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ANSWER:
POINTS: 1
6. The following shows an intermediate used in a Grignard synthesis. Which atom will inductively donate electrons in this
species?
a. C
b. Br
c. Mg
d. H
e. both b and c
ANSWER: c
POINTS: 1
In the electrostatic potential map of acetic acid, in which of the following bonds would the terminal atom appear as the
deepest shade of red?
a. C=O
b. C−H
c. C−C
d. O−H
ANSWER: a
POINTS: 1
8. Which of the following molecules would exhibit the largest dipole moment?
a. CH3CH3
b. CH3CH2F
c. CH3CH2Cl
d. CH3CH2Br
ANSWER: b
POINTS: 1
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Chapter 02 - Polar Covalent Bonds; Acids and Bases
9. Among the following compounds which can function only as a Brønsted-Lowry base?
a. A
b. B
c. C
d. D
ANSWER: d
POINTS: 1
10. What is the formal charge on the nitrogen atom indicated with the arrow in the following compound?
a. 0
b. −1
c. +1
d. −2
e. +2
ANSWER: c
POINTS: 1
ANSWER:
POINTS: 1
12. Refer to instructions. The strongest Brønsted-Lowry acid in the equation is indicated by letter _____.
ANSWER: D
POINTS: 1
13. Refer to instructions. The strongest Brønsted-Lowry base in the equation is indicated by letter _____.
ANSWER: C
POINTS: 1
14. Refer to instructions. Will this reaction take place as written in the forward direction? Explain.
ANSWER: No, the reaction will not take place as written because the strongest acid reacts with the strongest base to give
the weakest conjugate acid and the weakest conjugate base. D (pKa = 15.7) is a stronger acid than A (pKa =
18).
POINTS: 1
ANSWER:
POINTS: 1
BF3 Fe2+
ANSWER:
POINTS: 1
phenol ethanol
ANSWER: Phenol is more acidic (has a lower pKa) than ethanol because the phenoxide anion is resonance stabilized by
the pi electrons in the ring. Sharing (delocalizing) the negative charge on oxygen with the three ring carbons
stabilizes the phenoxide anion relative to undissociated phenol.
Ethoxide anion has no resonance stabilization. The negative charge is borne fully by oxygen.
POINTS: 1
19. Refer to instructions. Using the curved arrow formalism, show the flow of electrons for this reaction.
ANSWER:
POINTS: 1
Instructions: Indole is pleasant smelling in highly dilute solutions and has been used in perfumery. Use the structure of
indole, below, to answer the following question(s).
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THE WAY OF THE WHITE SOULS
(To the Memory of Joyce Kilmer, killed in action, July 30, 1918)
I stood in the summer night, when the hosts of heaven seemed nigh,
And I saw the powdery swirl of stars, where it swept across the sky,
The wide way of the white stars, where it ran up and down,
And my heart was sad for the man who said It was Main Street,
Heaventown.
He knelt down with his fellows, in the warm faith of the throng;
He went forth with his fellows to fight a monstrous Wrong;
He marched away to the true tune that the hearts of brave men beat,
Shoulder to brown shoulder, with the men in the Main Street.
A road runs bright through the night of Time, since ever the world
began,
The wide Way of the White Souls, the Main Street of Man,
The sky-road of the star-souls, beyond all wars and scars;
And there the singing soul of him goes on with the marching stars.
So, as I stand in the summer night, when the hosts of heaven seem
nigh,
And look at the powdery swirl of stars, where it sweeps across the
sky,
The wide way of the white stars, where it runs up and down,
My heart shall be glad for the friend who said It was Main Street,
Heaventown.
RESPITE
Pink-purple foxgloves
Leaning to the breeze—
And all the sweet of Devon
Sweeps back across the seas:
From the old kind books came the old friends trooping,
And the old songs called, like the curlew swooping;
And like a sudden sup that was hot and strong and sweet,
The love of bonny Scotland, it ran from head to feet.
What far-away workman made her, and what was his meaning?
Was she a Victory? or Hope, or Faith?
O flag, though you were not my own, I know I should love you:
I love all flowers, all flags:
Their colors in the wind flowing, in the sun brightening:
Deep blue of the night sky, or the splendor of flame,
Or green of spring, or the daring imperious scarlet,
The color of men’s blood:
Their curious blazonry I love, heraldic, historic,
Leopard or eagle, stripe or star or raying sun,
Or the Cross of St. George and the Cross of St. Andrew,
Or whatsoever sign men have loved and followed.