 x 10° M's. What is the reaction rate constant at 150.0°C, if the activation energy is 100.0 kJ/mol? {2 36.123 hye! ° A. 9.90x109M'st oo ee : B. 1.27 x 105 M's" ‘ P C.1.63x107Mtst 9 yp LY / { @O278x10'Mist | ~~4)? bk, hye E. 3.60x 109 M*s* 2 hogs 0-233 13. If the initial concentration of a second-order reaction is 0.355 M and k 0.141 L mol min", what is the half-life of the reaction? A. 7.55x10's 2

» O2(g) _ Nz 40 A. N2Os (g) + 20 (g) —» 2NO2 (g) B. NzOs (g) + NOs (g) > NO2 (g) + 2 (g) C. N2Os (g) + 20 (g) —» NO2 (g) + O2 (g) D. N2Os (g) + 2NO2 (g) ~ Or (g) ©) N20s (g) + 0 (g) > 2NO2 (g) + O2(g) 15. The reaction CHa (g) + 2Clz (g) > CHsCl (g) + HCI (g) + CI’ (g) is thought to proceed via the following mechanism: el Step 1: CHa (g) + Clz (g) + CHs (g) + HCI (g) 8 = Step 2: CHs (g) + Cle (g) > CHaCl (g) + Cr (g) a The energy profile for the mechanism is shown below. What is the rate law for the reaction? Reaction progress (A) Rate = k[CH«][Ch] B. Rate = k[CHs][HCl] C. Rate = k[CHs][Ck] D. Rate = k[CHsCI][Cr] E. Rate = KICHdJ[Ch)?CHEMISTRY 115 MIDTERM EXAM (Term I! 2019-20) Page 5 16. Which of the following is true for a chemical reaction at equilibrium regarding the concentration of products? A. They will not change because there are no more reactants. B. They will not change because the limiting reagent is gone. \< C. They will not change because this is a constant for each reaction.” (D) They will not change because the forward and reverse rates are equal. E. They will change continually because of reversibility. > 17. Which expression corresponds to the equilibrium constant for the reaction written as 4.NH3 (g) + 5 O2 (g) = 4 NO (g) + 6 H20 (g) {NO} [02] i , A. Kos) a gO] l ae ) B. Ke = LNHaI# 102) ‘ : ~ ie [NO] 4 [H20]6 2). _ INO [H20]6 © Ke Teas] #[02)5 NH3]3 [02] [NO] [H20] _ [4NO} [6 H20]6 © [4NH3] 4[5 02] D. K E. Ke 18. For the following reaction, Kp = 137 at a temperature of 350 K. What is the value of K:? 2.CaH10 (f)+ 13 O2 (g) = 8 COZ (g)+10H20(@) > N= 1K =3 A. 2.67 x 109 M (8) 7.03 x 10-6 M” C. 6.79 x 10-3 Mf D. 4.77 M E. 3.24 x 106 Mf 19. Given the following reactions and associated equilibrium constants: N20 (g) + % O2 (g) = 2NO (g) Kez 1.70 x 10-13 NO2 (g) = NO(g)+% 02 (g) Ke = 1.46 * 10-7 What is the equilibrium constant for the following reaction? 4 NO2 (g) = 2 N20 (g) + 3 02 (g) Koa? (A) 1.87 « 10-2 B. 1.31 x 10-53 C. 4.22 x 10-33 D. 2.37 x 1032 E. 63.6 Z2bLM0.2CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 6 20. In the following reaction, which of the statements is true, given the concentrations of each species? E CeHe (9) + 3 H2 (g) = CeH12 (9) Ke=1.23« 103 => Qc > Ke [C6He6] = [H2] = 0.170 M and [CgH42] = 0.025 M A. More hydrogen must be consumed to achieve equilibrium. / ( (1 B. More cyclohexane (CgH12) must form to achieve equilibrium. : J C. The reaction is at equilibrium. \ ©) More benzene (CeHe) must be formed to achieve equilibrium. E. Equilibrium cannot be established in the system.» ZO 21. Addition of reactants to a chemical reaction in solution or gas phase at equilibrium results in >) no change in K and a shift in equilibrium to produce more products. (/7 an increase in K and a shift in equilibrium to produce more products /\ * an increase in K and a shift in equilibrium to produce more reactants. » a decrease in K and a shift in equilibrium to produce more products.~ a decrease in K and a shift in equilibrium to produce more reactants. > moow 22. What happens to the equilibrium between NO2 (g) and N2O4 (g) in inert argon when the volume is increased and additional argon is added to maintain a constant total pressure? < Drewwve Got Bh, v 2 NO2 (g) = N204 (g) (A) The amount of NO2 increases solely because of the increase in volume i The amount of NO2 increases solely because of the addition of argon. i B. C. The amount of NO? decreases solely because of the increase in volume. D. E. The amount of NO2 decreases solely because of the addition of argon. The amount of NO2 remains the same, because the effects of the two processes cancel each other out. 23. What is the correct expression for Kp in the following reaction: 4 KO2(s)+ 2. CO2 (g) = 2 K2C03(s)* 3 02 (a) cox oo 2 ca Po: . f 2 B Kp = Roos 1 & Kp = Gay — (Px2c03)*(Po2)* D. Kp = (Px2603)*Po2)* S, _ (Pon? SP con®CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 7 24. Consider the following reaction at 298 K. Which of the following will shift the equilibrium reaction to the left to form ie reactants. ce o2 (g) = CO2 (g)» i at AH = - 393.5 kJ/mol Remove some solid C.> Increase the temperature. Add O2. Remove CO2. Decrease the temperature, 25. Consider the following reaction: 3.N2(g) + H2(g) = 2 N3H(g) Initially 0.20 M Nz (g) and 0.10 H2 (g) are placed in an empty container. At equilibrium, the concentration of N3H (g) is found to be 0.050 M. What is the Kc for the reaction? @ 17 = 2 B. 63 >| } C. 0.059 oy; >1-0°9?8) D. 36 ol-x = x E. 0.83 T0-.060M 2x =o: eSEM y= 0-025mM is 26. For the following exothermic reaction, Kc=3.8 x 10-2 at 250°C, PCI (a) = PCIs(@) + Cl2(a) 7 p ¢ if 0.550 mol of PCI (g) is initially placed in a 2.5L flask. What is the concentration of Clg (9) at equilibrium? Con: 0.112M 2 0.074 M , C. 0.220M g D. 0.550 M 1 E. 0.148 M 27. Which of the following is a strong acid? A. nitrous acid, HNO2 B. sulfurous acid, H2SO3 C. carbonic acid, HxCO3 D. hydrofluoric acid, HF y (E) perchloric acid, HCIO4 28. Which of the following is a conjugate acid-base pair? A. NaF and F> — B. HNO3 and HNOz © Hland D. NHg* and NH2 >< I E. H20 and H202CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 8 29. The pH of a popular soft drink is 3.4; what is its hydronium ion concentration? A. 5.0 x 10" M B. 2.5x 10°M © 4.0x10*M D. 1.0x10-7M E. 5.0x 105M Ch, ot) ~A ule 30. What is the percent ionization of HF ina 1.0 MHF solution given that Ka of HF is 6.8 x 104? @ 26% B. 97% C. 94% D. 0.068% E. 100%Atomic mass unit u 4.6605 x 10-?”_kg Avogadro number Na__| 6.0221 x 1023 mol Faraday constant F__| 9.64853415 x 10* C mot? Gas Constant R_ | 8.314472 J mol" K-* 0.0820574 L atm mol? K-! 1 atm = 760 Torr= 760 mm Hg Roots of a Quadratic equation Standard Temperature and Pressure: = 101.325 kPa. °C = 273.15 K | Joule unit conversion 401.3 =1Latm _| bab? - 4ac 2a Some Equations pV =nRT k = Ae tant [Ak = -kt + [Alo tua = [A]o/2k tu2 =0.693/k Kw= [HsO*][OH"] = 1.00 x 10-4 at 298.15 K In (Kolks) = (Ea/R)(1/Ts — 1/T2) In{{Al/{Alo} = - kt the =1/(K[Alo) Ink = -Ea/RT + InA Kp=K.(RT)" ANA = 1/[A]o + kt pH = -log[H30"] Kw = Ka Ky = 1.00 x 10-4 CHEMISTRY 115 MIDTERM EXAM (Term II 2019-20) Page 9 1 Periodic Table of the Elements 18 7 re Hele 1314 15 16 17 |He 2 [ot 3 7 es] Li |Be c O |F |Ne sae | sage sens | on |r| ram | so | a Na|Mgl3 4 5 6 7 8 9 10 11 12/A,/Si/P. |S. |Cl Ar oie grap psig 22g [ina wh | Et | | epee eof see fae K_ |Ca/Sc|Ti |V (Cr |Mn|Fe |Co | Ni | Cu |Zn |Ga/|Ge | As | Se Br Kr esr 8p ae | ao) at | ae] pata a] a a8 a Bs a Rb |Sr /Y | Zr |Nb | Mo| Tc |Ru |Rh |Pd | Ag |Cd jin |Sn |Sb |Te |1 | Xe fee | ie Le bezel aes | oe | oe | toe gee | ve | ae | ge | | mn | ze | ote | a Cs |Ba|La |Hf Ta |W |Re r |Pt |Au|Hg |TI |Pb Bi |/Po | At | Rn “er |e | a3] toe) 105-106} tor] toe] 100] “110 Po ee Fr |Ra|Ac |Rf | Db | Sg | Bh/Hs | Mt een | sees [arom | gen | cen Lom | aen | ees Lo | aon | on | om = on fa STS OTA Te, se, a) es) se) ae] ae] ey aT Ce | Pr | Nd |Pm|Sm|Eu | Gd | Tb | Dy |Ho | Er |Tm|Yb | Lu “sop | fs oe as] separ} ae] aa | 100 | or | ae Th |Pa|U_ |Np | Pu |Am|Cm| Bk | Cf | Es | Fm|Md| No | Lr zee | aio | aso | art | een | os | oor | am Loon [ase | an | ae | co | ato Useful Data Physical Constants Constant ‘Symbol | Value