Chemistry XII Practice Paper BOOK 2

Class XII Chemistry 2023-24
Practice Papers NCERT BOOK PART 2
Set 01
Class: XII Chemistry Practice paper BOOK 2 MM 33
Chapter MCQ VSA I SA I Case LA Total

S.No A/R Based
1 1 2 3 Marks 4 5
Marks Marks Marks Marks Marks
6 Haloalkanes and 1(1) 5(1) 6(2)

Haloarenes
7 Alcohols, Phenols and 1(1) 2(1) 3(1) 6(3)

Ethers
8 Aldehydes, Ketones and 1(1) 3(1) 4(1) 8(3)

Carboxylic Acids
9 Amines 1(1) 2(2) 3(1) 6(4)
10 Biomolecules 2(2) 2(1) 3(1) 7(4)
Total 4(4) 4(4) 4(2) 12(4) 4(1) 5(1) 33(16)
Set 01
Practice Paper BOOK 2 (2023-24)
MM:33 CHEMISTRY THEORY (043) Time: 1 ½ hours
SECTION A
Compiled by Vijay Kumar Sethi 9461169967 Page 1 of 82

The following questions are multiple-choice questions with one correct answer. Each question carries
1 mark. There is no internal choice in this section.
1 Which reagent will you use for the following reaction? 1
CH3CH2CH2CH3 → CH3CH2CH2CH2Cl + CH3CH2CHClCH3
(a) Cl2/UV light (b) NaCl + H2SO4
(c) Cl2 gas in presence of Fe in dark (d) Cl2 gas in dark
2 Phenol is less acidic than 1

(a) Ethanol (b) o-nitrophenol (c) o-methylphenol (d) o-methoxyphenol
3 Which out of the following reactions need α-H atom to get started? 1
(a) Etard reaction (b) Cannizaro’s reaction
(c) Aldol condensation (d) HVZ reaction
4 Hoffmann Bromamide Degradation reaction is shown by 1

(a) ArNH2 (b) ArCONH2 (c) ArNO2 (d) ArCH2NH2
In the Following questions a statement of Assertion(A) is followed by a statement of Reason(R). Select
the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
5 Assertion (A): Aromatic 1o amine can be prepared by Gabriel pthalamide synthesis. 1
Reason (R): Primary Alkylhalide undergoes nucleophilic substitution reaction with anion
formed by pthalamide.
6 Assertion (A): Nitration of aniline can be conventionally done by protecting the amino group 1
by acetylation.
Reason (R):Acetylation increases the electron density in benzene ring.
7 Assertion (A):Sucrose is a non-reducing sugar. 1

Reason (R):In sucrose, the aldehydic group of glucose and ketonic group of fructose are
involved in glycosidic linkage.
8 Assertion (A): D-(+)-Glucose is dextrorotatory in nature. 1

Reason (R): D-(+) Glucose rotates the plane polarised light in clockwise direction.
SECTION B
The following questions are very short answer type and carry 2 marks each.
9 Arrange the following sets of compounds in order of their increasing boiling points:
(a) Pentan-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol.
(b) Pentan-1-ol, n-butane, pentanal, ethoxyethane. 2
OR
Explain the mechanism of the acid catalysed hydration of ethene.
10 What happens when D-glucose is treated with the following reagents? 2

(i) HI (ii) Bromine water
SECTION C
The following questions are short answer types and carry 3 marks each.
11 How will you convert the following in not more than two steps: 3

(i) Benzoic acid to benzaldehyde
(ii) Acetophenone to benzoic acid
(iii) Ethanoic acid to 2-hydroxyethanoic acid
12 Give reasons for the following: - 3

(a) Alcohols are more soluble in water than the hydrocarbon of comparable molecular
masses.
(b)Phenoxide ion is more stable than phenol.
(c) Ortho nitro phenol is more acidic than Ortho-methoxyphenol.
OR
Write Short notes on the following reactions
(a) Williamson Synthesis
(b) Reimer Tiemann
(C)Kolbe’ Reaction
13 Arrange the following: 3

(i) CH3NH2, (CH3)2NH, NH3, (CH3)3N [decreasing order of basic strength in gaseous
phase]
(ii) C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH [increasing order of
basic strength]
(iii) C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2 [Increasing order of
basic basic strength]
14 Give answer for the following: 3

(i) Give one structural difference between amylose and amylopectin
(ii) Name the protein and its shape present in the oxygen carrier in the human body.
(iii) What type of linkage is present in proteins?
SECTION D
The following questions are case-based questions. Each question has an internal choice and carries 4
(1+1+2) marks each. Read the passage carefully and answer the questions that follow.
15 Read the passage given below and answer the following questions:
The carboxylic acids evolve hydrogen with electropositive metals and form salts with 4
alkalies. Carboxylic acids also react with weaker bases such as carbonates and
hydrogencarbonates to evolve carbon dioxide. Carboxylic acids dissociate in water to
give resonance stabilized carboxylate anions and hydronium ion. The strength of an
acid is generally indicated by its pKa value rather than its Ka value. Smaller the pKa, the
stronger the acid (the better it is as a proton donor).
Electron withdrawing groups increase the acidity of carboxylic acids by stabilising
the conjugate base through delocalisation of the negative charge by inductive
and/or resonance effects. Conversely, electron donating groups decrease the
acidity by destabilising the conjugate base
Answer the following questions:
(a) Give a chemical test, based on acidic nature, to distinguish between phenol and
benzoic acid
(b)Out of chloroacetic acid and acetic acid which one is stronger acid and why?
(c)Arrange the following compounds in increasing order of acid strength
(i)CH 3 C H 2 CH ( Br ) COOH , CH 3 CH ( Br ) C H 2 COOH , ¿ ¿, CH 3 CH 2 CH 2 COOH
(ii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-

Methoxybenzoic acid
OR
(c)Carboxylic acids are stronger acids compared to phenols. Explain
SECTION E
The following questions are long answer type and carry 5 marks each.
16 (i) Among all the isomers of molecular formula C4H9Br, identify-
(a) the one isomer which is optically active. 5
(b) the one isomer which is highly reactive towards SN2.
(c) the two isomers which give the same product on dehydrohalogenation with
alcoholic KOH.
(ii) Give IUPAC the name of the following organic compounds:
OR
What happens when-
(i) n-butyl chloride is treated with alcoholic KOH,
(ii) bromobenzene is treated with Mg in the presence of dry ether,
(iii) chlorobenzene is subjected to hydrolysis,
(iv) ethyl chloride is treated with aqueous KOH,
(v) methyl bromide is treated with sodium in the presence of dry ether.
MARKING SCHEME: PRACTICE PAPER BOOK 2 SET-1

1 2 3 4 5 6 7 8
a b c b d c a a
Q. Value Point/ Expected Answer Marks

No.
9 (a) Methanol, ethanol, propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol. 1

(b)n-Butane, ethoxyethane, pentanal and pentan-1-ol. 1
OR + ¿¿
+¿∨ H ¿
Step 1: Protonation of ethene to form carbocation by electrophilic attack of H 3 O .
10 (i) n-Hexane, (ii)Gluconic acid 1

1
11
12 (a)Alcohols have hydrogen bonding whereas hydrocarbons have weak vander waal‘s force of attraction. 1
(b) Phenoxide ion is stabilised by the delocalization of negative charge caused by the benzene ring's
resonance. While in phenol charge separation occurs during resonance. 1
(c)Ortho nitrophenol is more acidic due to electron withdrawing effect of nitro group which facilitates
release of proton.
1
OR
(a) an alkyl halide is reacted with sodium alkoxide to form ether.
1
1
(b) On treating phenol with chloroform in the presence of sodium hydroxide, a –CHO group is
introduced at ortho position of benzene ring. 1
(c) Sodium phenoxide undergoes electrophilic substitution with carbon dioxide, a weak electrophile.
Ortho hydroxybenzoic acid is formed as the main reaction product.
13 (i) (CH3)3N > (CH3)2NH >CH3NH2> NH3 1

(ii) C6H5NH2< NH3< C6H5CH2NH2< C2H5NH2< (C2H5)2NH
1
(iii) C6H5NH2< C6H5N(CH3)2< CH3NH2< (C2H5)2NH
1
14 (i) Amylose is a long unbranched chain polymer of α -D(+) glucose. Amylopectin is a branched 1
chain polymer of α -D(+) glucose. Amylose is water soluble, Amylopectin is insoluble in water 1
(any one) 1
(ii) Globular protein (haemoglobin) and its shape are spherical.
(iii) Peptide linkage
15 (a) Benzoic acid gives effervescence of CO 2 when treated with NaHC O3 while phenol does 1
not.
1
(b)Chloroacetic acid is stronger acid. Because of -I effect of Cl .
2
(c)(i) ¿ ¿, CH 3 CH 2 CH 2 COOH , CH 3 CH ( Br ) C H 2 COOH , CH 3 C H 2 CH ( Br ) COOH
(ii) 4-Methoxybenzoic acid, Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid

OR
(c) The conjugate base of carboxylic acid, a carboxylate ion, is stabilised by two equivalent
resonance structures in which the negative charge is at the more electronegative oxygen
atom.
The conjugate base of phenol, a phenoxide ion, has resonance structures in which the
negative charge is at the less electronegative carbon atom
16 1
1
1
1x5
OR

Set 02
Class: XII Chemistry Practice paper BOOK 2 MM 33

UNI
T
NO
NAME OF UNIT MCQ 1 AR SA1 SA II CB LA WT
5
1 2 3
9 Halo-alkanes and 1(1) 2(1) 3(1) 6(3)

6 Halo-arenes
7 Alcohols, Phenols 1(1) 5(1 6(2)

and Ethers )
8 Aldehydes, Ketones 2(2) 6(2) 8(4)

and Acids
9 Amines 1(1) 2(2) 3(1) 6(4)
10 Biomolecules 2(2) 2(1) 3(1) 7(4)
TOTAL 5(5) 4(4) 4(2) 15(5) 5(1) 33(17)
Set 02
—--------------------------------------------------------------------------------------------------------------------------------
SECTION A

The following questions are multiple -choice questions with one correct answer. Each question
carries 1 mark. There is no internal choice in this section.
1. Ethylidene chloride is a/an ______________.

(a) vic-dihalide (b) gem-dihalide (c) allylic halide (d) vinylic halide
2. The IUPAC name of m-cresol is ___________.
(a) 3-Methylphenol (b) 3-Chlorophenol (c) 3-Methoxyphenol (d) Benzene-1,3-diol
3. In the nitration of benzene using a mixture of conc. H2SO4 and conc. HNO3, the species which
initiates the reaction is __________.
+¿¿ −¿¿
(a) NO 2 (b) NO +¿¿ (c) NO 2 (d) NO 2
4. Nucleic acids are the polymers of ______________.
(a) Nucleosides (b) Nucleotides (c) Amino acids (d) Monosaccharides
5. Which of the following statements is not true about glucose?
(a) It is an aldohexose. (b) On heating with HI, it forms n-hexane.
(c) It is present in furanose form. (d) It does not give 2,4-DNP test.
Select the most appropriate answer from the options given below:
6. Assertion(A) :Benzoic acid does not undergo Friedel-Crafts reaction.
Reason(R): carboxyl group is deactivating and the catalyst aluminium chloride (Lewis acid)
gets bonded to the carboxyl group.
7. Assertion(A) : Benzaldehyde is more reactive in nucleophilic addition reactions than
propanal.
Reason(R): The polarity of the carbonyl group attached to benzene ring is reduced in
benzaldehyde due to resonance.
8. Assertion(A) : Acetanilide is more basic than aniline.
Reason(R): Acetylation of aniline results in decrease of electron density on nitrogen.
9. Assertion(A) : Hoffmann’s bromamide reaction is given by primary amines.
Reason(R): Primary amines are more basic than secondary amines.
SECTION B
10. Give reasons:
(i) The presence of nitro group (-NO2) at o/p positions increases the reactivity of haloarenes
towards nucleophilic substitution reactions.
(ii) Grignard’s reagents should be prepared under anhydrous conditions.
11. Explain what is meant by

(i) a peptide linkage (ii) a glycosidic linkage.
SECTION C
The following questions are short answer type and carry 3 marks each.
12. How will you distinguish between
(i) Propanal and propanone
ii) Propanone and ethanal
iii) Ethanoic acid and methanoic acid
13. Explain the following reactions with one chemical reaction
(i) Cannizaro reaction
(ii) Aldol condensation reaction
14. (a) Why is the -NH2 group of aniline acetylated before carrying out nitration?
(b) Write the name and structure of the product when CH3NH2 reacts with HNO2?
(c) What is the best reagent to convert Nitrile to primary Amines?
15. (i)Write the chemical reaction of glucose which indicates the presence of straight chain of six
carbon atoms in it.
(ii)How amino acid act as zwitter ion? Explain.
(iii) Name the amino acid which is optically inactive.
16. What happens when?
(a) n-butyl chloride is treated with alcoholic KOH
(b) methyl bromide is treated with sodium in the presence of dry ether
(c) methyl chloride is treated with KCN
SECTION D
The following questions are long answer-type and carry 5 marks each. All questions have an
internal choice.
17. (a) Give reasons for the following-

i) Phenol is more acidic than methanol.
ii) Cumene is a better starting material for the preparation of phenol.
(b)Give simple chemical test to distinguish between-
i) Ethanol and phenol ii)butan-1-ol and butan-2-ol
(c) What happens when phenol is treated with conc. HNO3
OR
(a) Write the mechanism of acidic dehydration of ethanol at 413K.
(b) How will you convert-
(i) Phenol to benzene (ii) Propanone to tert-butyl alcohol
MARKING SCHEME Practice paper NCERT BOOK 2

Set 2
1 2 3 4 5 6 7 8 9
B A C B C A D D C
Q.NO ANSWERS/ HINTS MARKS

10 (i) The presence of nitro group (-NO2) at ortho and para positions withdraws the
electron density’ from benzene ring and thus facilitating the attack of nucleophile. 1
(ii) Grignard’s reagents are very reactive. They react with alcohol, water, amines
etc. to form corresponding hydrocarbon.
R-MgX + HOH → RH + Mg(OH)X 1
Therefore, Grignard’s reagents must be prepared under anhydrous conditions.
11 (i) Peptide linkage: A peptide linkage is an amide linkage formed between – COOH 1
group of one α-amino acid and NH2 group of the other a-amino acid by loss of a
molecule of water.
(ii) Glycosidic linkage : The two monosaccharide units are joined together
through an ethereal or oxide linkage formed by loss of a molecule of water. Such a 1
linkage between two monosaccharide units through oxygen atom.
12 a) Propanone will give iodoform test 1+1+1

b) Aldehyde will give silver mirror with tollens reagents
c) Acetic acid will not give silver mirror test
13 i) Aldehydes which do not have alpha hydrogen Reacts with alkali and give 1.5
alcohols and acids. One chemical reaction 1.5
ii) Aldehydes and ketones having alpha hydrogen give aldols and then enals,
when reacts with alkali. One chemical reaction
14 a) by acetylation we can control the reactivity of aniline so that only mono 1

product is formed. 1
b) Methanol, CH3OH 1
c) LiAlH4
15 i )C 6 H 12 O6+ HI ∆ CH 3 CH 2 CH 2 CH 2 CH 2 CH 3 (n-hexane) 1
→
1
ii) In aqueous condition it form NH3+ and COO- ions which both acidic as well as
basic nature and form zwitter ions.
1
iii) glycine
16 The following major products are formed 1x3

(a) But-1-ene (b) Ethane (c) Ethanenitrile
17
a) i) Phenoxide ion is more stable due to resonance than alkoxide ion. 2
ii) It forms a useful byproduct acetone.
b)i) FeCl3gives violet colour with phenol but not with ethanol. 2
ii)Butan-2-ol gives positive iodoform test .
c) 2,4,6 tri nitro phenol is formed( Or Chemical equation) 1

OR a) Three steps(1 mark for each step)
1x3
2
i) Reaction of phenol with Zn dust to form benzene
ii) Reaction of propanone with CH3MgBr followed by hydrolysis
PRACTICE PAPER NECRT BOK 2 SET-3

BLUE PRINT
S.No Name of Chapter MCQ A/R SA1 SA2 Case LA Total

. Base
1 1 2 3 4 Mark 5
mark Mark Mark mark mark
6 Haloalkanes and haloarenes 1(1) - 2(1) 3(1) - 6(3)
7 Alcohols, Phenols and Ethers 1(1) 2(2) 3(1) - 6(4)
8 Aldehydes, Ketones and Carboxylic 1(1) 2(2) - 5(1) 8(4)
acids
9 Amines 1(1) 2(1) 3(1) - 6(3)
10 Biomolecules 2(2) 2(1)) 3(1) - 7(4)
Total 6(6) 4(4) 6(3) 12(4) 5(1) 33(18)
Set 03
SECTION-A
1 Which of the following is not chiral? 1
(a) 2-Hydroxypropanoic acid (b) 2-Butanol
(c) 2-bromo-3- chlorobutane (d) 3- Bromopentane
2 Methyl ketones are usually characterized through-- 1

(a) Tollen’s reagent (b) Iodoform test
(c) Schiff’stest (d) Benedict solution test.
3 Benzoic acid is treated with SOCl2 and the product (X) formed is heated with ammonia 1
to give (Y). (Y) on reaction with Br2 and KOH gives (Z). (Z) in the reaction is –
(a) aniline (b) chlorobenzene (c) benzamide (d) benzoyl chloride
4 Each polypeptide in a protein has amino acids linked with each other in a specific 1
sequence and it is a sequence of amino acids that is said to be the---
a) primary structure of that protein
b) secondary structure of that protein.
c) tertiary structure of that protein.
d) quaternary structure of that protein.
5 Which of these cyclic structures of monosaccharides are anomers? 1
(a) I and III (b) II and III (c) I and II (d) none
6 The system that forms maximum boiling azeotrope is— 1

(a) Acetone-chloroform (b) ethanol-acetone
(c) n-hexane-n-heptane (d) carbon disulphide-acetone
Assertion-and-Reason Type Questions:
Each question consists of two statements, namely, Assertion (A) and Reason (R). For
selecting the correct answer, use the following code:
(a) Both Assertion (A) and Reason (R) are the true and Reason (R) is a correct explanation
of Assertion (A).
(b) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a correct
explanation of Assertion (A).
(c) Assertion (A) is true and Reason (R) is false.
(d) Assertion (A) is false and Reason (R) is true.
7 Assertion: t-Butyl ethyl ether is not prepared by the reaction of t-butyl bromide with 1
sodium ethoxide.
Reason: Sodium ethoxide is a strong nucleophile as well as strong base.Thus
elimination reaction pre-dominants over substitution.
8 Assertion : Phenol is less acidic than 4-Nitrophenol. 1

Reason : Phenoxide ion is more stable than 4-nitrophenoxide ion.
9 Assertion : Acetophenone and benzophenone can be distinguished by iodoform test. 1

Reason : Acetophenone has CH3CO group, Thus it react with NaOH and I2 gives yellow
ppt of iodoform but benzophenone does not contain CH3CO group .
10 Assertion : Propanal on treatment with aqueous NaOH gives aldol. 1
Reason : Propanal molecules contains  hydrogen atom.
SECTION-B
11 (i) Name any two bases which are common to both DNA and RNA 2
(ii) Which vitamin deficiency causes:
a) bone deformities in children
b) pernicious anemia
OR
(i)Why do amino acids show amphoteric behavior?
(ii)What happen when D-Glucose is treated with hydroxylamine?
12 An alkyl halide (A) of molecular formula C6H13Cl on treatment with alcoholic KOH 2
gives two isomeric alkenes (B) and (C) of molecular formula C 6H12. Write the structure
of (A), (B) and (C).
13 Arrange the following: 2

(a)In increasing order of their basic strength
C6H5—NH2, CH3—CH2—NH2, CH3—NH—CH3
(b)In increasing order of solubility in water
CH3—NH2, (CH3)3N, CH3—NH—CH3
SECTION-C
14 How do you convert the following? 3
a) Phenol to anisole
b) Propan-2-ol to 2-methylpropan-2-ol
c) Aniline to phenol
15 a) Draw the pyranose structure of glucose. 3
b) What type of linkage is present in proteins?
C)Give one example each for water-soluble vitamins and fat-soluble vitamins.
16 Account for the following: 3
a) pKbof aniline is more than that of methylamine.
b) Ethylamine is soluble in water, whereas aniline is not.
c) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric
oxide.
17 Following compounds are given to you: 3

2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane
a)Write the compound which is most reactive towards SN2 reaction.
b) Write the compound which is optically active.
c) Write the compound which is most reactive towards β-elimination reaction.
SECTION-D
18 An organic compound A which has a characteristic odour on treatment with conc. 5
NaOH forms two compounds B and C. Compound B has a molecular formula C7H8O
which on oxidation gives back compound A. Compound C is sodium salt of acid. C
when heated with soda lime yields an aromatic hydrocarbon D. Deduce structures A-
D . Write appropriate chemical equations.
OR
a)Give Reasons: -
1. Carboxylic acid is stronger acid than phenol.
2. Ethanol is more soluble in water than ethyl chloride
2
b) Write the following name reactions:
3
(i) Aldol Condensation (ii)Stephen Reaction (iii)Hell Volhard Zelinsky Reaction
Practice paper NCERT BOOK 2 Set 3 (2023-24)

Answer Key
1 2 3 4 5 6 7 8 9 10
D B A A C A A C A A
Q.NO ANSWER MARKING

.
11 (i) Adenine, Guanine, Cytosine (any two) ½+½
(ii) a) Vitamin D ½
b) Vitamin B 12 ½
OR
a) due to the presence of both acidic and basic group in the same 1
moleculke/ they form zwitter ion
b)
1
12 1+1
13 1
a) C6H5−NH2,CH3−CH2−NH2,CH3−NH−CH3
b) (CH3)3N<(CH3)2NH<CH3NH2 1

14
1
15
1
16 (i) In aniline due to resonance, the lone pair of electrons on the N-atom 1
are delocalised over the benzene ring. Due to this, electron density on
the nitrogen decreases. On the other hand, in CH3NH2, +I-effect of
CH3 increases the electron density on the N-atom. Consequently
aniline is a weaker base than methylamine and hence its pKb value is
higher than that of methylamine. 1
(ii) Ethylamine dissolves in water because it forms H-bonds with water
molecules 1
(iii) Methylamine being more basic than water, accepts a proton from
water, liberating OH– ions.
17 (i) 1-Bromopentane, it is primary halide therefore undergoes SN2 reaction 1
faster.
(ii) 2-Bromopentane as carbon number two is symmetric carbon. 1
(iii) 2-Bromo-2-methyl butane, because tertiary alkyl halides on
dehydrogenation form most substituted 1
alkene which is more stable.

18 C6H5CHO NaOH C6H5CH2OH+C6H5COONa 1x5
→
(A) (B) (C)Sodium salt of Benzoic acid
C6H5CH2OH PCC
→
C6H5CHO
(B) (A)
C6H5COONa NaOH→/CaO C6H6+Na2CO3

(C) (D)
OR
a)
i). Carboxylic acid on dissociation form carboxylate ion which is stabilized by
1
two equivalent resonance structure in which negative charge is at the more
electronegative oxygen atom, whereas the conjugate base of phenol, phenoxide
ion, has non – equivalent resonance structures in which negative charge is at
the less electronegative carbon atom. Therefore, resonance is not as important
as it is in carboxylate ion. Moreover, the negative charge is delocalized over two
more electronegative oxygen atoms in carboxylate ion whereas it is less
effectively delocalized over one oxygen atom and one carbon atom in phenoxide
ion. Therefore, the carboxylate ion is more stabilized than phenoxide ion and
carboxylic acids are stronger acids than phenol.
ii). Ethanol can form intermolecular Hydrogen bonding with water molecules,
ethyl chloride cannot. Therefore, ethanol is soluble in water and ethyl chloride
is not.
1
b) i) Aldol condensation: The aldol and ketol readily lose water to give α,β-
unsaturated carbonylcompounds which are aldol condensation products and the
reaction iscalledAldol condensation 1
CH3CHO NaOH / H 2O CH3CH=CHCHO
→
ii)Nitrilesarereduced tocorrespondingiminewithstannous chloridein the presence of

hydrochloric acid, which on hydrolysis givecorrespondingaldehyde.
ThisreactioniscalledStephenreaction.
SnCL2
RCN + 2[H] dil HClRCH=NH.HCl H 3 O+ →¿ ¿ RCHO + NH4Cl 1
→
(iii)Hell Volhard Zelinsky Reaction: Carboxylic acids having an α-hydrogen are

halogenated at the α-
positionontreatmentwithchlorineorbromineinthepresenceofsmallamount of red
phosphorus to give α-halocarboxylic acids. The reactionisknown as Hell-Volhard- 1
Zelinskyreaction
X2
RCH2COOH H 2 O ¿ RCH(X)COOH X IS HALOGEN GROUP
RED P II ¿ →

PRACTICE PAPER NCERT BOOK 2 SET 4
Class XII Chemistry
S.No. Name of Chapter MCQ A/R SA1 SA2 Case LA Total

Base
1 1 2 3 4 5
mark Mark Mark mark Mark mark
6 Haloalkanes and 1(1) 2(2) 3(1) 6(4)
haloarenes
7 Alcohols, Phenols and - 2(2) 4(2) - 6(4)
Ethers
8 Aldehydes, Ketones and 3(3) 2(1) 3(1) 8(5)
Carboxylic acids
9 Amines 1(1) - 5(1) 6(2)
10 Biomolecules 1(1) 6(2) 7(3)
Total 6(6) 4(4) 6(3) 12(4) 5(1) 33(18)

Set 04
SECTION A
1 Correct order of SN2 rate for the given substrate is

1. (CH3)3C-CH2-Br
2. CH3-CH2-CH2-Br
3. (CH3)2CH-CH2-Br
(a) (i)>(ii)>(iii)
(b) (i)>(iii)>(ii)
(c) (ii)>(iii)>(i)
(d) (ii)>(i)>(iii)
2 Benzaldehyde can be prepared by oxidation of toluene by
(a) Acidic KMnO4 (b) K2Cr2O7 / H+
(c) CrO2Cl2 (d) All of these
3 Which aldehyde cannot be obtained by Rosenmund’s reaction?
(a) CH3CHO (b) HCHO
(c) CH3CH2CHO (d) All of these
4 The compound that neither forms semicarbazone nor oxime is
(a) HCHO (b)CH3COCH2Cl
(c) CH3CHO (d) CH3CONHCH3
5 In the reaction sequence the product ‘C’ is:
(a) benzonitrile (b) benzaldehyde

(c) benzoic acid (d) benzylamine
6 The term anomer of glucose refers to –
(a)isomers of glucose that differ in configuration at carbons one and four (C-1 and C-4)
(b)a mixture of (D) – glucose and (L) –glucose
(c) enantiomers of glucose
(d)isomers of glucose that differ in configuration at carbon one (C-1)
Instructions for following
(a)Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are correct statements but reason is not correct
explanation of assertion
(c) Assertion is correct but reason is wrong statement.
(d) Assertion is wrong but reason is correct statement.
Assertion: KCN reacts with methyl chloride to give methyl isocyanide.
7 Reason: CN– is an ambident nucleophile
8 Assertion: 2- Bromopantane on reaction with the alcoholic KOH gives Pent -2 ene as the
Major product.
Reason: In dehydrohalogenation reactions, The preferred product is that alkene which
has the greater number of alkyl groups attached to the doubly bonded carbon atoms.
9 Assertion: Anisole reacts with HI to give phenol and iodomethane.
Reason: The –OCH3 group in anisole enriches the electron density in the ring through
Resonance and CO bond has partially double bond character in anisol.
10 Assertion: Nitro phenol has lower pKa value than phenol.
Reason: The electron withdrawing nature of the nitro group further stabilises the
phenoxide ion formed
SECTION -B
11 Predict the products of the following reactions
12 How would you obtain

(i) Ethane-1, 2-diol from ethanol?
(j) Acetophenone from phenol ?
13 Give simple chemical tests to distinguish between the following pairs of compounds:
(i) Ethanol and Phenol
(ii) Propanol and 2-methylpropan-2-ol
SECTION -C
14 (a)In the following pair of compounds, which will react faster by S N1 mechanism and
why?
(CH3)3CCl and CH3 CH2 CH(Cl)CH2CH3
(b) The C – Cl bond length in chlorobenzene is shorter than that in CH 3 – Cl explain.
(c) Chloroform is stored in closed dark brown bottles.
15 (i) Write the name of two monosaccharide’s obtained on hydrolysis of lactose sugar.
(ii) Why Vitamin C cannot be stored in our body?
(iii) What products would be formed when a nucleotide from DNA containing thymine is
hydrolysed?
16 (a)Amino acids may be acidic, alkaline or neutral. How does this happen?
(b) What is the difference between a nucleoside and a nucleotide?
(c)Write down the structures of the products formed when D-glucose is treated with
Hydroxylamine
17 Arrange the following in increasing order of the property indicated:
(a) Acetaldehyde, Acetone, Di tert. butyl ketone, Methyl tert. butyl ketone
(reactivity towards HCN)
(b) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH
(acid strength)
(c) CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3 ( boiling points)
SECTION -D
18 A hydrocarbon ‘A’, (C4H8) on reaction with HCl gives a compound ‘B’, (C4H9CI), which on
reaction with 1 mol of NH3 gives compound ‘C’, (C4H11N).On reacting with NaNO2 and HCI
followed by treatment with water, compound ‘C’ yields optically active alcohol, ‘D’.
Ozonolysis of ‘A’ gives 2 moles of acetaldehyde. Write the IUPAC name of compounds ‘A’
to ‘D’. Explain the reactions involved.
Or
(a) A primary amine, RNH2 can be reacted with CH3-X to get secondary amine, R-
NHCH3 but the
only disadvantage is that 3º amine and quaternary ammonium salts are also obtained
as
side products. Can you suggest a method where RNH2 forms only 2º amine?
(b) Arrange the following compounds in increasing order of -
(i) Dipole moment. CH3CH2CH3, CH3CH2NH2, CH3CH2OH.
(ii) Basic nature (vapour phase). NH3, H2O, CH3NH2, (CH3)3CNH2
Practice Paper NCERT BOOK 2 Set 4

Marking Scheme
1 2 3 4 5 6 7 8 9 10
c c b d d d d a a a
11 1+1
12 (i) 1+1
(ii)
13 1+1
14 (i)(CH3)3CCl is more reactive because of +I effect of 3 methyl group 1+1+1

(ii) As in chloromethane carbon holding chloride is sp hybridised, while in
3
chlorobenzene it is sp2 hybridized. The delocalisation of electrons by resonance in

chlorobenzene attribute for partial double bond character due to which bond length is
shorter than a single bond
(iii) Thus, to avoid the formation of phosgene, chloroform is stored away from light
and air. In dark coloured bottles, no light can enter. Thus, oxidation of chloroform to
phosgene can be avoided. Thus, chloroform is stored in closed dark coloured bottles.
15 (i) On hydrolysis, lactose gives β-D-galactose and β-D-glucose. 1+1+1
(ii) Vitamin C is mainly ascorbic acid which is water soluble and is readily excreted
through urine and thus cannot be stored in the body.
(iii)β-D- 2-deoxyribose, phosphoric acid and thymine.
16 (i) depending upon the relative number of amino and carboxyl groups in their 1+1+1
molecule
(ii) The main difference lies in their molecular composition as Nucleosides contain
only sugar and a base whereas Nucleotides contain sugar, base and a phosphate group
as well
(iii) D-glucose reacts with hydroxylamine to form oxime
17 (a) Di tert. butyl ketone < Methyl tert. butyl ketone < Acetone < Acetaldehyde 1+1+1
(b) (CH3)2CHCOOH< CH3CH2CH2COOH < CH3CH(Br)CH2COOH < CH3CH2CH(Br) COOH
(c) CH3CH2CH3 < CH3OCH3 < CH3CHO <CH3CH2OH
18 (1/2x4)+(1x3)
OR
(b) (i) CH3CH2CH3, < CH3CH2NH2 < CH3CH2OH. 3+1+1

(ii) H2O < NH3, < CH3NH2<(CH3)3CNH2
Practice paper NCERT BOOK 2 Set 5

SESSION -2023-24
CHEMISTRY THEORY (043)
CLASS:XII

Sr. CHAPTER NAME
MCQ ASSERTION REASON

No.
Case study (4 MARKS)
LONG ANSWER
(1 MARKS )
(5 MARKS )
(1 MARKS)
(2 MARKS)
(3 MARKS)
MARKS
TOTAL
MCQ
VSA
SA
6 HALOALKANES AND 2(2) -- -- -- 4(1) -- 6(3)
HALOARENES
7 ALCOHOLS, PHENOLS 1(1) -- 2(1) 3(1) -- -- 6(3)
AND ETHERS
8 ALDEHYDES, 2(2) -- -- 6(2) -- -- 8(4)
KETONES AND
CARBOXYLIC ACIDS
9 AMINES -- -- -- 6(2) -- -- 6(2)
10 BIOMOLECULES -- 2(2 -- -- -- 5(1) 7(3)
)
TOTAL 5(5) 2(2 2(1) 15(5 4(1) 5(1) 33(15
(MARKS ) ) )
)

Set 05
S.N. SECTION-A MARKS
8 Haloalkanes contain halogen atom attached to the sp3 hybridised carbon atom of an 1
alkyl group. Identify haloalkane from the following compounds.
(a) 2-Bromopentane (b) Vinyl chloride (chloroethene)
(c) 2-chloroacetophenone (d) chlorobenzene
9 The ether 1
when treated with HI produces
(c) (a) and (b) both (d) None of above

10 Which of the following compound (s) formed when benzyl alcohol is oxidised with 1
KMnO4?
(a) CO2 and H2O (b) Benzoic acid
(c) Benzaldehyde (d) Benzophenone
11 Chlorination of toluene in the presence of light and heat followed by treatment with 1
aqueous NaOH gives
(a) o-Cresol (b) p-Cresol
(c) 2,4-Dihdroxytoluene (d) Benzyl alcohol
12 (CH3)2C = CHCOCH3 can be oxidised to (CH3)2C= CHCOOH by 1
(a) Chromic acid (b) NaOI (c) Cu at 575 K (d) KMnO 4
Select the most appropriate answer from the options given below.
(a) Both A and R are true and R is the correct explanation of A.
13 Assertion (A): Vitamin D can be stored in our body. 1
Reason (R): Vitamin D is fat soluble vitamin.
14 Assertion (A): D (+) – Glucose is dextrorotatory in nature. 1
Reason (R): D’ represents its dextrorotatory nature.
SECTION-B
21 Out of 2-chloroethanol and ethanol which is more acidic and why? 2
SECTION-C
23 Account for the following observations: 3
(i) pKb for aniline is more than that for methylamine.
(ii) Gabriel phthalimide synthesis is preferred for synthesising primary amines
(iii) Aniline does not undergo Friedel-Craft’s reaction.
25 Perform the following conversions in not more than two steps: 3
(i) Benzoic acid to benzaldehyde
(ii) Ethyl benzene to Benzoic acid
(iii) Propanone to Propene
26 (a) Give chemical tests to distinguish between the following pairs of compounds: 3
(i) Pentan-2-one and Pentan-3-one (ii) Methanol and Phenol
(b) o-nitro phenol is steam volatile while p- nitro phenol is not. why?
27 Write the main product formed when propanal reacts with the following reagents:
(i) 2 moles of CH3OH in presence of dry HCl
(ii) Dilute NaOH
(iii) H2N – NH2 followed by heating with KOH in ethylene glycol.
28 Write the reactions involved in the following: 1+1+1=3
i) Hoffmann’s Bromamide degradation reaction
ii) Carbylamine reaction
iii) Sandmeyer reaction
Practice Paper NCERT BOOK 2 Set 5
MARKING SCHEME
CLASS XII CHEMISTRY(043)
1 2 3 4 5 6 7
A A B D A A C
S ANSWER MARKS
NO
8 The acidity of 2-chloroethanol is higher than that of ethanol. The Cl atom have
electron-withdrawing nature so it will withdraw the electron density from the O-H
bond thus making the O-H bond weak. As a result, the O-H bond of 2-chloroethanol
weakens compared to the O-H bond of ethanol. As a result, 2-chloroethanol is acidic
in comparison to ethanol.
Cl - CH2 - CH2 - O - H > CH3 - CH2 - O - H
Stronger acid due to the -I effect of Cl.
9 i) In aniline, the electron pair on nitrogen atom is involved in conjugation with ring
and is less available for protonation than in methyl amine. Therefore, pKb value of
aniline is more than that of methylamine and aniline is less basic, (As higher
the pKb value, less is the basicity)
ii) Gabriel phthalimide synthesis produces primary amines only without the traces
of secondary or tertiary amines. So, this method is preferred for the synthesis of
primary amines.
iii) Aniline being a Lewis base forms a complex with AlCl3, a Lewis acid. As a result,
nitrogen of aniline becomes positively charged and acts a strong deactivating group
for electrophilic substitution reaction. Consequently, aniline does not undergo
Friedel Crafts reaction.
C6H5.NH2Aniline(Lewis base)+AlCl3(Lewis acid)→[C6H5NH2]+[AlCl3]− (Complex)
10
11 a. i) Pentan-2-one gives iodoform test and Pentan-3-one does not gives iodoform
test.
ii) Phenol gives a violet colouration with FeCl3 solution while methanol does not.
b ) Ortho nitrophenol is more volatile than para nitrophenol because O-nitrophenol
has intramolecular hydrogen bonding whereas para nitrophenol has inter
molecular H bonding and so boils relatively at higher temperature
12 (i) When propanal reacts with excess of methanol in the presence of HCl, it 1+1+1
forms 1,1-dimethoxy propane.
(ii) Propanal having α-hydrogen atom undergo aldol condensation in presence of

dil. NaOH and forms 3-hydroxy-2-methyl pentanal.
(iii) The carbonyl group of propanal is reduced to CH2 group on treatment with
hydrazine followed by heating with KOH in ethylene glycol and the product formed
will be propane.
13 i)
ii)
iii)
14 1 CCl2F2
2 Freons can diffuse into the stratosphere and in stratosphere, freon is able to
initiate radical chain reactions by using UV rays that can upset the natural ozone
balance.
3 CFCs should be banned and its alternative should be used which would be safer
and has no environmental impact.
Hydrochloroflourocarbons and Hydroflourocarbons are some halogen containing
compounds are useful in daily life. Some compounds of this class are responsible
for exposure of flora and fauna to more and more of UV light which causes
destruction to a great extent. Name the class of these halocompounds.
OR
It is used in air conditioning and in domestic refrigeration for cooling purposes.
15 i) Enzymes
ii) Vit C
iii) Starch is a storage form of energy in plants. It contains two polymers composed
of glucose units: amylose (linear) and amylopectin (branched). Glycogen is a
storage form of energy in animals. It is a branched polymer composed of glucose
units.
iv) peptide linkage
v) Denaturation of proteins is an irreversible change in which proteins get
precipitated when they are heated with alcohol, concentrated inorganic acids or by
salts of heavy metals.
vi) A nucleotide consists of a sugar molecule (either ribose in RNA or deoxyribose
in DNA) attached to a phosphate group and a nitrogen-containing base.
vii) Hexane
PRACTICE PAPER NCERT BOOK2 SET 6

BLUE PRINT
Class XII Chemistry
Base
1 1 2 3 4 5
mark Mark Marks marks Marks marks
6 Haloalkanes and haloarenes 1(1) 5(1) 6(2)
7 Alcohols, Phenols and 3(3) 3(1) 6(4)
Ethers
8 Aldehydes, Ketones and 2(2) 6(2) 8(4)
Carboxylic acids
9 Amines 2(1) 4(1) 6(2)
10 Biomolecules 3(1) 4(1) 7(2)
Total 6(6) 2(1) 12(4) 8(2) 5(1) 33(14)

Set 06
Q.N SECTION A Ma
. rks
1 SN2 reaction proceed with _______of configuration 1
(a) Retention (b) Inversion
(c) racemisation (d) Both b & c
2 Phenol reacts with bromine water and produce white precipitation of - 1
(a) m-bromophenol (b) o-and p-bromophenol
(c) p-bromophenol (d) 2,4,6-tribromophenol
3 IUPAC name of m-cresol is: 1
(a) 3-methylphenol (b) benzene-1,3-diol
(c) 3-chlorophenol (d) 3-methoxyphenol
4 Arrange the following compounds in increasing order of boiling point. 1
Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
(a) propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol
(b) propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
(c)pentan-1-ol, butan-2-ol, butan-1-ol, propan-1-ol
(d) pentan-1-ol, butan-1-ol, butan-2-ol, propan-1-ol
5 Which of the following compounds do not give Cannizzaro reaction 1
(a) methanal (b) propanal
(c) benzaldehyde (d) 2,2-dimethyl propenal
6 Which of the following compounds is formed when benzyl alcohol is oxidized with KMnO 4? 1
(a) CO2 and H2O
(b) Benzoic acid
(c) Benzaldehyde
(d) Benzophenone
SECTION B
7 Complete the following reactions- 2
(i) C6H5NH2 + CHCl3 + Alc. KOH
(ii) C6H5N2Cl (i) HBF4 ,(ii) NaNO2/Cu,∆
SECTION C
8 Write a chemical test to distinguish between following : 3
(a) Primary, secondary and tertiary alcohols
(b) Ethanol and methanol
(c) Ethanol & phenol
9 Although phenoxide ion has more number of resonating structures than 3
carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two reasons.
10 Arrange the following compounds in the increasing order of their property as indicated. 3
(i) CH3COCH3, C6H5COCH3,CH3CHO (reactivity towards nucleophilic addition reaction)
(ii) CI-CH2-COOH, F-CH2-COOH, CH3 -COOH (acidic character)
(iii) Write the IUPAC name of the compound CH3 —CH(OH) — CH2—COOH.
11 What happens when D-glucose is treated with the following reagents 3
(a) Br₂ water
(b) HCN
(c) (CH3CO)2O
SECTION D.
12 Each organism has different vitamin requirements. For example, humans need to get vitamin 4
C from their diets — while dogs can produce all the vitamin C that they need. Most vitamins
need to come from food because the body either does not produce them or produces very
Compiled
little. by
ForVijay Kumar Sethi
humans, 9461169967
vitamin D is not available in large enough quantities in food. ThePage 31 of 82
human
body synthesizes the vitamin when exposed to sunlight, and this is the best source of vitamin
D. Different vitamins play different roles in the body and a person requires a different amount
of each vitamin to stay healthy.
BLUE PRINT (2023-2024)
Chapter MCQ R-A VSA SA CASE LONG TOTAL
(1M) (1M) (2M) (3M) BASED ANS MARKS
(4M) (5M) (70)
6. HALOALKNES AND 1 (1) 2(1) 3(1) 6(3)
HALOARENES
7. ALCOHOLS, PHENOLS AND 1 (1) 5(1) 6(2)
ETHERS
8. ALDEHYDES, KETONES AND 1 (1) 3(1) 4(1) 8(3)
CARBOXYLIC ACID
9. AMINES 2 (2) 4(1) 6(3)
10. BIOMOLECULES 2 (2) 2(1) 3(1) 7(4)
TOTAL QUESTIONS 7 (7) 4(2) 9(3) 8(2) 5(1) 33(15)
Set 07
SECTION A
1. Toluene reacts with a halogen in the presence of iron (III) Chloride giving ortho and para halo
compounds. The reaction is_____________.
(a) Electrophilic elimination reaction (b) Electrophilic addition reaction
(c) Nucleophilic substitution reaction (d) Electrophilic substitution reaction
2. Phenol is less acidic than________________.
(a) Ethanol (b) o-nitrophenol
(c) o-methylphenol (d) o-methoxyphenol
3. Cannizzaro’s reaction is not given by
(a) (CH3)3CCHO (b) HCHO
(c) C6H5CHO (d) C2H5CHO
4. CH3CONH2 on reaction with NaOH and Br2 in alcoholic medium gives
(a) CH3COONa (b) CH3CH2Br
(c) CH3NH2 (d) CH3CH2NH2
5. Which of the following cannot be prepared by Sandmeyer’s reaction
(a) Chlorobenzene (b) Bromobenzene
(c) Iodobenzene (d) all the above
6. Which of the following statement is not true about glucose.
(a) It is an aldohexoses (b) On heating with HI it forms n-hexane
(c) It gives gluconic acid with Br2 water (d) It is present in furanose form
7. Curdling of milk is an example of __________
(a) Breaking of peptide linkage (b) Hydrolysis of lactose
(c) Breaking of proteins into amino acids (d) Denaturation of proteins
SECTION B
8. Which one in the following pairs of substances undergoes SN2 substitution reaction faster and
why?
9. Explain the following terms:

(a) Reducing sugar (b) Polypeptides
SECTION C
The following questions are short answer type and carry 3 marks each
10. Give reasons :
(a)n-Butyl bromide has higher boiling point than t-butyl bromide.
(b)Racemic mixture is optically inactive.
(c) Which one of the following compounds is more easily hydrolyzed by KOH and why?
CH3CHClCH2CH3 or CH3CH2CH2Cl

11. (a) Write the chemical equations involved in the following name reactions:
(i) Clemmensen reduction (ii) Cannizzaro reaction
(b) Distinguish between following pair of compounds
CH3CHO and C6H5-CHO
12. (a) Deficiency of which vitamin causes night-blindness?

(b) Name the base that is found in nucleotide of RNA only.
(c) Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of
glucose?
SECTION D
The following questions are case -based questions. Each question has an internal choice and carries 4
(1+1+2) marks each. Read the passage carefully and answer the questions that follow.
13. Study the table in which pka of various is given. Answer the questions based on table and
related studied concepts.
Compounds pka
1. Acetic acid 4.76
2. HCOOH 3.75
3. CH3CH2COOH 4.38
4. Cl-CH2COOH 2.87
5. F-CH2COOH 2.59
6. CH2 = CH–COOH 4.30
7. Benzoic acid 4.19

8. p-Toluic acid 4.38
9. Salicylic acid 2.98
10. p-nitro benzoic acid 3.44
11. p-methoxy benzoic acid 4.88
12. p-chloro benzoic acid 3.99
13. p-hydroxy benzoic acid 4.58
(a) Why is HCOOH stronger acid than CH3COOH?

(b) Why is p-hydroxy benzoic acid more acidic than p-methoxy benzoic acid?
Or
(b)Why is salicylic acid stronger than benzoic acid?
(c) What happens when salicylic acid is heated with zinc dust? Write chemical equation.
14. Amines are treated as the alkyl derivatives of ammonia. These are obtained by replacing one,
two or three H atoms from ammonia by the same number of alkyl groups. Depending upon
the number of alkyl groups attached to N atom, amines are classified as primary, secondary
and tertiary amines. Amines are weak Lewis bases as there is a lone pair of electrons on N

atom. Methylamine and ethylamines are gases at room temperature.
Higher amines may be volatile liquids. These compounds can form intermolecular hydrogen bonds
and are associative in nature hence they have higher boiling points than the corresponding alkanes
of comparable molecular masses. Answer the following questions:
(a) Arrange primary, secondary and tertiary methylamines in increasing order of their basic
strength in gaseous medium.
(b) Why amines behave as nucleophiles during chemical reactions.
(c) Draw the structures of all the isomeric amines of molecular formula C 3H9N.
Or
(c) How will you separate the mixture of primary, secondary and tertiary amines?
SECTION E
15. A compound ‘A’ with molecular formula C4H10O is a unreactive towards sodium metal. It does
not decolourise Bromine water and does not react with NaHSO3 solution .On refluxing ‘A’ with
excess of HI gives ‘B’ which react with aq. NaOH to form ‘C’. ‘C’can be converted into ‘B’ by
reacting with red P and I2.‘C’ on heating with conc. H2SO4 forms ‘D’ which decolorizes bromine
water. Identify A to D and write the reactions involved
Or
(a) How would you obtain

(i) Picric acid (2, 4, 6-trinitrophenol) from phenol
(ii) Salicyaldehyde from phenol
(b) (i) o-nitro phenol is more acidic than o-methoxy phenol. Explain why.
(ii) Phenol is a stronger acid than alcohol
PRACTICE PAPER NCERT BOOK2 SET 7

Marking Scheme (2023-24)
1 2 3 4 5 6 7
d b d c c D d
8.
(1)
. (1)
9. (a) Sugars which reduce with tollen’s reagent and Fehling solutions are called reducing sugars. Eg.
Glucose. (1)
(b)Polypeptides : They are formed when several molecules of a-amino acids are joined together
by peptide bonds. (1)
10. (a) n-Butyl bromide has higher boiling point than t-butyl bromide because it has larger surface
area
hence have more Van der Waals’ forces. (1)
(b) Rotation due to one enantiomer is cancelled by another enantiomer
(c)
(1)
11. (a) Clemmensen reduction
(1)
( b) Cannizzaro reaction
(1)
(a) CH3CHO will give idoform test while C6H5-CHO will not give idoform test (1)
12. (i) Vitamin A causes night blindness. (1)

(ii) Uracil is found in nucleotide of RNA only. (1)
(iii) It suggests the open /straight chain structure of glucose. (1)
13. (a) It is because HCOO– is more stable than CH3COO- (1)
(b) It is because —OH has more —I effect than —OCH3 group (1)
Or
(b) It is because salicylate is more stable than benzoate ion due to intra molecular H- bonding.
(1)
(c) Salicylic acid

(2)
14. (a) primary < secondary < tertiary (1)
(b) Due to presence of lone of electrons on Nitrogen atom in amines it acts as Lewis base.
(1)
(c) Isomers of C3H9N are
(i) CH3CH2CH2NH2 Propan-1-amine ( primary)
(ii) CH3CH(NH2)CH3 Propan-2-amine (primary)
(iii) CH3CH2NHCH3 N- methyl ethanamine (Secondary)
(iv) CH3N(CH3)3N,N-dimethylmethanamine (tertiary) (1/2 x 4 =2)
Or
(c)Primary amine + Hinsberg’s reagent  Alkali soluble product
Secondary amine + Hinsberg’s reagent  Alkali insoluble product
Tert. Amine + + Hinsberg’s reagent  No reaction (2)

15. A is not alcohol therefore it does not react with Sodium metal. ‘A’ is not aldehydes and ketones as
it does not react with NaHSO3 ‘A’ is not unsaturated hydrocarbon as it does not add Br2 (aq) . It is
likely to be ether.
CH3CH2OC2H5 + 2HI  2C2H5I + H2O ( 1)
‘A’ excess ‘B’
2C2H5I + NaOH (aq)  C2H5OH + NaI (1)
‘B’ ‘C’
C2H5OH (P/I2)  C2H5I, (1)
C B
C2H5OH-----------> C2H4
C D
A= ethoxyethane, B = iodoethane, C= Ethanol, D= Ethene ½ x 4 =2
Or
(a) (i) Phenol to picric acid
(1)
(ii) Phenol to salicyaldehyde
(1)
(b) (i)Due to -I effect of NO2 group (1)
(ii)Due to stabilization of phenoxide ion by resonance (1)

Class XII Chemistry
CHAPTER NAME MCQ AR SA-1 SA-2 CBQ LAQ TOTAL
(1 M) (1M (2 M) (3M) (4M) (5M)
)
HALOALKANES AND 1(1) 2(1) 3(1) 6(3)
HALOARENES
ALCOHOL, PNHENOL 2(2) 4(1) 6(3)
AND ETHER
ALDEHYDES, 1(1) 2(1) 5(1) 8(3)
KETONE AND
CARBOXYLIC ACIDS
AMINES AND 1(1) 2(1) 3(1) 6(3)
DIAZONIUM SALTS
BIOMOLECULES 1(1) 6(2) 7(3)
TOTAL 6(6) 6(3) 12(4) 4(1) 5(1) 33(15)

Set 08
SECTION A (MCQ and A/R TYPE)
1. Which of following aldehyde does not have alpha hydrogen?
(a) HCHO (b) C6H5CHO (c) CCl3CHO (d) All of these
2. Lucas test can be used to distinguish between:
(a)Phenol and p-cresol (b)Propan-1-ol and ethanol
(c)Butan-1-ol and 2-methylpropan-2-ol (d)Ethanol and glycol
3. Which of the following is steam volatile?
(a) p-Nitrophenol (b)o-Nitrophenol
(c)Phenol (d)Resorcinol
4. The product of reaction between any aliphatic primary amine with chloroform and ethanolic
solution of KOH is
(a) Alkyl cyanide (b) alkyl isocyanide
(c)alcohol (d)amide
5. Which of the following reagent does not react with glucose?
(a)NH2OH (b)HCN
(c)2,4-DNP reagent (d)Br2 water
6. SN1 reaction of chiral alkyl halides leads to
(a) Retention of configuration (b) Inversion of configuration
(c ) Racemisation (d) None of these
SECTION B
7. The following compounds are given to you:
2-Bromopentane,2-Bromo-2-methylbutane,1-Bromopentane
(a)Write the compound which is most reactive towards SN2 reaction and why?
(b)Write the compound which is most reactive toward β-elimination reaction and why?
8. Distinguish between the following pairs of compounds :
(i) Benzaldehyde and Acetophenone (ii) Propanal and Propanone
9. Write the reaction involved in the following:
(i)Hoffmann bromamide degradation reaction (ii)Gabriel phthalimide synthesis
SECTION C
10. Write the reaction for the following :

(i) 2-Methyl-1-bromopropane is treated in the presence of dry ether.
(ii) Chloroethane is treated with silver nitrite.
(III) Bromopropane is treated with alcoholic KOH
11. What happens when D-glucose is treated with the following reagents?
(i) HI (ii)Bromine water (iii) Conc . HNO3
12. Give the answer following
(i) What do you mean by denaturation of proteins
(ii) Give an example each for fibrous protein and globular protein.
(iii)Write one difference between nucleoside and a nucleotide.
13. How will you convert the following:
(i) Ethanoic acid to methanamine
(ii) Benzene diazonium chloride to Phenol
(iii) 4-nitrotoluene to 2-bromobenzoic acid
SECTION D
14. When phenol is refluxed with chloroform in the presence of aq.Na0H/KOH, followed by
hydrolysis, an aldehyde group is introduced in the benzene ring at a position - ortho to the
phenolic group. The product is called ortho hydroxy benzaldehyde. In add to o-product, a small
amount of p-product is also formed but the major product is ortho if one of the position is
occupied, then para product is formed. The reaction is electrophillic substitution reaction.
a. What is the name of the reaction?
OR
Which is the electrophile in this reaction?
b. Give another example of ortho and para directing group in electrophilic substitution
reactions
c. (i) Write the product formed if CCl4 is used in place of CHCl3.
(ii) Write the reaction of product of above reaction with acetic anhydride in the
presence of conc. H2SO4.
OR
Draw the resonating structures of Phenol.
SECTION-E
15. (a) Arrange following in increasing order of reactivity with HCN:
(i) CH3-CO-CH3 (iii) CH3-CO-Ph (iii) CH3-CHO (iv) CH3-CH2-CHO
(b) Write structure of ethylene ketal of cyclopropanone
(c) Distinguish between following pair of organic compounds with the help of
suitable chemical test: Acetophenone and benzophenone
(d)Which of acetone and acetaldehyde will produce racemic mixture with HCN?
Why?
(e) Compare acidic strength of acetic acid, benzoic acid and formic acid.
OR
(a) Complete following reaction:
Dry HCl
(i) HCHO + CH3OH (Excess) ---------------------------
(ii) C6H5-CHO + [Ag(NH3)2]+1 ---------------------
(b) Write structure of 2-methylbut-3-enoic acid

(c) Write Cross-Aldol condensation reaction between acetaldehyde and benzaldehyde
(d) Write Cannizzaro’s reaction of Benzaldehyde

Practice paper NCERT BOOK 2 Set 8
MARKING SCHEME
Q.NO. 1 2 3 4 5 6
ANS D C B B C C
7. (a)1-Bromopentane due to less steric hinderance

(b)2-Bromo-2-methylbutane because of more highly substituted .
8. (a) By iodoform test
(b) any one out of Fehling’s , Tollen’s or iodoform test
9. a)
(b)
10. (i)
(ii)
(iii)
11. (i) n- Hexane (ii) Gluconic acid (iii) Saccharic acid

12. (i)When a protein in its native form,is subjected to physical change like change in temperature
or chemical change like change in pH,the hydrogen bonds are disturbed due to which globules
unfold and helix get uncoiled and protein loses its biological activity.This is called dnaturation
of proteins.
(ii)Keratin is a fibrous protein hile egg albumin is a globular protein.
(iii)Nucleoside=Sugar+Base
Nucleotide=Sugar+Base+Phosphate
13. (i) (ii)
(iii)
14. (i) Riemer Tiemann formylation OR Dichlorocarbene

(ii)-OR, -NH2 , or any other
(iii) (a) Salicylic acid
(b)
OR
15. (a) (iii) < (i) < (iv) < (iii)

(b)
(c) Acetophenone will give yellow ppt with NaOI

Benzophenone will not give
(d)Acetaldehyde as it has stereogenic centre at sp2 -carbon
(e) Formic acid > benzoic acid > acetic acid
OR
dry Hcl
❑
(a) (i)HCHO + CH3OH (Excess)

(ii)C6H5-CHO + [Ag(NH3)4]+1 --------------------- C6H5- COOH + Ag + H2O
(b)
(c)
(d)

Practice Paper NCERT BOOK 2 Set - 9
BLUE PRINT
Base
1 1 2 3 4 Mark 5
6 Haloalkanes and haloarenes 2(2) 4(1) 6(3)
7 Alcohols, Phenols and Ethers 2(1) 4(1) 6(2)
Carboxylic acids
9 Amines 1(1) 5(1) 6(2)
10 Biomolecules 2(2) 2(1) 3(1) 7(4)
Total 7(7) 4(2) 9(3) 8(2) 5(1) 33(15)

Set 09
SECTION: A
1. Which of the following is an example of vic-dihalide
(a) Dichloromethane (b)1,2-dicholoroethane (c)Ethylidene chloride (d) allyl choloride
2. The decreasing order of boiling points of alkyl halides is :
(a) RF > RCl > RBr > RI (b) RBr > RCl > RI > RF
(c) RI > RBr > RCl > RF (d) RCl > RF > RI > RBr
3. The conversions that can be made under Wolff-Kishner reduction circumstances include :
(a) cyclohexanone to cyclohexane conversion (b) benzaldehyde to benzyl alcohol transformation
(c) cyclohexanone to cyclohexanol conversion (d) diphenylmethane to benzophenone
4. When a mixture of sodium benzoate and soda lime is heated, it produces
(a) benzoate of calcium (b) benzene
(c) Ethane (d) methane
5. Hofmann bromamide degradation reaction is shown by:
(a) ArNH2 (b) ArCONH2 (c) ArNO2 (d) ArCH2NH2
6. In DNA, what are the purine nitrogen bases?
(a) Uracil and Guanine (b) Guanine and Adenine (c) Adenine and cytosine (d) None of
these
7. Plants do not contain which of the following sugars?
(a) Sucrose (b) Glucose (c) Lactose (d) Fructose
SECTION B
8. Give one chemical test each to distinguish between the following pairs of compounds: (i)
Phenol and Benzoic acid (ii) Propan-1-ol and Propan-2-ol
9. (i)Define Glycosidic linkage
(ii) Why cannot vitamin C be stored in our body.
OR
(i) What type of linkage is present in nucleic acids?
(ii) Give one example each for fibrous protein and globular protein.
section – c
10. What happens when D-glucose is treated with the following reagents?
(i) HI (ii) Bromine water (iii) HNO3
OR
Define the following as related to proteins:
(i) Peptide linkage (ii) Primary structure (iii) Denaturation
11. An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative, reduces
Tollen’s reagent, and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1,2-
benzenedicarboxylic acid. Identify the compound. Also write the reactions involved.
12. Arrange the following carbonyl compounds in increasing order of their reactivity in
nucleophilic addition reactions and give the reason.
(a) Ethanal, propanal, propanone, butanone
(b) Benzaldehyde, p-tolualdehyde, p-nitrobenzaldehyde, acetophenone
SECTION D
Case-based question (4 Marks)
Read the passage given below and answer the following questions:
13. The substitution reaction of alkyl halides occurs in S N1 and SN2 mechanism, whatever
mechanism alkyl halide follow for substitution reaction to occur, the polarity of the carbon
halogen bond is responsible for the substitution reaction. The rate of S N1 reactions is governed
by the stability of carbocation whereas for SN2 reactions steric factor is a deciding factor. If the
starting material is a chiral compound, we may end up with an inverted product or racemic
mixture depending upon the type of mechanism followed by alkyl halide.
(a) Among 1-bromopropane and 2-methyl-2-bromo propane, which will follow S N1

mechanism?
(b)Among following in which inversion of configuration will occur on reaction with aq alkali
1-bromo propane, and 2-methyl-2-bromo butane
(c)What is the role of polar protic solvent in SN1 reaction?
OR
(c) How will a protic solvent system affect the SN2 reaction?
14. Both alcohols and phenols are acidic in nature, but phenols are more acidic than alcohols.
Acidic strength of alcohols mainly depends upon the inductive effect. Acidic strength of phenols
depends upon a combination of both inductive effect and resonance effects of the substituent
and its position on the benzene ring. Electron withdrawing groups increases the acidic strength
of phenols whereas electron donating groups decreases the acidic strength of phenols. Phenol
is a weaker acid than carboxylic acid.
(a)Arrange the following compounds in increasing order of their acid strength:
Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-
methylphenol
(b)Alcohols act as Bronsted bases also. Explain
(c) Draw the resonating structures of phenol and phenoxide ions
OR
(c)Explain why phenoxide ion is more stable than phenol.
SECTION-E
15. In the following reaction chart identify A, B, C, D and E. Write their name and rewrite the
following reaction.
OR
(a) An amine “X” with formula C3H9N reacts with benzenesulphonyl chloride to give a precipitate
which is insoluble in alkali. Give the structure and IUPAC name of amine “X”. Write the chemical
reaction.
(b) How will bring out the following conversions: (i) Aniline to Phenol (ii) Aniline to Iodobenzene.

PRACTICE PAPER NCERT BOOK 2 SET-9(2023 -24)
MARKING SCHEME
1. B 2. C 3. A 4. B 5. B 6. B 7. C
8. (i) NaHCO3 test, Phenol will not react, whereas benzoic acid will give brisk effervescence.
(ii) Propan-2-ol will give yellow ppt. of iodoform (iodoform test),
whereas propan-1-ol will not give yellow ppt.
9. (i) The linkage between two monosaccharides through oxygen atom in an oligosaccharide or a
polysaccharide is known as glycosidic linkage.
(ii) As vitamin C is water soluble, therefore, it is readily excreted in urine and hence cannot be
stored in the body.
OR
(i) Phosphodiester linkage.
(ii) Fibrous protein: Myosin, keratin, collagen, etc. Globular protein: Insulin, haemoglobin, etc.
10.
OR
(a) Peptide bond: Proteins are condensation polymers of α-amino acids in which the same or different
α-amino acids are joined by peptide bonds. Chemically, a peptide bond is an amide linkage formed
between – COOH group of one α-amino acid and -NH-, group of the other α-amino acid by loss of a
molecule of water.
(b) Primary structure: Proteins may contain one or more polypeptide chains. Each . polypeptide chain
has a large number of α-amino acids which are linked to one another in a specific manner. The specific
sequence in which the various amino acids present in a protein linked to one another is called its
primary structure. Any change in the sequence of α-amino acids creates a different protein.
(c) Denaturation: When a protein in its native form is subjected to a physical change such as change in
temperature or a chemical change like change in pH, etc., results in loss of biological activity of the
proteins, is called denaturation. During denaturation, 2° and 3° structures of proteins are destroyed
but 1° structure remains.
11. forms 2,4-DNP derivative-carbonyl group present
reduces Tollen’s reagent-carbonyl group is aldehyde
undergoes Cannizzaro reaction-absence of α-H
On vigorous oxidation, it gives 1,2-benzenedicarboxylic acid so according to molecular formula
C9H10O it’s structure is

Reactions are-
12. (a) The increasing order of reactivity of the carbonyl compounds towards nucleophilic
addition reactions is :
butanone < propanone < propanal < ethanal
The reactivity is based upon two factors. These are: steric factors and electronic factors.
(b) The increasing order of reactivity is :
acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde
Explanation: Acetophenone being a ketone is the least reactive towards nucleophilic addition.
All others are aldehydes. Among them, p-tolualdehyde is less reactive than benzaldehyde
because CH3 group present at the para position w.r.t. -CHO group will increase the electron
density on the carbonyl carbon atom due to hyper conjugation effect. As a result, the
nucleophile attack occurs to lesser extent as compared to benzaldehyde.
In p-nitrobenzaldehyde, the nitro group has an opposing effect. It is electron withdrawing in
nature due to -I effect as well as -R effect. The electron density on the carbonyl carbon atom
decreases and this favours the nucleophile attack.
SECTION D
13. (a). 2-methyl-2-bromo propane
(b). 1-bromo propane
(c). Polar protic solvents help to stabilize both the carbocation and the anion and that solvation
of both cations and anions helps the SN1 mechanism proceed. So that's why polar protic solvent
will favor an SN1 mechanism.
OR
(c)For SN2 reactions involving anions as the nucleophile, protic solvents act to decrease the
nucleophilicity of that anion by solvation through hydrogen bonding. The anion acquires a
“coating” of solvent molecules thus inhibiting the ability of the anion to approach the substrate.
14. (a) Propan-1-ol, 4-methylphenol, phenol, 3-nitrophenol, 3,5-dinitrophenol, 2,4, 6-
trinitrophenol
(b) It is due to the presence of unshared electron pairs on oxygen, which makes them proton
acceptors.
(c)

OR
(c) Resonance structures of phenol have charge separation due to which the phenol molecule is
less stable than phenoxide ion which has charge delocalization.
Section E
15. A = cyclohexane carboxamide B= Chloroform C = cyclohexylcarbylamine
D= N- methylcyclohexylamine E = Chloromethane
OR
(a) N-methyl ethanamine (C2H5 NH CH3)
−¿+ NaCl+ 2 H2 O¿
+¿Cl ¿
(b) (i) C 6 H 5 −NH 2 + HNO2 273−278 K C 6 H 5 −N 2
→
−¿+ H 2 O ∆ C 6 H 5 OH + N 2 + HCl ¿
+¿Cl →
¿
C6 H5 N 2
−¿+ NaCl+ 2 H2 O¿
+¿Cl ¿
(ii) C 6 H 5 −NH 2 + HNO2 273−278 K C 6 H 5 −N 2
→
−¿+ KI →C 6 H 5 +N 2 ¿
C 6 H 5 N +¿Cl
2
¿

Practice Paper NCERT BOOK 2 Set – 10
BLUE PRINT

Base
1 1 2 3 4 Mark 5
6 Haloalkanes and haloarenes 1(1) 2(2) - 3(1) 6(4)
7 Alcohols, Phenols and Ethers 1(1) - 2(1) 3(1) 6(3)
8 Aldehydes, Ketones and - - - 3(1) 5(1) 8(2)
Carboxylic acids
9 Amines 1(1) - 2(1) 3(1) 6(3)
10 Biomolecules - - - 3(1) 4(1) 7(2)
Total 3(3) 2(2) 4(2) 15(5) 4(1) 5(1) 33(14)

Set 10
SECTION -A
1. If two same halogen atoms are attached with adjacent carbon atoms, then they are known as
(a)vicinal dihalide (b) Polymethylenedihalide
(c)gem dihalide (d)allylic halide
2. Which of the following reagent can be used to oxidise primary alcohols to aldehyde?
(I) PCC (II) Cu/573k (III)CrO3 (IV)KMnO4 in Acidic medium
(a) I, II and III (b)I,III, and IV (c)II,III, and IV (d) III and IV
3. Ritu heated a mixture of primary ammine and chloroform with ethanolic KOH to form
Isocyanide which has foul smelling. What is the name of reaction involved in the statement
(a)Hinsberg test (b)Diazotization
(c)Gabriel phthalimide synthesis (d)Carbylamines
Choose the correct answer out of the following choices
(a)Both A and R are true and R is correct explanation of A.
(b) Both A and R are true but R is not correct explanation of A.
(c)A is true but R is false.
(d)A is false but R is true.
4. Assertion: Propene react with HBr to form 2-Bromopropane.
Reason: 2-Bromo propane is formed by free radical mechanism
5. Assertion: Carbon halogen bond of haloalkane is polarised
Reason: Halogen atoms are more electronegative than carbon atom.
SECTON -B
6. (a) Arrange the following compounds in increasing order of their acid strength:
(i)Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol
(b)Alcohols act as Bronsted bases also. Explain
7. Complete the following reaction
(i)C6H5NH2 +Br2(aq) → (ii)C6H5N2Cl + C2H5OH→
Or
Write short notes on following
(i) Coupling reaction (ii)Hofmann’s bromamide reaction
Section -C
8. Among the isomeric alkanes of molecular formula C5H12, identify the one that on
photochemical chlorination yields
(i) A single monochloride.
(ii) Three isomeric monochlorides.
(iii) Four isomeric monochlorides.
9. Write the mechanism of hydration of ethene to yield ethanol.
Or
Give one chemical test each to distinguish between the following pairs of compounds:
(i) Phenol and Benzoic acid (ii) Propan-1-ol and Propan-2-ol (iii) Methanol and ethanol.
10. Arrange the following compounds in an increasing order of their indicated property:
(i) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid
strength)
(ii) CH3CH2CH (Br) COOH, CH3CH (Br) CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH (acid
strength)

(iii)Reactivity towards HCN of Propanal, Methanal, Propanone
11. (a) Give reasons:
(i) Although – NH2 group is ortho and para directing in electrophilic substitution
reactions, yet aniline, on nitration gives good yield of m-nitroaniline.
(ii) (CH3)2 NH is more basic than (CH3)3 N in an aqueous solution.
(iii) Ammonolysis of alkyl halides is not a good method to prepare pure primary
amines.
12. What happens when D-glucose is treated with. the following reagents.
(i) HI (ii) Bromine water (iii) HNO3
Section -D
The following questions are case based question each question has internal choice and carries four
marks (1+1+2) each. Read the passage carefully and answer the questions that follow.
13. When a protein in its native form, is subjected to physical changes like change in temperature
or chemical changes like change in pH, the hydrogen bonds are disturbed. Due to this, globules
unfold and helix get uncoiled and protein loses its biological activity. This is called
denaturation of protein.
The denaturation causes change in secondary and tertiary structures but primary structures
remain intact. Examples of denaturation of protein are coagulation of egg white on boiling,
curdling of milk, formation of cheese when an acid is added to milk.
(i)Which structure of proteins are unaffected with denaturation of protein?
(ii) All α-amino acids are optically active except one α-amino acid. Give named of it.
(iii)Write the difference between globular protein and fibrous protein with one example.
Or
(iii)State the difference between essential and non-essential amino acids with one example.
Section -E
14. (a) Illustrate the following name reactions by giving example:

(i) Cannizzaro’s reaction (ii) Clemmensen reduction
(b) An organic compound A contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The
molecular mass of the compound is 86. It does not reduce Tollens’s reagent but forms an
addition compound with sodium hydrogen sulphite and gives positive iodoform test. On
vigorous oxidation it gives ethanoic and propanoic acids. Derive the possible structure of
compound A.
OR
(a) An organic compound (A) having molecular formula C4H8O gives orange red precipitate
with 2, 4-DNP reagent. It does not reduce Tollens’ reagent but gives yellow precipitate of
iodoform on heating with NaOH and I2. Compound (A) on reduction with NaBH4 gives
compound (B) which undergoes dehydration reaction on heating with conc. H 2SO4 to form
compound (C). Compound (C) on Ozonolysis gives two molecules of ethanal. Identify (A), (B)
and (C) and write their structures. Write the reactions of compound (A) with (i) NaOH/I 2 and
(ii) NaBH4.
(b) Write the products formed when acetone reacts with the following reagent(i)phenyl
hydrazine(ii) acetone heated with Dilute NaOH

PRACTICE PAPER NCERT BOOK 2 SET- 10
MARKING SCHEME
Q 1 2 3 4 5
AN a a d c a
S
Q.NO ANSWER MARKS

6 (i)Propan-1-ol, 4-methylphenol, phenol, 3-nitrophenol, 3,5-dinitrophenol, 2,4, 6- 1+1
trinitrophenol
(ii) It is due to the presence of unshared electron pairs on oxygen, which makes
them proton acceptors.
7 (i) 2,4,6tribromo aniline (ii)Benzene 1+1
7(or) Answer: (i) 1+1
(ii)
8 (i) Neo pentane (ii) n-pentane (iii) 2-Methylbutane 1+1+1

9 Direct addition of H2O to ethene in presence of an acid does not occur. Indirectly, 1+1+1
ethene is first passed through concentrated H2SO4, when ethyl hydrogen sulphate
is formed.
9(or) (i) Add NaHCO 3to each. Phenol will not react, whereas benzoic acid will give 1+1+1
brisk effervescence due to CO 2.
(ii) Add I 2 and NaOH to each one. Propan-2-ol will give yellow ppt. of iodoform
(iodoform test), whereas propan-1-ol will not give yellow ppt.
(iii) Add I 2 and NaOH to each one. Ethanol will give yellow ppt. of iodoform
(iodoform test), whereas methanol will not give yellow ppt.
10 (i) 4-Methoxy benzoic acid < Benzoic acid < 4-Nitrobenzoic acid < 3, 4- 1+1+1
Dinitrobenzoic acid.
The order is due to increasing -I effect.
(ii) (CH3)2CHCOOH< CH3CH2CH2COOH< CH3CH (Br) CH2COOH< CH3CH2CH (Br)
COOH,
(iii)Propanone< Propanal<Methanal
11 (i) During nitration, aniline is protonated to form the anilium ion which is meta 1+1+1
directing. That is why besides the ortho and para derivatives, significant amount
of meta derivative is also formed.
(ii) (CH3)2NH is a secondary amine and (CH3)3N is a tertiary amine. Tertiary amine
due to the presence of three alkyl groups is more hindered than secondary amine
which has only two alkyl group attached to it. Therefore, formation of ammonium
ion is easier in secondary amine than tertiary amine. Henceforth, makes
secondary amine less basic than tertiary
amine.
(iii) The ammonolysis of alkyl halide leads to the formation of a mixture of
primary, secondary and tertiary amine along with the formation of quaternary
salt. It is very difficult to separate pure primary amine from this mixture.
12 1+1+1
13 (i)Primary protein structure (ii)glycine 1+1+2

(iii)Any one difference with one example
Or
(iii) Any one difference with one example
14 (a) (i) Cannizzaro’s reaction: Aldehydes, which do not have an alpha-hydrogen 3+2
atom undergo self-oxidation and reduction on treatment with cone, alkali and
produce alcohol and carboxylic acid salt.
(ii)
(b) (b) An organic compound contains 69.77% C, 11.63% H and rest O. The molecular
mass of the compound is 86.
% O= 100−(69.77+11.63) =18.60
Simple atomic ratio C:H:O=69.77/12 ,11.63/1,18.6/16=5.88.11.63,1.16=5:10:1
The empirical formula is C5H10O
Empirical formula mass =5×12+10×1+1×16=86.
It is equal to molecular formula mass. Hence, molecular formula is same as empirical
formula.
It does not reduce Tollens reagent. Hence, it is not an aldehyde

It forms an addition compound with sodium hydrogen sulphite.
Hence, it contains carbonyl group.
It give positive iodoform test.
Hence, it is a methyl ketone
On vigorous oxidation it gives ethanoic and propanoic acid.
Hence, it is 2-pentanone.
14(or) (a) A= Butanone(CH3 CO CH2 CH3) 3+2
B = Butan2-ol (CH3CH(OH)CH2CH3) C=But-2-ene
(b) (i) (CH3 )2C= N NH C6H5 (ii)Aldol
condensation (CH3)2C= CHCOCH3

PRACTICE PAPER NCERT BOOK 2 SET-11
2023-24
BLUE-PRINT SUBJECT- CHEMISTRY
Class: XII

A/R Based
S.No
1 1 2 3 Marks 4 5
Marks Marks
Marks Marks Marks
6 Haloalkanes and 1(1) 2(1) 3(1) 6(3)

Haloarenes

Ethers
8 Aldehydes, Ketones and 2(2) 1(1) 2(1) 3(1) 8(5)

Carboxylic Acids
9 Amines 1(1) 5(1) 6(2)
10 Biomolecules 1(1) 1(1) 2(1) 3(1) 7(4)
Total 7(7) 3(3) 6(3) 12(4) 5(1) 33(18)

Set 11
SECTION A
The following questions are multiple-choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section.
Q. QUESTIONS MA
N. RK
S
1 Methyl ketones are usually characterized through-- 1

(a) Tollen’s reagent (b) Iodoform test (c) Schiff ’stest (d) Benedict solution test.
2 The term anomer of glucose refers to – 1

(a)isomers of glucose that differ in configuration at carbons one and four (C-1 and C-4)
(b)a mixture of (D) – glucose and (L) –glucose
(c)enantiomers of glucose
(d)isomers of glucose that differ in configuration at carbon one (C-1)
3 (CH3)2C = CHCOCH3 can be oxidised to (CH3)2C= CHCOOH by 1

(a) Chromic acid (b) NaOI (c) Cu at 575 K (d) Tollen,s reagent
4 Toluene reacts with a halogen in the presence of iron (III) Chloride giving ortho and para 1
halo compounds. The reaction is_____________.
(a) Electrophilic elimination reaction (b) Electrophilic addition reaction
(c) Nucleophilic substitution reaction (d) Electrophilic substitution reaction
5 Ritu heated a mixture of primary ammine and chloroform with ethanolic KOH to form 1
Isocyanide which has foul smelling. What is the name of reaction involved in the
statement
(a)Hinsberg test (b)Diazotization
(c)Gabriel phthalimide synthesis (d)Carbylamine
6 The IUPAC name of m-cresol is ___________. 1

(a) 3-Methylphenol (b) 3-Chlorophenol (c) 3-Methoxyphenol (d) Benzene-1,3-diol
7 Which of the following compounds do not give Cannizzaro reaction 1

(a) methanal (b) propanal
(c) benzaldehyde (d) 2,2-dimethyl propenal
In the Following questions a statement of Assertion(A) is followed by a statement of

Reason(R). Select the most appropriate answer from the options given below:
8 Assertion: p-hydroxybenzoic acid is more acidic than phenol. 1

Reason: carboxyl group helps in the stabilisation of the phenoxide ion by dispersal of
negative charge due to resonance.
9 Assertion: Compounds containing –CHO group are easily oxidised to corresponding 1

carboxylic acids.
Reason: Carboxylic acids can be reduced to alcohols by treatment with LiAlH4.
10 Assertion (A): Globular proteins are soluble in water. 1

Reason(R): Keratin is a fibrous protein.
SECTION B
11 Which compound in each of the following pairs will react faster in SN2 reaction with 2
—OH? and why?
(a) CH3Br or CH3I (b) (CH3)3CCl or CH3Cl
12 Arrange the following compounds in increasing order of their property as indicated:

(i) CH COCH , C H COCH , CH CHO (reactivity towards nucleophilic addition
3 3 6 5 3 3
reaction)
(ii) Cl—CH —COOH, F—CH —COOH, CH —COOH (acidic character)
2 2 3 2
OR
Give reasons:
(i) Oxidation of aldehydes is easier than ketones
(ii) Benzoic acid is a stronger acid than acetic acid
13 (i) Which of the following biomolecules is insoluble in water? Justify. Insulin, 2

Haemoglobin, Keratin.
(ii) Why cannot vitamin C be stored in our body?
SECTION C
14 Give reasons: 3
(a) n-Butyl bromide has higher boiling point than t-butyl bromide.
(b) Racemic mixture is optically inactive.
(c) The presence of nitro group (-NO 2) at o/p positions increases the reactivity of
haloarenes towards nucleophilic substitution reactions.
15 Give one chemical test each to distinguish between the following pairs of 3
compounds:
(i) Phenol and Benzoic acid (ii)Propan-1-ol and Propan-2-ol (iii) Methanol and
ethanol.
OR

Give reasons for the following: -
(a) Alcohols are more soluble in water than the hydrocarbon of comparable
molecular masses.
(b)Phenoxide ion is more stable than phenol.
(c) Ortho nitro phenol is more acidic than Ortho-methoxyphenol.
16 Give reasons: 3
(i) Alpha hydrogen of aldehydes and ketones are acidic in nature.
(ii)Propanone is less reactive than ethanal towards addition of HCN.
(iii) Benzoic acid does not give Friedel-Crafts reaction.
17 (i) What are the products of hydrolysis of maltose? 3

(ii)Name the protein and its shape present in the oxygen carrier in the human
body.
(iii) Name the linkages which join the amino acids in proteins?
SECTION D
18 An aromatic compound A of molecular formula C7H7ON undergoes a series of

reactions as shown below. Write the structures of A, B, C, D and E in the following
reactions : 5
OR
(A) Arrange the following:
(i) In decreasing order of the pKb values:
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
(ii) In decreasing order of basic strength: C6H5NH2, C6H5N (CH3)2, (C2H5)2NH and
CH3NH2
(B) An aromatic compound ‘A’ on treatment with aqueous ammonia and heating
forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of
molecular formula C6H7N. Write the structures and IUPAC names of compounds A,
B and C.

ANSWER KEY
Class: XII SUBJECT: CHEMISTRY
Q.N. 1 2 3 4 5 6 7 8 9 10
ANS- b d a d d a b a b b
Q. Value Point/ Expected Answer Marks

No
.
11 (a) CH3I: Because Iodide is better leaving group than bromide. 1+1
(b) CH3Cl: Carbon atom leaving group is less hindered.
12 (i) C H COCH < CH COCH < CH CHO

6 5 3 3 3 3 1+1
(ii) CH —COOH < Cl—CH —COOH < F—CH —COOH
3 2 2
OR
(i) As aldehydes contain H atoms on the carbonyl group but ketones do not.
Cleavage of C—H bond in aldehydes is easier than cleavage of C—C bond in
ketones. 1+1
(ii) This is because of greater electronegativity of sp2 hybridised carbon to which
carboxyl carbon is attached in benzoic acid. or any other suitable answer
13 (i) Keratin being a fibrous protein insoluble in water 1

(ii) As vitamin C is water soluble, therefore, it is readily excreted in urine and hence 1
cannot be stored in the body.
14 (a) n-Butyl bromide has higher boiling point than t-butyl bromide because it has larger 1
surface area hence have more Van der Waals’ forces.
(b)Rotation due to one enantiomer is cancelled by another enantiomer. 1
(c)The presence of nitro group (-NO2) at ortho and para positions withdraws the 1
electron density’ from benzene ring and thus facilitating the attack of nucleophile.
15 (i)Add NaHCO 3to each. Phenol will not react, whereas benzoic acid will give brisk 1
effervescence due to CO 2. ( Any other correct test also)
1
(ii)Add I 2 and NaOH to each one. Propan-2-ol will give yellow ppt. of iodoform
(iodoform test), whereas propan-1-ol will not give yellow ppt. ( Any other correct test 1
also)
(iii)Add I 2 and NaOH to each one. Ethanol will give yellow ppt. of iodoform (iodoform 1
test), whereas methanol will not give yellow ppt. ( Any other correct test also) 1

OR 1
(a)Alcohols make H bond with water molecules whereas hydrocarbons do not..
(b) in phenoxide ion delocalisation of negative charge while in phenol separation of
charges.
(c)Ortho nitrophenol is more acidic due to electron withdrawing effect of nitro group
which facilitates release of proton.
16 (i) due to the strong withdrawing effect of the carbonyl group and resonance 1
stabilisation of the conjugate base.
(ii) the presence of two methyl groups in propanone hinders more the approach of 1
nucleophile to carbonyl carbon than in ethanal having one methyl group and two
methyl groups reduce the positivity of the carbonyl carbon more effectively in
propanone than in ethanal.
(iii) Carboxyl group is strongly deactivated and catalyst AlCl is a lewis acid that gets
3 1
bonded to the carboxyl group strongly.
17 (i) The product of hydrolysis of maltose are two molecules of α−D Glucose. 1
(ii) Globular protein (haemoglobin) and its shape are spherical. 1
(iii) Peptide linkage 1
18 1x
5=
5
OR
(A)(i) Stronger the base lesser the pKb values. C6H5NH2> C6H5NHCH3> C2H5NH2>
(C2H5)2NH 2
(ii) (C2H5)2NH > CH3NH2 > C6H5N (CH3)2> C6H5NH2
(B)
A= benzoic acid, B= benzamide, C= aniline

2023-24
Class: XII
S NO NAME OF MCQ Assertion SA I (2 SA TYPE- Case Based LONG TOTAL
CHAPTER (1Mark & reason Mark) II ( 3 (4 Marks) ANSWER marks
) Mark) (5MARKS)
6 Haloalkanes and 1(1) 2(1) 3(1) 6(3)
Haloarenes
7 Alcohols, 2(2) 1(1) 3(1) 6(4)
Phenols and
Ethers
8 Aldehydes, 2(2) 1(1) 2(1) 3(1) 8(5)
Ketones and
Carboxylic Acids
9 Amines 1(1) 5(1) 6(2)
10 Biomolecules 1(1) 1(1) 2(1) 3(1) 7(4)
7(7) 3(3) 6(3) 12(4) 5(1) 33(18)

Set 12
SECTION A
The following questions are multiple -choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section.
Q.1 Arrange the following compounds in order of decreasing acidity :
(a) II > IV > I > III (b) I > II > III > IV (c) III > I > II > IV (d) IV > III > I > II
Q 2. In order to make alcohol undrinkable, pyridine or methanol are added to it. The resulting
alcohol is called-
(a) Power alcohol (b) Proof spirit (c) Denatured spirit (d) Poison alcohol
Q3.Which one is electrophilic reagent during nitration of aromatic compounds
(a) NO2+ (b) NO3- (c) NO2 (d) NO+
Q.4.Which compound undergoes Cannizzaro reaction?
(a)Ethanol (b)Propanal (c)Acetone (d)Benzaldehyde
Q5.What is the product of the oxidation of a primary alcohol with PCC (pyridiniumchloro-
chromate)?
(a))Aldehyde (b)Ketone (c) Carboxylic acid (d) Alcohol

Q.6. The α-D glucose and β-D glucose differ from each other due to difference in carbon atom with
respect to its
(a) conformation (b) configuration (c) number of OH groups (d) size of hemiacetal ring
Q.7.The acylation reaction of amines is carried out in presence of pyridine because
(a) Pyridine is absorbed ammonia formed.
(b) Pyridine is weaker base than amine.
(c) Pyridine is stronger base than amine and it removes HCl formed and shifts the equilibrium to
the right hand side.
(d) Pyridine removes HCl formed and shifts the equilibrium to the left hand side.

Q.8.Assertion: Aldehydes are generally more reactive than ketones towards nucleophilic addition
reactions.
Reason: Aldehydes have a more electrophilic carbonyl group due to the presence of an H
atom, making them more susceptible to nucleophilic attack.
Q.9.Assertion: Amino acids are amphoteric in their function.
Reason: All amino acids are necessary for our body.
Q 10. Assertion : boiling points of alcohols are much higher than those of alkanes, halo alkanes
or ethers of comparable molecular masses.
Reason : Strong intermolecular hydrogen bonding exists in Alcohols.
SECTION B
Q.11.Arrange the following compounds in increasing order of their property as indicated:
(i) Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards
HCN)
(ii) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH,CH3CH2CH2COOH (acid
strength)
OR
Give reasons:
(i) Oxidation of aldehydes is easier than ketones
(ii) Benzoic acid is a stronger acid than acetic acid
Q.12.(a) Why cannot Vitamin C be stored in our body?
(b)Name the component of starch, that is insoluble and also a branched polymer of α-
glucose.
Q.13(a)Which compound in the following pair will react faster in SN2 reaction with OH ? and why?
(CH3)3 C Cl orCH3 Cl
(b)An alkyl halide having molecular formula C4H9Cl is optically active .Write its structure.
SECTION C
Q.14.(a)Aryl halides are extremely less reactive towards Nucleophilic Substitution reactions. why
(b)Write the full form of DDT.
(c)Why chloroform stored in dark coloured bottles.
Q.15.An aromatic compound “A” (Molecular formula C 8H8O) gives positive 2,4 –DNP test .It give
yellow precipitate of compound “B” on treatment with iodine and sodium hydroxide solution.
Compound “A” does not give Tollen’s and Fehling’s test. On drastic oxidation with Potassium
permanganate it forms a carboxylic acid “C” (Molecular formula C 7H6O2), which is also formed
along with the yellow compound in the above reaction .
With the above observations and information , draw out logical inference and identify A , B and C.
Q.16(a)Write the mechanism of Acid catalyzed hydration of Alkene to Alcohol.
(b)Give a chemical test to distinguish between the following pair of compounds.
1-Propanol and ethanol
OR

(a)While separating a mixture of ortho and para nitrophenols by steam distillation, name the
isomer which will be steam volatile. Give reason.
(b) Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular
masses. Explain this fact.
(c) Give major products that are formed by heating of the following ethers with HI
Q.17(a)Write any two difference between DNA and RNA

(b) Given reason for why sucrose is not a reducing sugar?
SECTION D
Q18 Attempt any five of the following-
(a)Arrange the following in decreasing order of the pKb values:
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
(b) Arrange the following in increasing order of boiling point:

C2H5OH,(CH3)2NH,C2H5NH2
(c) Why does aniline not undergo Friedel-Crafts reaction.

(d) Aromatic primary amines cannot be prepared by Gabriel phthalimide synthesis. Why?
(e)Diazonium salts of aromatic amines are more stable than those of aliphatic amines.Explain.
(f) How will you covert Aniline to p-bromoaniline
(g) Convert :-Benzamide to Benzene

ANSWER KEY
Class: XII SUBJECT: CHEMISTRY
1 2 3 4 5 6 7 8 9 10
C C A D A B C A B A
11 (i) Di-tert-butylketone<Methyltert-butylketone<Acetone<Acetaldehyde 1+1

(ii)
(CH3)2CHCOOH<CH3CH2CH2COOH<CH3CH(Br)CH2COOH<CH3CH2CH(Br)
COOH
OR
(i) As aldehydes contain H atoms on the carbonyl group but ketones do not.
Cleavage of C—H bond in aldehydes is easier than cleavage of C—C bond
in ketones.
(ii) This is because of greater electronegativity of sp2 hybridised carbon to
which carboxyl carbon is attached in benzoic acid. or any other suitable
answer
12 (a) It is a water-soluble vitamin and gets excreted from the body with 1+1
sweat or urine.
(b) Amylopectin
13 (a) CH3 Cl , less hindered 1+1
(b)
14 (a) Due to resonance, C-X bond gets double bond character and 1+1+1
becomes shorter and stronger and cannot be easily replaced by
nucleophiles.
(b) p, p’- Dichlorodiphenyltrichloroethane
(c) To avoid the formation of phosgene gas.
15 A forms, 2, 4-DNP derivative. Therefore, it is an aldehyde or a ketone. Since 3
it does not reduce Tollen’s or Fehling reagent, (A) must be a ketone. (A)
responds to iodoform test. Compound (B), being an oxidation product of a
ketone should be a carboxylic acid. The molecular formula of (B) indicates
that it should be benzoic acid and compound (A) should, therefore, be a
mono-substituted aromatic methyl ketone.
16 The mechanism of the reaction involves the following three steps: 2+1

Step 1: Protonation of alkene to form carbocation by electrophilic attack of
H3O+.
Step 2: Nucleophilic attack of water on carbocation
Step 3: Deprotonation to form an alcohol.
(b) Iodofom test will be given by ethanol
OR
Ans- (a) Intramolecular H-bonding is present in o-nitrophenol. In p-
nitrophenol, the molecules are strongly associated due to the presence of
intermolecular bonding. Hence, o-nitrophenol is steam volatile.
(b) Alcohols form H-bonds with water due to the presence of −OH group.
However, hydrocarbons cannot form H-bonds with water.
1+1+1
(c)As a result, alcohols are comparatively more soluble in water than

hydrocarbons of comparable molecular masses.
17 (a) (i)DNA contain β-D-2-deoxyribose sugar where RNA β-D-ribose 1+1

sugar
(ii)DNA contains thymine whereas RNA contain uracil (any other) 1
(b) Sucrose is a non-reducing sugar since the reducing groups of
glucose and fructose are involved in the creation of glycosidic bonds.
18 (a) C6H5NH2>C6H5NHCH3>C2H5NH2>(C2H5)2NH
(b) (CH3)2NH<C2H5NH2<C2H5OH 1+1+1+
(c) due to salt formation with aluminium chloride which is 1+1
used as a Lewis acid catalyst. Positive charge on
nitrogen is strongly electron-withdrawing and thus
deactivates the ring for further acylation or alkylation
reactions.
(d) Aromatic primary amines cannot be prepared by Gabriel
phthalimide synthesis as aryl halides do not undergo
nucleophilic substitution with the salt formed by
phthalimide.
(e) Aromatic diazonium salts exhibit resonance, which
causes the positive charge to become dispersed. In
aliphatic diazonium salts, no similar resonance is seen.
(f)
(g)

2023-24
Class: XII

A/R Based
S.No
1 1 2 3 Marks 4 5
Marks Marks
Marks Marks Marks
6 Haloalkanes and 1(1) 2(1) 3(1) 6(3)

Haloarenes

Ethers

Carboxylic Acids
9 Amines 2(2) 1(1) 3(1) 6(4)
10 Biomolecules 1(1) 2(1) 4(1) 7(3)
Total 5(5) 3(3) 4(2) 12(4) 4(1) 5(1) 33(16)
Set 13
SECTION A
1. Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
(a) Benzyl chloride (b) Ethyl choride (c)Chlorobenzene (d) Isopropylchloride
2.Arrange the following In increasing order of basic strength:
Aniline, p-nitroaniline and p-toluidine
(a) Aniline< p-nitroaniline< p-toluidine
(b) Aniline< p-toluidine < p-nitroaniline
(c ) p-toluidine < p-nitroaniline<Aniline
(d)p-nitroaniline< Aniline <p-toluidine
3. How many alcohols with molecular formula C4H10O are chiral in nature?
(a) 1 (b) 2 (c) 3 (d) 4
4. Which of the following species are involved in the carbylamine test ?
(a) R-NC (b) NaNO2+HCl (c) COCl2 (d) All of the above
5. Which of the following alcohols gives 2-butene on dehydration by conc. H2SO4?

(a) 2-methyl propene-2-ol (b) 2-methyl 1 -propanol
(c) Butane-2-ol (d) Butane 1-ol

6. Assertion (A): CH3CH2OH can be converted into CH3CHO by treatment with PCC.
Reason (R): PCC is a better reagent for oxidation of primary alcohols to aldehydes.
7. Assertion (A): Acetanilide is less basic than aniline.

Reason (R): Acetylation of aniline results in decrease of electron density on nitrogen
8. Assertion (A): All naturally occurring α− amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L - configuration.
SECTION B
9. Give reasons
(a) C-Cl bond length in chlorobenzene is shorter than C-Cl bond length in CH3-Cl
(b) SN1 reactions are accompanied by racemization in optically active alkyl halides.
OR
What happens when-
(a) CH3-Cl is treated with aqueous KOH
(b) CH3Br is treated with Mg in the presence of dry ether?
10. Write the reaction involved when D-glucose is treated with the following reagents.
(a) Br2 water (b) NH2-OH
SECTION C
11. Write the equations for the following conversion
(a) Phenol to Anisol
(b) Salicylic acid to aspirin
(c) Ethyl alcohol to Ethoxyethane
12. Give reason for the following

(a) pKa value of aniline is more than that of methylamine.
(b) Aniline does not undergo friedel-crafts reaction.
(c ) Diazonium salts of aromatic amines are more stable than those of aliphatic amines.
13. In the following pairs of halogen compounds, which compound undergoes
faster SN1 reaction? And why?
(a) (b)
14. Predict the main product of the following reactions:
OR
Give reasons:
(i) Alpha hydrogen of aldehydes and ketones are acidic in nature.
(ii)Propanone is less reactive than ethanal towards addition of HCN.
(iii) Benzoic acid does not give Friedel-Crafts reaction.
SECTION D
The following questions are case -based questions. Each question has an internal choice
and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions
that follow.
15. Read the passage given below and answer the following questions:
Polysaccharides may be very large molecules. Starch, glycogen, cellulose, and chitin are
examples of polysaccharides. Starch is the stored form of sugars in plants and is made up of
amylose and amylopectin (both polymers of glucose). Amylose is soluble in water and can be

hydrolyzed into glucose units breaking glycoside bonds, by the enzymes α- amylase and β-
amylase. It is straight chain polymer. Amylopectin is a branched chain polymer of several D-
glucose molecules. 80% of amylopectin is present in starch. Plants are able to synthesize
glucose, and the excess glucose is stored as starch in different plant parts, including roots and
seeds. The starch that is consumed by animals is broken down into smaller molecules, such as
glucose. The cells can then absorb the glucose. Glycogen is the storage form of glucose in
humans and other vertebrates, and is made up of monomers of glucose. It is structurally quite
similar to amylopectin. Glycogen is the animal equivalent of starch. It is stored in liver and skeletal
muscles. Cellulose is one of the most abundant natural biopolymers. The cell walls of plants are
mostly made of cellulose, which provides structural support to the cell. Wood and paper are mostly
cellulosic in nature.
Answer the following questions.
(a) Differentiate between Amylose and Amylopectine
(b) Define polysaccharides.
(c) Write chemical reaction to show that open structure of D-glucose contains the following.
(i). Straight chain (ii). Five alcohol group
OR
(c) What are the products of hydrolysis of (i) Maltose (ii) lactose
.
SECTION E
16. An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric
acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced
(B). (C) on dehydration gives but-1-ene. Identify A, B and C. Write equations for the reactions
involved.
OR
Complete the following
*****************************************************************************************************

ANSWER KEY
Class: XII SUBJECT:
CHEMISTRY
1 2 3 4 5 6 7 8
a d a a c a a b
9. (a) Partial Double bond character in C-Cl bond due to resonance in chlorobenzene. 1
(b) Intermediate carbocation is a planar molecule which will lead to form d and l products.
Hence racemization is occurs. 1
OR
(a) CH3-Cl + KOH CH3-OH + K-Cl 1
(b) CH3-Br+ Mg CH3MgBr 1
10. (a) 1+1
(b)
11. (a) 1
(b) 1
(c) 1
12. (a) Due to resonance electrons on the N-atom are delocalized over the benzene ring. 1
(b) Friedel –crafts undergo in presence of AlCl3 which is acidic in nature,aniline is basic in nature form salt .
1
(c ) Diazonium salt of aniline undergo resonance. 1
13. (a) ½ +1
because 30 carbocation is formed which is more stable,reaction proceed via carbocation formation
(b)
2o carbocation is formed which is more stable than 1o ½ +1
14. 1 +1 + 1
OR
(i) due to the strong withdrawing effect of the carbonyl group and resonance stabilisation of the
conjugate base.
(ii) the presence of two methyl groups in propanone hinders more the approach of nucleophile to
carbonyl carbon than in ethanal having one methyl group and two methyl groups reduce the
positivity of the carbonyl carbon more effectively in propanone than in ethanal.
(iii) Carboxyl group is strongly deactivated and catalyst AlCl is a lewis acid that gets bonded to the
3
carboxyl group strongly

15.(a) 1
SN Amylose Amylopectine
1 Amylose is a straight chai polymer of Branched chain polymer of D-glucose

D-glucose
2 They are linked by 1,4-glycosidic They are linked by alpha-1,4 glycosidic and alpha-
linkage 1,6-glycosidic linkage
(b) These are complex long chains of monosaccharides linked by glycosidic bonds, eg starch, cellulose
1
(c) 1+1
OR
(c)
(i) the products formed after hydrolysis of maltose are two D- glucose units 1
(ii) Glucose and Galactose are the hydrolysis products of lactose 1
(d) The absence of unpaired d-electron in Sc3+ whereas in Ti3+ there is one unpaired electron or
Ti3+ shows the d-d transition.
(e) 5 Fe+2 + MnO4- + 8 H+ Mn+2 + 4 H2O + 5 Fe+3
(f) due to incomplete d orbitals and presence of unpaired electron.
(g) MnO4- + 4 H++3e- MnO2+ 2 H2O
16. Identification of A 1 mark
Identification of B and C ½ + ½
Equation for hydrolysis of A 1 mark
Equation for oxidation of C 1 mark
Equation for dehydration of C 1 mark

OR
Each 1 mark
*************************************************************************

2023-24
Class XII CHEMISTRY
S.No Chapter MCQ VSA I SA I Case LA Total
A/R Based wt
1 2 3 4 5
1
Marks Mark Marks Marks Mark
Marks
s s
Haloalkanes and 2(1) 6(3)
6 1(1) 3(1)
Haloarenes
Alcohols, Phenols 1(1) 6(2)

7 5(1)
and Ethers
Aldehydes, 1(1) 3(1) 4(1) 8(3)
8 Ketones and
Carboxylic Acids
9 Amines 2(2) 1(1) 3(1) 6(4)
10 Biomolecules 1(1) 1(1) 2(1) 3(1) 7(4)
Total 5 (5) 3(3) 4(2) 12(4) 4(1) 5(1) 33(16)

Set 14
SECTION A
1. What products are obtained when following compound reacts with HI?
(a) Iodobenzene and Methanol (c) Phenol and Iodomethane

(b) Methanol and Iodomethane (d) Benzene and Methanol
2. Addition of water to alkynes occurs in acidic medium and in the presence of Hg2+¿ ¿ ions as a catalyst.
Which of the following products will be formed on addition of water to but-1-yne under these
conditions.
(a) CH 3 CH 2 CH 2 CHO (c) CH 3 CH 2 CH 2 COOH +CO 2
(b) CH 3 CH 2 COCH 3 (d) CH 3 COOH + HCOOH
3. When n-propyl amine is heated with alc. KOH and chloroform an offensive smelling compound (X)
is formed. The compound (X) is
(a) CH3CH2CN (b) CH3CH2NC (c) CH3CH2CH2NC (d) CH3CH2CH2CN
4. Nitration of aniline also gives m-nitro aniline, in strong acidic medium because-
(a)In electrophilic substitution reaction amino group is meta directive
(b)In spite of substituents nitro group always goes to m- position
(c)In strong acidic medium, nitration of aniline is a nucleophilic substitution reaction
(d)In strong acidic medium aniline is present as anilinium ion
5. Which nitrogenous base is not present in DNA –
(a) adenine (A) (b)guanine (G) (c)cytosine (d)uracil
In the Following questions a statement of Assertion(A) is followed by a statement of Reason(R). Select
the most appropriate answer from the options given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
6. Assertion (A): Aryl halides are extremely less reactive towards nucleophilic substitution reactions.
Reason (R): In aryl halides, C—Cl bond acquires a partial double bond character due to resonance.
7. Assertion (A): The diazotisation reaction must be carried in ice cold solution (0 to 4⁰C).
Reason (R): At higher temperature, benzenediazonium chloride reacts with water to give phenol.
8. Assertion (A): Glucose gets oxidised to six carbon carboxylic acid (gluconic acid) on reaction with a mild
oxidizing agent like bromine water.
Reason (R): The carbonyl group present in glucose is a ketonic group.
SECTION B
9. Arrange each set of compounds in increasing order of the property mentioned.
(i) Bromomethane, Bromoform, Chloromethane, Dibromomethane- Boiling point
(ii) The four isomeric bromobutanes- reactivity towards SN1reaction
10. (a)Draw the Pyranose structure of∝−D−¿.
(b) Name the linkage that binds two nucleotides in polunucleotide.

SECTION C
11. (a)IUPAC name of the following compound is
(b)Identify A and B in the following
(c) Name the major product formed when 2-cyclohexylchloroethane undergoes a dehydrohalogenation
reaction.
12. Below reactants of some organic name reactions are given. Write the structure of the main product in
each and also identify the name reaction.
13. (a)Give plausible explanation for each of the following:

(i) Why do primary amines have higher boiling point than tertiary amines?
(ii) Why are aliphatic amines stronger bases than aromatic amines?
(b)Write structures and IUPAC names of the amide which gives propanamine by Hoffmann bromamide
reaction.
14. (a) What is the difference between native protein and denatured protein?
(b) Write the name of the vitamin responsible for the (i)coagulation of blood (ii) fragility of RBCs .
(c)Write the structural difference between starch and cellulose.
SECTION D
The following questions are case -based questions. Each question has an internal choice
and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions
that follow.
15. The carboxylic acids evolve hydrogen with electropositive metals and form salts with alkalies.
Carboxylic acids also react with weaker bases such as carbonates and hydrogencarbonates to evolve
carbon dioxide. Carboxylic acids dissociate in water to give resonance stabilized carboxylate anions and
hydronium ion. The strength of an acid is generally indicated by its pK a value rather than its Ka value.
Smaller the pKa, the stronger the acid (the better it is as a proton donor).

Electron withdrawing groups increase the acidity of carboxylic acids by stabilising the conjugate
base through delocalisation of the negative charge by inductive and/or resonance effects.
Conversely, electron donating groups decrease the acidity by destabilising the conjugate base
(a) Give a chemical test, based on acidic nature, to distinguish between phenol and benzoic acid
(b)Out of chloroacetic acid and acetic acid which one is stronger acid and why?
(c)Arrange the following compounds in increasing order of acid strength
(i)CH 3 C H 2 CH ( Br ) COOH , CH 3 CH ( Br ) C H 2 COOH , ¿ ¿, CH 3 CH 2 CH 2 COOH
(ii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid

OR
(c)Carboxylic acids are stronger acids compared to phenols. Explain
SECTION E
16. Answer any five questions from the following-

a) Write the name of the major product of reaction of Bromine in CS2 with phenol
b) Write the equation involved in the Reimer - Tiemann reaction
c) Give the structures and IUPAC names of the products expected from the Reaction
of propanone with methylmagnesium bromide followed by hydrolysis.
d) Ortho nitro phenol is more volatile than para nitro phenol. Give reason.
e) Give name of the reagent to bring about the transformations: Propan-1-ol to
propanal
f) Write the structures of the major products expected from the Mononitration of 3-
methylphenol
g) Give the equations of reactions for the preparation of phenol from cumene.

ANSWER KEY
Class: XII SUBJECT:
CHEMISTRY
QNo 1 2 3 4 5 6 7 8
Answe c b c d d a a c
r
Q. Probable Answer Weightag

No e
9 (i)Chloromethane < Bromomethane < Dibromomethane < Bromoform 1+1
(ii)
10 (a) 1+1
(b) Phosphodiester link

11 (a) 4-Bromopent-2-ene 1
(b) A- CH 3 CH 2 Mg Br and B-CH 3 CH 3 1
(c) 1- cyclohexylethene 1
12 3x1
13 (a)(i) Due to strong intermolecular H‐bonding in primary amines. 1

(ii) In aromatic amines lone pair is engaged with benzene in resonance 1
(b)
½+½
14 (a) Protein found in a biological system with unique three-dimensional 1

structure and biological activity is called native protein. When a protein in its
native form is subjected to physical and chemical change, its 2° and 3°
structures are destroyed and it loses its biological activity. The protein thus
formed is called denatured protein. ½+½
(b) (i)Vitamin K (ii) Vitamin E
(c) Starch contains the α−D Glucose while cellulose contains β-D- glucose as 1
monomer units.

15 (a) Benzoic acid gives effervescence of CO 2 when treated with NaHC O3 while
phenol does not. Or any other suitable distinguish test 1
(b)Chloroacetic acid is stronger acid. Because of -I effect of Cl .
(c)(i) ¿ ¿, CH 3 CH 2 CH 2 COOH , CH 3 CH ( Br ) C H 2 COOH , CH 3 C H 2 CH ( Br ) COOH
1
(ii) 4-Methoxybenzoic acid, Benzoic acid, 4-Nitrobenzoic acid, 3,4-
Dinitrobenzoic acid
OR 2
(c) The conjugate base of carboxylic acid, a carboxylate ion, is stabilised by two
equivalent resonance structures in which the negative charge is at the more
electronegative oxygen atom.
The conjugate base of phenol, a phenoxide ion, has resonance structures in
which the negative charge is at the less electronegative carbon atom
16 (a) 4-Bromophenol 1
(b)
(c) 2-methylpropan-2-ol
½+½
(d) Ortho nitro phenol has intramolecular hydrogen bonding and so

molecules are less associated with each other whereas para nitro phenol
1
has intermolecular hydrogen bonding.
(e) CrO3 in anhydrous medium or PCC (pyridinium chlorochromate) 1
(f)
½+½
(g)

Chemistry XII Practice Paper BOOK 2

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Chemistry XII Practice Paper BOOK 2

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Class XII Chemistry 2023-24

Practice Papers NCERT BOOK PART 2

Class: XII Chemistry Practice paper BOOK 2 MM 33

Chapter MCQ VSA I SA I Case LA Total

6 Haloalkanes and 1(1) 5(1) 6(2)

7 Alcohols, Phenols and 1(1) 2(1) 3(1) 6(3)

8 Aldehydes, Ketones and 1(1) 3(1) 4(1) 8(3)

9 Amines 1(1) 2(2) 3(1) 6(4)

10 Biomolecules 2(2) 2(1) 3(1) 7(4)

Total 4(4) 4(4) 4(2) 12(4) 4(1) 5(1) 33(16)

Compiled by Vijay Kumar Sethi 9461169967 Page 1 of 82

2 Phenol is less acidic than 1

4 Hoffmann Bromamide Degradation reaction is shown by 1

7 Assertion (A):Sucrose is a non-reducing sugar. 1

8 Assertion (A): D-(+)-Glucose is dextrorotatory in nature. 1

10 What happens when D-glucose is treated with the following reagents? 2

Compiled by Vijay Kumar Sethi 9461169967 Page 2 of 82

12 Give reasons for the following: - 3

13 Arrange the following: 3

14 Give answer for the following: 3

(ii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-

Compiled by Vijay Kumar Sethi 9461169967 Page 3 of 82

MARKING SCHEME: PRACTICE PAPER BOOK 2 SET-1

Q. Value Point/ Expected Answer Marks

9 (a) Methanol, ethanol, propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol. 1

10 (i) n-Hexane, (ii)Gluconic acid 1

13 (i) (CH3)3N > (CH3)2NH >CH3NH2> NH3 1

Compiled by Vijay Kumar Sethi 9461169967 Page 5 of 82

(ii) 4-Methoxybenzoic acid, Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid

Compiled by Vijay Kumar Sethi 9461169967 Page 6 of 82

Class: XII Chemistry Practice paper BOOK 2 MM 33

Compiled by Vijay Kumar Sethi 9461169967 Page 7 of 82

9 Halo-alkanes and 1(1) 2(1) 3(1) 6(3)

7 Alcohols, Phenols 1(1) 5(1 6(2)

8 Aldehydes, Ketones 2(2) 6(2) 8(4)

9 Amines 1(1) 2(2) 3(1) 6(4)

10 Biomolecules 2(2) 2(1) 3(1) 7(4)

TOTAL 5(5) 4(4) 4(2) 15(5) 5(1) 33(17)

Compiled by Vijay Kumar Sethi 9461169967 Page 8 of 82

1. Ethylidene chloride is a/an ______________.

11. Explain what is meant by

17. (a) Give reasons for the following-

MARKING SCHEME Practice paper NCERT BOOK 2

Q.NO ANSWERS/ HINTS MARKS

Compiled by Vijay Kumar Sethi 9461169967 Page 10 of 82

12 a) Propanone will give iodoform test 1+1+1

14 a) by acetylation we can control the reactivity of aniline so that only mono 1

16 The following major products are formed 1x3

Compiled by Vijay Kumar Sethi 9461169967 Page 11 of 82

PRACTICE PAPER NECRT BOK 2 SET-3

S.No Name of Chapter MCQ A/R SA1 SA2 Case LA Total

7 Alcohols, Phenols and Ethers 1(1) 2(2) 3(1) - 6(4)

8 Aldehydes, Ketones and Carboxylic 1(1) 2(2) - 5(1) 8(4)

9 Amines 1(1) 2(1) 3(1) - 6(3)

10 Biomolecules 2(2) 2(1)) 3(1) - 7(4)

Total 6(6) 4(4) 6(3) 12(4) 5(1) 33(18)

2 Methyl ketones are usually characterized through-- 1

5 Which of these cyclic structures of monosaccharides are anomers? 1

6 The system that forms maximum boiling azeotrope is— 1

Assertion-and-Reason Type Questions:

8 Assertion : Phenol is less acidic than 4-Nitrophenol. 1

9 Assertion : Acetophenone and benzophenone can be distinguished by iodoform test. 1

13 Arrange the following: 2

17 Following compounds are given to you: 3