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SuperBattery

Technology & Safety

Curved Graphene-based Energy Storage


A Pan-European Company
European value chain, European energy storage innovation

Tallinn, Estonia Berlin, Germany


Software development Sales & application engineering +
Electronics engineering Grant & IP management
Module & system development Solid-state battery development

+
Großröhrsdorf, Germany Varkaus, Finland
SuperBattery R&D and production SuperBattery pilot production
Supercapacitor research & development center Electrode manufacturing
Main production location from cells to systems

Markranstädt, Germany
The largest and most modern supercapacitor factory
in the world
+
Start of production in 2024 ++
+

Bitterfeld-Wolfen, Germany
Curved Graphene synthesis and production
Material pilot & development plant
Solid-state material research
Key Enabling Technology to Power Electrification Across Industries
A qualified supplier & system provider to industry leaders

Automotive Transportation & Grid & Industrial


Selected applications
Heavy Equipment Renewables Selected applications

Selected applications Selected applications

Fuel cell power support Peak load shaving to cover


KERS for light rail Wind turbine pitch control short-term peak power
solutions
Engine start Virtual inertia / Grid forming demands
48V active suspension
Mild hybrid bus energy storage in STATCOMs KERS for port cranes, forklifts,
KERS / Push-to-pass and elevators
Fuel cell power support solutions Microgrid power back-up and
12V board net stabilization & for rail and bus transportation quality Fast-charging for warehouse
back-up solutions AGVs and shuttles

03
German Quality, Certified According to the Highest Standards
Qualified supplier to some of the largest OEMs in the world

“ Quality is the bedrock of


Certified

Skeleton’s success and


something we have put an 9001:2015 14001:2015

enormous amount of work in – Compliance and selected

to produce the most robust and product certifications

Linus Froböse long-lasting products for our


customers. ”
COO

4
A Qualified Supplier & System Provider to Industry Leaders
To automotive, grid, transportation, and industrial companies, OEMs & Tier 1s

German automotive
OEM

North-American
Truck OEM

5
Technology Advantage Throughout the Entire Energy Storage Industry
Highest performance and quality for every energy storage application, powered by Curved Graphene

2024

2024

2017

SuperBatteries

Graphene supercapacitors High energy density


SkelCap supercapacitors (Gen 2) (65 Wh/kg)
(Gen 1) 50,000+ lifecycles
+72% increase in energy
Fast charging (60s)
4x power density compared (16 Wh/L), while maintaining high
to competitors power Extremely competitive cost-
base compared to similar
High power (up to 60x compared to 1,000,000+ lifecycles
energy storage technologies
batteries) Ultrafast charging times (<1 s)
1,000,000+ lifecycles Increased efficiency & lower footprint
Ultrafast charging times (<1 s)

06
Technological Advantage Through Superior Carbon Raw Material
Backed by the largest R&D team in the industry

Li-ion Batteries SuperBattery


use a chemical reaction to store energy Based on supercapacitor technology

+ High power density (4 kW/kg)


+ Limited power density (0.5 kW/kg)
+ Increased energy density (65 Wh/kg)
+ High energy density (205 Wh/kg)
+ Long cycle life (50,000)
+ Limited cycle life (<6000)
+ Fast charge (60s)
+ Slow charge rate (1.5 C)
+ Extreme power (20 C continuous, 100 C peak)
+ Safety concerns
+ High inherent safety
+ Utilizes critical raw materials
+ High recyclability and sustainability
(Li, Graphite, Co)
+ No Graphite, no Co, <5% Li

7
Addressable Energy Storage Application Space
High power from sub-second to up to 15 minutes duration

Skeleton products provide high power energy storage Lower cost compared
for applications with <5-minute charge / <15-minute to Li-ion batteries in this
discharge cycle durations application space

Supercapacitors SuperBatteries Lithium-Ion batteries

Fast
charging

<1s to 60s 1-5 min 1-15 min >15 min

8
Independent 3rd Party Verified Advantage
Superior power and energy densities in energy storage

“ Your cells have very low resistance Supercapacitors


so are truly high-power devices. power density
I think they are the best in the 4X vs competitors

world of the carbon/carbon type. ” 64.3 kW/L

15.6 kW/L
Dr. Andrew F. Burke

SuperBattery
“ One property that stands out is the ESR of the Uniquely fast charge times with high energy density

60 sec
Skeleton capacitor, which is significantly less than
the others. ” Charge time > 10 min Competition

C. N. Nybeck, D. A. Dodson, D. A. Wetz and J. M. Heinzel, "Characterization of


Ultracapacitors for Transient Load Applications," in IEEE Transactions on Plasma
Science, vol. 47, no. 5, pp. 2493-2499, May 2019

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SuperBattery: A Sustainable Energy Storage Product
Advantages over Li-ion batteries from materials to cell design

27 Terminal

Liquid electrolyte Aluminium can


Organic components between layers
41 Aluminum
Other (No Co, Ni, Cu)
Anode – CG Cathode – CG
with metal oxide content with metal oxide content
32
Aluminium current collector Aluminium current collector

Separator paper

+ Narrow range of materials + No Cobalt, no Nickel, no Copper, <5% Lithium


+ Minimal number of components + Aqueous processing for recycling possible
+ Aqueous coating for both Anode and Cathode + No risk of fire or explosion upon disassembly

10
Energy and Power Characteristics
SuperBattery

Max energy on cell level: 65 Wh/kg and 125 Wh/L Max power on cell level: 4.19 kW/kg and 8.5 kW/L
+ D60L138 cell, 0-100% SOC
+ Reachable between -30 and +50 °C and 1.0-3.0 V cell voltage

D60 SOC-OCV
3

2.5

2
Voltage, V

D60 Discharge
1.5 D60 Charge

0.5

0
0 10 20 30 40 50 60 70 80 90 100
SOC, %

11
Superbattery: Charging In 60 Seconds
Advantages over Li-ion batteries from materials to cell design

1250
3,0 1000A, 60s charge
1000
Voltage (V)
2,5

Current (A)
750

2,0 500

250
1,5

0
1,0
-250
26 27 28 29 30 31
Time / s (x1000)

+ 60 mm diameter, 138 mm length cell + No Cobalt, no Copper, no Graphite, <5% Lithium


+ 1000 A charge in 60 seconds + Aqueous processing for recycling possible
+ No risk of fire or explosion upon disassembly

12
Increased Safety Compared to Lithium-ion Batteries
Lower cost due to Curved Graphene and abundance of other raw materials

8 27

28 41

63 32

Organic components Organic components


Aluminum Aluminum
Other Other

Curved Supercapacitor SuperBattery


Graphene Composition Composition
Proprietary carbon, produced Mostly carbon and aluminum – Safer to handle than Li-Ion batteries
without any rare earth materials easy to recycle (no lithiated graphite)
Synthesis byproducts re-usable Contains no heavy metals Contains lower cost elements
– zero waste created compared to Li-Ion

013
SuperBattery – Short Circuit Through 0.18 mOhm
Industrial prototypes

A large 60 mm diameter, 138 mm


length cell was short circuited
Cell is completely
Current drops to discharged after 30 + 7.1 kA peak current
2 kA seconds + <2 kA current for 30 seconds
After 20
seconds, the cell
Initial current
vents
peak: 7.1 kA + Cell voltage (red) and circuitry current (blue).
+ Short-circuit was created on 26th second of the
log.
+ Voltage spikes can be explained by three poles
(connected in parallel) ABB OTDC switch-
disconnector contacts closing not being 100%
synced.
+ Recorded peak short-circuit current 7.1 kA. After
2 sec. current dropped below 2k and was
continuously running through the circuitry around
30 sec.
SuperBattery – Short Circuit Through 0.18 mOhm
Industrial prototypes

95 °C max temperature

Picture of temperature graph:


+ Pink line is cell body
temperature
Cell body and negative + Green line is cell negative
terminal show almost terminal temperature
equal temperature of 95°C
SuperBattery – Short Circuit Through 0.18 mOhm
Industrial prototypes

Cell venting event upon short circuiting. No fire or explosion witnessed.


SuperBattery – Short Circuit Through 0.18 mOhm
Industrial prototypes

Cell thermal image before and during short-circuit.


SuperBattery – Overcharge to 6V (200% Rated Voltage)
Industrial prototypes

+ Cell vented at 3.6 V after reaching 4.2 V


+ Cell charged to 6 V temporarily – no fire
+ No fire or explosion at 6 V

Cell before the test Test setup

Vented cell after test Cleaned cell after test

Key Achievements:
No safety risk during massive overcharge of 200% 018
SuperBattery – Crushing
Industrial prototypes

+ Fully charged (3.0 V) D40L85 cell crushed with a cylinder


(d = 30 mm) at 1 mm/s
+ No fire or explosion
+ Cell deformed completely – no fire or explosion

Cell before the test Test setup

Cell after crushing


IR-image of cell during crushing

Key Achievements:
No safety risk during complete deformation of cell

019
SuperBattery – Nail Penetration
Industrial prototypes

+ Fully charged (3.0V) D40L85 cell penetrated with a rod


(d = 3 mm) at 10 mm/s
+ No fire or explosion

Cell before the test Test setup

Cell after nail penetration IR-image of cell during penetration

Key Achievements:
Nail completely penetrated the cell – no safety risk

020
SuperBattery – Overheating
Industrial prototypes

+ Fully charged (3.0V) D40L85 cell heated to 250 °C in oven


+ Safety valve opened at 135 °C
+ Maximum cell terminal temperature 363 °C
+ No fire or explosion

Cell before the test Test setup

Cell after overheating


Safety valve after overheating

Key Achievements:
No thermal runaway – no need to for Thermal
Propagation measures
021
Thank you!
For more information
contact us:
www.skeletontech.com

Skeleton Technologies GmbH | info@skeletontech.com | +49 3595 2416 040

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