Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-7(N) Date: 05-01-24

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 D 2 C 3 A 4 A 5 A
6 A 7 C 8 A 9 A 10 C
11 D 12 B 13 C 14 A 15 B
16 A 17 B 18 A 19 A 20 A
21 5 22 5 23 2 24 2 25 3
26 1 27 3 28 120 29 6 30 3

CHEMISTRY
31 D 32 D 33 D 34 C 35 B
36 A 37 A 38 D 39 A 40 D
41 B 42 B 43 C 44 A 45 D
46 C 47 C 48 D 49 B 50 A
51 3 52 5 53 4 54 3 55 4
56 3 57 4 58 5 59 27 60 5

MATHEMATICS
61 B 62 D 63 B 64 B 65 B
66 D 67 B 68 B 69 C 70 D
71 C 72 A 73 A 74 C 75 C
76 D 77 C 78 C 79 C 80 A
81 2 82 6 83 3 84 2 85 1
86 18 87 101 88 4 89 4 90 2

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 Narayana IIT Academy 05-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-7(N)_KEY&SOL
SOLUTIONS
PHYSICS
1.

F  2T  2ma 1
3T  4ma 2
2a 1  3a 2
solving we get
3F
a2 
17m
A 0 A0

cc x (a  b  x)
2. c 1 2 
c1  c2 A0  A 0
x (a  b  x)
A0
c independent of x
(a  b)
1 PV
3. Wcyclic  V0P0  0 0
2 2
For theprocess AB,P  KV  PV 1  constant
Molar heat capacity of the gas in the process AB,
R 3R R
C  Cv     2R
(1  x) 2 2
Q AB  nCT  n2R(4T0  T0 )  6nRT0  6P0 V0
Q BC  0 and Q CA  0
Wcyclic P0 V0
The efficiency of the cyclic process,    100   100
Qsup plied 2  6P0 V0
25
  8.33%
3 
4. By the symmetry, B total  0
5. Let us observe the motion of A and B relative to C.
AA BB

2d d

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1 2
AA vt  at
BB   2
2 2
Vt 1 2
BB'   at
2 4
V
is initially speed of B w.r.t C as well as ground.
2
a
is acceleration of B w.r.t C
2
  
aB/ g  aB/C  aC/ g
a 1
 a  a
2 2
6. Conceptual
7. v cos   u cos 
u cos 
v
cos 
v sin   u sin   gt
u cos  sin 
 u sin    gt
cos 
u cos  sin   u sin  cos 
  gt
cos 
u sin    
t
g cos 
8. m1s1T1  m 2s 2 T2
Since m1s1  m 2s 2
T1  T2
9.

3
tan 2 
D
10. Q  (80  7)  (120  8)  (200  6.5) MeV  220 MeV
11. By the property of full wave rectifier
n
 V0 
12. Pfinal  Pinitial  
 V0  V 
w 
13. 15Vg  Vg  w    V  a
g 
 14Vg  w 
a  g
 w  Vg 
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14. Time period of a spring mass system will remain constant when fluid is non-viscous.
15. v c  2v 0  1.414 v 0 % increase in orbital
v0  v0
velocity   100  41.4%
v0
16.

A) phase difference between current and voltage in a purely resistive AC circuit is zero.

B) phase difference between current and voltage in a pure inductive AC circuit is ; current lags
2
voltage.

C) phase difference between current and voltage in a pure capacitive AC circuit is ; current leads
2
voltage.
 X  XL 
D) phase difference between current and voltage in an LCR series circuit is tan 1  C .
 R 
1 1
17.    R 2B1  B2 3R 2
2 2
d R  dB1 3R 2 dB2
2
  
dt 2 dt 2 dt
R 2 3R 2
 .2K 0   4K 0
2 2
 emf  5R 2 K 0
18. At node, energy is maximum when all particle reach to there extreme position.
19. Vs  tan .   C
4V  tan . 2 0  C
10V  tan . 4 0  C
3V
6V  20 tan   tan  
0
Wc
4V  6V 
e
Wc  (2V)e
(3V)e
h
0

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20.

v2 V 2
w1   P
R v2
P
2
 V  4V 2 .P 4P
w2    .4R  
 5R  25V 2 25
21.

a 0  a cm  R........1
a1  a cm  R....... 2 
Solivng equation 1 &  2 
a 1  a 0  2R   4a 0
a 1  5a 0
K  5.00
22. Tension of rope is maximum at lowest point
mv 2
Tmax  mg  ........(1)

By energy conservation,
 1
mg  mv2  v  g
2 2
From (1),
m(g)
Tmax  mg   Tmax  2mg

For 8 kg block, Tmax  f L
2mg   (8g)
4g   (8g)
  0.5
23.

Phasor diagram

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I8  I C  I L  5  3  2A
24. E  E0 cos  kz   t  i
 6  108
k  2
Vwave 3  108
P02 V
25. I
2B
P02  340
102 
2  1.6  105
320 160
P0  
34 17
P0  3
p 2 hc hc h2
26.     
2m   2m 2
h 6.60  1034 11
  31
  1011 m  1.2 pm
2mc 2  9.1  10  3  10 91
8

27. Consider prism of mass 4 m by joining 4 prism given in question.Total MOI of this system will be

 4m   
2
2a ma 2
I   4I prism    I prism 
6 3
28.   R Th. C, R Th is the Thevenin’s resistance at the capacitor terminals.
R Th  8  (20 (9  (70 30))  20 k
  0.12 s
2T cos 
29. h  59.6mm
 rg
Here h is greater than protruding part of tube hence water will rise to maximum length of tube such
hr
that radius of meniscus is given by R 
l
30. White spot on screen would be central maxima
Where
d d 3d
x  0 y   
2 8 8

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CHEMISTRY
31. As 'q' is noble gas, p, r and s having atomic number Z-1, Z+1 and Z+2 should belong to halogen,
alkali metal and alkaline earth metal respectively. As halogen has one electron less than stable noble
gas configuration it has greater tendency to accept an additional electron forming anion. Alkaline
earth metal having valence shell configuration ns2 exists in +2 oxidation state.
32. VA group hydrides: (a) reducing properties increases down the group.
(b) Basic nature decreases down the group.
(c) Thermal stability decreases down the group.
(d) Bond angles decreases down the group.
34. Mn2O7: multiple bonds

AgNO 3   Ag   NO 2   O 2 
 5  6   7 
V O  Cr2 O  Mn O 4

2
2
7
When I is oxidized by MnO4 in alkaline medium, I converts into IO3
37. Conceptual
38. Yellow coloured solution of metal ion belonging to basic radicals of group-III → Fe³ is metalion
Fe+3 + SCN– → [Fe(SCN)2]+ (Red solution) + other species
Fe+3 + C2O42– → [Fe(C2O4)3] (stable complex)
Fe3+ + F– → [FeF6]3- (stable complex)
F- and C2O42– are stronger ligand than SCN–.
Hg2+ forms stable complex with SCN–
39. Conceptual
41. X = 1-Bromo 1,2-dimethylcyclopentane, Y= 1,2 -dimethylcyclopentene,
Z = Heptane -2,6 –dione
43. Decarboxylation of betaketo acid after ester hydrolysis
44.
CH 3
N
3 2
N

N (CH 3 )2 CH 3
N

1 2

46. Initial volume of gas  1000  VO 2

x
Final volume of gas  1000  VO2 
2
 vol of CO  20ml
47. Freezing is exothermic process. The heat released increases the entropy of surrounding.
48. Psolution  160
Solution have positive deviation from Raoult’s law.
Ptotal  200  0.5  100  0.5  150
G m ix  0 Vmix  0 H mix  0
Ssurr  0
49. Justification: K increases with increase in temperature.
Q > K, Therefore, reaction proceeds in the backward direction.
∆n > 0, Therefore, ∆S > 0.
50. Conceptual
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51. Two cis, one trans
52. Conceptual
53. Conceptual
55.

56. III, V & VI are less reactive

 B  3k1  3   at any time
57.  
C 8k1 8
C  8k1  8   at any time
 
 D 7.5k 2 7.5
   0.4
n1 3n 2 n
58.  0.8   2
2000 8000 4000
n  0.8 5n 2
 1 
2000 8000
n 5
 1 
n 2 4  0.8
n 5 5
 1  
4n 2 16  0.8 12.8
P1V1 P2 V2 T 6
59.   2 
T1 T2 T1 3
 T P
S  2.303  n CP log 2  R log 1 
 T1 P2 
S  27.22 J / K / mole
60. pH of HOCl  2.85
But,  pH  log  H  
2.85  log  H  
3.15  log  H  
For weak mono basic acid  H +   K a  C

1.413  10 3 
2 2
 H  
Ka  
C 0.08
 24.957  10  2.4957  105
6

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MATHS
61. Since  0, 0   R, R is not reflexive, we have
z1  z2
 z1 , z2   R  is real
z1  z2
z2  z1
 is real   z2 , z1   R
z1  z2
Therefore R is symmetric,
Since  0, z   R and  z , 0   R , but  0, 0   R there fore R is not transitive. Hence R is not an
equivalence relation.
63 Suppose that   2    2  x 2     2  x  1  0
For all real x,
 2    2  0 and    2   4   2    2   0
2

   2    1  0 and 5 2  8  4  0
2    1 and    2  5  2   0
2
2    1 and 2   
5
These inequalities imply
 2
   2, 
 5
64. Note that every solution of f  x   x is also a
solution of f  f  x    x
f  x   x  x 2  4 x  3  0  x  3 or 1
Therefore, 3 and 1 are roots of f  x   x , also
f  f  x    x   x 2  3 x  3  3  x 2  3 x  3  3  x
2

 x 4  6 x3  12 x 2  10 x  3  0
Since 3 and 1 are roots of f  x   x , then are roots of
f  f  x    x also and therefore.
f  f  x    x   x  3 x  1  x 2  2 x  1   x  3 x  1
3

Therefore 3, 1, 1, 1 are solutions of f  f  x    x . Hence

The number of arrangements of the solutions is
4!
4
3!
3 n 2n  4
66. e  1 
1 n n 1
Put n  48
10
e is a rational number
7
x2 y 2
 1
49 51
2b 2 102
l 
a 7

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69. Let
tan x cot x
t dt
F  x   dt  
1/ e
1 t 2
1/ e t 1  t
2
 
Then
 tan x  2 1
F ' x    sec x 
 1  tan x 
2
cot x 1  cot x 
2   cos ec 2 x 

 tan x  1/ cot x  =0

Therefore F is a constant function. Now
 
1 1
t 1
F   dt   dt
 4  1/ e 1  t 1/ e t 1  t 
2 2

1
t2 1
 dt   log e t 1/ e
1

1/ e t 1  t 
2

= 0   0  log e e  =1
Hence F  x   1
70. The two curves intersect at  4, 4  which is a vertex of the given square. Therefore
4
Required area (Shaded portion ) =  2 x
1
4
x2 2 1
  dx   2  1  1 = 2   x 3/ 2    x3   1
4 4

1
4 3 1 12 2

Y
(1,4)
(4,4)
y2  4x

x2  4 y
(1,1)
(2,1)
O 1 2 4 X
4 1 28 56 112  56  12
  8  1   64  8   1 =   1 
3 12 3 12 12
44 11
 
12 3
71. The given equation is
dy
sec 2 y  x  2 tan y   x3
dx
Put tan y  z , Therefore
dz
  2 x  z  x3 (Linear in z)
dx
The integrating factor is
I.F = e 
2 xdx 2
 ex
Therefore
ze x   x 3e x dx  c
2 2

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1 2 x2
  x 2 e x xdx  c  x e  2 x  dx  c
2
2

1 1
  tet dt  c where t  x 2  et  t  1  c
2 2
1 x2 2
 e  x  1  c
2
So
1
tan y   x 2  1  ce x
2

2
The curve passes through  0,  / 4  . This implies
1 3
1  c  c 
2 2
1 2 3  x2
Therefore tan y   x  1  e
2 2
72. 3  a 2  b 2  c 2  1  2  a  b  c  ab  bc  ca   0

 a  1   b  1   c  1   a  b    b  c    c  a   0
2 2 2 2 2 2

 a=b=c=1
73. Let a1 , a2 , a3 , a 4 be the coefficients of rth,  r  1 th ,  r  2  th and  r  3 th terms, respectively.
Then
a1  n Cr 1 , a2 n Cr , a3  n Cr 1 , a4 n Cr  2
We know that
n
CK n  K 1
n

CK 1 K
Therefore
a2 n  r  1 a n 1
  1 2 
a1 r a1 r
a3 n  r a n 1
  1 3 
a2 r  1 a2 r  1
a4 n  r  1 a n 1
  1 4 
a3 r 1 a3 r  2
And hence
a1 a3 r r2  r 1   a2 
    2   2 
a1  a2 a3  a4 n  1 n  1  n 1   a2  a3 

74.  x   x 
2 2
 2 x1 x j  300;
x 2
1
 30
1 i
10
2
x12  x1 
   ;   30  25  5
10  10 
75. (A) tan 2   sin  cos   sin   cos 3 
 (1  sin 2  )  (1  3sin 2  )  3sin 4   sin 6 
 cos 2   (1  sin 2  )3  cos 2   cos 6   cos 2   sin 2   1
(B) sin 400  sin(600  200 )
3 1
2sin 200 cos 200  cos 200  sin 200
2 2

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4cos 20  3 cot 20  1
0 0

3  cot 760 cot160 3sin 760 sin160  cos 760 cos160

(C) 
cot 760  cot160 sin(760  160 )
2sin 760 sin160  cos(760  160 ) cos 600  cos 920  cos 600 1  cos 920
    tan 460  cot 440
sin(76  16 )
0 0
sin 92 0
sin 92 0

   2  2  
(D) sin 2    sin 2    ....  sin   = 5
 18   18  2
76. We have
k 3  1  k  1  k  k  1  k  1   
2
k 2  k 1
     
k 3  1  k  1  k 2  k  1  k  1    k  12   k  1  1 
For k  2,3,.............n Therefore
 2 1 3 1 4 1 n  2 n 1   7 13 21 n2  n  1 
Pn   , , ..... .    . . ......... 
 2 1 3 1 4 1 n n 1  n  1   n  1  1 
2
 3 7 13
1 2 3 n  2 n  1   7 13 21 n2  n  1 
=  . . ..... .   . . ..... 
3 4 5 n n  1   3 7 13  n  1   n  1  1 
2

 2   n2  n  1  2  1 
      1  
 n  n  1   3  3  n  n  1 
2 2
Therefore lim Pn  1  0  
n  3 3
3
77. We have seen that x is not differentiable at x  0 , Whereas x is differentiable at x  0 . Also
2
x  x 2 is differentiable for all real x. If a2  0 , then
f  x   a0 x  a1 x  a3
3 2

Is differentiable at x  0 . Conversely, if f  x  is differentiable at x  0 , then

a2 x  f  x   a0 x  a1 x  a3
3 2

Is differentiable at x  0 which is possible when a2  0

78. Let n  X  denote the number of elements in X
Then,
n  A  B  C   n  A  n  B   n  C   n  A  B 
n  B  C   n  C  A  n  A  B  C 
 n  A   n  A  B 
(since A  B  C   )
Now
AB   A  B    B  A    A  B    A  B 
Therefore
n  AB   n  A  B   n  A  B 
n  A   n  B   2n  A  B 
And
300  n  AB     n  A   n  B   2n  A  B    2 n  A   n  A  B  
Therefore n  A  B  C   n  A   n  A  B   300 / 2  150

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79.

80.

81.
B  0, 2
A  0,1
yx

A ' 1, 0
PA  PB will be minimum
Where A and A ' are mirror image
A ' , P, B are collinear equation of line A ' B : 2x+y=2 Solve A ' B with y =x
2 2
x  , y 
3 3
2
 P  1  i 
3
k  2

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82. Number of ways to distribute at least one toy to each 141 C31 13 C2  78
If toys are distributed in the following way then two will get equal number of toys
No.of ways
3!
1 1 12  3ways
2!
2 2 10 3 ways
338 3 ways
446 3 ways
554 3 ways
662 3 ways
 Required number of ways = 78-18= 60
83.

84. Differentiating the given function we have

2
f '  x   x 2/3   x  1 x 1/3
3
3x  2  x  1 5 x  2
 
3 x1/3 3 x1/3
Now f '  x   0  x  2 / 5 . Also f  x  is defined and continuous at x  0 , f is not differentiable
at x  0 . Thus, zero is a critical point. Therefore, 0 and 2/5 are critical points of f  x 
(i) x  0  f '  x   0 and x  0  f '  x   0 . Therefore at x  0 , f is maximum and the
maximum value = f  0   0
ii) x  2 / 5  f '  x   0 and x  2 / 5  f '  x   0 . Thus f is minimum at x  2 / 5 and the
minimum value
1/3
2 3 4 
f    
5 5  25 
86. Let the equation of the line L, by hypothesis, be y  2  m  x  8 
Where m  0 . Therefore
 2 
p   8  , 0  and Q   0, 2  8m 
 m 
Now,

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 2
OP  OQ   8     2  8m  m  0 
 m
2  2
10    8m   10  2   8m 
m  m
 10  8  AM  GM 
And equality occurs if and only if
2 1
  8m or m  
m 2
Hence, the absolute minimum of OP  OQ is 12 + 6 = 18
87.

88.

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5x  7
8 6
5 x 6  7 x 8
89.  14  1 1  dx    1 1 2 dx
x  5  7  2 2 5  7 
x x   x x 
1 1
Put 2  5  7  t
x x
 5 x  7 x  dx  dt
6 8

 dt 1
  c
t2 t
x7
f  x  7 c
2 x  x2  1
1
f  0   0  C  0  f 1  k 4
4
90. 6  x 2  3ax  2a 2 
= 6  x  a  x  2a  ; a  0
x = a is point of maxima
x = 2a is point of minima
 a 2  2a
 a  0 or a  2
But a  0  a  2

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